JPH03284616A - 消臭剤 - Google Patents
消臭剤Info
- Publication number
- JPH03284616A JPH03284616A JP2086899A JP8689990A JPH03284616A JP H03284616 A JPH03284616 A JP H03284616A JP 2086899 A JP2086899 A JP 2086899A JP 8689990 A JP8689990 A JP 8689990A JP H03284616 A JPH03284616 A JP H03284616A
- Authority
- JP
- Japan
- Prior art keywords
- deodorant
- hacd
- present
- hydroxypropylated
- cyclodextrin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002781 deodorant agent Substances 0.000 title claims abstract description 14
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 20
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical class O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 claims abstract description 10
- WHGYBXFWUBPSRW-FOUAGVGXSA-N beta-cyclodextrin Chemical class OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO WHGYBXFWUBPSRW-FOUAGVGXSA-N 0.000 abstract description 14
- 101710159621 Very-long-chain (3R)-3-hydroxyacyl-CoA dehydratase Proteins 0.000 abstract description 10
- 238000006467 substitution reaction Methods 0.000 abstract description 5
- 229920000858 Cyclodextrin Polymers 0.000 description 8
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 8
- 235000019645 odor Nutrition 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 239000006210 lotion Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000003205 fragrance Substances 0.000 description 5
- 239000008213 purified water Substances 0.000 description 5
- 230000001877 deodorizing effect Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 4
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 4
- 229960002216 methylparaben Drugs 0.000 description 4
- 208000035985 Body Odor Diseases 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 206010040904 Skin odour abnormal Diseases 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- HFHDHCJBZVLPGP-RWMJIURBSA-N alpha-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO HFHDHCJBZVLPGP-RWMJIURBSA-N 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 3
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 3
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- 239000001116 FEMA 4028 Substances 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 235000011175 beta-cyclodextrine Nutrition 0.000 description 2
- 229960004853 betadex Drugs 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- -1 cyclic oligosaccharide Chemical class 0.000 description 2
- 238000000354 decomposition reaction Methods 0.000 description 2
- 239000000645 desinfectant Substances 0.000 description 2
- OSVXSBDYLRYLIG-UHFFFAOYSA-N dioxidochlorine(.) Chemical compound O=Cl=O OSVXSBDYLRYLIG-UHFFFAOYSA-N 0.000 description 2
- 239000002552 dosage form Substances 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- BBEAQIROQSPTKN-UHFFFAOYSA-N pyrene Chemical compound C1=CC=C2C=CC3=CC=CC4=CC=C1C2=C43 BBEAQIROQSPTKN-UHFFFAOYSA-N 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 206010006326 Breath odour Diseases 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- 239000004155 Chlorine dioxide Substances 0.000 description 1
- 244000223760 Cinnamomum zeylanicum Species 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 244000246386 Mentha pulegium Species 0.000 description 1
- 235000016257 Mentha pulegium Nutrition 0.000 description 1
