JPH03243242A - ダイカスト用粉末離型剤 - Google Patents

ダイカスト用粉末離型剤

Info

Publication number
JPH03243242A
JPH03243242A JP1044339A JP4433989A JPH03243242A JP H03243242 A JPH03243242 A JP H03243242A JP 1044339 A JP1044339 A JP 1044339A JP 4433989 A JP4433989 A JP 4433989A JP H03243242 A JPH03243242 A JP H03243242A
Authority
JP
Japan
Prior art keywords
release agent
mold release
base material
powder
die casting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP1044339A
Other languages
English (en)
Other versions
JPH069730B2 (ja
Inventor
Takashi Hanano
花野 孝
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hanano Shoji KK
Original Assignee
Hanano Shoji KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hanano Shoji KK filed Critical Hanano Shoji KK
Priority to JP1044339A priority Critical patent/JPH069730B2/ja
Priority to US07/344,564 priority patent/US5039435A/en
Priority to DE3917726A priority patent/DE3917726C2/de
Priority to KR1019890008257A priority patent/KR920004450B1/ko
Priority to GB8918078A priority patent/GB2227022B/en
Priority to CA000610922A priority patent/CA1335315C/en
Publication of JPH03243242A publication Critical patent/JPH03243242A/ja
Publication of JPH069730B2 publication Critical patent/JPH069730B2/ja
Priority to HK122695A priority patent/HK122695A/xx
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。

