JPH038652B2 - - Google Patents
Info
- Publication number
- JPH038652B2 JPH038652B2 JP7217084A JP7217084A JPH038652B2 JP H038652 B2 JPH038652 B2 JP H038652B2 JP 7217084 A JP7217084 A JP 7217084A JP 7217084 A JP7217084 A JP 7217084A JP H038652 B2 JPH038652 B2 JP H038652B2
- Authority
- JP
- Japan
- Prior art keywords
- coating film
- weight
- glass plate
- acid
- same manner
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000178 monomer Substances 0.000 claims description 18
- 229920000642 polymer Polymers 0.000 claims description 14
- 150000001875 compounds Chemical class 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 9
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 7
- 150000007513 acids Chemical class 0.000 claims description 7
- 150000008064 anhydrides Chemical class 0.000 claims description 7
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 2
- 238000000576 coating method Methods 0.000 description 116
- 239000011248 coating agent Substances 0.000 description 111
- 239000000203 mixture Substances 0.000 description 46
- 239000011521 glass Substances 0.000 description 41
- 239000000758 substrate Substances 0.000 description 19
- 238000000034 method Methods 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 238000001723 curing Methods 0.000 description 13
- 239000002904 solvent Substances 0.000 description 12
- 238000004528 spin coating Methods 0.000 description 12
- 239000004793 Polystyrene Substances 0.000 description 11
- 229920001577 copolymer Polymers 0.000 description 11
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 11
- 229920002454 poly(glycidyl methacrylate) polymer Polymers 0.000 description 11
- 229920002223 polystyrene Polymers 0.000 description 11
- 239000004848 polyfunctional curative Substances 0.000 description 10
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 10
- 238000004043 dyeing Methods 0.000 description 8
- -1 green Polymers 0.000 description 8
- 238000002156 mixing Methods 0.000 description 8
- 239000010410 layer Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 6
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 description 6
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 6
- 230000005856 abnormality Effects 0.000 description 6
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 6
- 229920001187 thermosetting polymer Polymers 0.000 description 6
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 6
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 4
- SOGAXMICEFXMKE-UHFFFAOYSA-N Butylmethacrylate Chemical compound CCCCOC(=O)C(C)=C SOGAXMICEFXMKE-UHFFFAOYSA-N 0.000 description 4
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 4
- 150000008065 acid anhydrides Chemical class 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 4
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical class C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 description 4
- 239000003973 paint Substances 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- 239000011253 protective coating Substances 0.000 description 4
- 239000011241 protective layer Substances 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 108010010803 Gelatin Proteins 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 238000000862 absorption spectrum Methods 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- STZIXLPVKZUAMV-UHFFFAOYSA-N cyclopentane-1,1,2,2-tetracarboxylic acid Chemical compound OC(=O)C1(C(O)=O)CCCC1(C(O)=O)C(O)=O STZIXLPVKZUAMV-UHFFFAOYSA-N 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 229920000159 gelatin Polymers 0.000 description 3
- 239000008273 gelatin Substances 0.000 description 3
- 235000019322 gelatine Nutrition 0.000 description 3
- 235000011852 gelatine desserts Nutrition 0.000 description 3
- 239000012456 homogeneous solution Substances 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000002834 transmittance Methods 0.000 description 3
- QQZOPKMRPOGIEB-UHFFFAOYSA-N 2-Oxohexane Chemical compound CCCCC(C)=O QQZOPKMRPOGIEB-UHFFFAOYSA-N 0.000 description 2
- SYBYTAAJFKOIEJ-UHFFFAOYSA-N 3-Methylbutan-2-one Chemical compound CC(C)C(C)=O SYBYTAAJFKOIEJ-UHFFFAOYSA-N 0.000 description 2
- VQVIHDPBMFABCQ-UHFFFAOYSA-N 5-(1,3-dioxo-2-benzofuran-5-carbonyl)-2-benzofuran-1,3-dione Chemical compound C1=C2C(=O)OC(=O)C2=CC(C(C=2C=C3C(=O)OC(=O)C3=CC=2)=O)=C1 VQVIHDPBMFABCQ-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- XTHFKEDIFFGKHM-UHFFFAOYSA-N Dimethoxyethane Chemical compound COCCOC XTHFKEDIFFGKHM-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- GTDPSWPPOUPBNX-UHFFFAOYSA-N ac1mqpva Chemical compound CC12C(=O)OC(=O)C1(C)C1(C)C2(C)C(=O)OC1=O GTDPSWPPOUPBNX-UHFFFAOYSA-N 0.000 description 2
- 229960000583 acetic acid Drugs 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 238000009835 boiling Methods 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 2
- NMJJFJNHVMGPGM-UHFFFAOYSA-N butyl formate Chemical compound CCCCOC=O NMJJFJNHVMGPGM-UHFFFAOYSA-N 0.000 description 2
- 150000001244 carboxylic acid anhydrides Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000007334 copolymerization reaction Methods 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- 238000002845 discoloration Methods 0.000 description 2
- 239000012153 distilled water Substances 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- 239000003822 epoxy resin Substances 0.000 description 2
- XLLIQLLCWZCATF-UHFFFAOYSA-N ethylene glycol monomethyl ether acetate Natural products COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 2
- 239000012362 glacial acetic acid Substances 0.000 description 2
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 2
- NGAZZOYFWWSOGK-UHFFFAOYSA-N heptan-3-one Chemical compound CCCCC(=O)CC NGAZZOYFWWSOGK-UHFFFAOYSA-N 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 2
- FDPIMTJIUBPUKL-UHFFFAOYSA-N pentan-3-one Chemical compound CCC(=O)CC FDPIMTJIUBPUKL-UHFFFAOYSA-N 0.000 description 2
- PGMYKACGEOXYJE-UHFFFAOYSA-N pentyl acetate Chemical compound CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 2
- 229920000647 polyepoxide Polymers 0.000 description 2
- YKYONYBAUNKHLG-UHFFFAOYSA-N propyl acetate Chemical compound CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- SRPWOOOHEPICQU-UHFFFAOYSA-N trimellitic anhydride Chemical compound OC(=O)C1=CC=C2C(=O)OC(=O)C2=C1 SRPWOOOHEPICQU-UHFFFAOYSA-N 0.000 description 2
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical group C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 2
- GGAUUQHSCNMCAU-ZXZARUISSA-N (2s,3r)-butane-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)C[C@H](C(O)=O)[C@H](C(O)=O)CC(O)=O GGAUUQHSCNMCAU-ZXZARUISSA-N 0.000 description 1
- MUTGBJKUEZFXGO-OLQVQODUSA-N (3as,7ar)-3a,4,5,6,7,7a-hexahydro-2-benzofuran-1,3-dione Chemical compound C1CCC[C@@H]2C(=O)OC(=O)[C@@H]21 MUTGBJKUEZFXGO-OLQVQODUSA-N 0.000 description 1
- OLQWMCSSZKNOLQ-ZXZARUISSA-N (3s)-3-[(3r)-2,5-dioxooxolan-3-yl]oxolane-2,5-dione Chemical compound O=C1OC(=O)C[C@H]1[C@@H]1C(=O)OC(=O)C1 OLQWMCSSZKNOLQ-ZXZARUISSA-N 0.000 description 1
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical group C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 1
- LZDKZFUFMNSQCJ-UHFFFAOYSA-N 1,2-diethoxyethane Chemical compound CCOCCOCC LZDKZFUFMNSQCJ-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 1
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 1
- IGGDKDTUCAWDAN-UHFFFAOYSA-N 1-vinylnaphthalene Chemical compound C1=CC=C2C(C=C)=CC=CC2=C1 IGGDKDTUCAWDAN-UHFFFAOYSA-N 0.000 description 1