- 235000004357 Mentha x piperita Nutrition 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 206010040880 Skin irritation Diseases 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 229910021536 Zeolite Inorganic materials 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 229940112822 chewing gum Drugs 0.000 description 1
- 235000015218 chewing gum Nutrition 0.000 description 1
- 235000019398 chlorine dioxide Nutrition 0.000 description 1
- 235000017803 cinnamon Nutrition 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 229940097362 cyclodextrins Drugs 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- 238000000502 dialysis Methods 0.000 description 1
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
- GVEPBJHOBDJJJI-UHFFFAOYSA-N fluoranthrene Natural products C1=CC(C2=CC=CC=C22)=C3C2=CC=CC3=C1 GVEPBJHOBDJJJI-UHFFFAOYSA-N 0.000 description 1
- GDSRMADSINPKSL-HSEONFRVSA-N gamma-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO GDSRMADSINPKSL-HSEONFRVSA-N 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- ACGUYXCXAPNIKK-UHFFFAOYSA-N hexachlorophene Chemical compound OC1=C(Cl)C=C(Cl)C(Cl)=C1CC1=C(O)C(Cl)=CC(Cl)=C1Cl ACGUYXCXAPNIKK-UHFFFAOYSA-N 0.000 description 1
- 229960004068 hexachlorophene Drugs 0.000 description 1
- 235000001050 hortel pimenta Nutrition 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000007794 irritation Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000000873 masking effect Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229940041616 menthol Drugs 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 210000000214 mouth Anatomy 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 229920001542 oligosaccharide Polymers 0.000 description 1
- 239000007968 orange flavor Substances 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000012286 potassium permanganate Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000036556 skin irritation Effects 0.000 description 1
- 231100000475 skin irritation Toxicity 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 229940034610 toothpaste Drugs 0.000 description 1
- 239000000606 toothpaste Substances 0.000 description 1
- ICUTUKXCWQYESQ-UHFFFAOYSA-N triclocarban Chemical compound C1=CC(Cl)=CC=C1NC(=O)NC1=CC=C(Cl)C(Cl)=C1 ICUTUKXCWQYESQ-UHFFFAOYSA-N 0.000 description 1
- 229960001325 triclocarban Drugs 0.000 description 1
- XPFJYKARVSSRHE-UHFFFAOYSA-K trisodium;2-hydroxypropane-1,2,3-tricarboxylate;2-hydroxypropane-1,2,3-tricarboxylic acid Chemical compound [Na+].[Na+].[Na+].OC(=O)CC(O)(C(O)=O)CC(O)=O.[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O XPFJYKARVSSRHE-UHFFFAOYSA-K 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
め要約のデータは記録されません。
Description
下、HACDと略す)と水とアルコールを含有してなる
、安全性が高く、腋臭、足臭および口臭等の体臭抑制能
を有する消臭剤に関する。
理的作用によるもの、あるいは臭い物質に微生物が関与
している場合は殺菌剤を用いたり又強い臭いで悪臭をマ
スキングしたりする方法が知られている。例えば過マン
ガン酸カリや二酸化塩素を用いて硫化水素、フェノール
、アンモニア、メルカプタン等と反応きせ無臭化合物に
変えたり、活性炭、ゼオライト、シクロデキストリン等
の吸着能、包接能に優れた物質を共存させ悪臭物質を除
去する方法や、ヘキサクロロフェン、トリクロロカルバ
ニリド等の殺菌剤を配合し微生物による分解を阻止する
方法、更にはペパーミント、シナモン、オレンジフレー
バー等の強い香りで悪臭をマスキングする方法か一般的
に知られている。これらの消臭技術は悪臭物質およびそ
の発生源、適用場所、安全性、効果の持続性等の諸要因
により単独もしくは組合せて利用されることが多い。
磨、うがい液、チューインガムなどのなかに臭気成分吸
収物質としてシクロデキストリンを含有きせることが、
特開昭63−280013号公報および特開昭63−2
80014号公報には、マルトース結合シクロデキスト
リンを体臭および口腔防止用貼付側組成物に用いること
が開示されている。
β−シクロデキストリンの水に対する溶解性が悪いので
配合量が制限され、一方、マルトース結合シクロデキス
トリンは製造が難しく均一の品質を得られないので、そ
れを配合した消臭剤も効果にばらつきがあるという問題
点がある。また、貼付剤の場合、人によって貼付部分に
皮膚のかぶれを生じるという問題がよくある。
臭剤を開発することを目的として研究を行なった結果、
シクロデキストリン誘導体のうち、ヒドロキシアルキル
化シクロデキストリンが悪臭物質の包接能に優れており
、しかも水に対する溶解性が非常に高く、人体に対する
安全性にも優れていることを見出し、本発明を完成した
。
トリンと水と低級アルコールを含有することを特(敵と
する消臭剤に関するものである。
としてよく知られているシクロデキストリンの水酸基に
