JPH0323524B2 - - Google Patents
Info
- Publication number
- JPH0323524B2 JPH0323524B2 JP56008040A JP804081A JPH0323524B2 JP H0323524 B2 JPH0323524 B2 JP H0323524B2 JP 56008040 A JP56008040 A JP 56008040A JP 804081 A JP804081 A JP 804081A JP H0323524 B2 JPH0323524 B2 JP H0323524B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- weight
- dental
- polymerization
- mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 claims abstract description 48
- 239000003054 catalyst Substances 0.000 claims abstract description 36
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims abstract description 6
- -1 methacryl compound Chemical class 0.000 claims abstract description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 3
- 125000000547 substituted alkyl group Chemical group 0.000 claims abstract description 3
- 238000006116 polymerization reaction Methods 0.000 claims description 17
- 229920000642 polymer Polymers 0.000 claims description 15
- MFEWNFVBWPABCX-UHFFFAOYSA-N 1,1,2,2-tetraphenylethane-1,2-diol Chemical compound C=1C=CC=CC=1C(C(O)(C=1C=CC=CC=1)C=1C=CC=CC=1)(O)C1=CC=CC=C1 MFEWNFVBWPABCX-UHFFFAOYSA-N 0.000 claims description 7
- 239000003112 inhibitor Substances 0.000 claims description 4
- 125000005395 methacrylic acid group Chemical group 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 abstract description 8
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- 239000000178 monomer Substances 0.000 description 6
- 239000004342 Benzoyl peroxide Substances 0.000 description 5
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 5
- 235000019400 benzoyl peroxide Nutrition 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 4
- 229920002818 (Hydroxyethyl)methacrylate Polymers 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 238000002845 discoloration Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 150000002978 peroxides Chemical class 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- CKGKXGQVRVAKEA-UHFFFAOYSA-N (2-methylphenyl)-phenylmethanone Chemical compound CC1=CC=CC=C1C(=O)C1=CC=CC=C1 CKGKXGQVRVAKEA-UHFFFAOYSA-N 0.000 description 2
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 2
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 2
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000003111 delayed effect Effects 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 230000009969 flowable effect Effects 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- VZXPHDGHQXLXJC-UHFFFAOYSA-N 1,6-diisocyanato-5,6-dimethylheptane Chemical compound O=C=NC(C)(C)C(C)CCCCN=C=O VZXPHDGHQXLXJC-UHFFFAOYSA-N 0.000 description 1
- OYJAVFDOALZIRF-UHFFFAOYSA-N 2-methylprop-2-enoic acid;2-(2-methylprop-2-enoyloxy)ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(O)=O.CC(=C)C(=O)OCCOC(=O)C(C)=C OYJAVFDOALZIRF-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N Bisphenol A Natural products C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- AMFGWXWBFGVCKG-UHFFFAOYSA-N Panavia opaque Chemical compound C1=CC(OCC(O)COC(=O)C(=C)C)=CC=C1C(C)(C)C1=CC=C(OCC(O)COC(=O)C(C)=C)C=C1 AMFGWXWBFGVCKG-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004581 coalescence Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000011350 dental composite resin Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 230000007717 exclusion Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical class CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 210000004283 incisor Anatomy 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- IWVKTOUOPHGZRX-UHFFFAOYSA-N methyl 2-methylprop-2-enoate;2-methylprop-2-enoic acid Chemical compound CC(=C)C(O)=O.COC(=O)C(C)=C IWVKTOUOPHGZRX-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 238000005192 partition Methods 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 238000005502 peroxidation Methods 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 230000008707 rearrangement Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000012265 solid product Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S528/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S528/92—Polymers useful for replacing hard animal tissues, e.g. dentures, bones
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Veterinary Medicine (AREA)
- Engineering & Computer Science (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Epidemiology (AREA)
- Plastic & Reconstructive Surgery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dental Preparations (AREA)
- Polymerization Catalysts (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP80100639A EP0033750B1 (fr) | 1980-02-08 | 1980-02-08 | Catalyseur pour la préparation de compositions dentaires artificielles ou de prothèses dentaires, son utilisation, et compositions dentaires artificielles |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS56138108A JPS56138108A (en) | 1981-10-28 |