- SDJHPPZKZZWAKF-UHFFFAOYSA-N 2,3-dimethylbuta-1,3-diene Chemical compound CC(=C)C(C)=C SDJHPPZKZZWAKF-UHFFFAOYSA-N 0.000 description 1
- LYANEXCVXFZQFF-UHFFFAOYSA-N 2-(2,5-dioxooxolan-3-yl)acetic acid Chemical compound OC(=O)CC1CC(=O)OC1=O LYANEXCVXFZQFF-UHFFFAOYSA-N 0.000 description 1
- FPZWZCWUIYYYBU-UHFFFAOYSA-N 2-(2-ethoxyethoxy)ethyl acetate Chemical compound CCOCCOCCOC(C)=O FPZWZCWUIYYYBU-UHFFFAOYSA-N 0.000 description 1
- BJINVQNEBGOMCR-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethyl acetate Chemical compound COCCOCCOC(C)=O BJINVQNEBGOMCR-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- FALRKNHUBBKYCC-UHFFFAOYSA-N 2-(chloromethyl)pyridine-3-carbonitrile Chemical compound ClCC1=NC=CC=C1C#N FALRKNHUBBKYCC-UHFFFAOYSA-N 0.000 description 1
- PTBAHIRKWPUZAM-UHFFFAOYSA-N 2-(oxiran-2-yl)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCC1CO1 PTBAHIRKWPUZAM-UHFFFAOYSA-N 0.000 description 1
- CBKJLMZJKHOGEQ-UHFFFAOYSA-N 2-(oxiran-2-yl)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCC1CO1 CBKJLMZJKHOGEQ-UHFFFAOYSA-N 0.000 description 1
- PTTPXKJBFFKCEK-UHFFFAOYSA-N 2-Methyl-4-heptanone Chemical compound CC(C)CC(=O)CC(C)C PTTPXKJBFFKCEK-UHFFFAOYSA-N 0.000 description 1
- WDQMWEYDKDCEHT-UHFFFAOYSA-N 2-ethylhexyl 2-methylprop-2-enoate Chemical compound CCCCC(CC)COC(=O)C(C)=C WDQMWEYDKDCEHT-UHFFFAOYSA-N 0.000 description 1
- IEVADDDOVGMCSI-UHFFFAOYSA-N 2-hydroxybutyl 2-methylprop-2-enoate Chemical compound CCC(O)COC(=O)C(C)=C IEVADDDOVGMCSI-UHFFFAOYSA-N 0.000 description 1
- NJRHMGPRPPEGQL-UHFFFAOYSA-N 2-hydroxybutyl prop-2-enoate Chemical compound CCC(O)COC(=O)C=C NJRHMGPRPPEGQL-UHFFFAOYSA-N 0.000 description 1
- OMIGHNLMNHATMP-UHFFFAOYSA-N 2-hydroxyethyl prop-2-enoate Chemical compound OCCOC(=O)C=C OMIGHNLMNHATMP-UHFFFAOYSA-N 0.000 description 1
- VHSHLMUCYSAUQU-UHFFFAOYSA-N 2-hydroxypropyl methacrylate Chemical compound CC(O)COC(=O)C(C)=C VHSHLMUCYSAUQU-UHFFFAOYSA-N 0.000 description 1
- RUMACXVDVNRZJZ-UHFFFAOYSA-N 2-methylpropyl 2-methylprop-2-enoate Chemical compound CC(C)COC(=O)C(C)=C RUMACXVDVNRZJZ-UHFFFAOYSA-N 0.000 description 1
- ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 2-octanone Chemical compound CCCCCCC(C)=O ZPVFWPFBNIEHGJ-UHFFFAOYSA-N 0.000 description 1
- WYYQKWASBLTRIW-UHFFFAOYSA-N 2-trimethoxysilylbenzoic acid Chemical compound CO[Si](OC)(OC)C1=CC=CC=C1C(O)=O WYYQKWASBLTRIW-UHFFFAOYSA-N 0.000 description 1
- WVRNUXJQQFPNMN-VAWYXSNFSA-N 3-[(e)-dodec-1-enyl]oxolane-2,5-dione Chemical compound CCCCCCCCCC\C=C\C1CC(=O)OC1=O WVRNUXJQQFPNMN-VAWYXSNFSA-N 0.000 description 1
- AYKYXWQEBUNJCN-UHFFFAOYSA-N 3-methylfuran-2,5-dione Chemical compound CC1=CC(=O)OC1=O AYKYXWQEBUNJCN-UHFFFAOYSA-N 0.000 description 1
- OFNISBHGPNMTMS-UHFFFAOYSA-N 3-methylideneoxolane-2,5-dione Chemical compound C=C1CC(=O)OC1=O OFNISBHGPNMTMS-UHFFFAOYSA-N 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- UITKHKNFVCYWNG-UHFFFAOYSA-N 4-(3,4-dicarboxybenzoyl)phthalic acid Chemical compound C1=C(C(O)=O)C(C(=O)O)=CC=C1C(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 UITKHKNFVCYWNG-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- HCFAJYNVAYBARA-UHFFFAOYSA-N 4-heptanone Chemical compound CCCC(=O)CCC HCFAJYNVAYBARA-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- FERIUCNNQQJTOY-UHFFFAOYSA-M Butyrate Chemical compound CCCC([O-])=O FERIUCNNQQJTOY-UHFFFAOYSA-M 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- AQZGPSLYZOOYQP-UHFFFAOYSA-N Diisoamyl ether Chemical compound CC(C)CCOCCC(C)C AQZGPSLYZOOYQP-UHFFFAOYSA-N 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 1
- 239000004640 Melamine resin Substances 0.000 description 1
- 229920000877 Melamine resin Polymers 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- 206010034972 Photosensitivity reaction Diseases 0.000 description 1
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- NOZAQBYNLKNDRT-UHFFFAOYSA-N [diacetyloxy(ethenyl)silyl] acetate Chemical compound CC(=O)O[Si](OC(C)=O)(OC(C)=O)C=C NOZAQBYNLKNDRT-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000012644 addition polymerization Methods 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 125000002723 alicyclic group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- WTNDADANUZETTI-UHFFFAOYSA-N cyclohexane-1,2,4-tricarboxylic acid Chemical compound OC(=O)C1CCC(C(O)=O)C(C(O)=O)C1 WTNDADANUZETTI-UHFFFAOYSA-N 0.000 description 1
- QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 description 1
- 125000006159 dianhydride group Chemical group 0.000 description 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- CJSBUWDGPXGFGA-UHFFFAOYSA-N dimethyl-butadiene Natural products CC(C)=CC=C CJSBUWDGPXGFGA-UHFFFAOYSA-N 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000009977 dual effect Effects 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- WBJINCZRORDGAQ-UHFFFAOYSA-N formic acid ethyl ester Natural products CCOC=O WBJINCZRORDGAQ-UHFFFAOYSA-N 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 108010025899 gelatin film Proteins 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- JMMWKPVZQRWMSS-UHFFFAOYSA-N isopropanol acetate Natural products CC(C)OC(C)=O JMMWKPVZQRWMSS-UHFFFAOYSA-N 0.000 description 1
- 229940011051 isopropyl acetate Drugs 0.000 description 1
- GWYFCOCPABKNJV-UHFFFAOYSA-N isovaleric acid Chemical compound CC(C)CC(O)=O GWYFCOCPABKNJV-UHFFFAOYSA-N 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pentâ4âenâ2âone Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- QIWKUEJZZCOPFV-UHFFFAOYSA-N phenyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1=CC=CC=C1 QIWKUEJZZCOPFV-UHFFFAOYSA-N 0.000 description 1
- WRAQQYDMVSCOTE-UHFFFAOYSA-N phenyl prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1 WRAQQYDMVSCOTE-UHFFFAOYSA-N 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229940014800 succinic anhydride Drugs 0.000 description 1
- 235000012976 tarts Nutrition 0.000 description 1
- SJMYWORNLPSJQO-UHFFFAOYSA-N tert-butyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)(C)C SJMYWORNLPSJQO-UHFFFAOYSA-N 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- FRGPKMWIYVTFIQ-UHFFFAOYSA-N triethoxy(3-isocyanatopropyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCN=C=O FRGPKMWIYVTFIQ-UHFFFAOYSA-N 0.000 description 1
- HQYALQRYBUJWDH-UHFFFAOYSA-N trimethoxy(propyl)silane Chemical compound CCC[Si](OC)(OC)OC HQYALQRYBUJWDH-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Landscapes
- Epoxy Resins (AREA)
- Paints Or Removers (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
æ¬çºæã¯ãç±ç¡¬åæ§çµæç©ã«é¢ããç¹ã«å¡è圢
æææãšããŠçš®ã ã®å¡èç©æ§ã«åªããç±ç¡¬åæ§çµ
æç©ã«é¢ããã åŸæ¥ãåçš®ç©åã®åºäœè¡šé¢ã®å£åãæå·ãé²æ¢
ããããã«ããã®è¡šé¢ã«ä¿è·å¡èã圢æããããš
ãåºãè¡ãããŠããããã®ãããªä¿è·å¡èã«ãã
ãŠã¯ãåºäœãžã®æ¥çæ§ãé«ããå¡èãå¹³æ»ã§åŒ·é
ã§ããããšãèç±æ§ããã³èå æ§ãé«ããŠé·æã«
ããã€ãŠå€è²ãªã©ã®å€è³ªãããªãããšãèæ°Žæ§ã
ãã³è溶å€æ§ãåªããããšçã®æ§èœãèŠæ±ãã
ãã ãŸããè¿å¹Žãè²åé¢ãã€ã«ã¿ãŒãå èµããã«ã©
ãŒæ¶²æ¶è¡šç€ºçŽ åçãçš®ã çºè¡šãããŠããããã®ã«
ã©ãŒæ¶²æ¶è¡šç€ºçŽ åã®ã«ã©ãŒãã€ã«ã¿ãŒã¯ãã¬ã©ã¹
çã®éæåºäœäžã«æ¬¡ã®ãããªå·¥çšãçµãŠåœ¢æãã
ããããªãã¡ãããªããã«ã¢ã«ã³ãŒã«ãã°ãªãŠ
ãŒããŒã©ãã³çã«æå æ§ãä»äžãåºäœäžã«åäžã«
å¡åžãããã¹ã¯é²å æ³ã§ïŒè²ç®ã®è²çžéšåã®ã¿å
硬åããçŸåãããã®ä»ã®éšåãé€å»ããããã®
è²çžéšåã«æå®ã®åå ç¹æ§ãæããææã§æè²ã
ãã次ãã§éæãªé²æä¿è·å±€ã被èŠãããïŒè²ç®
ã®è²çžéšåã«ã€ããŠãåæ§ã®å·¥çšãçšãæè²ãã
é²æä¿è·å±€ã被èŠãããïŒè²ç®ã®è²çžéšåã«ã€ã
ãŠãåæ§ã®å·¥çšãçšãæè²ããæåŸã«è¡šé¢ä¿è·å±€
ã圢æããããã®é²æä¿è·å±€ããã³è¡šé¢ä¿è·å±€
ã¯ãåèšä¿è·å¡èã«å¿ èŠãªæ§èœãããªãã¡æ¥ç
æ§ãå¹³æ»æ§ã匷éæ§ãèç±æ§ãèå æ§ãèæ°Žæ§ã
ãã³è溶å€æ§ã®ä»ã«ãéææ§ããã³ææã«æè²ã
ããªãããã®èææ§çã®æ§èœãèŠæ±ãããããã
ãŠãããã«ããããã®å±€ãšãªãææã¯ãé²æä¿è·