ヒドロキシアルキル基を導入したものである。
ヒドロキシエチル、ヒドロキシプロピル、などの置換基
が使用され、これら置換反応の結果、ヒドロキシメチル
シクロデキストリン、ヒドロキシエチルシクロデキスト
リン、ヒドロキシプロピルシクロデキストリン、ヒドロ
キシブチルシクロデキストリン、ジヒドロキシプロピル
シクロデキストリンなどのHACDを得ることができる
。
置換度が高い程低級アルコールへの溶解度が向上する。
ースの数の違いによってα、β、7の構造をもつCD(
以下、α−CD、β−CD、 7−CDと略する。)が
知られているが、本発明はこれらのCDの一種または2
種以上をヒドロキシアルキル化して使用する。普通はβ
−CDを用いるか、α、γ−CDを母核としてもかまわ
ない。α、β、γのCDを同時に含有する澱粉分解物も
使用できる。
水溶解性を考慮した場合、ヒドロキシエチル化β−CD
またはヒドロキシプロピル化β−CDが好ましいが、こ
れに限定きれるものではない。 また、ヒドロキシエチ
ル化CDまたはヒドロキシプロピル化CDは製造状態に
おいてはα、β、7が混じりあった混合物となっている
が、混合物のままでもα、β、7のヒドロキシプロピル
化CDを単離したものでも使用することができる。
が知られているが、以下に一例を示す。
100gを20%NaOH水溶液150m lに溶解し
、30°Cに保持しつつ酸化プロピレン50m1を徐々
に滴下し、20時間撹拌し反応を続ける。反応終了後、
塩酸でpH6,0に中和し、透析膜チューブ中に入れ、
流水下24時間脱塩を行なった。その後凍結乾燥機で乾
燥を行なって、ヒドロキシプロピル化β−CD約90g
か得られた。このヒドロキシプロピル化β−CDのCD
当たりの置換度は5゜1であった。
以下、%と略す)〜10%か好ましい。
ると使用感触が劣る。
ソプロピルアルコール等である。低級アルコールの配合
量が多過ぎると人体に塗布した際に刺激を感する場合が
あり、本発明の消臭剤全量中5%〜30%の配合量か好
ましい。
アゾール等どのような剤型でも構わない。
他に、本発明の効果を損なわない範囲で香料、防腐剤、
pH調整剤、保湿剤等を添加することかできる。
全性にも優れている。
本発明はこれら実施例に限定されるものではない。なお
、配合量は重量%である。
。
消臭効果の試験をした。
右のわき部分に塗布してもらい3時間後にわき部分の臭
いを専門パネルにより5点法で判定した。
、男5名または女5名の判定結果の平均値であり数値が
高い程臭いの強いことを示す。
残余エタノール
4イソプロピルアルコール
1グリセリン 2香料
0.01メチルパラベ
ン 0.1各成分を混合溶解して
ボディーローションを得た。
キシプロピル化α−CD I精製水
残余エタノール
30メチルパラベン
0.1へキサメタリン酸ナトリウム
0.011−メントール 0
.2各成分を混合溶解して口腔用消臭剤を得た。
残余エタノール
10ジブaピレングリコー
ル 2香料
0.02メチルパラベン
0. 1へキサメタリン酸ナトリウム 0
.02り1ン酸 0.0
4クエン酸ナトリウム 0.06各成
分を混合溶解してローションを得た。
シブロビル化β−CD 5精製水
残余エタノール
201.3ブチレングリコール 3香料
0.05メチルパラ
ベン 0.1へキサメタリン酸ナ
トリウム 0.01クエン酸 クエン酸ナトリウム 0、 ○3 0、07 実施例6 シャワーコロン ヒドロキシプロピル化β−CD 5精製水
85エタノール
51.3ブチレングリコール
2香料 3各成分を
混合溶解してシャワーコロンを得た。
Claims (1)
- (1)ヒドロキシアルキル化シクロデキストリンと水と
低級アルコールを含有することを特徴とする消臭剤。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2086899A JP2857629B2 (ja) | 1990-03-30 | 1990-03-30 | 消臭剤 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2086899A JP2857629B2 (ja) | 1990-03-30 | 1990-03-30 | 消臭剤 |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH03284616A true JPH03284616A (ja) | 1991-12-16 |
JP2857629B2 JP2857629B2 (ja) | 1999-02-17 |
Family
ID=13899684
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2086899A Expired - Lifetime JP2857629B2 (ja) | 1990-03-30 | 1990-03-30 | 消臭剤 |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2857629B2 (ja) |
Cited By (45)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996004937A1 (en) * | 1994-08-12 | 1996-02-22 | The Procter & Gamble Company | Uncomplexed cyclodextrin solutions for odor control on inanimate surfaces |
US5534165A (en) * | 1994-08-12 | 1996-07-09 | The Procter & Gamble Company | Fabric treating composition containing beta-cyclodextrin and essentially free of perfume |
US5578563A (en) * | 1994-08-12 | 1996-11-26 | The Procter & Gamble Company | Composition for reducing malodor impression on inanimate surfaces |
US5593670A (en) * | 1994-08-12 | 1997-01-14 | The Proctor & Gamble Company | Uncomplexed cyclodextrin solutions for odor control on inanimate surfaces |
US5663134A (en) * | 1994-08-12 | 1997-09-02 | The Procter & Gamble Company | Composition for reducing malodor impression on inanimate surfaces |
US5668097A (en) * | 1994-08-12 | 1997-09-16 | The Procter & Gamble Company | Uncomplexed cyclodextrin solutions for odor control on inanimate surfaces |
US5714137A (en) * | 1994-08-12 | 1998-02-03 | The Procter & Gamble Company | Uncomplexed cyclodextrin solutions for odor control on inanimate surfaces |
US5780020A (en) * | 1996-10-28 | 1998-07-14 | The Proctor & Gamble Company | Methods and compositions for reducing body odor |