Description

【発明の詳細な説明】 (産業上の利用分野) 本発明は、ダイカスト作業において金型内面に吹付けて
用いる離型剤に関するものである。
(従来の技術) ダイカスト法は高精度の鋳造品を連続して且つ大量に製
造できるので、自動車や電気機器等の各種部品の製造に
多く利用されている。そしてこのダイカスト法において
は、成形型の゛金型と溶湯との直接接触を避けて焼付を
防止し製品の型離れを良くするために離型剤が用いられ
ている。
ダイカスト用離型剤は一般に水溶性離型剤と不水溶性離
型剤とに大別される。そして不水溶性離型剤は発煙、引
火性の危険性が高く安全性に問題があるため、水溶性離
型剤が多用されている。水溶性離型剤は一般に、水、鉱
物油等の離型剤基材に、界面活性剤や極圧性付ち剤とし
て用いられるシリコーンオイル、合成又は天然のワック
ス、油脂類、脂肪酸エステル等が添加されてなるもので
ある。
(発明が解決しようとする問題点) ところで近年ダイカスト技術の進歩に伴ってより高品質
の製品をより作業性良く得るための離型剤が要望される
ようになってきた。そして水溶性離型剤ではそのような
要望を満足させられなくなってきた。即ち水溶性離型剤
で【よ、水溶性であるために金型温度のコントU−ルが
困難であり、また木桟りに起因して製品内部に欠陥が生
じる可能性が高いという問題があった。更に使用後の水
質汚濁防止のために廃水処理を必要としそのための設備
投資等の諸経費を必要とするという問題があった。そこ
で新しい形態の離型剤が強く望まれるようになってきた
本発明は以上のような点に鑑みて鋭意研究し各種の系統
的実験を行なった結果なされたもので、ダイカスト法に
おいてより高品質の鋳造品をより作業性良く且つ環境を
悪化させることなく得るために用いられるダイカスト用
離型剤、即ち具体的には製品の焼付や内部欠陥の発生を
確実に防止でき、しかも製品の金型からの型離れをより
良好に行なわせることができ、また使用後に金型内面や
製品表面から取除き易く、更には使用中のガスの発生が
少なく、使用後に水質を汚染することのないダイカスト
用離型剤を提供することを目的とする。
(問題点を解決するための手段) 本発明のダイカスト用粉末離型剤は、固体で潤滑剤とし
て用いられる無機化合物からなる粉末状又は顆粒状の離
型剤基材と、離型剤基材に付着性を付与する有機化合物
とを混合してなる離型剤であって、両者とも粉末状又は
顆粒状の形態を有し、又は離型剤基材に有機化合物が被
覆された形態を有することを特徴とするものである。
本発明の最大の特徴は、離型剤基材が粉末状又は顆粒状
の形態を有することである。
そして有機化合物の無機化合物に対する含有割合は0.
1〜45重量%の範囲から選択するのが有効である。0
.1重量%より小さいと無機化合物の金型内面に対する
付着効果が充分には得られず、45重量%より大きいと
ビルドアップが発生し、離型剤が金型内面から取除きに
くくなったり即ち離型効果が悪くなったり製品の寸法精
度が悪くなったりするからである。
本発明で用い得る離型剤基材は、固体で8!lW4剤と
して用いられる無機化合物であれば特に制限はない。一
般には窒化ホウ素、雲母、金属酸化物、窒化ケイ素が好
ましく用いられるが、その他従来から離型剤として用い
られている公知の固体1111W4剤、例えば二硫化モ
リブデン、グラファイト等も用いることができる。そし
てこれらの無機化合物は粉末状又は顆粒状の形態で、そ
の1種類のみが、又は2種類以上が組合せて用いられる
また本発明で用い得る有機化合物は、上述のような無機
化合物に付着性、接着性を付与する性質を有するもので
あれば、特に制限はない。一般には金属石鹸や高分子化
合物が好ましく用いられる。
金属石鹸としてはカルボン酸骨格にナトリウム、カルシ
ウム、バリウム、リチウム、カリウム、マグネシウム、
又は亜鉛を付加したものが、また高分子化合物としては
ポリエチレン、ポリプロピレン、エポキシ樹脂、ケイ素
樹脂、フェノール樹脂、アクリル樹脂、アルキッド樹脂
、又はポリスチレンが特に好ましく用いられる。そして
これらの有機化合物は、粉末状又は顆粒状の形態で離型
剤基材と混合され、又は加熱溶融された状態で離型剤基
材と混合される。従って本発明の離型剤は、離型剤基材
と有機化合物の両方が粉末状又は顆粒状の形態を有し、
又は粉末状又は顆粒状の離型剤基材に有機化合物が被覆
された形態を有することとなる。なお有機化合物は、上
述した化合物の1種類のみが、又は2種類以上が組合せ
て用いられる。
金属石鹸と高分子化合物とを組合せて用いてもよい。
(作用) 本発明のダイカスト用粉末離型剤は少なくとも離型剤基
材が粉末状又は顆粒状の形態を有しているので、離型剤
が付着された金型内面の部分では製品と金型内面とが確
実に少なくとも離型剤基材の粉末又は顆粒の粒子径だけ
隔てられることとなる。従って離型剤が金型内面にまん
べんなく付着されることにより、製品と金型内面とが直
接に接触することによる焼付は確実に防止される。また
本発明の離型剤は有機化合物と無機化合物とからなり水
分を含有してはいないので、製品内部に水洩りに起因す
る欠陥が発生することもない。従って製品の品質は向上
することとなる。
また本発明の離型剤は少なくとも離型剤基材が粉末状又
は顆粒状の形態を右し、水分を含有してはいないので、
金型内面と製品との間で働く張力は弱い。従って製品の
金型からの取出しは容易となる。しかも金型内面及び製
品表面から容易に取除かれる。
更に本発明の離型剤は少なくとも離型剤基材が粉末状又
は顆粒状の形態を有しているので、ダイカスト中に熱が
加わっても反応しにくくガスを殆んど発生しない。また
水溶性離型剤のように使用後に水質を汚染することもな
い。従って作業場の環境を悪化させることはなく、また
廃水処理のための経費が不要となり安価に用いられるこ
ととなる。
(発明の効果〉 本発明によれば無機化合物からなる離型剤基材と有機化
合物との混合物からなるダイカスト用離型剤を、少なく
とも離型剤基材が粉末状又は顆粒状の形態を有するもの
としたので、ダイカスト法により得られる例えばアルミ
ニウム合金や亜鉛合金等の鋳造品の焼付や内部の欠陥発
生を確実に防止してその品質を向上させることができ、
しかもダイカスト法による鋳造をより作業性良く行なわ
せることができ、更には使用中及び使用後における環境
の悪化を充分に防止することができる。特に有機化合物
の無機化合物に対する含有割合を0゜1〜45重量%の
範囲とすることにより、得られる鋳造品の品質をより良
好なものにすることができる。更に無機化合物として、
窒化ホウ素、雲母、金属酸化物、窒化ケイ素を、また有
機化合物として、カルボン酸骨格にナトリウム、カルシ
ウム、バリウム、リチウム、カリウム、マグネシウム、
又は亜鉛を付加してなる金属石鹸や、ポリエチレン、ポ
リプロピレン、エポキシ樹脂、ケイ素樹脂、フェノール
樹脂、アクリル樹脂、アルキッド樹脂、又はポリスチレ
ンの高分子化合物を用いることにより上記効果をより良
好に発揮することができる。
そして上記の無機化合物、有機化合物の内、それぞれ2
種類以上のものを組合せて用いることにより、各ダイカ
スト作業においてより最適に用い得る離型剤を得ること
ができる。
(実施例〉 以下、本発明の実施例を示すが、本発明はこれに限定さ
れるものではない。
次に示す(A)〜(E)の離型剤を得、これらの離型剤
を用いてダイカスト法による鋳造の試験を行ない、[表
]に示す各項目について比較検討した。
本発明の例である(^)〜(C)の混合物としては、用
いる有機化合物を粉末状又は顆粒状の形態で無機化合物
に混合したものと、加熱溶融した状態で無機化合物に混
合したものとの両方を得、それぞれについて検討したが
、結果は両者とも同じであった。なお(A)〜(E)の
離型剤において用いる各化合物は市販のものである。
(A)窒化ホウ素(平均粒度1〜5μ)95部と、ステ
アリン酸カルシウム5部との混合物からなる本発明の第
1の例、 (B)窒化ホウ素20部と、雲母75部と、ポリエチレ
ン5部との混合物からなる本発明の第2の例、 (C)窒化ホウ素50部と、窒化ケイ素45部と、ステ
アリン酸バリウム3部と、ポリプロピレン2部との混合
物からなる本発明の第3の例、(D)窒化ホウ素のみ(
比較例1) (E)ワックスとシリコーンオイルを1=80の比で主
成分として含有してなる水溶性離型剤(比較例2)、 [表] ×:全くない、−二測定不能、 Δ:小さい、○:普通、◎二人きい