å±€ããã³è¡šé¢ä¿è·å±€ã圢æãããããã«ã溶液ãš
ããŠå¡åžããããåäžãªå¡èã圢æãããããã«
ã¹ãã³ã³ãŒã¿ã«ããå転å¡åžæ³ãçšããå Žåãã
ãããã®å¡åžæ³ã«ãé©ããããšãèŠæ±ãããã åŸæ¥ãå¡è圢æææã®äžã€ãšããŠããªã¹ãã¬
ã³ãããªã«ãŒãããŒãçã®ç±å¯å¡æ§æš¹èãç¥ãã
ãŠãããããããã®å¡èã¯ãåºäœãšã®æ¥çæ§ãè
ç±æ§ããã³è溶å€æ§ãäœããšããæ¬ ç¹ãæããã
ãŸããå¥ã®å¡è圢æææãšããŠã¡ã©ãã³æš¹èããš
ããã·æš¹èçã®ç±ç¡¬åæ§æš¹èãç¥ãããŠãããã
ãããã®å¡èã¯ç¡¬ããŠããããç¹ã«éææ§ãšèæ
æ§ãäœãããã®äžå転å¡åžæ³ã«ã¯é©ããªããšãã
æ¬ ç¹ãæãããããã«ç±ç¡¬åæ§ã¢ã¯ãªã«æš¹èãå¡
è圢æææãšããŠç¥ãããŠãããããã®å¡èã¯åº
äœãžã®æ¥çæ§ãäœãããã€å転å¡åžæ³ã«ã¯é©ããª
ããšããæ¬ ç¹ãæããã ãã®ããã«ãåŸæ¥ã®å¡è圢æææã§ã¯åèšã®èŠ
æ±è«žç¹æ§ããã©ã³ã¹ããæºããããå¡èãåŸãã
ãšãã§ããããšãããæ¥çæ§ãéææ§ãèæ°Žæ§ã
è溶å€æ§ããã³èææ§ã調åãããããšãå°é£ã§
ãããããã«å転å¡åžæ³ã«ã¯é©ããªããã®ãå€ã
ã€ãã æ¬çºæã®ç®çã¯ãäžèšåŸæ¥æè¡ã®æ¬ ç¹ã«éã¿ã
å¹³æ»ã匷éã§èç±æ§ããã³èå æ§ãé«ãããã«ã
åºäœçãžã®æ¥çæ§ãéææ§ãèæ°Žæ§ãè溶å€æ§ã
ãã³èææ§ã®ãããã®ç¹ã§ãåªããŠããå¡èã圢
æã§ãããã€è©²å¡èã®ç¡¬åºŠãé«ãããããå転å¡
åžæ³ã«é©ããç±ç¡¬åæ§çµæç©ãæäŸããããšã§ã
ãã ããªãã¡æ¬çºæã¯ã (A) äžè¬åŒïŒïŒ åŒäžãã¯æ°ŽçŽ ååãŸãã¯ã¡ãã«åºããšã
ã«åºããããã«åºãããã«åºçã®äœçŽã¢ã«ãã«
åºã§ãããïœã¯ïŒãïŒã®æŽæ°ã§ãã ã§è¡šãããååç©ã«ç±æ¥ããåéäœãŠãããã
60ééïŒ ä»¥äžå«æããéåäœãšã (B) åèšéåäœ100éééšåœãïŒã100éééšã®å€
䟡ã«ã«ãã³é žç¡æ°Žç©ããã³å€äŸ¡ã«ã«ãã³é žãã
éžã°ããå°ãªããšãïŒçš®ã®ååç©ãšã (C) åèšéåäœ100éééšåœã0.1ã30éééšã®å®
èœæ§ã·ã©ã³ã«ãããªã³ã°å€ãš ãå«ãã§ãªãç±ç¡¬åæ§çµæç©ãæäŸãããã®ã§ã
ãã æ¬çºæã®çµæç©ã«çšããããäžèšæå(A)ã®éå
äœãšããŠã¯ãäžè¬åŒïŒïŒã®ååç©ã®ïŒçš®ãããª
ãåç¬éåäœãäžè¬åŒïŒïŒã®ååç©ã®ïŒçš®ä»¥äž
ãããªãå ±éåäœãããã³äžè¬åŒïŒïŒã®ååç©
ïŒçš®ãããã¯ïŒçš®ä»¥äžãšãã®ä»ã®éåäœåéäœãš
ãããªãå ±éåäœãæããããšãã§ããã äžè¬åŒïŒïŒã®ååç©ã®å ·äœäŸãšããŠã¯ãã¢ã¯
ãªã«é žã°ãªã·ãžã«ãã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ãα
âãšãã«ã¢ã¯ãªã«é žã°ãªã·ãžã«ãαâïœâããã
ã«ã¢ã¯ãªã«é žã°ãªã·ãžã«ãαâïœâããã«ã¢ã¯ãª
ã«é žã°ãªã·ãžã«ãã¢ã¯ãªã«é žâïŒïŒïŒâãšããã·
ããã«ãã¡ã¿ã¯ãªã«é žâïŒïŒïŒâãšããã·ãã
ã«ãã¡ã¿ã¯ãªã«é žâïŒïŒïŒâãšããã·ãã³ãã«ã
ã¢ã¯ãªã«é žâïŒïŒïŒâãšããã·ãã³ãã«ãã¡ã¿ã¯
ãªã«é žâïŒïŒïŒâãšããã·ãã³ãã«ãαâãšãã«
ã¢ã¯ãªã«é žâïŒïŒïŒâãšããã·ãã³ãã«çãæã
ãããšãã§ããããããã®ååç©ã®äžã§ããäžè¬
åŒïŒïŒã«ãããŠïŒ²ãæ°ŽçŽ ååãã¡ãã«åºãŸãã¯
ãšãã«åºã奜ãŸãããïœã¯ïŒãŸãã¯ïŒã奜ãŸã
ãã æ¬çºæçµæç©ã®æå(A)ã§ããéåäœã®äžè¬åŒ
ïŒïŒã®ååç©ã«ç±æ¥ããåéäœãŠãããå«éã¯ã
60ééïŒ ä»¥äžã§ããããšãå¿ èŠã§ã奜ãŸããã¯80
ééïŒ ä»¥äžã§ãããç¹ã«å¥œãŸããã¯100ééïŒ ã§
ããã該åéäœãŠãããå«éã60ééïŒ æªæºã§ã
ããšãçµæç©ã®åºäœãšã®æ¥çæ§ãäžååã§ææã®
ç®çãéæããããšãã§ããªãããã®å«éã80é
éïŒ ä»¥äžã§ããçµæç©ã¯ãçš®ã ã®åºäœã«å¯ŸããŠç¹
ã«åªããæ¥çæ§ã瀺ãã æå(A)ã®éåäœã«ãããŠãäžè¬åŒïŒïŒã®åå
ç©ãšãšãã«å ±éåäœã圢æããã®ã«çšããããšã
ã§ããä»ã®éåæ§åéäœãšããŠã¯ãäŸãã°ã¢ã¯ãª
ã«é žã¡ãã«ãã¡ã¿ã¯ãªã«é žã¡ãã«ããã¢ã¯ãªã«é ž
ãšãã«ãã¡ã¿ã¯ãªã«é žãšãã«ãã¢ã¯ãªã«é žãã
ã«ãã¡ã¿ã¯ãªã«é žããã«ãã¡ã¿ã¯ãªã«é žâïŒâãš
ãã«ããã·ã«ãã¢ã¯ãªã«é žããšãã«ãã¡ã¿ã¯ãªã«
é žããšãã«çã®ã¢ã¯ãªã«é žãããã¯ã¡ã¿ã¯ãªã«é ž
ã®ãšã¹ãã«ïŒã¹ãã¬ã³ãαâã¡ãã«ã¹ãã¬ã³ãïœ
âã¡ãã«ã¹ãã¬ã³ãããã«ããã¿ã¬ã³çã®ããã«
è³éŠæååç©ãæããããšãã§ããããããã®é
åæ§åéäœã®ãã¡ã§ããã¢ã¯ãªã«é žãããã¯ã¡ã¿
ã¯ãªã«é žã®ãšã¹ãã«ãçšããããšãããã匷éã§
éææ§ã®é«ãå¡èã圢æããç¹ã«ãããŠç¹ã«å¥œãŸ
ããããŸããéåæ§åéäœãšããŠã¯ãã¢ã¯ãªã«
é žãã¡ã¿ã¯ãªã«é žãã¡ã¿ã¯ãªã«é žããããã·ãšã
ã«ãã¢ã¯ãªã«é žããããã·ãšãã«ãã¢ã¯ãªã«é žâ
ïŒâããããã·ãããã«ãã¡ã¿ã¯ãªã«é žâïŒâã
ãããã·ãããã«ãã¢ã¯ãªã«é žâïŒâããããã·
ããã«ãã¡ã¿ã¯ãªã«é žâïŒâããããã·ããã«ç
ã®å®èœæ§ã¢ã¯ãªã«ååç©ïŒãã¿ãžãšã³ãã€ãœãã¬
ã³ããããªã¬ã³ããžã¡ãã«ãã¿ãžãšã³çã®ãžãšã³
ç³»ååç©ã䜿çšããããšãã§ãããããããã«ç±
æ¥ããåéäœãŠãããã®å«éã¯æå(A)ã®éåäœã®
10ééïŒ ãè¶ ããªãç¯å²ã§ããããšãæãŸããã
ãããã®å«éã10ééïŒ ãè¶ ãããšãåºäœã«å¯Ÿã
ãæ¥çåãäœäžããã äžèšã®éåæ§åéäœãšäžè¬åŒïŒïŒã®ååç©ã®
å ±éåäœã®å ±éå圢æ ã¯ç¹ã«å¶éããããä»å é
åã«ããã©ã³ãã å ±éåäœããããã¯å ±éåäœç
ã®ãããã§ãããããŸãå ±éåæ¹æ³ã溶液éå
æ³ãä¹³åéåæ³çã®ãããã§ãããã (A)æåã®éåäœã®ååéã¯ãæ¬çºæçµæç©ãåº
äœã«åäžãªèãšããŠå¡åžããããšãã§ããéãç¹
ã«éå®ãããªãããéåžžããªã¹ãã¬ã³æç®ééå¹³
åååéã5000ã300000ã§ããã圢æããå¡èã®
åããå¡åžæ¹æ³çã®å¡è圢æã®ç®çãæ¡ä»¶ã«å¿ã
ãŠé©å®éžæããããšãã§ããã æ¬çºæã®çµæç©ã¯ãåèš(B)æåãšããŠå€äŸ¡ã«ã«
ãã³é žç¡æ°Žç©ãŸãã¯å€äŸ¡ã«ã«ãã³é žãå«æããã
å€äŸ¡ã«ã«ãã³é žç¡æ°Žç©ã®å ·äœäŸãšããŠã¯ãç¡æ°Žã
ã¿ã«é žãç¡æ°Žã€ã¿ã³ã³é žãç¡æ°Žã³ãã¯é žãç¡æ°Žã·
ãã©ã³ã³é žãç¡æ°Žããã»ãã«ã³ãã¯é žãç¡æ°Žããª
ã«ã«ããªã«é žãç¡æ°Žãã€ã¬ã³é žãç¡æ°Žãããµãã
ããã¿ã«é žãç¡æ°Žã¡ãã«ããã©ããããã¿ã«é žã
ç¡æ°Žãã€ããã¯é žçã®èèªæãžã«ã«ãã³é žç¡æ°Ž
ç©ïŒïŒïŒïŒïŒïŒïŒïŒâãã¿ã³ããã©ã«ã«ãã³é žäº
ç¡æ°Žç©ãã·ã¯ããã³ã¿ã³ããã©ã«ã«ãã³é žäºç¡æ°Ž
ç©çã®èèªæå€äŸ¡ã«ã«ãã³é žäºç¡æ°Žç©ïŒç¡æ°Žãã
ã¡ãªããé žãç¡æ°Žããªã¡ãªããé žãç¡æ°Žãã³ãŸã
ãšãã³ããã©ã«ã«ãã³é žçã®è³éŠæå€äŸ¡ã«ã«ãã³
é žç¡æ°Žç©ïŒãšãã¬ã³ã°ãªã³ãŒã«ãã¹ããªã¡ãªãã€
ããã°ãªã»ãªã³ããªã¹ããªã¡ãã€ãçã®ãšã¹ãã«
åºå«æé žç¡æ°Žç©ãæããããšãã§ããç¹ã«å¥œãŸã
ãã¯è³éŠæå€äŸ¡ã«ã«ãã³é žç¡æ°Žç©ã§ããã ãŸãããã®ã«ã«ãã³é žç¡æ°Žç©ãšããŠã¯ãåžè²©ã®
ç¡è²ã®é žç¡æ°Žç©ãããªããšããã·æš¹è硬åå€ã奜
é©ã«çšããããšãã§ããå ·äœäŸãšããŠã¢ãã«ããŒ
ãããŒEHâ700ïŒåååïŒä»¥äžåãïŒãæé»åå·¥
æ¥(æ ª)補ïŒããªã«ã·ããâHHãåMHâ700ïŒæ°æ¥
æ¬çå(æ ª)補ïŒããšãããã¢126ãåYHâ306ãå
DXâ126ïŒæ²¹åã·ãšã«ãšããã·(æ ª)補ïŒçãæãã
ããšãã§ããã ãŸããæ¬çºæã«çšããããå€äŸ¡ã«ã«ãã³é žã®å ·
äœäŸãšããŠã¯ãã³ãã¯é žãã°ã«ã¿ã«é žãã¢ãžãã³
é žããã¿ã³ããã©ã«ã«ãã³é žããã¬ã€ã³é žãã€ã¿
ã³ã³é žçã®èèªæå€äŸ¡ã«ã«ãã³é žïŒãããµããã
ãã¿ã«é žãïŒïŒïŒâã·ã¯ããããµã³ã«ã«ãã³é žã
ïŒïŒïŒïŒïŒâã·ã¯ããããµã³ããªã«ã«ãã³é žãã·
ã¯ããã³ã¿ã³ããã©ã«ã«ãã³é žçã®èç°åŒå€äŸ¡ã«
ã«ãã³é žããã³ãã¿ã«é žãã€ãœãã¿ã«é žããã¬ã
ã¿ã«é žãããªã¡ãªããé žãããã¡ãªããé žãïŒïŒ
ïŒïŒïŒïŒïŒâããã¿ã¬ã³ããã©ã«ã«ãã³é žããã³
ãŸããšãã³ããã©ã«ã«ãã³é žçã®è³éŠæå€äŸ¡ã«ã«
ãã³é žãæããããšãã§ãã奜ãŸããã¯è³éŠæå€
䟡ã«ã«ãã³é žã§ããã äžèšã®å€äŸ¡ã«ã«ãã³é žç¡æ°Žç©ããã³å€äŸ¡ã«ã«ã
ã³é žã¯ãïŒçš®åç¬ã§ãïŒçš®ä»¥äžã®çµåãã§ãçšã
ãããšãã§ããã æ¬çºæã®çµæç©ã«ããã(B)æåã®é åéã¯ã(A)
æåã§ããéåäœ100éééšåœãïŒã100éééšã®
ç¯å²ã§ããã奜ãŸããã¯ïŒã50éééšã§ããã(B)
æåã®é åéãïŒéééšæªæºã§ãããšã硬åãäž
ååãšãªã€ãŠåŒ·éãªå¡èã圢æããããšãã§ã
ãããŸãã100éééšãè¶ ãããšå¡èã®åºäœãžã®
æ¥çæ§ãäœäžããäžã«å転å¡åžæ³ã«ããåäžã§å¹³
æ»ãªå¡èã圢æããããšãå°é£ã§ããã æ¬çºæã®çµæç©ã¯ãåèš(C)æåãšããŠå®èœæ§ã·
ã©ã³ã«ãããªã³ã°å€ãå«æãããããã§ãå®èœæ§
ã·ã©ã³ã«ãããªã³ã°å€ãšã¯ãã«ã«ããã·ã«åºãã¡
ã¿ã¯ãªãã€ã«åºãã€ãœã·ã¢ããŒãåºããšããã·åº
çã®åå¿æ§çœ®æåºãæããã·ã©ã³ã«ãããªã³ã°å€
ãæå³ããå ·äœäŸãšããŠã¯ããªã¡ããã·ã·ãªã«å®
æ¯éŠé žãγâã¡ã¿ã¯ãªããã·ãããã«ããªã¡ãã
ã·ã·ã©ã³ãããã«ããªã¢ã»ããã·ã·ã©ã³ãããã«
ããªã¡ããã·ã·ãªã³ãγâã€ãœã·ã¢ãããããã«
ããªãšããã·ã·ã©ã³ãγâã°ãªã·ããã·ãããã«
ããªã¡ããã·ã·ã©ã³ãβâïŒïŒïŒïŒâãšããã·ã·
ã¯ãããã·ã«ïŒãšãã«ããªã¡ããã·ã·ã©ã³çãæ
ããããšãã§ãããäžã§ããγâã°ãªã·ããã·ã
ããã«ããªã¡ããã·ã·ã©ã³ãβâïŒïŒïŒïŒâãšã
ãã·ã·ã¯ãããã·ã«ïŒãšãã«ããªã¡ããã·ã·ã©ã³
çã®ãšããã·åºãæããã·ã©ã³ã«ãããªã³ã°å€
ããçš®ã ã®åºäœã«å¯Ÿããå¡èãšããŠç¹ã«åªããå¹³
æ»æ§ãæ¥çæ§ãèæ°Žæ§ããã³è溶å€æ§ã瀺ãç¹ã§
奜ãŸããããããã®ã·ã©ã³ã«ãããªã³ã°å€ã¯ãïŒ
çš®åç¬ã§ãïŒçš®ä»¥äžã®çµåãã§ã䜿çšããããšã
ã§ããã æ¬çºæã®çµæç©ã«ãããã(C)æåã®é åéã¯ã
(A)æåã§ããéåäœ100éééšåœã0.1ã30éééš
ã®ç¯å²ã§ããã奜ãŸããã¯0.5ã20éééšã§ããã
(C)æåã®é åéã0.1éééšæªæºã§ã¯ã圢æãã
ãå¡èã®å¹³æ»æ§ãªãã³ã«åºäœãšã®æ¥çæ§ãèæ°Žæ§
ããã³è溶å€æ§ãäžååã§ããããŸã30éééšã
è¶ ããŠãæ¥çæ§ã®åäžã¯ãã¯ãæããªãã°ããã§
ãªãã圢æãããå¡èã®ç¡¬åãäœäžããã æ¬çºæã®çµæç©ã«ã¯ãäžè¿°ãã(A)ã(C)ã®å¿ é æ
åã®ã»ãã«ãå¿ èŠã«å¿ããŠãäŸãã°èåé²æ¢å€ã
玫å€ç·åžåå€çã®å®å®å€ãéææ§ãæããªãçšåºŠ
ã«æ·»å ããããšãã§ããããªããå¡èã®ç®çã«ã
ã€ãŠéææ§ãæ±ããããªãå Žåã«ã¯ãé¡æãå¡
æãå å¡«å€çãé åããããšãã§ãããããã®å Ž
åã§ããã®ä»ã®è«žç¹æ§ã¯äœãæãããªãã æ¬çºæã®çµæç©ã¯ãäžèšè«žæåãåäžã«æ··åã
ãããšã«ããåŸãããããããã®æåãæ··åãã
æ¹æ³ãšããŠã¯ãéåžžããããã®æåãé©åœãªæº¶åª
ã«æº¶è§£ããããšã«ãã€ãŠæ··åãã溶液混åæ³ã奜
ãŸããã溶液混åã«çšãã溶åªãšããŠã¯ãäžèšå
æåã溶解ãããã€ãããã®æåãšåå¿ããªãã
ã®ã§ããã°ãç¹ã«éå®ããããã®ã§ã¯ãªããçš®ã
ã®æº¶åªã䜿çšããããšãã§ããå ·äœäŸãšããŠã¯ã
ã¢ã»ãã³ãã¡ãã«ãšãã«ã±ãã³ãã¡ãã«âïœâã
ããã«ã±ãã³ãã¡ãã«ã€ãœãããã«ã±ãã³ãã¡ã
ã«âïœâããã«ã±ãã³ãã¡ãã«ã€ãœããã«ã±ã
ã³ãã¡ãã«âïœâã¢ãã«ã±ãã³ãã¡ãã«âïœâã
ãã·ã«ã±ãã³ããžãšãã«ã±ãã³ããšãã«âïœâã
ãã«ã±ãã³ããžâïœâãããã«ã±ãã³ããžã€ãœã
ãã«ã±ãã³ãã·ã¯ããããµãã³ãããã³çã®ã±ã
ã³ç³»æº¶åªïŒ ãšãã«ãšãŒãã«ãã€ãœãã«ãã«ãšãŒãã«ãïœâã
ãã«ãšãŒãã«ããžã€ãœã¢ãã«ãšãŒãã«ããšãã¬ã³
ã°ãªã³ãŒã«ãžã¡ãã«ãšãŒãã«ããšãã¬ã³ã°ãªã³ãŒ
ã«ãžãšãã«ãšãŒãã«ããžãšãã¬ã³ã°ãªã³ãŒã«ãžã¡
ãã«ãšãŒãã«ããžãšãã¬ã³ã°ãªã³ãŒã«ããžãªããµ
ã³ãããã©ããããã©ã³çã®ãšãŒãã«ç³»æº¶åªïŒ ã®é žãšãã«ãã®é žãããã«ãã®é žâïœâããã«ã
é ¢é žãšãã«ãé ¢é žâïœâãããã«ãé ¢é žã€ãœãã