US5858335A (en) * | 1997-06-09 | 1999-01-12 | The Procter & Gamble Company | Method of reducing body odor using perfume-free two phase compositions |
US5861145A (en) * | 1997-06-09 | 1999-01-19 | The Procter & Gamble Company | Method of reducing body odor using perfumed, odor absorbing, two phase compositions |
US5861144A (en) * | 1997-06-09 | 1999-01-19 | The Procter & Gamble Company | Perfumed compositions for reducing body odors and excess moisture |
US5861147A (en) * | 1997-06-09 | 1999-01-19 | The Procter & Gamble Company | Methods for controlling environmental odors on the body using compositions comprising uncomplexed cyclodextrins and perfume |
US5861146A (en) * | 1997-06-09 | 1999-01-19 | The Procter & Gamble Company | Method for reducing body odor |
US5871719A (en) * | 1997-06-09 | 1999-02-16 | The Procter & Gamble Company | Perfume-free two phase compositions for reducing body odor |
US5871718A (en) * | 1997-06-09 | 1999-02-16 | The Procter & Gamble Company | Perfumed two phase compositions for reducing body odor |
US5874070A (en) * | 1997-06-09 | 1999-02-23 | The Procter & Gamble Company | Compositions for reducing body odor |
US5874067A (en) * | 1996-10-24 | 1999-02-23 | The Procter & Gamble Company | Methods for controlling environmental odors on the body |
US5879666A (en) * | 1996-10-24 | 1999-03-09 | The Procter & Gamble Company | Methods and compositions for reducing body odor |
US5882638A (en) * | 1996-10-24 | 1999-03-16 | The Proctor & Gamble Company | Methods using uncomplexed cyclodextrin solutions for controlling environmental odors |
US5885599A (en) * | 1996-10-28 | 1999-03-23 | The Procter & Gamble Company | Methods and compositions for reducing body odors and excess moisture |
US5897856A (en) * | 1996-10-24 | 1999-04-27 | The Procter & Gamble Company | Methods and compositions for reducing body odor |
US5897855A (en) * | 1996-10-24 | 1999-04-27 | The Procter & Gamble Company | Methods and compositions for reducing body odor |
US5897854A (en) * | 1997-06-09 | 1999-04-27 | The Procter & Gamble Company | Methods for reducing body odor |
US5911976A (en) * | 1996-10-24 | 1999-06-15 | The Procter & Gamble Company | Compositions for reducing body odor |
US5928631A (en) * | 1997-06-09 | 1999-07-27 | The Procter & Gamble Company | Methods for controlling environmental odors on the body using compositions comprising uncomplexed cyclodextrins |
US5942214A (en) * | 1997-06-09 | 1999-08-24 | The Procter & Gamble Company | Methods for controlling environmental odors on the body using compositions comprising uncomplexed cyclodextrins and perfume |
US5955093A (en) * | 1997-06-09 | 1999-09-21 | The Procter & Gamble Company | Uncomplexed cyclodextrin compositions for odor control |
US5968404A (en) * | 1997-06-09 | 1999-10-19 | The Procter & Gamble Company | Uncomplexed cyclodextrin compositions for odor and wrinkle control |
EP0822821A4 (en) * | 1995-04-17 | 1999-10-27 | Robert A Sanchez | COMPLEXING URUSHIOLES |
US6001343A (en) * | 1997-06-09 | 1999-12-14 | The Procter & Gamble Company | Uncomplexed cyclodextrin compositions for odor and wrinkle control |
WO2000030599A1 (en) * | 1998-11-23 | 2000-06-02 | The Procter & Gamble Company | Skin deodorizing and sanitizing compositions |
WO2000030601A1 (en) * | 1998-11-23 | 2000-06-02 | The Procter & Gamble Company | Skin deodorizing and sanitizing compositions |
US6077318A (en) * | 1994-08-12 | 2000-06-20 | The Procter & Gamble Company | Method of using a composition for reducing malodor impression |
