JPH03207884A - 高耐食性の工業用硬質クロム層を直接的又は間接的に析出させる方法 - Google Patents
高耐食性の工業用硬質クロム層を直接的又は間接的に析出させる方法Info
- Publication number
- JPH03207884A JPH03207884A JP2270685A JP27068590A JPH03207884A JP H03207884 A JPH03207884 A JP H03207884A JP 2270685 A JP2270685 A JP 2270685A JP 27068590 A JP27068590 A JP 27068590A JP H03207884 A JPH03207884 A JP H03207884A
- Authority
- JP
- Japan
- Prior art keywords
- pulse frequency
- current density
- shiny
- current
- range
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 230000008021 deposition Effects 0.000 title claims abstract description 17
- 230000007797 corrosion Effects 0.000 title claims abstract description 12
- 238000005260 corrosion Methods 0.000 title claims abstract description 12
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 36
- 239000011651 chromium Substances 0.000 claims abstract description 36
- 150000003839 salts Chemical class 0.000 claims abstract description 7
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims abstract description 5
- 239000003792 electrolyte Substances 0.000 claims description 22
- 238000000151 deposition Methods 0.000 claims description 19
- 238000000034 method Methods 0.000 claims description 18
- 238000001556 precipitation Methods 0.000 claims description 10
- -1 sulphate ions Chemical class 0.000 claims description 5
- 230000007704 transition Effects 0.000 claims description 4
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 claims description 3
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 claims description 3
- 125000001931 aliphatic group Chemical group 0.000 claims description 2
- 230000001419 dependent effect Effects 0.000 claims description 2
- 229910052736 halogen Chemical class 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 229910052751 metal Inorganic materials 0.000 claims description 2
- 239000002184 metal Substances 0.000 claims description 2
- 125000000542 sulfonic acid group Chemical group 0.000 claims description 2
- 239000012224 working solution Substances 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 1
- 239000011696 chromium(III) sulphate Substances 0.000 claims 1
- 229910021653 sulphate ion Inorganic materials 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 abstract description 3
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 abstract 2
- 238000005868 electrolysis reaction Methods 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 238000000576 coating method Methods 0.000 description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 5
- 239000000203 mixture Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 150000002222 fluorine compounds Chemical class 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000001465 metallisation Methods 0.000 description 3
- 239000007921 spray Substances 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 238000005457 optimization Methods 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- MFEVGQHCNVXMER-UHFFFAOYSA-L 1,3,2$l^{2}-dioxaplumbetan-4-one Chemical compound [Pb+2].[O-]C([O-])=O MFEVGQHCNVXMER-UHFFFAOYSA-L 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- 241000473391 Archosargus rhomboidalis Species 0.000 description 1
- 229910000521 B alloy Inorganic materials 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910000881 Cu alloy Inorganic materials 0.000 description 1
- 229910000003 Lead carbonate Inorganic materials 0.000 description 1
- 229910000990 Ni alloy Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 229910001297 Zn alloy Inorganic materials 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- NJPNZJFVJXSSKZ-UHFFFAOYSA-N azanium;1-fluorooctane-1-sulfonate Chemical compound [NH4+].CCCCCCCC(F)S([O-])(=O)=O NJPNZJFVJXSSKZ-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000005137 deposition process Methods 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 150000002221 fluorine Chemical class 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 239000012458 free base Substances 0.000 description 1