ãã«ãé ¢é žâïœâããã«ãé ¢é žâïœâã¢ãã«ããš
ãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«ã¢ã»ã¿ãŒ
ãããšãã¬ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã«ã¢ã»
ã¿ãŒãããžãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒã
ã«ã¢ã»ã¿ãŒãããžãšãã¬ã³ã°ãªã³ãŒã«ã¢ããšãã«
ãšãŒãã«ã¢ã»ã¿ãŒãçã®ãšã¹ãã«ç³»ååªãæãã
ããšãã§ããã æ¬çºæã®çµæç©ã溶液混åã«ãã調補ããå Žå
ã®æ··åé åºã¯ç¹ã«éå®ãããã®ã§ã¯ãªããäŸãã°
å šæåãåæã«ååªã«æº¶è§£ããŠæ¬çºæçµæç©ã®æº¶
液ã調補ããŠãããããå¿ èŠã«å¿ãåæåãå¥ã
ã«åäžãŸãã¯ç°çš®ã®æº¶åªã«æº¶è§£ããŠïŒä»¥äžã®æº¶æ¶²
ãšãããããã®æº¶æ¶²ãæ··åããŠæ¬çºæçµæç©ã®æº¶
液ã調補ããŠããããäŸãã°(B)æåã®æº¶æ¶²ãšãæ®
ãã®ä»ã®æåã®æº¶æ¶²ã®ïŒçš®ãšã調補ããŠããã䜿
çšçŽåã«ææã®æ¯çã§æ··åããããšã«ãã€ãŠãå
æåã®é·æã«ããã貯èµå®å®æ§ãåäžããããã
ïŒçš®ã®æº¶æ¶²ã®æ··åæ¯çããããã ãã§ãç®çã«å¿
ãç°¡åã«å¡èæ§èœãå€åãããããšãå¯èœã«ãª
ãã çµæç©æº¶æ¶²ã®æ¿åºŠã¯ãç¹ã«éå®ããããã®ã§ã¯
ãªãã䜿çšç®çã«å¿ããŠé©å®éžå®ããããšãã§ã
ãããäžè¬çã«ã¯ïŒã50ééïŒ çšåºŠã䜿çšããã äžèšã®ããã«ããŠèª¿è£œããæ¬çºæã®çµæç©ã®æº¶
液ãåºäœè¡šé¢ã«å¡åžããå ç±ã«ãã硬åãããã
ãšã«ããææã®å¡èãåŸãããšãã§ããã æ¬çºæã®çµæç©ã®æº¶æ¶²ãåºäœè¡šé¢ã«å¡åžããæ¹
æ³ã¯ç¹ã«éå®ããããäŸãã°ã¹ãã¬ãŒæ³ãããŒã«
ã³ãŒãæ³ãå転å¡åžæ³ãªã©åçš®ã®æ¹æ³ãçšããã
ãšãã§ããæ¬çºæã®çµæç©ãå転å¡åžæ³ã«ãé©ã
ãŠããç¹ã¯æ¬çºæã®ç¹é·ã®äžã€ã§ããã æ¬çºæçµæç©ã®ç±ç¡¬åæ¡ä»¶ã¯ãçµæç©ã®åæå
ã®å ·äœççš®é¡ãé åå²åçã«ãã€ãŠé©å®éžæãã
ãããéåžž80ã250âã§15åã10æéçšåºŠã§ããã ãã®ããã«ããŠåŸãããæ¬çºæçµæç©ã®å¡è
ã¯ã玫å€ããå¯èŠã®é åã«ãããåºãç¯å²ã®æ³¢é·
åã«ãããŠé«ãå ç·ééçãæããŠéææ§ã«åªã
ãŠããã»ããã¬ã©ã¹ãéå±ããã©ã¹ããã¯çã®
çš®ã ã®ææãããªãåºäœã«å¯ŸããŠåªããæ¥çæ§ã
瀺ãããŸãããã®å¡èã¯å¹³æ»ã匷éã§ãèå æ§ã
ãã³èç±æ§ã«åªããŠãããé·æã«ããã䜿çšã«ã
ã€ãŠãå€è²ãªã©ã®å€è³ªãèµ·ãããšããªãããã
ã«ãèæ°Žæ§ãè溶å€æ§ããã³èææ§ã«ãåªããã
ã®ã§ããã€ç¡¬åºŠã®é«ããã®ã§ããããããã®ç¹åŸŽ
ã«ãããæ¬çºæã®çµæç©ã«ãã圢æãããå¡è
ã¯ãåçš®ç©åã®åºäœè¡šé¢ã®ä¿è·å¡èãšããŠæçšã§
ããã®ã¿ãªãããè²åé¢ãã€ã«ã¿ãŒã®é²æä¿è·
å±€ãè¡šé¢ä¿è·å±€çãšããŠæ¥µããŠå¥œé©ã§ãããè²ã®
é®®æ床ãæããã«åªããä¿¡é Œæ§ã®é«ãè²åé¢ãã€
ã«ã¿ãŒãåŸãããšãã§ããã 次ã«å®æœäŸã«ãã€ãŠæ¬çºæãããã«è©³çŽ°ã«èª¬æ
ããããæ¬çºæã¯ãããå®æœäŸã«ããéå®ããã
ãã®ã§ã¯ãªãã å®æœäŸ ïŒ ããªã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ïŒããªã¹ãã¬ã³æ
ç®ééå¹³åååéçŽ80000ïŒïŒïœãã¬ã©ã¹å®¹åšäž
ã§ãšãã«ã»ããœã«ãã¢ã»ããŒã49ïœäžã«å ããå®
å šã«æº¶è§£ãããŸã§å®€æž©ã§ãããŸãããããããŠåŸ
ããã溶液ã«ã¢ãã«ããŒãããŒEHXâ700 0.6ïœ
ïŒæé»åå·¥æ¥(æ ª)補ïŒããã³Î³âã°ãªã·ããã·ãã
ãã«ããªã¡ããã·ã·ã©ã³0.3ïœãå ããåäžã«æ··
åãããŸã§ãããŸãããããããŠåŸããã溶液ã
ååŸ0.2ÎŒïœã®ãã€ã«ã¿ãŒã§ãéããã®ã¡ãã¹ãã³
ã³ãŒã¿ãŒãçšããŠã¬ã©ã¹æ¿äžã«å転æ°3000rpmã§
å転å¡åžãããå¡åžåŸã¬ã©ã¹æ¿ã150âã®æ枩槜
äžã«ãŠïŒæéç±åŠçãå¡èã硬åããããåŸãã
ãå¡èã®è¡šé¢ã¯æ¥µããŠæ»ããã§ãããèèãã¯å š
ãèŠãããªãã€ããäºå éå¹²æžé¡åŸ®é¡æ³ã«ãã€ãŠ
枬å®ããèåã¯0.39ÎŒïœã§ãã€ãã 以äžã®ããã«ããŠäœè£œããå¡èã«ã€ã以äžã®è©Š
éšãè¡ãªã€ãããŸãäžèšã®æ¹æ³ã§å¡èãã€ããã¬
ã©ã¹æ¿ã®åžåã¹ãã¯ãã«ããå¡åžãããã®ãšåã
ã¬ã©ã¹æ¿ãå¯Ÿç §ãšããŠæž¬å®ããã350nmã800nm
ã®å šé åã«ãããŠå ç·ééçã¯95ïŒ ä»¥äžã§ãã€
ãã次ã«ãã®ã¬ã©ã¹æ¿ã«å¡åžç¡¬åããå¡èã®æ¥ç
æ§ã調ã¹ãããã«ããŒãå¥é¢ã«ãããŽãã³ç®è©Šéš
ïŒJIS â5400ïŒãè¡ãªã€ãããã®çµæå¥é¢ã¯å š
ãèªããããªãã€ãããŸããã®ã¬ã©ã¹æ¿ã沞隰氎
äžã«å ¥ããŠïŒæéæŸçœ®ããã®ã¡ãåæ§ã«ããŠãŽã
ã³ç®è©Šéšãè¡ãªã€ããããã®å Žåãå¥é¢ã¯å šãèŠ
ãããªãã€ãããŸããäžèšã®å¡èã€ãã®ã¬ã©ã¹æ¿
ããã«ãšã³äžã«å ¥ããŠãïŒæéå ç±éæµããã®ã¡
ãŽãã³ç®è©Šéšãè¡ãªã€ããããã®å Žåãå¥é¢ã¯å š
ãèªããããªãã€ãããŸããäžèšãšåæ§ã«ããŠäœ
補ããå¡èã€ãã®ã¬ã©ã¹æ¿ã200âã®ã®ã€ãªãŒã
ã³äžã§200æéç±åŠçããçµæãå¡èã«ã¯ã©ãã¯
ã®å ¥ãããšã¯ãªãããŸãåžåã¹ãã¯ãã«ã®å€åã
èªããããªãã€ãã ããã«ãäžèšãšåæ§ã«ããŠäœè£œããå¡èã€ãã®
ã¬ã©ã¹æ¿ãäžèšã®çµæã®æè²æµŽäžã«å ¥ã100âã§
30åéæŸçœ®ããã®ã¡ãã¬ã©ã¹æ¿ããšãåºããŠãã
æ°ŽæŽã也ç¥ããã®ã¡å¡èã®æ§åãç®èŠã§èª¿ã¹ã
ããã¯ã©ãã¯ãèèãçã®ç°åžžã¯èªããããããŸ
ãå¡èã¯ç¡è²éæã®ãŸãŸã§å šãæè²ãããŠããªã
ã€ãã 以äžã®çµæããæ¬çºæã®çµæç©ã®å¡èãå¹³æ»ã§
ãããéææ§ãæ¥çæ§ãèæ°Žæ§ãè溶å€æ§ãèç±
æ§ããã³èææ§ã«æ¥µããŠããããŠããããšãæã
ãã§ããã æè²æµŽ é žæ§ææïŒããªãªã¢ã³ããã«ãŒFCFïŒ âŠâŠïŒïœ æ°·é ¢é ž âŠâŠïŒïœ èžçæ°Ž 100ïœ å®æœäŸ ïŒ å®æœäŸïŒã«ãããã¢ãã«ããŒãããŒEHXâ700
ã®äœ¿çšéã0.3ïœã«ãããŠãä»ã¯å®æœäŸïŒãšåæ§
ã«ããŠçµæç©æº¶æ¶²ã調補ããããªããšãã«ã»ããœ
ã«ãã¢ã»ããŒãã®äœ¿çšéã¯å šåºåœ¢åå«éãå®æœäŸ
ïŒãšåãã«ãªãããã«èª¿ç¯ããã次ãã§å®æœäŸïŒ
ãšåæ§ã«ããŠå転å¡åžæ³ã«ããã¬ã©ã¹æ¿äžã«ç¡¬å
åŸã®èå0.38ÎŒïœã®å¡èã圢æããããå¡èã®è¡š
é¢ã¯éåžžã«å¹³æ»ã§ãã€ããåŸãããå¡èã«ã€ããŠ
å®æœäŸïŒãšåãè©Šéšãè¡ãªã€ãçµæã¯è¡šïŒã«ç€ºã
éãã§ãã€ãã å®æœäŸ ïŒ å®æœäŸïŒã«ãããγâã°ãªã·ããã·ãããã«ã
ãªã¡ããã·ã·ã©ã³ã®äœ¿çšéã0.6ïœãšããŠãä»ã¯
å®æœäŸïŒãšåæ§ã«çµæç©æº¶æ¶²ã調補ããããªããš
ãã«ã»ããœã«ãã¢ã»ããŒãã®äœ¿çšéã¯å šåºåœ¢åå«
éãå®æœäŸïŒãšåãã«ãªãããã«èª¿ç¯ããã次ã
ã§å®æœäŸïŒãšåæ§ã«ããŠå転å¡åžæ³ã«ããã¬ã©ã¹
æ¿äžã«ç¡¬ååŸã®èå0.41ÎŒïœã®å¡èã圢æãããã
å¡èã®è¡šé¢ã¯éåžžã«å¹³æ»ã§ãã€ããåŸãããå¡è
ã®è©Šéšçµæã¯è¡šïŒã«ç€ºããéãã§ãã€ãã å®æœäŸ ïŒ å®æœäŸïŒã§çšããããªã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«
5.5ïœãã¬ã©ã¹å®¹åšäžã§ã·ã¯ããããµãã³45ïœã«
溶解ããããããããŠåŸããã溶液ã«ç¡æ°Žããã¡
ãªããé ž1.7ïœãšÎ³âã°ãªã·ããã·ãããã«ããª
ã¡ããã·ã·ã©ã³0.28ïœãå ããŠåäžãªæº¶æ¶²ãšãªã
ãŸã§æ··åããã次ãã§å®æœäŸïŒãšåæ§ã«ããŠçµæ
ç©æº¶æ¶²ã調補åŸã溶液ãã¬ã©ã¹æ¿äžã«å転å¡åžã
ãŠ180âã§ïŒæé硬åãã硬ååŸã®èå0.41ÎŒïœã®
å¡èã圢æããããå¡èã®è¡šé¢ã¯éåžžã«å¹³æ»ã§ã
ã€ããåŸãããå¡èã®è©Šéšçµæã¯è¡šïŒã«ç€ºããé
ãã§ãã€ãããŸãäžèšãšåæ§ã«ããŠå¡èã圢æã
ãã¬ã©ã¹æ¿ãäžèšã®çµæã®æè²æµŽäžã«å ¥ã100â
ã§ïŒæéæŸçœ®ããã®ã¡ãã¬ã©ã¹æ¿ããšãåºããŠã
ãæ°ŽæŽãã也ç¥ããã®ã¡å¡èã®æ§åãç®èŠã§èª¿ã¹
ãããã¯ã©ãã¯ãèèãçã®ç°åžžã¯èªããããã
ãŸãå¡èã¯ç¡è²éæã®ãŸãŸã§å šãæè²ãããŠããª
ãã€ãã æè²æµŽ é žæ§ææïŒã¹ãããŒã«ããªã³ã°ã¬ããRS äœåååŠ(æ ª)è£œïŒ âŠâŠïŒïœ æ°·é ¢é ž âŠâŠïŒïœ èžçæ°Ž âŠâŠ100ïœ å®æœäŸ ïŒ ã¢ã¯ãªã«é žã°ãªã·ãžã«ãšã¡ã¿ã¯ãªã«é žã¡ãã«ã®
å ±éåäœïŒããªã¹ãã¬ã³æç®ééå¹³åååéçŽ
95000ïŒNMRã¹ãã¯ãã«ã«ãã€ãŠæ±ããã¢ã¯ãª
ã«é žã°ãªã·ãžã«ã«ç±æ¥ããåéäœãŠãããå«é80
ééïŒ ïŒïŒïœãã·ã¯ããããµã³49ïœã«æº¶è§£ããã
åŸããã溶液ã«ç¡æ°Žããªã¡ãªããé žïŒïœããã³Î²
âïŒïŒïŒïŒâãšããã·ã·ã¯ãããã·ã«ïŒãšãã«ã
ãªã¡ããã·ã·ã©ã³0.4ïœãå ããŠåäžãªæº¶æ¶²ãšãª
ããŸã§æ··åããã次ãã§å®æœäŸïŒãšåæ§ã«ããŠçµ
æç©æº¶æ¶²ã調補ããã®ã¡ã溶液ãã¬ã©ã¹æ¿äžã«å
転å¡åžããŠ180âã§ïŒæé硬åãã硬ååŸã®èå
0.45ÎŒïœã®å¡èã圢æããããå¡èã®è¡šé¢ã¯éåžž
ã«å¹³æ»ã§ãã€ããåŸãããå¡èã®è©Šéšçµæã¯è¡šïŒ
ã«ç€ºããéãã§ãã€ãããŸããäžèšãšåæ§ããŠäœ
æããå¡èã€ãã®ã¬ã©ã¹æ¿ãå®æœäŸïŒãšåæ§ã®æ
è²æµŽãçšãåæ§ã«æäœããããã¯ã©ãã¯ãèèã
çã®ç°åžžã¯èªããããããŸãå¡èã¯ç¡è²éæã®ãŸ
ãŸã§å šãæè²ãããŠããªãã€ãã å®æœäŸ ïŒ å®æœäŸïŒã§äœ¿çšããããªã¡ã¿ã¯ãªã«é žã°ãªã·ãž
ã«ïŒïœããšãã«ã»ããœã«ãã¢ã»ããŒã49ïœã«æº¶è§£
ãããŠåŸããã溶液ã«ãç¡æ°Žãã€ããã¯é ž1.2ïœ
ããã³Î³âã°ãªã·ããã·ãããã«ããªã¡ããã·ã·
ã©ã³0.5ïœãå ãåäžãªæº¶æ¶²ãšãªããŸã§æ··åããã
次ãã§å®æœäŸïŒãšåæ§ã«ããŠçµæç©æº¶æ¶²ã調補ã
ãã®ã¡ã溶液ãã¬ã©ã¹æ¿äžã«å転å¡åžããŠ180â
ã§ïŒæé硬åãã硬ååŸã®èå0.42ÎŒïœã®å¡èã
圢æããããå¡èã®è¡šé¢ã¯éåžžã«å¹³æ»ã§ãã€ãã
åŸãããå¡èã®è©Šéšçµæã¯è¡šïŒã«ç€ºããéãã§ã
ã€ãã å®æœäŸ ïŒ å®æœäŸïŒã«ãããç¡æ°Žããã¡ãªããé žã®ä»£ãã«
ã·ã¯ããã³ã¿ã³ããã©ã«ã«ãã³é žäºç¡æ°Žç©1.7ïœ
ã䜿çšããä»ã¯å®æœäŸïŒãšåæ§ã«ããŠçµæç©æº¶æ¶²
ã調補ããã¬ã©ã¹æ¿äžã«ç¡¬ååŸã®èå0.35ÎŒïœã®
å¡èã圢æãããåŸãããå¡èã®è©Šéšçµæã¯è¡šïŒ
ã«ç€ºããéãã§ãã€ãããªãå¡èã®è¡šé¢ã¯éåžžã«
å¹³æ»ã§ãã€ãã å®æœäŸ ïŒ å®æœäŸïŒã«ãããç¡æ°Žããã¡ãªããé žã®ä»£ãã«
ãã³ãŸããšãã³ããã©ã«ã«ãã³é žäºç¡æ°Žç©1.7ïœ
ã䜿çšããä»ã¯å®æœäŸïŒãšåæ§ã«ããŠã¬ã©ã¹æ¿äž
ã«å¡èã圢æããã硬ååŸã®å¡èã®èåã¯0.46ÎŒ
ïœãå¡èã®è©Šéšçµæã¯è¡šïŒã«ç€ºããéãã§ãã€
ãããªãå¡èã®è¡šé¢ã¯éåžžã«å¹³æ»ã§ãã€ãã ãŸããäžèšãšåæ§ã«ããŠäœæããå¡èã€ãã®ã¬
ã©ã¹æ¿ãå®æœäŸïŒãšåæ§ã®æè²æµŽãçšãåæ§ã«æ
äœããããã¯ã©ãã¯ãèèãçã®ç°åžžã¯èªããã
ãããŸãå¡èã¯ç¡è²éæã®ãŸãŸã§å šãæè²ãããŠ
ããªãã€ãã å®æœäŸ ïŒ å®æœäŸïŒã«ãããã¢ãã«ããŒãããŒEHXâ700
ã«ãããŠããªã«ã·ãããŒHHïŒæ°æ¥æ¬çå(æ ª)補ïŒ
1.8ïœã䜿çšããä»ã¯å®æœäŸïŒãšåæ§ã«ããŠèª¿è£œ
ããçµæç©æº¶æ¶²ãã¬ã©ã¹æ¿äžã«å転å¡åžåŸã180
âã§ïŒæé硬åãããŠãèå0.52ÎŒïœã®å¡èãåŸ
ããå¡èã®è¡šé¢ã¯éåžžã«å¹³æ»ã§ãã€ãããã®å¡è
ã®è©Šéšçµæã¯è¡šïŒã«ç€ºããéãã§ãã€ãã å®æœäŸ 10 å®æœäŸïŒã«ãããã¢ãã«ããŒãããŒEHXâ700
ã«ãããŠããªã«ã·ããMHâ700ïŒæ°æ¥æ¬çå(æ ª)
補ïŒ1.8ïœã䜿çšããä»ã¯å®æœäŸïŒãšåæ§ã«ããŠ
調補ããçµæç©æº¶æ¶²ãã¬ã©ã¹æ¿äžã«å転å¡åžåŸã
180âã§ïŒæé硬åãããŠãèå0.47ÎŒïœã®å¡èã
åŸããå¡èã®è¡šé¢ã¯éåžžã«å¹³æ»ã§ãã€ãããã®å¡
èã®è©Šéšçµæã¯è¡šïŒã«ç€ºããéãã§ãã€ãã å®æœäŸ 11 å®æœäŸïŒã«ãããã¢ãã«ããŒãããŒEHXâ700
ã«ãããŠããã¬ãã¿ã«é ž0.8ïœã䜿çšããä»ã¯å®
æœäŸïŒãšåæ§ã«ããŠèª¿è£œããçµæç©æº¶æ¶²ãã¬ã©ã¹
æ¿äžã«å転å¡åžåŸã180âã§ïŒæé硬åãããŠã
èå0.44ÎŒïœã®å¡èãåŸããå¡èã®è¡šé¢ã¯éåžžã«
å¹³æ»ã§ãã€ãããã®å¡èã®è©Šéšçµæã¯è¡šïŒã«ç€ºã
ãéãã§ãã€ãã å®æœäŸ 12 å®æœäŸïŒã«ãããã¢ãã«ããŒãããŒEHXâ700