US6110449A (en) * | 1999-06-14 | 2000-08-29 | The Procter & Gamble Company | Anhydrous antiperspirant cream compositions improved perfume longevity |
US6123932A (en) * | 1999-06-14 | 2000-09-26 | The Procter & Gamble Company | Deodorant compositions containing cyclodextrin odor controlling agents |
US6146621A (en) * | 1994-08-12 | 2000-11-14 | The Procter & Gamble Company | Composition for reducing malodor impression on inanimate surfaces |
US6344218B1 (en) | 1998-11-23 | 2002-02-05 | The Procter & Gamble Company | Skin deodorizing and santizing compositions |
US6358469B1 (en) | 1998-12-01 | 2002-03-19 | S. C. Johnson & Son, Inc. | Odor eliminating aqueous formulation |
WO2001087360A3 (en) * | 2000-05-15 | 2002-04-04 | Procter & Gamble | Compositions comprising cyclodextrin derivatives |
US6528013B1 (en) | 1998-04-27 | 2003-03-04 | The Procter & Gamble Company | Uncomplexed cyclodextrin compositions for odor and wrinkle control |
US6592813B1 (en) | 1998-07-02 | 2003-07-15 | University Of Southampton | Malodour counteracting treatment |
US6656923B1 (en) | 1997-06-09 | 2003-12-02 | The Procter & Gamble Company | Uncomplexed cyclodextrin compositions for odor and wrinkle control |
US6682694B2 (en) * | 1994-08-12 | 2004-01-27 | The Procter & Gamble Company | Uncomplexed cyclodextrin solutions for odor control on inanimate surfaces |
US7645746B1 (en) | 2000-11-13 | 2010-01-12 | The Procter & Gamble Company | Composition for reducing malodor impression on inanimate surfaces |
JP2016515867A (ja) * | 2013-03-15 | 2016-06-02 | ザ プロクター アンド ギャンブル カンパニー | パーソナルケア組成物 |
-
1990
- 1990-03-30 JP JP2086899A patent/JP2857629B2/ja not_active Expired - Lifetime
Cited By (49)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1996004937A1 (en) * | 1994-08-12 | 1996-02-22 | The Procter & Gamble Company | Uncomplexed cyclodextrin solutions for odor control on inanimate surfaces |
US5534165A (en) * | 1994-08-12 | 1996-07-09 | The Procter & Gamble Company | Fabric treating composition containing beta-cyclodextrin and essentially free of perfume |
US5578563A (en) * | 1994-08-12 | 1996-11-26 | The Procter & Gamble Company | Composition for reducing malodor impression on inanimate surfaces |
US5593670A (en) * | 1994-08-12 | 1997-01-14 | The Proctor & Gamble Company | Uncomplexed cyclodextrin solutions for odor control on inanimate surfaces |
US5663134A (en) * | 1994-08-12 | 1997-09-02 | The Procter & Gamble Company | Composition for reducing malodor impression on inanimate surfaces |
US5668097A (en) * | 1994-08-12 | 1997-09-16 | The Procter & Gamble Company | Uncomplexed cyclodextrin solutions for odor control on inanimate surfaces |
US5714137A (en) * | 1994-08-12 | 1998-02-03 | The Procter & Gamble Company | Uncomplexed cyclodextrin solutions for odor control on inanimate surfaces |
EP0776220B1 (en) * | 1994-08-12 | 2004-04-21 | The Procter & Gamble Company | Fabric treating composition containing beta-cyclodextrin |
US5783544A (en) * | 1994-08-12 | 1998-07-21 | The Procter & Gamble Company | Composition for reducing malodor impression on inanimate surfaces |
US6682694B2 (en) * | 1994-08-12 | 2004-01-27 | The Procter & Gamble Company | Uncomplexed cyclodextrin solutions for odor control on inanimate surfaces |
US6146621A (en) * | 1994-08-12 | 2000-11-14 | The Procter & Gamble Company | Composition for reducing malodor impression on inanimate surfaces |