| JPH0323524B2 true JPH0323524B2 (fr) | 1991-03-29 |
Family
ID=8186592
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP804081A Granted JPS56138108A (en) | 1980-02-08 | 1981-01-23 | Synthetic dental composition for dental repairment part manufacture and dental repairment part |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US4330283A (fr) |
| EP (1) | EP0033750B1 (fr) |
| JP (1) | JPS56138108A (fr) |
| AT (1) | ATE5460T1 (fr) |
| AU (1) | AU532435B2 (fr) |
| CA (1) | CA1149999A (fr) |
| DE (1) | DE3065741D1 (fr) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4288527A (en) * | 1980-08-13 | 1981-09-08 | W. R. Grace & Co. | Dual UV/thermally curable acrylate compositions with pinacol |
| US4816597A (en) * | 1983-10-02 | 1989-03-28 | New Jersey Institute Of Technology | Dental restorative materials based upon blocked isocyanates |
| JPS60152406A (ja) * | 1984-01-18 | 1985-08-10 | Mitsubishi Rayon Co Ltd | 歯科用材料 |
| US5028661A (en) * | 1986-10-14 | 1991-07-02 | Loctite Corporation | Adhesion promoters for thiolene adhesive formulations |
| US5183834A (en) * | 1989-04-05 | 1993-02-02 | Dentsply G.M.B.H. | Pasty dental veneer making composition |
| US5145374A (en) * | 1989-10-03 | 1992-09-08 | The United States Of America As Represented By The Secretary Of Commerce | Synthetic dental compositions formed from cyclopolymerizable bis-acrylate and multi-functional oligomer and bonding method |
| US5709548A (en) * | 1990-02-23 | 1998-01-20 | Minnesota Mining And Manufacturing Company | Dental crown liner composition and methods of preparing provisional applications |
| DE69004245T2 (de) * | 1990-02-23 | 1994-05-11 | Minnesota Mining & Mfg | Semi-thermoplastische Formmasse mit thermostabilem Formerinnerungsvermögen. |
| US5380901A (en) * | 1992-01-30 | 1995-01-10 | The United States Of America As Represented By The Secretary Of Commerce | Multifunctional acrylates and the synthesis thereof |
| US5502087A (en) * | 1993-06-23 | 1996-03-26 | Dentsply Research & Development Corp. | Dental composition, prosthesis, and method for making dental prosthesis |
| SE508716C2 (sv) * | 1996-01-15 | 1998-11-02 | Tetra Laval Holdings & Finance | Botten för en förpackning med inre övertryck |
| US6872403B2 (en) | 2000-02-01 | 2005-03-29 | University Of Kentucky Research Foundation | Polymethylmethacrylate augmented with carbon nanotubes |
| US6599961B1 (en) | 2000-02-01 | 2003-07-29 | University Of Kentucky Research Foundation | Polymethylmethacrylate augmented with carbon nanotubes |
| DE102011050035A1 (de) | 2011-05-02 | 2012-11-08 | Byk-Chemie Gmbh | Emissionsarmes, durch radikalische Polymerisation thermisch härtbares Faser-Matrix-Halbzeug |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2181102A (en) * | 1937-06-04 | 1939-11-21 | Dow Chemical Co | Stabilization of polymerizable vinyl compouds |
| US3084436A (en) * | 1960-02-25 | 1963-04-09 | Howe Sound Co | Polymers prepared by polymerizing a mixture of esters in the presence of a vinyl stearate-vinyl acetate copolymer, and a denture therewith |
| DE1219224B (de) * | 1963-02-25 | 1966-06-16 | Bayer Ag | Polyesterformmassen |
| FR1385958A (fr) * | 1963-04-03 | 1965-01-15 | Bayer Ag | Procédé de préparation de polymères stables |
| FR2094493A5 (en) * | 1970-06-28 | 1972-02-04 | Hofacker Erich | Forming dental prosthesis base - with self hardenable plastic eg polymethylmethacrylate |
| DE2403211C3 (de) * | 1974-01-23 | 1981-12-24 | Etablissement Dentaire Ivoclar, Schaan | Werkstoff für Dentalzwecke |
| JPS5272749A (en) * | 1975-12-15 | 1977-06-17 | G C Dental Ind Corp | Resin material for repair of crown of tooth |
| US4020233A (en) * | 1976-01-22 | 1977-04-26 | W. R. Grace & Co. | Heat activated ethylenically unsaturated-polythiol compositions |
| US4288221A (en) * | 1980-01-28 | 1981-09-08 | Minnesota Mining And Manufacturing Company | Durable, polishable direct filling material |
-
1980
- 1980-02-08 AT AT80100639T patent/ATE5460T1/de not_active IP Right Cessation
- 1980-02-08 DE DE8080100639T patent/DE3065741D1/de not_active Expired
- 1980-02-08 EP EP80100639A patent/EP0033750B1/fr not_active Expired
-
1981
- 1981-01-23 JP JP804081A patent/JPS56138108A/ja active Granted
- 1981-01-28 AU AU66666/81A patent/AU532435B2/en not_active Ceased
- 1981-02-04 US US06/231,549 patent/US4330283A/en not_active Expired - Lifetime
- 1981-02-06 CA CA000370244A patent/CA1149999A/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| US4330283A (en) | 1982-05-18 |
| JPS56138108A (en) | 1981-10-28 |
| EP0033750B1 (fr) | 1983-11-30 |
| CA1149999A (fr) | 1983-07-12 |
| AU532435B2 (en) | 1983-09-29 |
| ATE5460T1 (de) | 1983-12-15 |
| EP0033750A1 (fr) | 1981-08-19 |
| DE3065741D1 (en) | 1984-01-05 |
| AU6666681A (en) | 1981-08-13 |
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