ã«ãããŠãããªã¡ãªããé ž0.6ïœã䜿çšããä»ã¯
å®æœäŸïŒãšåæ§ã«ããŠèª¿è£œããçµæç©æº¶æ¶²ãã¬ã©
ã¹æ¿äžã«å転å¡åžåŸã150âã§ïŒæé硬åãããŠã
èå0.40ÎŒïœã®å¡èãåŸããå¡èã®è¡šé¢ã¯éåžžã«
å¹³æ»ã§ãã€ãããã®å¡èã®è©Šéšçµæã¯è¡šïŒã«ç€ºã
ãéãã§ãã€ãã å®æœäŸ 13 å®æœäŸïŒã®ããªã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ã«ãã
ãŠãããªã¢ã¯ãªã«é žã°ãªã·ãžã«ïŒããªã¹ãã¬ã³æ
ç®ééå¹³åååé100000ïŒïŒïœãçšããä»ã¯å®æœ
äŸïŒãšåæ§ã«ããŠçµæç©æº¶æ¶²ã調補ããã次ãã§
å®æœäŸïŒãšåæ§ã«ããŠã¬ã©ã¹æ¿äžã«å転å¡åžãã
硬åããŠåã0.51ÎŒïœã®å¡èãåŸããå¡èã®è¡šé¢
ã¯éåžžã«å¹³æ»ã§ãã€ããåŸãããå¡èã®è©Šéšçµæ
ã¯è¡šïŒã«ç€ºãéãã§ãã€ãã å®æœäŸ 14 å®æœäŸïŒã®ããªã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ã«ãã
ãŠãã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ãšã¡ã¿ã¯ãªã«é žã¡ã
ã«ã®å ±éåäœïŒããªã¹ãã¬ã³æç®ééå¹³åååé
84000ïŒNMRã¹ãã¯ãã«ããæ±ããã¡ã¿ã¯ãªã«
é žã°ãªã·ãžã«ã«ç±æ¥ããåéäœãŠãããå«é72é
éïŒ ïŒ5.8ïœãçšããä»ã¯å®æœäŸïŒãšåæ§ã«ããŠ
çµæç©æº¶æ¶²ãåŸãã次ãã§å®æœäŸïŒãšåæ§ã«ããŠ
ã¬ã©ã¹æ¿äžã«å転å¡åžãã硬åããŠåã0.37ÎŒïœ
ã®å¡èãåŸããå¡èã®è¡šé¢ã¯éåžžã«å¹³æ»ã§ãã€
ããåŸãããå¡èã®è©Šéšçµæã¯è¡šïŒã«ç€ºãéãã§
ãã€ãã å®æœäŸ 15 å®æœäŸïŒã«ãããããªã°ãªã·ãžã«é žã°ãªã·ãžã«
ã«ä»£ããŠãã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ãšã¡ã¿ã¯ãªã«
é žïœâããã«ã®å ±éåäœïŒããªã¹ãã¬ã³æç®éé
å¹³åååé120000ïŒNMRã¹ãã¯ãã«ããæ±ãã
ã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ã«ç±æ¥ããåéäœãŠãã
ãå«é63ééïŒ ïŒïŒïœãçšãããŸãã¢ãã«ããŒã
ããŒEHXâ700ã«ä»£ããŠãããªã¡ãªããé ž0.6ïœ
ãçšããä»ã¯å®æœäŸïŒãšåæ§ã«ããŠçµæç©æº¶æ¶²ã
åŸãã次ãã§å®æœäŸïŒãšåæ§ã«ããŠã¬ã©ã¹æ¿äžã«
å転å¡åžã硬åããŠåã0.35ÎŒïœã®å¡èãåŸãã
åŸãããå¡èã¯éåžžã«å¹³æ»ã§ããããŸããã®å¡è
ã®è©Šéšçµæã¯è¡šïŒã«ç€ºãéãã§ãã€ãã å®æœäŸ 16 å®æœäŸïŒã«ãããããªã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«
ã«ä»£ããŠãã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ãšã¡ã¿ã¯ãªã«
é žã€ãœããã«ã®å ±éåäœïŒããªã¹ãã¬ã³æç®éé
å¹³åååé125000ïŒNMRã¹ãã¯ãã«ããæ±ãã
ã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ã«ç±æ¥ããåéäœãŠãã
ãå«é65ïŒ ïŒ6.2ïœãçšãããŸãå®æœäŸïŒã«ãã
ãã¢ãã«ããŒãããŒEHXâ700ã«ä»£ããŠããã¬ã
ã¿ã«é ž0.63ïœã䜿çšããä»ã¯å®æœäŸïŒãšåæ§ã«ã
ãŠã¬ã©ã¹æ¿äžã«åãã0.38ÎŒïœã®å¡èã圢æãã
ãããã®å¡èã«ã€ããŠã®è©Šéšçµæã¯è¡šïŒã«ç€ºãé
ãã§ãã€ãã å®æœäŸ 17 å®æœäŸïŒã«ãããããªã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«
ã«ä»£ããŠãã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ãšã¡ã¿ã¯ãªã«
é žç¬¬ïŒããã«ã®å ±éåäœïŒããªã¹ãã¬ã³æç®éé
å¹³åååé150000ïŒNMRã¹ãã¯ãã«ããæ±ãã
ã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ã«ç±æ¥ããåéäœãŠãã
ãå«é62.5ééïŒ ïŒ6.2ïœãçšãããŸãå®æœäŸïŒ
ã«ãããã¢ãã«ããŒãããŒEHXâ700ã«ä»£ããŠã
ããªã¡ãªããé ž0.6ïœãçšããä»ã¯å®æœäŸïŒãšå
æ§ã«ããŠåãã0.32ÎŒïœã®å¡èã圢æããããã®
å¡èã«ã€ããŠã®è©Šéšçµæã¯è¡šïŒã«ç€ºãéãã§ãã€
ãã å®æœäŸ 18 å®æœäŸïŒã«ãããããªã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«
ã«ä»£ããŠãã¢ã¯ãªã«é žã°ãªã·ãžã«ãšã¢ã¯ãªã«é žç¬¬
ïŒããã«ã®å ±éåäœïŒããªã¹ãã¬ã³æç®ééå¹³å
ååé1450000ïŒNMRããæ±ããã¢ã¯ãªã«é žã°
ãªã·ãžã«ã«ç±æ¥ããåéäœãŠããã60ééïŒ ïŒ
6.0ïœãçšããä»ã¯å®æœäŸïŒãšåæ§ã«ããŠåãã
0.35ÎŒïœã®å¡èã圢æããããã®å¡èã«ã€ããŠã®
è©Šéšçµæã¯è¡šïŒã«ç€ºãéãã§ãã€ãã æ¯èŒäŸ ïŒ å®æœäŸïŒã«ãããŠãγâãããã«ããªã¡ããã·
ã·ã©ã³ã䜿çšããã«èª¿è£œããçµæç©ã®æº¶æ¶²ã䜿çš
ããå®æœäŸïŒãšåæ§ã«ããŠã¬ã©ã¹æ¿äžã«ç¡¬ååŸã®
èå0.38ÎŒïœã®å¡èã圢æããããåŸãããå¡è
ã®è©Šéšçµæã¯è¡šïŒã«ç€ºããéãã§ãã€ãã æ¯èŒäŸ ïŒ å®æœäŸïŒã«ãããŠãããªã¡ã¿ã¯ãªã«é žã°ãªã·ãž
ã«ã«ãããŠãããªã¡ã¿ã¯ãªã«é žã¡ãã«5.5ïœã䜿
çšããŠãå®æœäŸïŒãšåæ§ã«ããŠçµæç©æº¶æ¶²ã調補
ããå®æœäŸïŒãšåæ§ã«ããŠã¬ã©ã¹æ¿äžã«ç¡¬ååŸã®
èå0.55ÎŒïœã®å¡èãåŸããåŸãããå¡èã®è©Šéš
çµæã¯è¡šïŒã«ç€ºããéãã§ãã€ãã æ¯èŒäŸ ïŒ å®æœäŸïŒã®ããªã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ã«ãã
ãŠãã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ãšã¡ã¿ã¯ãªã«é žã¡ã
ã«ã®å ±éåäœïŒããªã¹ãã¬ã³æç®ééå¹³åååé
83000NMRã¹ãã¯ãã«ããæ±ããã¡ã¿ã¯ãªã«é ž
ã°ãªã·ãžã«ã«ç±æ¥ããåéäœãŠãããå«é45ïŒ ïŒ
ïŒïœãçšããä»ã¯å®æœäŸïŒãšåæ§ã«ããŠçµæç©æº¶
液ãåŸãã次ãã§å®æœäŸïŒãšåæ§ã«ããŠã¬ã©ã¹æ¿
äžã«å転å¡åžãã硬åããŠåã0.31ÎŒïœã®å¡èã
åŸããåŸãããå¡èã®è©Šéšçµæã¯è¡šïŒã«ç€ºãéã
ã§ãã€ãã
æææãšããŠçš®ã ã®å¡èç©æ§ã«åªããç±ç¡¬åæ§çµ
æç©ã«é¢ããã åŸæ¥ãåçš®ç©åã®åºäœè¡šé¢ã®å£åãæå·ãé²æ¢
ããããã«ããã®è¡šé¢ã«ä¿è·å¡èã圢æããããš
ãåºãè¡ãããŠããããã®ãããªä¿è·å¡èã«ãã
ãŠã¯ãåºäœãžã®æ¥çæ§ãé«ããå¡èãå¹³æ»ã§åŒ·é
ã§ããããšãèç±æ§ããã³èå æ§ãé«ããŠé·æã«
ããã€ãŠå€è²ãªã©ã®å€è³ªãããªãããšãèæ°Žæ§ã
ãã³è溶å€æ§ãåªããããšçã®æ§èœãèŠæ±ãã
ãã ãŸããè¿å¹Žãè²åé¢ãã€ã«ã¿ãŒãå èµããã«ã©
ãŒæ¶²æ¶è¡šç€ºçŽ åçãçš®ã çºè¡šãããŠããããã®ã«
ã©ãŒæ¶²æ¶è¡šç€ºçŽ åã®ã«ã©ãŒãã€ã«ã¿ãŒã¯ãã¬ã©ã¹
çã®éæåºäœäžã«æ¬¡ã®ãããªå·¥çšãçµãŠåœ¢æãã
ããããªãã¡ãããªããã«ã¢ã«ã³ãŒã«ãã°ãªãŠ
ãŒããŒã©ãã³çã«æå æ§ãä»äžãåºäœäžã«åäžã«
å¡åžãããã¹ã¯é²å æ³ã§ïŒè²ç®ã®è²çžéšåã®ã¿å
硬åããçŸåãããã®ä»ã®éšåãé€å»ããããã®
è²çžéšåã«æå®ã®åå ç¹æ§ãæããææã§æè²ã
ãã次ãã§éæãªé²æä¿è·å±€ã被èŠãããïŒè²ç®
ã®è²çžéšåã«ã€ããŠãåæ§ã®å·¥çšãçšãæè²ãã
é²æä¿è·å±€ã被èŠãããïŒè²ç®ã®è²çžéšåã«ã€ã
ãŠãåæ§ã®å·¥çšãçšãæè²ããæåŸã«è¡šé¢ä¿è·å±€
ã圢æããããã®é²æä¿è·å±€ããã³è¡šé¢ä¿è·å±€
ã¯ãåèšä¿è·å¡èã«å¿ èŠãªæ§èœãããªãã¡æ¥ç
æ§ãå¹³æ»æ§ã匷éæ§ãèç±æ§ãèå æ§ãèæ°Žæ§ã
ãã³è溶å€æ§ã®ä»ã«ãéææ§ããã³ææã«æè²ã
ããªãããã®èææ§çã®æ§èœãèŠæ±ãããããã
ãŠãããã«ããããã®å±€ãšãªãææã¯ãé²æä¿è·
å±€ããã³è¡šé¢ä¿è·å±€ã圢æãããããã«ã溶液ãš
ããŠå¡åžããããåäžãªå¡èã圢æãããããã«
ã¹ãã³ã³ãŒã¿ã«ããå転å¡åžæ³ãçšããå Žåãã
ãããã®å¡åžæ³ã«ãé©ããããšãèŠæ±ãããã åŸæ¥ãå¡è圢æææã®äžã€ãšããŠããªã¹ãã¬
ã³ãããªã«ãŒãããŒãçã®ç±å¯å¡æ§æš¹èãç¥ãã
ãŠãããããããã®å¡èã¯ãåºäœãšã®æ¥çæ§ãè
ç±æ§ããã³è溶å€æ§ãäœããšããæ¬ ç¹ãæããã
ãŸããå¥ã®å¡è圢æææãšããŠã¡ã©ãã³æš¹èããš
ããã·æš¹èçã®ç±ç¡¬åæ§æš¹èãç¥ãããŠãããã
ãããã®å¡èã¯ç¡¬ããŠããããç¹ã«éææ§ãšèæ
æ§ãäœãããã®äžå転å¡åžæ³ã«ã¯é©ããªããšãã
æ¬ ç¹ãæãããããã«ç±ç¡¬åæ§ã¢ã¯ãªã«æš¹èãå¡
è圢æææãšããŠç¥ãããŠãããããã®å¡èã¯åº
äœãžã®æ¥çæ§ãäœãããã€å転å¡åžæ³ã«ã¯é©ããª
ããšããæ¬ ç¹ãæããã ãã®ããã«ãåŸæ¥ã®å¡è圢æææã§ã¯åèšã®èŠ
æ±è«žç¹æ§ããã©ã³ã¹ããæºããããå¡èãåŸãã
ãšãã§ããããšãããæ¥çæ§ãéææ§ãèæ°Žæ§ã
è溶å€æ§ããã³èææ§ã調åãããããšãå°é£ã§
ãããããã«å転å¡åžæ³ã«ã¯é©ããªããã®ãå€ã
ã€ãã æ¬çºæã®ç®çã¯ãäžèšåŸæ¥æè¡ã®æ¬ ç¹ã«éã¿ã
å¹³æ»ã匷éã§èç±æ§ããã³èå æ§ãé«ãããã«ã
åºäœçãžã®æ¥çæ§ãéææ§ãèæ°Žæ§ãè溶å€æ§ã
ãã³èææ§ã®ãããã®ç¹ã§ãåªããŠããå¡èã圢
æã§ãããã€è©²å¡èã®ç¡¬åºŠãé«ãããããå転å¡
åžæ³ã«é©ããç±ç¡¬åæ§çµæç©ãæäŸããããšã§ã
ãã ããªãã¡æ¬çºæã¯ã (A) äžè¬åŒïŒïŒ åŒäžãã¯æ°ŽçŽ ååãŸãã¯ã¡ãã«åºããšã
ã«åºããããã«åºãããã«åºçã®äœçŽã¢ã«ãã«
åºã§ãããïœã¯ïŒãïŒã®æŽæ°ã§ãã ã§è¡šãããååç©ã«ç±æ¥ããåéäœãŠãããã
60ééïŒ ä»¥äžå«æããéåäœãšã (B) åèšéåäœ100éééšåœãïŒã100éééšã®å€
䟡ã«ã«ãã³é žç¡æ°Žç©ããã³å€äŸ¡ã«ã«ãã³é žãã
éžã°ããå°ãªããšãïŒçš®ã®ååç©ãšã (C) åèšéåäœ100éééšåœã0.1ã30éééšã®å®
èœæ§ã·ã©ã³ã«ãããªã³ã°å€ãš ãå«ãã§ãªãç±ç¡¬åæ§çµæç©ãæäŸãããã®ã§ã
ãã æ¬çºæã®çµæç©ã«çšããããäžèšæå(A)ã®éå
äœãšããŠã¯ãäžè¬åŒïŒïŒã®ååç©ã®ïŒçš®ãããª
ãåç¬éåäœãäžè¬åŒïŒïŒã®ååç©ã®ïŒçš®ä»¥äž
ãããªãå ±éåäœãããã³äžè¬åŒïŒïŒã®ååç©
ïŒçš®ãããã¯ïŒçš®ä»¥äžãšãã®ä»ã®éåäœåéäœãš
ãããªãå ±éåäœãæããããšãã§ããã äžè¬åŒïŒïŒã®ååç©ã®å ·äœäŸãšããŠã¯ãã¢ã¯
ãªã«é žã°ãªã·ãžã«ãã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ãα
âãšãã«ã¢ã¯ãªã«é žã°ãªã·ãžã«ãαâïœâããã
ã«ã¢ã¯ãªã«é žã°ãªã·ãžã«ãαâïœâããã«ã¢ã¯ãª
ã«é žã°ãªã·ãžã«ãã¢ã¯ãªã«é žâïŒïŒïŒâãšããã·
ããã«ãã¡ã¿ã¯ãªã«é žâïŒïŒïŒâãšããã·ãã
ã«ãã¡ã¿ã¯ãªã«é žâïŒïŒïŒâãšããã·ãã³ãã«ã
ã¢ã¯ãªã«é žâïŒïŒïŒâãšããã·ãã³ãã«ãã¡ã¿ã¯
ãªã«é žâïŒïŒïŒâãšããã·ãã³ãã«ãαâãšãã«
ã¢ã¯ãªã«é žâïŒïŒïŒâãšããã·ãã³ãã«çãæã
ãããšãã§ããããããã®ååç©ã®äžã§ããäžè¬
åŒïŒïŒã«ãããŠïŒ²ãæ°ŽçŽ ååãã¡ãã«åºãŸãã¯
ãšãã«åºã奜ãŸãããïœã¯ïŒãŸãã¯ïŒã奜ãŸã
ãã æ¬çºæçµæç©ã®æå(A)ã§ããéåäœã®äžè¬åŒ
ïŒïŒã®ååç©ã«ç±æ¥ããåéäœãŠãããå«éã¯ã
60ééïŒ ä»¥äžã§ããããšãå¿ èŠã§ã奜ãŸããã¯80
ééïŒ ä»¥äžã§ãããç¹ã«å¥œãŸããã¯100ééïŒ ã§
ããã該åéäœãŠãããå«éã60ééïŒ æªæºã§ã
ããšãçµæç©ã®åºäœãšã®æ¥çæ§ãäžååã§ææã®
ç®çãéæããããšãã§ããªãããã®å«éã80é
éïŒ ä»¥äžã§ããçµæç©ã¯ãçš®ã ã®åºäœã«å¯ŸããŠç¹
ã«åªããæ¥çæ§ã瀺ãã æå(A)ã®éåäœã«ãããŠãäžè¬åŒïŒïŒã®åå
ç©ãšãšãã«å ±éåäœã圢æããã®ã«çšããããšã
ã§ããä»ã®éåæ§åéäœãšããŠã¯ãäŸãã°ã¢ã¯ãª
ã«é žã¡ãã«ãã¡ã¿ã¯ãªã«é žã¡ãã«ããã¢ã¯ãªã«é ž
ãšãã«ãã¡ã¿ã¯ãªã«é žãšãã«ãã¢ã¯ãªã«é žãã
ã«ãã¡ã¿ã¯ãªã«é žããã«ãã¡ã¿ã¯ãªã«é žâïŒâãš
ãã«ããã·ã«ãã¢ã¯ãªã«é žããšãã«ãã¡ã¿ã¯ãªã«
é žããšãã«çã®ã¢ã¯ãªã«é žãããã¯ã¡ã¿ã¯ãªã«é ž
ã®ãšã¹ãã«ïŒã¹ãã¬ã³ãαâã¡ãã«ã¹ãã¬ã³ãïœ
âã¡ãã«ã¹ãã¬ã³ãããã«ããã¿ã¬ã³çã®ããã«
è³éŠæååç©ãæããããšãã§ããããããã®é
åæ§åéäœã®ãã¡ã§ããã¢ã¯ãªã«é žãããã¯ã¡ã¿
ã¯ãªã«é žã®ãšã¹ãã«ãçšããããšãããã匷éã§
éææ§ã®é«ãå¡èã圢æããç¹ã«ãããŠç¹ã«å¥œãŸ