US6077318A (en) * | 1994-08-12 | 2000-06-20 | The Procter & Gamble Company | Method of using a composition for reducing malodor impression |
EP0822821A4 (en) * | 1995-04-17 | 1999-10-27 | Robert A Sanchez | COMPLEXING URUSHIOLES |
US5911976A (en) * | 1996-10-24 | 1999-06-15 | The Procter & Gamble Company | Compositions for reducing body odor |
US5897856A (en) * | 1996-10-24 | 1999-04-27 | The Procter & Gamble Company | Methods and compositions for reducing body odor |
US5897855A (en) * | 1996-10-24 | 1999-04-27 | The Procter & Gamble Company | Methods and compositions for reducing body odor |
US5874067A (en) * | 1996-10-24 | 1999-02-23 | The Procter & Gamble Company | Methods for controlling environmental odors on the body |
US5879666A (en) * | 1996-10-24 | 1999-03-09 | The Procter & Gamble Company | Methods and compositions for reducing body odor |
US5882638A (en) * | 1996-10-24 | 1999-03-16 | The Proctor & Gamble Company | Methods using uncomplexed cyclodextrin solutions for controlling environmental odors |
US5780020A (en) * | 1996-10-28 | 1998-07-14 | The Proctor & Gamble Company | Methods and compositions for reducing body odor |
US5885599A (en) * | 1996-10-28 | 1999-03-23 | The Procter & Gamble Company | Methods and compositions for reducing body odors and excess moisture |
US6001343A (en) * | 1997-06-09 | 1999-12-14 | The Procter & Gamble Company | Uncomplexed cyclodextrin compositions for odor and wrinkle control |
US5968404A (en) * | 1997-06-09 | 1999-10-19 | The Procter & Gamble Company | Uncomplexed cyclodextrin compositions for odor and wrinkle control |
US5897854A (en) * | 1997-06-09 | 1999-04-27 | The Procter & Gamble Company | Methods for reducing body odor |
US5861146A (en) * | 1997-06-09 | 1999-01-19 | The Procter & Gamble Company | Method for reducing body odor |
US5928631A (en) * | 1997-06-09 | 1999-07-27 | The Procter & Gamble Company | Methods for controlling environmental odors on the body using compositions comprising uncomplexed cyclodextrins |
US5942214A (en) * | 1997-06-09 | 1999-08-24 | The Procter & Gamble Company | Methods for controlling environmental odors on the body using compositions comprising uncomplexed cyclodextrins and perfume |
US5955093A (en) * | 1997-06-09 | 1999-09-21 | The Procter & Gamble Company | Uncomplexed cyclodextrin compositions for odor control |
US5861145A (en) * | 1997-06-09 | 1999-01-19 | The Procter & Gamble Company | Method of reducing body odor using perfumed, odor absorbing, two phase compositions |
US5861147A (en) * | 1997-06-09 | 1999-01-19 | The Procter & Gamble Company | Methods for controlling environmental odors on the body using compositions comprising uncomplexed cyclodextrins and perfume |
US5871719A (en) * | 1997-06-09 | 1999-02-16 | The Procter & Gamble Company | Perfume-free two phase compositions for reducing body odor |
US5871718A (en) * | 1997-06-09 | 1999-02-16 | The Procter & Gamble Company | Perfumed two phase compositions for reducing body odor |
US5858335A (en) * | 1997-06-09 | 1999-01-12 | The Procter & Gamble Company | Method of reducing body odor using perfume-free two phase compositions |
US5861144A (en) * | 1997-06-09 | 1999-01-19 | The Procter & Gamble Company | Perfumed compositions for reducing body odors and excess moisture |
US6656923B1 (en) | 1997-06-09 | 2003-12-02 | The Procter & Gamble Company | Uncomplexed cyclodextrin compositions for odor and wrinkle control |
US5874070A (en) * | 1997-06-09 | 1999-02-23 | The Procter & Gamble Company | Compositions for reducing body odor |