Claims (6)

    【特許請求の範囲】
  1. (1)固体で潤滑剤として用いられる無機化合物からな
    る粉末状又は顆粒状の離型剤基材と、離型剤基材に付着
    性を付与する有機化合物とを混合してなる離型剤であつ
    て、両者とも粉末状又は顆粒状の形態を有し、又は離型
    剤基材に有機化合物が被覆された形態を有することを特
    徴とするダイカスト用粉末離型剤。
  2. (2)有機化合物を無機化合物に対して0.1〜45重
    量%の割合で含有した特許請求の範囲第1項記載のダイ
    カスト用粉末離型剤。
  3. (3)無機化合物としては、窒化ホウ素、雲母、金属酸
    化物、窒化ケイ素のうち、1種類以上が用いられる特許
    請求の範囲第1項又は第2項記載のダイカスト用粉末離
    型剤。
  4. (4)有機化合物としては、複数種類の金属石鹸や複数
    種類の高分子化合物のうち、1種類以上が用いられる特
    許請求の範囲第1項ないし第3項のいずれかに記載のダ
    イカスト用粉末離型剤。
  5. (5)金属石鹸は、カルボン酸骨格にナトリウム、カル
    シウム、バリウム、リチウム、カリウム、マグネシウム
    、又は亜鉛を付加したものである特許請求の範囲第4項
    記載のダイカスト用粉末離型剤。
  6. (6)高分子化合物は、ポリエチレン、ポリプロピレン
    、エポキシ樹脂、ケイ素樹脂、フェノール樹脂、アクリ
    ル樹脂、アルキッド樹脂、又はポリスチレンである特許
    請求の範囲第4項又は第5項記載のダイカスト用粉末離
    型剤。
JP1044339A 1989-01-13 1989-02-23 ダイカスト用粉末離型剤 Expired - Fee Related JPH069730B2 (ja)

Priority Applications (7)

Application Number Priority Date Filing Date Title
JP1044339A JPH069730B2 (ja) 1989-01-13 1989-02-23 ダイカスト用粉末離型剤
US07/344,564 US5039435A (en) 1989-01-13 1989-04-28 Die-casting powdery mold releasing agent
DE3917726A DE3917726C2 (de) 1989-01-13 1989-05-31 Formentrennmittel für Druckgußverfahren
KR1019890008257A KR920004450B1 (ko) 1989-02-23 1989-06-14 다이캐스트용 분말이형제(粉末離型劑)
GB8918078A GB2227022B (en) 1989-01-13 1989-08-08 Die-casting powdery mould releasing agent
CA000610922A CA1335315C (en) 1989-01-13 1989-09-11 Die-casting powdery mold releasing agent
HK122695A HK122695A (en) 1989-01-13 1995-07-27 Die-casting powdery mould releasing agent

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
JP1-7135 1989-01-13
JP713589 1989-01-13
JP1044339A JPH069730B2 (ja) 1989-01-13 1989-02-23 ダイカスト用粉末離型剤

Publications (2)

Publication Number Publication Date
JPH03243242A true JPH03243242A (ja) 1991-10-30
JPH069730B2 JPH069730B2 (ja) 1994-02-09

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Country Status (6)

Country Link
US (1) US5039435A (ja)
JP (1) JPH069730B2 (ja)
CA (1) CA1335315C (ja)
DE (1) DE3917726C2 (ja)
GB (1) GB2227022B (ja)
HK (1) HK122695A (ja)

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Also Published As

Publication number Publication date
US5039435A (en) 1991-08-13
GB2227022A (en) 1990-07-18
GB2227022B (en) 1992-11-04
CA1335315C (en) 1995-04-18
GB8918078D0 (en) 1989-09-20
HK122695A (en) 1995-08-04
JPH069730B2 (ja) 1994-02-09
DE3917726C2 (de) 1994-07-07
DE3917726A1 (de) 1990-07-19

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