ããããŸããéåæ§åéäœãšããŠã¯ãã¢ã¯ãªã«
é žãã¡ã¿ã¯ãªã«é žãã¡ã¿ã¯ãªã«é žããããã·ãšã
ã«ãã¢ã¯ãªã«é žããããã·ãšãã«ãã¢ã¯ãªã«é žâ
ïŒâããããã·ãããã«ãã¡ã¿ã¯ãªã«é žâïŒâã
ãããã·ãããã«ãã¢ã¯ãªã«é žâïŒâããããã·
ããã«ãã¡ã¿ã¯ãªã«é žâïŒâããããã·ããã«ç
ã®å®èœæ§ã¢ã¯ãªã«ååç©ïŒãã¿ãžãšã³ãã€ãœãã¬
ã³ããããªã¬ã³ããžã¡ãã«ãã¿ãžãšã³çã®ãžãšã³
ç³»ååç©ã䜿çšããããšãã§ãããããããã«ç±
æ¥ããåéäœãŠãããã®å«éã¯æå(A)ã®éåäœã®
10ééïŒ ãè¶ ããªãç¯å²ã§ããããšãæãŸããã
ãããã®å«éã10ééïŒ ãè¶ ãããšãåºäœã«å¯Ÿã
ãæ¥çåãäœäžããã äžèšã®éåæ§åéäœãšäžè¬åŒïŒïŒã®ååç©ã®
å ±éåäœã®å ±éå圢æ ã¯ç¹ã«å¶éããããä»å é
åã«ããã©ã³ãã å ±éåäœããããã¯å ±éåäœç
ã®ãããã§ãããããŸãå ±éåæ¹æ³ã溶液éå
æ³ãä¹³åéåæ³çã®ãããã§ãããã (A)æåã®éåäœã®ååéã¯ãæ¬çºæçµæç©ãåº
äœã«åäžãªèãšããŠå¡åžããããšãã§ããéãç¹
ã«éå®ãããªãããéåžžããªã¹ãã¬ã³æç®ééå¹³
åååéã5000ã300000ã§ããã圢æããå¡èã®
åããå¡åžæ¹æ³çã®å¡è圢æã®ç®çãæ¡ä»¶ã«å¿ã
ãŠé©å®éžæããããšãã§ããã æ¬çºæã®çµæç©ã¯ãåèš(B)æåãšããŠå€äŸ¡ã«ã«
ãã³é žç¡æ°Žç©ãŸãã¯å€äŸ¡ã«ã«ãã³é žãå«æããã
å€äŸ¡ã«ã«ãã³é žç¡æ°Žç©ã®å ·äœäŸãšããŠã¯ãç¡æ°Žã
ã¿ã«é žãç¡æ°Žã€ã¿ã³ã³é žãç¡æ°Žã³ãã¯é žãç¡æ°Žã·
ãã©ã³ã³é žãç¡æ°Žããã»ãã«ã³ãã¯é žãç¡æ°Žããª
ã«ã«ããªã«é žãç¡æ°Žãã€ã¬ã³é žãç¡æ°Žãããµãã
ããã¿ã«é žãç¡æ°Žã¡ãã«ããã©ããããã¿ã«é žã
ç¡æ°Žãã€ããã¯é žçã®èèªæãžã«ã«ãã³é žç¡æ°Ž
ç©ïŒïŒïŒïŒïŒïŒïŒïŒâãã¿ã³ããã©ã«ã«ãã³é žäº
ç¡æ°Žç©ãã·ã¯ããã³ã¿ã³ããã©ã«ã«ãã³é žäºç¡æ°Ž
ç©çã®èèªæå€äŸ¡ã«ã«ãã³é žäºç¡æ°Žç©ïŒç¡æ°Žãã
ã¡ãªããé žãç¡æ°Žããªã¡ãªããé žãç¡æ°Žãã³ãŸã
ãšãã³ããã©ã«ã«ãã³é žçã®è³éŠæå€äŸ¡ã«ã«ãã³
é žç¡æ°Žç©ïŒãšãã¬ã³ã°ãªã³ãŒã«ãã¹ããªã¡ãªãã€
ããã°ãªã»ãªã³ããªã¹ããªã¡ãã€ãçã®ãšã¹ãã«
åºå«æé žç¡æ°Žç©ãæããããšãã§ããç¹ã«å¥œãŸã
ãã¯è³éŠæå€äŸ¡ã«ã«ãã³é žç¡æ°Žç©ã§ããã ãŸãããã®ã«ã«ãã³é žç¡æ°Žç©ãšããŠã¯ãåžè²©ã®
ç¡è²ã®é žç¡æ°Žç©ãããªããšããã·æš¹è硬åå€ã奜
é©ã«çšããããšãã§ããå ·äœäŸãšããŠã¢ãã«ããŒ
ãããŒEHâ700ïŒåååïŒä»¥äžåãïŒãæé»åå·¥
æ¥(æ ª)補ïŒããªã«ã·ããâHHãåMHâ700ïŒæ°æ¥
æ¬çå(æ ª)補ïŒããšãããã¢126ãåYHâ306ãå
DXâ126ïŒæ²¹åã·ãšã«ãšããã·(æ ª)補ïŒçãæãã
ããšãã§ããã ãŸããæ¬çºæã«çšããããå€äŸ¡ã«ã«ãã³é žã®å ·
äœäŸãšããŠã¯ãã³ãã¯é žãã°ã«ã¿ã«é žãã¢ãžãã³
é žããã¿ã³ããã©ã«ã«ãã³é žããã¬ã€ã³é žãã€ã¿
ã³ã³é žçã®èèªæå€äŸ¡ã«ã«ãã³é žïŒãããµããã
ãã¿ã«é žãïŒïŒïŒâã·ã¯ããããµã³ã«ã«ãã³é žã
ïŒïŒïŒïŒïŒâã·ã¯ããããµã³ããªã«ã«ãã³é žãã·
ã¯ããã³ã¿ã³ããã©ã«ã«ãã³é žçã®èç°åŒå€äŸ¡ã«
ã«ãã³é žããã³ãã¿ã«é žãã€ãœãã¿ã«é žããã¬ã
ã¿ã«é žãããªã¡ãªããé žãããã¡ãªããé žãïŒïŒ
ïŒïŒïŒïŒïŒâããã¿ã¬ã³ããã©ã«ã«ãã³é žããã³
ãŸããšãã³ããã©ã«ã«ãã³é žçã®è³éŠæå€äŸ¡ã«ã«
ãã³é žãæããããšãã§ãã奜ãŸããã¯è³éŠæå€
䟡ã«ã«ãã³é žã§ããã äžèšã®å€äŸ¡ã«ã«ãã³é žç¡æ°Žç©ããã³å€äŸ¡ã«ã«ã
ã³é žã¯ãïŒçš®åç¬ã§ãïŒçš®ä»¥äžã®çµåãã§ãçšã
ãããšãã§ããã æ¬çºæã®çµæç©ã«ããã(B)æåã®é åéã¯ã(A)
æåã§ããéåäœ100éééšåœãïŒã100éééšã®
ç¯å²ã§ããã奜ãŸããã¯ïŒã50éééšã§ããã(B)
æåã®é åéãïŒéééšæªæºã§ãããšã硬åãäž
ååãšãªã€ãŠåŒ·éãªå¡èã圢æããããšãã§ã
ãããŸãã100éééšãè¶ ãããšå¡èã®åºäœãžã®
æ¥çæ§ãäœäžããäžã«å転å¡åžæ³ã«ããåäžã§å¹³
æ»ãªå¡èã圢æããããšãå°é£ã§ããã æ¬çºæã®çµæç©ã¯ãåèš(C)æåãšããŠå®èœæ§ã·
ã©ã³ã«ãããªã³ã°å€ãå«æãããããã§ãå®èœæ§
ã·ã©ã³ã«ãããªã³ã°å€ãšã¯ãã«ã«ããã·ã«åºãã¡
ã¿ã¯ãªãã€ã«åºãã€ãœã·ã¢ããŒãåºããšããã·åº
çã®åå¿æ§çœ®æåºãæããã·ã©ã³ã«ãããªã³ã°å€
ãæå³ããå ·äœäŸãšããŠã¯ããªã¡ããã·ã·ãªã«å®
æ¯éŠé žãγâã¡ã¿ã¯ãªããã·ãããã«ããªã¡ãã
ã·ã·ã©ã³ãããã«ããªã¢ã»ããã·ã·ã©ã³ãããã«
ããªã¡ããã·ã·ãªã³ãγâã€ãœã·ã¢ãããããã«
ããªãšããã·ã·ã©ã³ãγâã°ãªã·ããã·ãããã«
ããªã¡ããã·ã·ã©ã³ãβâïŒïŒïŒïŒâãšããã·ã·
ã¯ãããã·ã«ïŒãšãã«ããªã¡ããã·ã·ã©ã³çãæ
ããããšãã§ãããäžã§ããγâã°ãªã·ããã·ã
ããã«ããªã¡ããã·ã·ã©ã³ãβâïŒïŒïŒïŒâãšã
ãã·ã·ã¯ãããã·ã«ïŒãšãã«ããªã¡ããã·ã·ã©ã³
çã®ãšããã·åºãæããã·ã©ã³ã«ãããªã³ã°å€
ããçš®ã ã®åºäœã«å¯Ÿããå¡èãšããŠç¹ã«åªããå¹³
æ»æ§ãæ¥çæ§ãèæ°Žæ§ããã³è溶å€æ§ã瀺ãç¹ã§
奜ãŸããããããã®ã·ã©ã³ã«ãããªã³ã°å€ã¯ãïŒ
çš®åç¬ã§ãïŒçš®ä»¥äžã®çµåãã§ã䜿çšããããšã
ã§ããã æ¬çºæã®çµæç©ã«ãããã(C)æåã®é åéã¯ã
(A)æåã§ããéåäœ100éééšåœã0.1ã30éééš
ã®ç¯å²ã§ããã奜ãŸããã¯0.5ã20éééšã§ããã
(C)æåã®é åéã0.1éééšæªæºã§ã¯ã圢æãã
ãå¡èã®å¹³æ»æ§ãªãã³ã«åºäœãšã®æ¥çæ§ãèæ°Žæ§
ããã³è溶å€æ§ãäžååã§ããããŸã30éééšã
è¶ ããŠãæ¥çæ§ã®åäžã¯ãã¯ãæããªãã°ããã§
ãªãã圢æãããå¡èã®ç¡¬åãäœäžããã æ¬çºæã®çµæç©ã«ã¯ãäžè¿°ãã(A)ã(C)ã®å¿ é æ
åã®ã»ãã«ãå¿ èŠã«å¿ããŠãäŸãã°èåé²æ¢å€ã
玫å€ç·åžåå€çã®å®å®å€ãéææ§ãæããªãçšåºŠ
ã«æ·»å ããããšãã§ããããªããå¡èã®ç®çã«ã
ã€ãŠéææ§ãæ±ããããªãå Žåã«ã¯ãé¡æãå¡
æãå å¡«å€çãé åããããšãã§ãããããã®å Ž
åã§ããã®ä»ã®è«žç¹æ§ã¯äœãæãããªãã æ¬çºæã®çµæç©ã¯ãäžèšè«žæåãåäžã«æ··åã
ãããšã«ããåŸãããããããã®æåãæ··åãã
æ¹æ³ãšããŠã¯ãéåžžããããã®æåãé©åœãªæº¶åª
ã«æº¶è§£ããããšã«ãã€ãŠæ··åãã溶液混åæ³ã奜
ãŸããã溶液混åã«çšãã溶åªãšããŠã¯ãäžèšå
æåã溶解ãããã€ãããã®æåãšåå¿ããªãã
ã®ã§ããã°ãç¹ã«éå®ããããã®ã§ã¯ãªããçš®ã
ã®æº¶åªã䜿çšããããšãã§ããå ·äœäŸãšããŠã¯ã
ã¢ã»ãã³ãã¡ãã«ãšãã«ã±ãã³ãã¡ãã«âïœâã
ããã«ã±ãã³ãã¡ãã«ã€ãœãããã«ã±ãã³ãã¡ã
ã«âïœâããã«ã±ãã³ãã¡ãã«ã€ãœããã«ã±ã
ã³ãã¡ãã«âïœâã¢ãã«ã±ãã³ãã¡ãã«âïœâã
ãã·ã«ã±ãã³ããžãšãã«ã±ãã³ããšãã«âïœâã
ãã«ã±ãã³ããžâïœâãããã«ã±ãã³ããžã€ãœã
ãã«ã±ãã³ãã·ã¯ããããµãã³ãããã³çã®ã±ã
ã³ç³»æº¶åªïŒ ãšãã«ãšãŒãã«ãã€ãœãã«ãã«ãšãŒãã«ãïœâã
ãã«ãšãŒãã«ããžã€ãœã¢ãã«ãšãŒãã«ããšãã¬ã³
ã°ãªã³ãŒã«ãžã¡ãã«ãšãŒãã«ããšãã¬ã³ã°ãªã³ãŒ
ã«ãžãšãã«ãšãŒãã«ããžãšãã¬ã³ã°ãªã³ãŒã«ãžã¡
ãã«ãšãŒãã«ããžãšãã¬ã³ã°ãªã³ãŒã«ããžãªããµ
ã³ãããã©ããããã©ã³çã®ãšãŒãã«ç³»æº¶åªïŒ ã®é žãšãã«ãã®é žãããã«ãã®é žâïœâããã«ã
é ¢é žãšãã«ãé ¢é žâïœâãããã«ãé ¢é žã€ãœãã
ãã«ãé ¢é žâïœâããã«ãé ¢é žâïœâã¢ãã«ããš
ãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒãã«ã¢ã»ã¿ãŒ
ãããšãã¬ã³ã°ãªã³ãŒã«ã¢ããšãã«ãšãŒãã«ã¢ã»
ã¿ãŒãããžãšãã¬ã³ã°ãªã³ãŒã«ã¢ãã¡ãã«ãšãŒã
ã«ã¢ã»ã¿ãŒãããžãšãã¬ã³ã°ãªã³ãŒã«ã¢ããšãã«
ãšãŒãã«ã¢ã»ã¿ãŒãçã®ãšã¹ãã«ç³»ååªãæãã
ããšãã§ããã æ¬çºæã®çµæç©ã溶液混åã«ãã調補ããå Žå
ã®æ··åé åºã¯ç¹ã«éå®ãããã®ã§ã¯ãªããäŸãã°
å šæåãåæã«ååªã«æº¶è§£ããŠæ¬çºæçµæç©ã®æº¶
液ã調補ããŠãããããå¿ èŠã«å¿ãåæåãå¥ã
ã«åäžãŸãã¯ç°çš®ã®æº¶åªã«æº¶è§£ããŠïŒä»¥äžã®æº¶æ¶²
ãšãããããã®æº¶æ¶²ãæ··åããŠæ¬çºæçµæç©ã®æº¶
液ã調補ããŠããããäŸãã°(B)æåã®æº¶æ¶²ãšãæ®
ãã®ä»ã®æåã®æº¶æ¶²ã®ïŒçš®ãšã調補ããŠããã䜿
çšçŽåã«ææã®æ¯çã§æ··åããããšã«ãã€ãŠãå
æåã®é·æã«ããã貯èµå®å®æ§ãåäžããããã
ïŒçš®ã®æº¶æ¶²ã®æ··åæ¯çããããã ãã§ãç®çã«å¿
ãç°¡åã«å¡èæ§èœãå€åãããããšãå¯èœã«ãª
ãã çµæç©æº¶æ¶²ã®æ¿åºŠã¯ãç¹ã«éå®ããããã®ã§ã¯
ãªãã䜿çšç®çã«å¿ããŠé©å®éžå®ããããšãã§ã
ãããäžè¬çã«ã¯ïŒã50ééïŒ çšåºŠã䜿çšããã äžèšã®ããã«ããŠèª¿è£œããæ¬çºæã®çµæç©ã®æº¶
液ãåºäœè¡šé¢ã«å¡åžããå ç±ã«ãã硬åãããã
ãšã«ããææã®å¡èãåŸãããšãã§ããã æ¬çºæã®çµæç©ã®æº¶æ¶²ãåºäœè¡šé¢ã«å¡åžããæ¹
æ³ã¯ç¹ã«éå®ããããäŸãã°ã¹ãã¬ãŒæ³ãããŒã«
ã³ãŒãæ³ãå転å¡åžæ³ãªã©åçš®ã®æ¹æ³ãçšããã
ãšãã§ããæ¬çºæã®çµæç©ãå転å¡åžæ³ã«ãé©ã
ãŠããç¹ã¯æ¬çºæã®ç¹é·ã®äžã€ã§ããã æ¬çºæçµæç©ã®ç±ç¡¬åæ¡ä»¶ã¯ãçµæç©ã®åæå
ã®å ·äœççš®é¡ãé åå²åçã«ãã€ãŠé©å®éžæãã
ãããéåžž80ã250âã§15åã10æéçšåºŠã§ããã ãã®ããã«ããŠåŸãããæ¬çºæçµæç©ã®å¡è
ã¯ã玫å€ããå¯èŠã®é åã«ãããåºãç¯å²ã®æ³¢é·
åã«ãããŠé«ãå ç·ééçãæããŠéææ§ã«åªã
ãŠããã»ããã¬ã©ã¹ãéå±ããã©ã¹ããã¯çã®
çš®ã ã®ææãããªãåºäœã«å¯ŸããŠåªããæ¥çæ§ã
瀺ãããŸãããã®å¡èã¯å¹³æ»ã匷éã§ãèå æ§ã
ãã³èç±æ§ã«åªããŠãããé·æã«ããã䜿çšã«ã
ã€ãŠãå€è²ãªã©ã®å€è³ªãèµ·ãããšããªãããã
ã«ãèæ°Žæ§ãè溶å€æ§ããã³èææ§ã«ãåªããã
ã®ã§ããã€ç¡¬åºŠã®é«ããã®ã§ããããããã®ç¹åŸŽ
ã«ãããæ¬çºæã®çµæç©ã«ãã圢æãããå¡è
ã¯ãåçš®ç©åã®åºäœè¡šé¢ã®ä¿è·å¡èãšããŠæçšã§
ããã®ã¿ãªãããè²åé¢ãã€ã«ã¿ãŒã®é²æä¿è·
å±€ãè¡šé¢ä¿è·å±€çãšããŠæ¥µããŠå¥œé©ã§ãããè²ã®
é®®æ床ãæããã«åªããä¿¡é Œæ§ã®é«ãè²åé¢ãã€
ã«ã¿ãŒãåŸãããšãã§ããã 次ã«å®æœäŸã«ãã€ãŠæ¬çºæãããã«è©³çŽ°ã«èª¬æ
ããããæ¬çºæã¯ãããå®æœäŸã«ããéå®ããã
ãã®ã§ã¯ãªãã å®æœäŸ ïŒ ããªã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ïŒããªã¹ãã¬ã³æ
ç®ééå¹³åååéçŽ80000ïŒïŒïœãã¬ã©ã¹å®¹åšäž
ã§ãšãã«ã»ããœã«ãã¢ã»ããŒã49ïœäžã«å ããå®
å šã«æº¶è§£ãããŸã§å®€æž©ã§ãããŸãããããããŠåŸ
ããã溶液ã«ã¢ãã«ããŒãããŒEHXâ700 0.6ïœ
ïŒæé»åå·¥æ¥(æ ª)補ïŒããã³Î³âã°ãªã·ããã·ãã
ãã«ããªã¡ããã·ã·ã©ã³0.3ïœãå ããåäžã«æ··
åãããŸã§ãããŸãããããããŠåŸããã溶液ã
ååŸ0.2ÎŒïœã®ãã€ã«ã¿ãŒã§ãéããã®ã¡ãã¹ãã³
ã³ãŒã¿ãŒãçšããŠã¬ã©ã¹æ¿äžã«å転æ°3000rpmã§
å転å¡åžãããå¡åžåŸã¬ã©ã¹æ¿ã150âã®æ枩槜
äžã«ãŠïŒæéç±åŠçãå¡èã硬åããããåŸãã
ãå¡èã®è¡šé¢ã¯æ¥µããŠæ»ããã§ãããèèãã¯å š
ãèŠãããªãã€ããäºå éå¹²æžé¡åŸ®é¡æ³ã«ãã€ãŠ
枬å®ããèåã¯0.39ÎŒïœã§ãã€ãã 以äžã®ããã«ããŠäœè£œããå¡èã«ã€ã以äžã®è©Š
éšãè¡ãªã€ãããŸãäžèšã®æ¹æ³ã§å¡èãã€ããã¬
ã©ã¹æ¿ã®åžåã¹ãã¯ãã«ããå¡åžãããã®ãšåã
ã¬ã©ã¹æ¿ãå¯Ÿç §ãšããŠæž¬å®ããã350nmã800nm
ã®å šé åã«ãããŠå ç·ééçã¯95ïŒ ä»¥äžã§ãã€
ãã次ã«ãã®ã¬ã©ã¹æ¿ã«å¡åžç¡¬åããå¡èã®æ¥ç
æ§ã調ã¹ãããã«ããŒãå¥é¢ã«ãããŽãã³ç®è©Šéš
ïŒJIS â5400ïŒãè¡ãªã€ãããã®çµæå¥é¢ã¯å š
ãèªããããªãã€ãããŸããã®ã¬ã©ã¹æ¿ã沞隰氎
äžã«å ¥ããŠïŒæéæŸçœ®ããã®ã¡ãåæ§ã«ããŠãŽã
ã³ç®è©Šéšãè¡ãªã€ããããã®å Žåãå¥é¢ã¯å šãèŠ
ãããªãã€ãããŸããäžèšã®å¡èã€ãã®ã¬ã©ã¹æ¿