US6528013B1 (en) | 1998-04-27 | 2003-03-04 | The Procter & Gamble Company | Uncomplexed cyclodextrin compositions for odor and wrinkle control |
US6592813B1 (en) | 1998-07-02 | 2003-07-15 | University Of Southampton | Malodour counteracting treatment |
US6344218B1 (en) | 1998-11-23 | 2002-02-05 | The Procter & Gamble Company | Skin deodorizing and santizing compositions |
WO2000030601A1 (en) * | 1998-11-23 | 2000-06-02 | The Procter & Gamble Company | Skin deodorizing and sanitizing compositions |
WO2000030599A1 (en) * | 1998-11-23 | 2000-06-02 | The Procter & Gamble Company | Skin deodorizing and sanitizing compositions |
US6358469B1 (en) | 1998-12-01 | 2002-03-19 | S. C. Johnson & Son, Inc. | Odor eliminating aqueous formulation |
US6123932A (en) * | 1999-06-14 | 2000-09-26 | The Procter & Gamble Company | Deodorant compositions containing cyclodextrin odor controlling agents |
US6110449A (en) * | 1999-06-14 | 2000-08-29 | The Procter & Gamble Company | Anhydrous antiperspirant cream compositions improved perfume longevity |
WO2001087360A3 (en) * | 2000-05-15 | 2002-04-04 | Procter & Gamble | Compositions comprising cyclodextrin derivatives |
US6878695B2 (en) | 2000-05-15 | 2005-04-12 | The Procter & Gamble Company | Compositions comprising cyclodextrin derivatives |
US7645746B1 (en) | 2000-11-13 | 2010-01-12 | The Procter & Gamble Company | Composition for reducing malodor impression on inanimate surfaces |
JP2016515867A (ja) * | 2013-03-15 | 2016-06-02 | ザ プロクター アンド ギャンブル カンパニー | パーソナルケア組成物 |
JP2018029970A (ja) * | 2013-03-15 | 2018-03-01 | ザ プロクター アンド ギャンブル カンパニー | パーソナルケア組成物 |
Also Published As
Publication number | Publication date |
---|---|
JP2857629B2 (ja) | 1999-02-17 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP2857629B2 (ja) | 消臭剤 | |
RU2440095C2 (ru) | Средство личной гигиены, содержащее циклодекстрин в качестве материала, связывающего ароматические вещества | |
US4267166A (en) | Cyclodextrins as malodorous breath reducing agents | |
US5942214A (en) | Methods for controlling environmental odors on the body using compositions comprising uncomplexed cyclodextrins and perfume | |
AU731790B2 (en) | Compositions for reducing odor on skin | |
GB2084872A (en) | A composition for treatment and prevention of malodor generating skin conditions | |
JPS6331442B2 (ja) | ||
US5871719A (en) | Perfume-free two phase compositions for reducing body odor | |
JPS60136506A (ja) | 脱臭・消臭剤 | |
Duchêne et al. | Cyclodextrins in cosmetics | |
EP3313533B1 (en) | Deodorant composition comprising a mixture of alpha, beta and gamma cyclodextrin | |
JP2954634B2 (ja) | 化粧料 | |
JPH0566143B2 (ja) | ||
JPH0366899B2 (ja) | ||
JPH01265964A (ja) | 消臭剤 | |
JP2004189633A (ja) | 防臭化粧料 | |
JPH0321003B2 (ja) | ||
JP6445759B2 (ja) | 化粧料組成物 | |
JP2804823B2 (ja) | 消臭剤 | |
JPH03287512A (ja) | ピールオフ型パック化粧料 | |
JPS58152808A (ja) | 含嗽剤組成物 | |
JP2007031386A (ja) | 化粧料 | |
JP2014009229A (ja) | フルボ酸を用いたパーマネントウェーブ用消臭剤 | |
JPH01193209A (ja) | パック化粧料 | |
KR20050029906A (ko) | 구취 억제 및 제거용 필름 및 이를 제조하기 위한필름형성용 조성물 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20081204 Year of fee payment: 10 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20091204 Year of fee payment: 11 |
|
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20101204 Year of fee payment: 12 |
|
EXPY | Cancellation because of completion of term | ||
FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20101204 Year of fee payment: 12 |