- 238000009499 grossing Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000003746 surface roughness Effects 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/627—Electroplating characterised by the visual appearance of the layers, e.g. colour, brightness or mat appearance
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/04—Electroplating: Baths therefor from solutions of chromium
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D3/00—Electroplating: Baths therefor
- C25D3/02—Electroplating: Baths therefor from solutions
- C25D3/04—Electroplating: Baths therefor from solutions of chromium
- C25D3/10—Electroplating: Baths therefor from solutions of chromium characterised by the organic bath constituents used
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/10—Electroplating with more than one layer of the same or of different metals
- C25D5/12—Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium
- C25D5/14—Electroplating with more than one layer of the same or of different metals at least one layer being of nickel or chromium two or more layers being of nickel or chromium, e.g. duplex or triplex layers
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/18—Electroplating using modulated, pulsed or reversing current
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electroplating Methods And Accessories (AREA)
- Electroplating And Plating Baths Therefor (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3933896.7 | 1989-10-11 | ||
| DE3933896A DE3933896C1 (de) | 1989-10-11 | 1989-10-11 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH03207884A true JPH03207884A (ja) | 1991-09-11 |
Family
ID=6391241
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2270685A Pending JPH03207884A (ja) | 1989-10-11 | 1990-10-11 | 高耐食性の工業用硬質クロム層を直接的又は間接的に析出させる方法 |
Country Status (5)
| Country | Link |
|---|---|
| JP (1) | JPH03207884A (de) |
| DE (1) | DE3933896C1 (de) |
| ES (1) | ES2023577A6 (de) |
| FR (1) | FR2652825B1 (de) |
| GB (1) | GB2236763B (de) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05161904A (ja) * | 1991-12-12 | 1993-06-29 | Mishima Kosan Co Ltd | 冷間圧延用ロール |
| US6329071B1 (en) | 1998-11-06 | 2001-12-11 | Tokico Ltd. | Chrome plated parts and chrome plating method |
| US6641710B2 (en) | 2000-08-29 | 2003-11-04 | Soqi, Inc. | Metal plating method |
| JP2007533852A (ja) * | 2004-04-21 | 2007-11-22 | フェデラル−モーグル ブルシャイト ゲゼルシャフト ミット ベシュレンクテル ハフツング | 構造化硬質クロム層の製造およびコーティングの製造 |
| USRE40386E1 (en) | 1998-11-06 | 2008-06-17 | Hitachi Ltd. | Chrome plated parts and chrome plating method |
| US8173004B2 (en) | 2003-09-30 | 2012-05-08 | Hitachi, Ltd. | Method of manufacturing chromium plated article and chromium plating apparatus |
| KR20180005180A (ko) | 2015-05-12 | 2018-01-15 | 히다치 오토모티브 시스템즈 가부시키가이샤 | 크롬 도금 부품의 제조 방법 및 크롬 도금 장치 |
| KR20220043575A (ko) | 2020-09-29 | 2022-04-05 | 주식회사 원탑플레이팅 | 크롬 도금 부품의 제조 방법 및 크롬 도금 장치 |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4011201C1 (en) * | 1990-04-06 | 1991-08-22 | Lpw-Chemie Gmbh, 4040 Neuss, De | Coating workpiece with chromium for improved corrosion resistance - comprises using aq. electrolyte soln. contg. chromic acid sulphate ions, and fluoro:complexes to increase deposition |
| US5670265A (en) * | 1990-10-20 | 1997-09-23 | Ina Walzlager Schaeffler Kg | Steel component with an electroplated anti-corrosive coating and process for producing same |
| DE4125585A1 (de) * | 1990-10-20 | 1992-04-30 | Schaeffler Waelzlager Kg | Bauteil aus stahl mit galvanisch aufgebrachter korrosionsschutzschicht |
| USRE35860F1 (en) * | 1991-06-05 | 2001-01-02 | Timken Co | Corrosion-resistant zinc-nickel plated bearing races |
| US5352266A (en) * | 1992-11-30 | 1994-10-04 | Queen'university At Kingston | Nanocrystalline metals and process of producing the same |
| IT1267394B1 (it) * | 1994-02-18 | 1997-02-05 | Ind S R L | Procedimento per la realizzazione di riporti galvanici compositi in cromo duro con una fase dispersa e riporto anti-usura realizzato con |