ããã«ãšã³äžã«å ¥ããŠãïŒæéå ç±éæµããã®ã¡
ãŽãã³ç®è©Šéšãè¡ãªã€ããããã®å Žåãå¥é¢ã¯å š
ãèªããããªãã€ãããŸããäžèšãšåæ§ã«ããŠäœ
補ããå¡èã€ãã®ã¬ã©ã¹æ¿ã200âã®ã®ã€ãªãŒã
ã³äžã§200æéç±åŠçããçµæãå¡èã«ã¯ã©ãã¯
ã®å ¥ãããšã¯ãªãããŸãåžåã¹ãã¯ãã«ã®å€åã
èªããããªãã€ãã ããã«ãäžèšãšåæ§ã«ããŠäœè£œããå¡èã€ãã®
ã¬ã©ã¹æ¿ãäžèšã®çµæã®æè²æµŽäžã«å ¥ã100âã§
30åéæŸçœ®ããã®ã¡ãã¬ã©ã¹æ¿ããšãåºããŠãã
æ°ŽæŽã也ç¥ããã®ã¡å¡èã®æ§åãç®èŠã§èª¿ã¹ã
ããã¯ã©ãã¯ãèèãçã®ç°åžžã¯èªããããããŸ
ãå¡èã¯ç¡è²éæã®ãŸãŸã§å šãæè²ãããŠããªã
ã€ãã 以äžã®çµæããæ¬çºæã®çµæç©ã®å¡èãå¹³æ»ã§
ãããéææ§ãæ¥çæ§ãèæ°Žæ§ãè溶å€æ§ãèç±
æ§ããã³èææ§ã«æ¥µããŠããããŠããããšãæã
ãã§ããã æè²æµŽ é žæ§ææïŒããªãªã¢ã³ããã«ãŒFCFïŒ âŠâŠïŒïœ æ°·é ¢é ž âŠâŠïŒïœ èžçæ°Ž 100ïœ å®æœäŸ ïŒ å®æœäŸïŒã«ãããã¢ãã«ããŒãããŒEHXâ700
ã®äœ¿çšéã0.3ïœã«ãããŠãä»ã¯å®æœäŸïŒãšåæ§
ã«ããŠçµæç©æº¶æ¶²ã調補ããããªããšãã«ã»ããœ
ã«ãã¢ã»ããŒãã®äœ¿çšéã¯å šåºåœ¢åå«éãå®æœäŸ
ïŒãšåãã«ãªãããã«èª¿ç¯ããã次ãã§å®æœäŸïŒ
ãšåæ§ã«ããŠå転å¡åžæ³ã«ããã¬ã©ã¹æ¿äžã«ç¡¬å
åŸã®èå0.38ÎŒïœã®å¡èã圢æããããå¡èã®è¡š
é¢ã¯éåžžã«å¹³æ»ã§ãã€ããåŸãããå¡èã«ã€ããŠ
å®æœäŸïŒãšåãè©Šéšãè¡ãªã€ãçµæã¯è¡šïŒã«ç€ºã
éãã§ãã€ãã å®æœäŸ ïŒ å®æœäŸïŒã«ãããγâã°ãªã·ããã·ãããã«ã
ãªã¡ããã·ã·ã©ã³ã®äœ¿çšéã0.6ïœãšããŠãä»ã¯
å®æœäŸïŒãšåæ§ã«çµæç©æº¶æ¶²ã調補ããããªããš
ãã«ã»ããœã«ãã¢ã»ããŒãã®äœ¿çšéã¯å šåºåœ¢åå«
éãå®æœäŸïŒãšåãã«ãªãããã«èª¿ç¯ããã次ã
ã§å®æœäŸïŒãšåæ§ã«ããŠå転å¡åžæ³ã«ããã¬ã©ã¹
æ¿äžã«ç¡¬ååŸã®èå0.41ÎŒïœã®å¡èã圢æãããã
å¡èã®è¡šé¢ã¯éåžžã«å¹³æ»ã§ãã€ããåŸãããå¡è
ã®è©Šéšçµæã¯è¡šïŒã«ç€ºããéãã§ãã€ãã å®æœäŸ ïŒ å®æœäŸïŒã§çšããããªã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«
5.5ïœãã¬ã©ã¹å®¹åšäžã§ã·ã¯ããããµãã³45ïœã«
溶解ããããããããŠåŸããã溶液ã«ç¡æ°Žããã¡
ãªããé ž1.7ïœãšÎ³âã°ãªã·ããã·ãããã«ããª
ã¡ããã·ã·ã©ã³0.28ïœãå ããŠåäžãªæº¶æ¶²ãšãªã
ãŸã§æ··åããã次ãã§å®æœäŸïŒãšåæ§ã«ããŠçµæ
ç©æº¶æ¶²ã調補åŸã溶液ãã¬ã©ã¹æ¿äžã«å転å¡åžã
ãŠ180âã§ïŒæé硬åãã硬ååŸã®èå0.41ÎŒïœã®
å¡èã圢æããããå¡èã®è¡šé¢ã¯éåžžã«å¹³æ»ã§ã
ã€ããåŸãããå¡èã®è©Šéšçµæã¯è¡šïŒã«ç€ºããé
ãã§ãã€ãããŸãäžèšãšåæ§ã«ããŠå¡èã圢æã
ãã¬ã©ã¹æ¿ãäžèšã®çµæã®æè²æµŽäžã«å ¥ã100â
ã§ïŒæéæŸçœ®ããã®ã¡ãã¬ã©ã¹æ¿ããšãåºããŠã
ãæ°ŽæŽãã也ç¥ããã®ã¡å¡èã®æ§åãç®èŠã§èª¿ã¹
ãããã¯ã©ãã¯ãèèãçã®ç°åžžã¯èªããããã
ãŸãå¡èã¯ç¡è²éæã®ãŸãŸã§å šãæè²ãããŠããª
ãã€ãã æè²æµŽ é žæ§ææïŒã¹ãããŒã«ããªã³ã°ã¬ããRS äœåååŠ(æ ª)è£œïŒ âŠâŠïŒïœ æ°·é ¢é ž âŠâŠïŒïœ èžçæ°Ž âŠâŠ100ïœ å®æœäŸ ïŒ ã¢ã¯ãªã«é žã°ãªã·ãžã«ãšã¡ã¿ã¯ãªã«é žã¡ãã«ã®
å ±éåäœïŒããªã¹ãã¬ã³æç®ééå¹³åååéçŽ
95000ïŒNMRã¹ãã¯ãã«ã«ãã€ãŠæ±ããã¢ã¯ãª
ã«é žã°ãªã·ãžã«ã«ç±æ¥ããåéäœãŠãããå«é80
ééïŒ ïŒïŒïœãã·ã¯ããããµã³49ïœã«æº¶è§£ããã
åŸããã溶液ã«ç¡æ°Žããªã¡ãªããé žïŒïœããã³Î²
âïŒïŒïŒïŒâãšããã·ã·ã¯ãããã·ã«ïŒãšãã«ã
ãªã¡ããã·ã·ã©ã³0.4ïœãå ããŠåäžãªæº¶æ¶²ãšãª
ããŸã§æ··åããã次ãã§å®æœäŸïŒãšåæ§ã«ããŠçµ
æç©æº¶æ¶²ã調補ããã®ã¡ã溶液ãã¬ã©ã¹æ¿äžã«å
転å¡åžããŠ180âã§ïŒæé硬åãã硬ååŸã®èå
0.45ÎŒïœã®å¡èã圢æããããå¡èã®è¡šé¢ã¯éåžž
ã«å¹³æ»ã§ãã€ããåŸãããå¡èã®è©Šéšçµæã¯è¡šïŒ
ã«ç€ºããéãã§ãã€ãããŸããäžèšãšåæ§ããŠäœ
æããå¡èã€ãã®ã¬ã©ã¹æ¿ãå®æœäŸïŒãšåæ§ã®æ
è²æµŽãçšãåæ§ã«æäœããããã¯ã©ãã¯ãèèã
çã®ç°åžžã¯èªããããããŸãå¡èã¯ç¡è²éæã®ãŸ
ãŸã§å šãæè²ãããŠããªãã€ãã å®æœäŸ ïŒ å®æœäŸïŒã§äœ¿çšããããªã¡ã¿ã¯ãªã«é žã°ãªã·ãž
ã«ïŒïœããšãã«ã»ããœã«ãã¢ã»ããŒã49ïœã«æº¶è§£
ãããŠåŸããã溶液ã«ãç¡æ°Žãã€ããã¯é ž1.2ïœ
ããã³Î³âã°ãªã·ããã·ãããã«ããªã¡ããã·ã·
ã©ã³0.5ïœãå ãåäžãªæº¶æ¶²ãšãªããŸã§æ··åããã
次ãã§å®æœäŸïŒãšåæ§ã«ããŠçµæç©æº¶æ¶²ã調補ã
ãã®ã¡ã溶液ãã¬ã©ã¹æ¿äžã«å転å¡åžããŠ180â
ã§ïŒæé硬åãã硬ååŸã®èå0.42ÎŒïœã®å¡èã
圢æããããå¡èã®è¡šé¢ã¯éåžžã«å¹³æ»ã§ãã€ãã
åŸãããå¡èã®è©Šéšçµæã¯è¡šïŒã«ç€ºããéãã§ã
ã€ãã å®æœäŸ ïŒ å®æœäŸïŒã«ãããç¡æ°Žããã¡ãªããé žã®ä»£ãã«
ã·ã¯ããã³ã¿ã³ããã©ã«ã«ãã³é žäºç¡æ°Žç©1.7ïœ
ã䜿çšããä»ã¯å®æœäŸïŒãšåæ§ã«ããŠçµæç©æº¶æ¶²
ã調補ããã¬ã©ã¹æ¿äžã«ç¡¬ååŸã®èå0.35ÎŒïœã®
å¡èã圢æãããåŸãããå¡èã®è©Šéšçµæã¯è¡šïŒ
ã«ç€ºããéãã§ãã€ãããªãå¡èã®è¡šé¢ã¯éåžžã«
å¹³æ»ã§ãã€ãã å®æœäŸ ïŒ å®æœäŸïŒã«ãããç¡æ°Žããã¡ãªããé žã®ä»£ãã«
ãã³ãŸããšãã³ããã©ã«ã«ãã³é žäºç¡æ°Žç©1.7ïœ
ã䜿çšããä»ã¯å®æœäŸïŒãšåæ§ã«ããŠã¬ã©ã¹æ¿äž
ã«å¡èã圢æããã硬ååŸã®å¡èã®èåã¯0.46ÎŒ
ïœãå¡èã®è©Šéšçµæã¯è¡šïŒã«ç€ºããéãã§ãã€
ãããªãå¡èã®è¡šé¢ã¯éåžžã«å¹³æ»ã§ãã€ãã ãŸããäžèšãšåæ§ã«ããŠäœæããå¡èã€ãã®ã¬
ã©ã¹æ¿ãå®æœäŸïŒãšåæ§ã®æè²æµŽãçšãåæ§ã«æ
äœããããã¯ã©ãã¯ãèèãçã®ç°åžžã¯èªããã
ãããŸãå¡èã¯ç¡è²éæã®ãŸãŸã§å šãæè²ãããŠ
ããªãã€ãã å®æœäŸ ïŒ å®æœäŸïŒã«ãããã¢ãã«ããŒãããŒEHXâ700
ã«ãããŠããªã«ã·ãããŒHHïŒæ°æ¥æ¬çå(æ ª)補ïŒ
1.8ïœã䜿çšããä»ã¯å®æœäŸïŒãšåæ§ã«ããŠèª¿è£œ
ããçµæç©æº¶æ¶²ãã¬ã©ã¹æ¿äžã«å転å¡åžåŸã180
âã§ïŒæé硬åãããŠãèå0.52ÎŒïœã®å¡èãåŸ
ããå¡èã®è¡šé¢ã¯éåžžã«å¹³æ»ã§ãã€ãããã®å¡è
ã®è©Šéšçµæã¯è¡šïŒã«ç€ºããéãã§ãã€ãã å®æœäŸ 10 å®æœäŸïŒã«ãããã¢ãã«ããŒãããŒEHXâ700
ã«ãããŠããªã«ã·ããMHâ700ïŒæ°æ¥æ¬çå(æ ª)
補ïŒ1.8ïœã䜿çšããä»ã¯å®æœäŸïŒãšåæ§ã«ããŠ
調補ããçµæç©æº¶æ¶²ãã¬ã©ã¹æ¿äžã«å転å¡åžåŸã
180âã§ïŒæé硬åãããŠãèå0.47ÎŒïœã®å¡èã
åŸããå¡èã®è¡šé¢ã¯éåžžã«å¹³æ»ã§ãã€ãããã®å¡
èã®è©Šéšçµæã¯è¡šïŒã«ç€ºããéãã§ãã€ãã å®æœäŸ 11 å®æœäŸïŒã«ãããã¢ãã«ããŒãããŒEHXâ700
ã«ãããŠããã¬ãã¿ã«é ž0.8ïœã䜿çšããä»ã¯å®
æœäŸïŒãšåæ§ã«ããŠèª¿è£œããçµæç©æº¶æ¶²ãã¬ã©ã¹
æ¿äžã«å転å¡åžåŸã180âã§ïŒæé硬åãããŠã
èå0.44ÎŒïœã®å¡èãåŸããå¡èã®è¡šé¢ã¯éåžžã«
å¹³æ»ã§ãã€ãããã®å¡èã®è©Šéšçµæã¯è¡šïŒã«ç€ºã
ãéãã§ãã€ãã å®æœäŸ 12 å®æœäŸïŒã«ãããã¢ãã«ããŒãããŒEHXâ700
ã«ãããŠãããªã¡ãªããé ž0.6ïœã䜿çšããä»ã¯
å®æœäŸïŒãšåæ§ã«ããŠèª¿è£œããçµæç©æº¶æ¶²ãã¬ã©
ã¹æ¿äžã«å転å¡åžåŸã150âã§ïŒæé硬åãããŠã
èå0.40ÎŒïœã®å¡èãåŸããå¡èã®è¡šé¢ã¯éåžžã«
å¹³æ»ã§ãã€ãããã®å¡èã®è©Šéšçµæã¯è¡šïŒã«ç€ºã
ãéãã§ãã€ãã å®æœäŸ 13 å®æœäŸïŒã®ããªã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ã«ãã
ãŠãããªã¢ã¯ãªã«é žã°ãªã·ãžã«ïŒããªã¹ãã¬ã³æ
ç®ééå¹³åååé100000ïŒïŒïœãçšããä»ã¯å®æœ
äŸïŒãšåæ§ã«ããŠçµæç©æº¶æ¶²ã調補ããã次ãã§
å®æœäŸïŒãšåæ§ã«ããŠã¬ã©ã¹æ¿äžã«å転å¡åžãã
硬åããŠåã0.51ÎŒïœã®å¡èãåŸããå¡èã®è¡šé¢
ã¯éåžžã«å¹³æ»ã§ãã€ããåŸãããå¡èã®è©Šéšçµæ
ã¯è¡šïŒã«ç€ºãéãã§ãã€ãã å®æœäŸ 14 å®æœäŸïŒã®ããªã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ã«ãã
ãŠãã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ãšã¡ã¿ã¯ãªã«é žã¡ã
ã«ã®å ±éåäœïŒããªã¹ãã¬ã³æç®ééå¹³åååé
84000ïŒNMRã¹ãã¯ãã«ããæ±ããã¡ã¿ã¯ãªã«
é žã°ãªã·ãžã«ã«ç±æ¥ããåéäœãŠãããå«é72é
éïŒ ïŒ5.8ïœãçšããä»ã¯å®æœäŸïŒãšåæ§ã«ããŠ
çµæç©æº¶æ¶²ãåŸãã次ãã§å®æœäŸïŒãšåæ§ã«ããŠ
ã¬ã©ã¹æ¿äžã«å転å¡åžãã硬åããŠåã0.37ÎŒïœ
ã®å¡èãåŸããå¡èã®è¡šé¢ã¯éåžžã«å¹³æ»ã§ãã€
ããåŸãããå¡èã®è©Šéšçµæã¯è¡šïŒã«ç€ºãéãã§
ãã€ãã å®æœäŸ 15 å®æœäŸïŒã«ãããããªã°ãªã·ãžã«é žã°ãªã·ãžã«
ã«ä»£ããŠãã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ãšã¡ã¿ã¯ãªã«
é žïœâããã«ã®å ±éåäœïŒããªã¹ãã¬ã³æç®éé
å¹³åååé120000ïŒNMRã¹ãã¯ãã«ããæ±ãã
ã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ã«ç±æ¥ããåéäœãŠãã
ãå«é63ééïŒ ïŒïŒïœãçšãããŸãã¢ãã«ããŒã
ããŒEHXâ700ã«ä»£ããŠãããªã¡ãªããé ž0.6ïœ
ãçšããä»ã¯å®æœäŸïŒãšåæ§ã«ããŠçµæç©æº¶æ¶²ã
åŸãã次ãã§å®æœäŸïŒãšåæ§ã«ããŠã¬ã©ã¹æ¿äžã«
å転å¡åžã硬åããŠåã0.35ÎŒïœã®å¡èãåŸãã
åŸãããå¡èã¯éåžžã«å¹³æ»ã§ããããŸããã®å¡è
ã®è©Šéšçµæã¯è¡šïŒã«ç€ºãéãã§ãã€ãã å®æœäŸ 16 å®æœäŸïŒã«ãããããªã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«
ã«ä»£ããŠãã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ãšã¡ã¿ã¯ãªã«
é žã€ãœããã«ã®å ±éåäœïŒããªã¹ãã¬ã³æç®éé
å¹³åååé125000ïŒNMRã¹ãã¯ãã«ããæ±ãã
ã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ã«ç±æ¥ããåéäœãŠãã
ãå«é65ïŒ ïŒ6.2ïœãçšãããŸãå®æœäŸïŒã«ãã
ãã¢ãã«ããŒãããŒEHXâ700ã«ä»£ããŠããã¬ã
ã¿ã«é ž0.63ïœã䜿çšããä»ã¯å®æœäŸïŒãšåæ§ã«ã
ãŠã¬ã©ã¹æ¿äžã«åãã0.38ÎŒïœã®å¡èã圢æãã
ãããã®å¡èã«ã€ããŠã®è©Šéšçµæã¯è¡šïŒã«ç€ºãé
ãã§ãã€ãã å®æœäŸ 17 å®æœäŸïŒã«ãããããªã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«
ã«ä»£ããŠãã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ãšã¡ã¿ã¯ãªã«
é žç¬¬ïŒããã«ã®å ±éåäœïŒããªã¹ãã¬ã³æç®éé
å¹³åååé150000ïŒNMRã¹ãã¯ãã«ããæ±ãã
ã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ã«ç±æ¥ããåéäœãŠãã
ãå«é62.5ééïŒ ïŒ6.2ïœãçšãããŸãå®æœäŸïŒ
ã«ãããã¢ãã«ããŒãããŒEHXâ700ã«ä»£ããŠã
ããªã¡ãªããé ž0.6ïœãçšããä»ã¯å®æœäŸïŒãšå
æ§ã«ããŠåãã0.32ÎŒïœã®å¡èã圢æããããã®
å¡èã«ã€ããŠã®è©Šéšçµæã¯è¡šïŒã«ç€ºãéãã§ãã€
ãã å®æœäŸ 18 å®æœäŸïŒã«ãããããªã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«
ã«ä»£ããŠãã¢ã¯ãªã«é žã°ãªã·ãžã«ãšã¢ã¯ãªã«é žç¬¬
ïŒããã«ã®å ±éåäœïŒããªã¹ãã¬ã³æç®ééå¹³å
ååé1450000ïŒNMRããæ±ããã¢ã¯ãªã«é žã°
ãªã·ãžã«ã«ç±æ¥ããåéäœãŠããã60ééïŒ ïŒ
6.0ïœãçšããä»ã¯å®æœäŸïŒãšåæ§ã«ããŠåãã
0.35ÎŒïœã®å¡èã圢æããããã®å¡èã«ã€ããŠã®
è©Šéšçµæã¯è¡šïŒã«ç€ºãéãã§ãã€ãã æ¯èŒäŸ ïŒ å®æœäŸïŒã«ãããŠãγâãããã«ããªã¡ããã·
ã·ã©ã³ã䜿çšããã«èª¿è£œããçµæç©ã®æº¶æ¶²ã䜿çš