| DE4430923C2 (de) * | 1994-08-31 | 1997-10-09 | Schaeffler Waelzlager Kg | Galvanisches Chrombad, Verfahren zur galvanischen Abscheidung von Chrom und Verwendung des Bades |
| DE10006151A1 (de) * | 2000-02-11 | 2001-09-06 | Heinz Busch | System mit einem Träger und einer Hartstoffbeschichtung |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5518789A (en) * | 1978-07-27 | 1980-02-09 | Mitsubishi Electric Corp | Temperature controller |
| JPS6332874A (ja) * | 1986-07-24 | 1988-02-12 | Matsushita Electric Works Ltd | 蓄電池の温度センサ取付構造 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3232854A (en) * | 1959-06-05 | 1966-02-01 | Diamond Alkali Co | Chromium plating |
| US4092226A (en) * | 1974-12-11 | 1978-05-30 | Nikolaus Laing | Process for the treatment of metal surfaces by electro-deposition of metal coatings at high current densities |
| DE2604628A1 (de) * | 1976-02-06 | 1977-08-11 | Rosenloecher Claus | Verfahren zur unmittelbaren galvanischen hartverchromung von nickel |
| DE3402554A1 (de) * | 1984-01-26 | 1985-08-08 | LPW-Chemie GmbH, 4040 Neuss | Abscheidung von hartchrom auf einer metallegierung aus einem waessrigen, chromsaeure und schwefelsaeure enthaltenden elektrolyten |
| US4789437A (en) * | 1986-07-11 | 1988-12-06 | University Of Hong Kong | Pulse electroplating process |
| IT1216808B (it) * | 1987-05-13 | 1990-03-14 | Sviluppo Materiali Spa | Processo di elettrodeposizione in continuo di cromo metallico e di ossido di cromo su superfici metalliche |
| IT1215985B (it) * | 1988-03-04 | 1990-02-22 | Elca Srl | Procedimento elettrochimico per la realizzazione di rivestimenti di cromo e metalli simili mediante corrente pulsante ad inversione periodica della polarita' |
-
1989
- 1989-10-11 DE DE3933896A patent/DE3933896C1/de not_active Expired - Lifetime
-
1990
- 1990-10-03 GB GB9021528A patent/GB2236763B/en not_active Expired - Fee Related
- 1990-10-05 ES ES9002531A patent/ES2023577A6/es not_active Expired - Lifetime
- 1990-10-05 FR FR9012326A patent/FR2652825B1/fr not_active Expired - Fee Related
- 1990-10-11 JP JP2270685A patent/JPH03207884A/ja active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5518789A (en) * | 1978-07-27 | 1980-02-09 | Mitsubishi Electric Corp | Temperature controller |
| JPS6332874A (ja) * | 1986-07-24 | 1988-02-12 | Matsushita Electric Works Ltd | 蓄電池の温度センサ取付構造 |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05161904A (ja) * | 1991-12-12 | 1993-06-29 | Mishima Kosan Co Ltd | 冷間圧延用ロール |
| US6329071B1 (en) | 1998-11-06 | 2001-12-11 | Tokico Ltd. | Chrome plated parts and chrome plating method |
| USRE40386E1 (en) | 1998-11-06 | 2008-06-17 | Hitachi Ltd. | Chrome plated parts and chrome plating method |
| US6641710B2 (en) | 2000-08-29 | 2003-11-04 | Soqi, Inc. | Metal plating method |
| US8173004B2 (en) | 2003-09-30 | 2012-05-08 | Hitachi, Ltd. | Method of manufacturing chromium plated article and chromium plating apparatus |
| JP2007533852A (ja) * | 2004-04-21 | 2007-11-22 | フェデラル−モーグル ブルシャイト ゲゼルシャフト ミット ベシュレンクテル ハフツング | 構造化硬質クロム層の製造およびコーティングの製造 |
| KR20180005180A (ko) | 2015-05-12 | 2018-01-15 | 히다치 오토모티브 시스템즈 가부시키가이샤 | 크롬 도금 부품의 제조 방법 및 크롬 도금 장치 |
| JPWO2016181955A1 (ja) * | 2015-05-12 | 2018-03-01 | 日立オートモティブシステムズ株式会社 | クロムめっき部品の製造方法およびクロムめっき装置 |
| US10851464B1 (en) | 2015-05-12 | 2020-12-01 | Hitachi Automotive Systems, Ltd. | Method for producing chromium plated parts, and chromium plating apparatus |
| KR20220043575A (ko) | 2020-09-29 | 2022-04-05 | 주식회사 원탑플레이팅 | 크롬 도금 부품의 제조 방법 및 크롬 도금 장치 |
Also Published As
| Publication number | Publication date |
|---|---|
| GB9021528D0 (en) | 1990-11-14 |
| DE3933896C1 (de) | 1990-10-11 |
| GB2236763B (en) | 1993-11-17 |
| ES2023577A6 (es) | 1992-01-16 |
| FR2652825A1 (fr) | 1991-04-12 |
| GB2236763A (en) | 1991-04-17 |
| FR2652825B1 (fr) | 1993-12-24 |
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