ããå®æœäŸïŒãšåæ§ã«ããŠã¬ã©ã¹æ¿äžã«ç¡¬ååŸã®
èå0.38ÎŒïœã®å¡èã圢æããããåŸãããå¡è
ã®è©Šéšçµæã¯è¡šïŒã«ç€ºããéãã§ãã€ãã æ¯èŒäŸ ïŒ å®æœäŸïŒã«ãããŠãããªã¡ã¿ã¯ãªã«é žã°ãªã·ãž
ã«ã«ãããŠãããªã¡ã¿ã¯ãªã«é žã¡ãã«5.5ïœã䜿
çšããŠãå®æœäŸïŒãšåæ§ã«ããŠçµæç©æº¶æ¶²ã調補
ããå®æœäŸïŒãšåæ§ã«ããŠã¬ã©ã¹æ¿äžã«ç¡¬ååŸã®
èå0.55ÎŒïœã®å¡èãåŸããåŸãããå¡èã®è©Šéš
çµæã¯è¡šïŒã«ç€ºããéãã§ãã€ãã æ¯èŒäŸ ïŒ å®æœäŸïŒã®ããªã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ã«ãã
ãŠãã¡ã¿ã¯ãªã«é žã°ãªã·ãžã«ãšã¡ã¿ã¯ãªã«é žã¡ã
ã«ã®å ±éåäœïŒããªã¹ãã¬ã³æç®ééå¹³åååé
83000NMRã¹ãã¯ãã«ããæ±ããã¡ã¿ã¯ãªã«é ž
ã°ãªã·ãžã«ã«ç±æ¥ããåéäœãŠãããå«é45ïŒ ïŒ
ïŒïœãçšããä»ã¯å®æœäŸïŒãšåæ§ã«ããŠçµæç©æº¶
液ãåŸãã次ãã§å®æœäŸïŒãšåæ§ã«ããŠã¬ã©ã¹æ¿
äžã«å転å¡åžãã硬åããŠåã0.31ÎŒïœã®å¡èã
åŸããåŸãããå¡èã®è©Šéšçµæã¯è¡šïŒã«ç€ºãéã
ã§ãã€ãã
ãè¡šã
ãè¡šã
å®æœäŸ 19
å®æœäŸïŒã§äœ¿çšããããªã¡ã¿ã¯ãªã«é
žã°ãªã·ãž
ã«11ïœãã¬ã©ã¹å®¹åšäžã§ãšãã«ã»ããœã«ãã¢ã»ã
ãŒã89ïœã«æº¶è§£ãããŠåŸããã溶液ã«ãã¢ãã«ã
ãŒãããŒEHXâ700 2.8ïœãγâã°ãªã·ããã·ã
ããã«ããªã¡ããã·ã·ã©ã³0.6ïœããã³ããªã¡ãª
ããé ž0.6ïœãå ããŠåäžãªæº¶æ¶²ãšãªããŸã§æ··å
ãããåŸãããçµæç©æº¶æ¶²ãå®æœäŸïŒãšåæ§ã«ã
ãŠã¬ã©ã¹æ¿äžã«å転å¡åžãã150âã§ïŒæé硬å
ããŠã硬ååŸã®èå0.44ÎŒïœã®å¡èã圢æããã
åŸãããå¡èã¯ç¡è²éæã§ããã350ã800nmã®
å šé åã«ãããŠ95ïŒ ä»¥äžã®å ç·ééçãæããã
ã®è¡šé¢ã¯éåžžã«å¹³æ»ã§ãã€ãããŸã硬ååŸã®å¡è
ããã³æ²žéš°æ°Žäžã§ïŒæéæŸçœ®ããåŸã®å¡èã®ãŽã
ã³ç®è©Šéšãè¡ãªã€ãçµæãå¥é¢ã¯å šãèŠãããªã
ã€ããããã«å¡èã圢æããã¬ã©ã¹æ¿ãã®ã€ãªãŒ
ãã³äž200âã§200æéç±åŠçããåŸãå¡èã«ã¯ã©
ãã¯ãèèãçã®ç°åžžã¯èªãããããåžåã¹ãã¯
ãã«ã«ãå€åã¯èªããããªãã€ãããŸããäžèšãš
åæ§ã«ããŠäœæããå¡èã€ãã®ã¬ã©ã¹æ¿ãå®æœäŸ
ïŒãšåæ§ã®æè²æµŽãçšãåæ§ã«æäœããããã¯ã©
ãã¯ãèèãçã®ç°åžžã¯èªããããããŸãå¡èã¯
ç¡è²éæã®ãŸãŸã§å šãæè²ãããŠããªãã€ãã äžæ¹ãã¬ã©ã¹æ¿äžã«åžè²©ã®ãŒã©ãã³ãæ°Žã«æº¶ã
ãã溶液ïŒåºåœ¢åå«é20ïŒ ïŒãå転å¡åžããŠèå
1.52ÎŒïœã®ãŒã©ãã³èã圢æããã®ã¡ãäžèšã®çµ
æç©æº¶æ¶²ãäžèšãšåäžæ¡ä»¶ã§å転å¡åžãã次ãã§
150âã§ïŒæé硬åãããŠå¡èã圢æããããã®
ããã«ããŠåŸãããå¡èã¯ãŒã©ãã³å±€ãšåŒ·åºã«å¯
çããŠãããå¥é¢ã¯å šãèªããããªãã€ãã å®æœäŸ 20 å®æœäŸïŒïŒïŒããã³11ã13ã§åœ¢æããå¡èã®è¡š
é¢ç¡¬åããããŽã€ç¡¬åºŠæ³ïŒJISKâ5400ïŒã«ãã
è©äŸ¡ãããçµæã¯è¡šïŒã«ç€ºãéãã§ãã€ãã
ã«11ïœãã¬ã©ã¹å®¹åšäžã§ãšãã«ã»ããœã«ãã¢ã»ã
ãŒã89ïœã«æº¶è§£ãããŠåŸããã溶液ã«ãã¢ãã«ã
ãŒãããŒEHXâ700 2.8ïœãγâã°ãªã·ããã·ã
ããã«ããªã¡ããã·ã·ã©ã³0.6ïœããã³ããªã¡ãª
ããé ž0.6ïœãå ããŠåäžãªæº¶æ¶²ãšãªããŸã§æ··å
ãããåŸãããçµæç©æº¶æ¶²ãå®æœäŸïŒãšåæ§ã«ã
ãŠã¬ã©ã¹æ¿äžã«å転å¡åžãã150âã§ïŒæé硬å
ããŠã硬ååŸã®èå0.44ÎŒïœã®å¡èã圢æããã
åŸãããå¡èã¯ç¡è²éæã§ããã350ã800nmã®
å šé åã«ãããŠ95ïŒ ä»¥äžã®å ç·ééçãæããã
ã®è¡šé¢ã¯éåžžã«å¹³æ»ã§ãã€ãããŸã硬ååŸã®å¡è
ããã³æ²žéš°æ°Žäžã§ïŒæéæŸçœ®ããåŸã®å¡èã®ãŽã
ã³ç®è©Šéšãè¡ãªã€ãçµæãå¥é¢ã¯å šãèŠãããªã
ã€ããããã«å¡èã圢æããã¬ã©ã¹æ¿ãã®ã€ãªãŒ
ãã³äž200âã§200æéç±åŠçããåŸãå¡èã«ã¯ã©
ãã¯ãèèãçã®ç°åžžã¯èªãããããåžåã¹ãã¯
ãã«ã«ãå€åã¯èªããããªãã€ãããŸããäžèšãš
åæ§ã«ããŠäœæããå¡èã€ãã®ã¬ã©ã¹æ¿ãå®æœäŸ
ïŒãšåæ§ã®æè²æµŽãçšãåæ§ã«æäœããããã¯ã©
ãã¯ãèèãçã®ç°åžžã¯èªããããããŸãå¡èã¯
ç¡è²éæã®ãŸãŸã§å šãæè²ãããŠããªãã€ãã äžæ¹ãã¬ã©ã¹æ¿äžã«åžè²©ã®ãŒã©ãã³ãæ°Žã«æº¶ã
ãã溶液ïŒåºåœ¢åå«é20ïŒ ïŒãå転å¡åžããŠèå
1.52ÎŒïœã®ãŒã©ãã³èã圢æããã®ã¡ãäžèšã®çµ
æç©æº¶æ¶²ãäžèšãšåäžæ¡ä»¶ã§å転å¡åžãã次ãã§
150âã§ïŒæé硬åãããŠå¡èã圢æããããã®
ããã«ããŠåŸãããå¡èã¯ãŒã©ãã³å±€ãšåŒ·åºã«å¯
çããŠãããå¥é¢ã¯å šãèªããããªãã€ãã å®æœäŸ 20 å®æœäŸïŒïŒïŒããã³11ã13ã§åœ¢æããå¡èã®è¡š
é¢ç¡¬åããããŽã€ç¡¬åºŠæ³ïŒJISKâ5400ïŒã«ãã
è©äŸ¡ãããçµæã¯è¡šïŒã«ç€ºãéãã§ãã€ãã
Claims (1)
- ãç¹èš±è«æ±ã®ç¯å²ã ïŒ (A) äžè¬åŒïŒïŒ åŒäžãã¯æ°ŽçŽ ååãŸãã¯äœçŽã¢ã«ãã«åº
ã§ãããïœã¯ïŒãïŒã®æŽæ°ã§ãã ã§è¡šãããååç©ã«ç±æ¥ããåéäœãŠãããã
60ééïŒ ä»¥äžå«æããéåäœãšã (B) åèšéåäœ100éééšåœãïŒã100éééšã®å€
䟡ã«ã«ãã³é žç¡æ°Žç©ããã³å€äŸ¡ã«ã«ãã³é žãã
éžã°ããå°ãªããšãïŒçš®ã®ååç©ãšã (C) åèšéåäœ100éééšåœã0.1ã30éééšã®å®
èœæ§ã·ã©ã³ã«ãããªã³ã°å€ãš ãå«ãã§ãªãç±ç¡¬åæ§çµæç©ã
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7217084A JPS60217230A (ja) | 1984-04-11 | 1984-04-11 | ç±ç¡¬åæ§çµæç© |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP7217084A JPS60217230A (ja) | 1984-04-11 | 1984-04-11 | ç±ç¡¬åæ§çµæç© |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP60063015A Division JPS60216307A (ja) | 1985-03-27 | 1985-03-27 | ã«ã©ãŒãã€ã«ã¿ãŒã®è£œæ³ |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS60217230A JPS60217230A (ja) | 1985-10-30 |
JPH038652B2 true JPH038652B2 (ja) | 1991-02-06 |
Family
ID=13481487
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP7217084A Granted JPS60217230A (ja) | 1984-04-11 | 1984-04-11 | ç±ç¡¬åæ§çµæç© |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS60217230A (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5524480B2 (ja) * | 2006-05-18 | 2014-06-18 | æ¥æ¬åè¬æ ªåŒäŒç€Ÿ | ç±ç¡¬åæ§æš¹èçµæç©åã³ãã®ç¡¬åç© |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5066698A (en) * | 1990-05-10 | 1991-11-19 | E. I. Du Pont De Nemours And Company | Coating composition of an acrylic polymer, a crosslinking agent and a silane oligomer |
JP2893875B2 (ja) * | 1990-06-20 | 1999-05-24 | ãžã§ã€ãšã¹ã¢ãŒã«æ ªåŒäŒç€Ÿ | ä¿è·è圢æçšææ |
JPH04132729A (ja) * | 1990-09-25 | 1992-05-07 | Sanyo Chem Ind Ltd | å¹³åŠåæããã³ãã®ç¡¬åæ³ |
JP3360546B2 (ja) * | 1996-10-22 | 2002-12-24 | 倧æ¥æ¬ã€ã³ãååŠå·¥æ¥æ ªåŒäŒç€Ÿ | ç±ç¡¬åæ§æš¹èçµæç© |
JPH10186652A (ja) * | 1996-12-20 | 1998-07-14 | Hitachi Chem Co Ltd | 硬åå¡èçšæš¹èçµæç©ããããçšããã«ã©ãŒãã£ã«ã¿ä¿è·èãã«ã©ãŒãã£ã«ã¿ããã³æ¶²æ¶è¡šç€ºçŽ å |
US7423083B2 (en) * | 2001-09-14 | 2008-09-09 | Sumitomo Chemical Company Limited | Photosemiconductor encapsulant of epoxy group-containing (meth) acrylic polymer and alicyclic anhydride |
JP4915500B2 (ja) * | 2006-01-11 | 2012-04-11 | ïœïœæ ªåŒäŒç€Ÿ | ç±ç¡¬åæ§æš¹èçµæç©ãã«ã©ãŒãã£ã«ã¿ã®ä¿è·èã®åœ¢ææ¹æ³ãããã³ã«ã©ãŒãã£ã«ã¿ã®ä¿è·è |
-
1984
- 1984-04-11 JP JP7217084A patent/JPS60217230A/ja active Granted
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5524480B2 (ja) * | 2006-05-18 | 2014-06-18 | æ¥æ¬åè¬æ ªåŒäŒç€Ÿ | ç±ç¡¬åæ§æš¹èçµæç©åã³ãã®ç¡¬åç© |
Also Published As
Publication number | Publication date |
---|---|
JPS60217230A (ja) | 1985-10-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6008152B2 (ja) | æš¹èçµæç©ã液æ¶é åæããã³äœçžå·®æ | |
WO1996034303A1 (fr) | Materiau permettant de realiser un film protecteur filtrant les couleurs et film protecteur filtrant ainsi les couleurs | |
JPH038652B2 (ja) | ||
JP3360546B2 (ja) | ç±ç¡¬åæ§æš¹èçµæç© | |
JPS60216307A (ja) | ã«ã©ãŒãã€ã«ã¿ãŒã®è£œæ³ | |
JPS61252225A (ja) | ç±ç¡¬åæ§éåäœçµæç© | |
JPH04272977A (ja) | 被èŠç¡¬åçšæš¹èçµæç©ããã³ãããçšããã«ã©ãŒãã£ã«ã¿ä¿è·èçšæš¹èçµæç© | |
JP3901242B2 (ja) | æš¹èçµæç©ãã«ã©ãŒãã€ã«ã¿ãŒä¿è·èçšæš¹èçµæç©åã³ãã®ç¡¬åç© | |
EP1138731B1 (en) | Coating composition | |
JPH04272978A (ja) | ã³ãŒãã£ã³ã°çšæš¹èçµæç©ããã³ãããçšããã«ã©ãŒãã£ã«ã¿ä¿è·èçšæš¹èçµæç© | |
JP3008512B2 (ja) | ã³ãŒãã£ã³ã°çšæš¹èçµæç©ããã³ãããçšããã«ã©ãŒãã£ã«ã¿ä¿è·èçšæš¹èçµæç© | |
JPH0554515B2 (ja) | ||
JPH061944A (ja) | ã³ãŒãã£ã³ã°çšæš¹èçµæç©ããã³ãããçšããã«ã©ãŒãã£ã«ã¿ä¿è·èçšæš¹èçµæç© | |
JPH10186652A (ja) | 硬åå¡èçšæš¹èçµæç©ããããçšããã«ã©ãŒãã£ã«ã¿ä¿è·èãã«ã©ãŒãã£ã«ã¿ããã³æ¶²æ¶è¡šç€ºçŽ å | |
JPH05173012A (ja) | ã«ã©ãŒãã£ã«ã¿ä¿è·èçšæš¹èçµæç© | |
JPH0593047A (ja) | ç±ç¡¬åæ§éåäœçµæç© | |
JPH04315103A (ja) | ã³ãŒãã£ã³ã°çšæš¹èçµæç©åã³ã«ã©ãŒãã£ã«ã¿ä¿è·èçšæš¹èçµæç© | |
JPH03188153A (ja) | ç±ç¡¬åæ§çµæç© | |
US20020182417A1 (en) | Coating composition | |
JPH0827348A (ja) | ç±ç¡¬åæ§æš¹èçµæç©ããã³ãããçšããã«ã©ãŒãã£ã«ã¿ä¿è·èçšæš¹èçµæç© | |
JPH10212448A (ja) | 硬åå¡èçšæš¹èçµæç©ããããçšããã«ã©ãŒãã£ã«ã¿ä¿è·èãã«ã©ãŒãã£ã«ã¿ããã³æ¶²æ¶è¡šç€ºçŽ å | |
JPH04315101A (ja) | ã³ãŒãã£ã³ã°çšæš¹èçµæç©åã³ã«ã©ãŒãã£ã«ã¿ä¿è·èçšæš¹èçµæç© | |
JPH04315102A (ja) | ã³ãŒãã£ã³ã°çšæš¹èçµæç©åã³ã«ã©ãŒãã£ã«ã¿ä¿è·èçšæš¹èçµæç© | |
JPH1135660A (ja) | äœæž©ç¡¬åå¯èœãªéææš¹èçµæç©ããããçšããã«ã©ãŒãã£ã«ã¿ä¿è·èãã«ã©ãŒãã£ã«ã¿åã³æ¶²æ¶è¡šç€ºè£ 眮 | |
JPH06145595A (ja) | 硬åæ§è¢«èŠçšæš¹èçµæç©ããã³ãããçšããã«ã©ãŒãã£ã«ã¿ä¿è·èçšæš¹èçµæç© |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
EXPY | Cancellation because of completion of term |