JPH02962B2 - - Google Patents
Info
- Publication number
- JPH02962B2 JPH02962B2 JP57190905A JP19090582A JPH02962B2 JP H02962 B2 JPH02962 B2 JP H02962B2 JP 57190905 A JP57190905 A JP 57190905A JP 19090582 A JP19090582 A JP 19090582A JP H02962 B2 JPH02962 B2 JP H02962B2
- Authority
- JP
- Japan
- Prior art keywords
- adsorber
- adsorption
- oxygen
- pressure
- gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 99
- 239000001301 oxygen Substances 0.000 claims description 99
- 229910052760 oxygen Inorganic materials 0.000 claims description 99
- 238000001179 sorption measurement Methods 0.000 claims description 74
- 239000007789 gas Substances 0.000 claims description 71
- 238000000034 method Methods 0.000 claims description 43
- 238000004140 cleaning Methods 0.000 claims description 27
- 230000008569 process Effects 0.000 claims description 12
- 239000002808 molecular sieve Substances 0.000 claims description 7
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 claims description 7
- 239000010457 zeolite Substances 0.000 claims description 6
- 229910021536 Zeolite Inorganic materials 0.000 claims description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 5
- 238000011049 filling Methods 0.000 claims description 5
- 230000008929 regeneration Effects 0.000 claims description 5
- 238000011069 regeneration method Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 4
- 239000003570 air Substances 0.000 description 56
- 239000000047 product Substances 0.000 description 53
- 238000003795 desorption Methods 0.000 description 20
- 239000003463 adsorbent Substances 0.000 description 16
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- 238000002474 experimental method Methods 0.000 description 12
- 230000000052 comparative effect Effects 0.000 description 9
- 239000012080 ambient air Substances 0.000 description 8
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 6
- 239000012043 crude product Substances 0.000 description 5
- 238000000926 separation method Methods 0.000 description 5
- 229910052786 argon Inorganic materials 0.000 description 3
- 238000010586 diagram Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 230000001105 regulatory effect Effects 0.000 description 2
- 239000000741 silica gel Substances 0.000 description 2
- 229910002027 silica gel Inorganic materials 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- QRSFFHRCBYCWBS-UHFFFAOYSA-N [O].[O] Chemical compound [O].[O] QRSFFHRCBYCWBS-UHFFFAOYSA-N 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005429 filling process Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011241 protective layer Substances 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 230000002000 scavenging effect Effects 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
- 238000010407 vacuum cleaning Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
- B01D53/0476—Vacuum pressure swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/10—Inorganic adsorbents
- B01D2253/106—Silica or silicates
- B01D2253/108—Zeolites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
- B01D2253/30—Physical properties of adsorbents
- B01D2253/302—Dimensions
- B01D2253/304—Linear dimensions, e.g. particle shape, diameter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/12—Oxygen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/10—Single element gases other than halogens
- B01D2257/102—Nitrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40028—Depressurization
- B01D2259/4003—Depressurization with two sub-steps
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40043—Purging
- B01D2259/4005—Nature of purge gas
- B01D2259/40052—Recycled product or process gas
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/40011—Methods relating to the process cycle in pressure or temperature swing adsorption
- B01D2259/40077—Direction of flow
- B01D2259/40081—Counter-current
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/403—Further details for adsorption processes and devices using three beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2259/00—Type of treatment
- B01D2259/40—Further details for adsorption processes and devices
- B01D2259/404—Further details for adsorption processes and devices using four beds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
- B01D53/0473—Rapid pressure swing adsorption
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Separation Of Gases By Adsorption (AREA)
- Oxygen, Ozone, And Oxides In General (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19813144012 DE3144012A1 (de) | 1981-11-05 | 1981-11-05 | Druckwechselverfahren zur trennung von gasgemischen mittels adsorption |
| DE31440126 | 1981-11-05 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5884020A JPS5884020A (ja) | 1983-05-20 |
| JPH02962B2 true JPH02962B2 (es) | 1990-01-10 |
Family
ID=6145721
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57190905A Granted JPS5884020A (ja) | 1981-11-05 | 1982-11-01 | 吸着による気体混合物分離のための圧力変動方法 |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JPS5884020A (es) |
| DE (1) | DE3144012A1 (es) |
| GB (1) | GB2109266B (es) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06254336A (ja) * | 1992-11-16 | 1994-09-13 | Air Prod And Chem Inc | 真空スイング吸着方法によるガス成分の分離法 |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5922625A (ja) * | 1982-07-27 | 1984-02-04 | Osaka Oxgen Ind Ltd | 一酸化炭素ガス及び窒素ガスを含む混合ガスより窒素ガスを吸着法により除去する方法 |
| DE3307087A1 (de) * | 1983-03-01 | 1984-09-06 | Bergwerksverband Gmbh, 4300 Essen | Verfahren zur entfernung von stickoxiden aus diese enthaltenden gasgemischen mittels druckwechseladsorption |
| US4509959A (en) * | 1983-07-28 | 1985-04-09 | Greene & Kellogg, Inc. | Modular industrial oxygen concentrator |
| JPS61133114A (ja) * | 1984-12-04 | 1986-06-20 | Showa Denko Kk | 富酸素ガスの製造方法 |
| JPS61133115A (ja) * | 1984-12-04 | 1986-06-20 | Showa Denko Kk | 富酸素ガスの製造法 |
| FI76003C (fi) * | 1986-02-12 | 1988-09-09 | A Happi Oy | Foerstaerkningsfoerfarande och -anordning foer gas. |
| US5074892A (en) * | 1990-05-30 | 1991-12-24 | Union Carbide Industrial Gases Technology Corporation | Air separation pressure swing adsorption process |
| US5258058A (en) * | 1992-10-05 | 1993-11-02 | Air Products And Chemicals, Inc. | Nitrogen adsorption with a divalent cation exchanged lithium X-zeolite |
| DE19503007C2 (de) * | 1995-01-31 | 2002-11-07 | Linde Ag | Druckwechseladsorptionsverfahren |
| DE19602450C1 (de) * | 1996-01-24 | 1997-02-13 | Linde Ag | Vakuumdruckwechseladsorptionsverfahren und -vorrichtung |
| WO2014056604A1 (de) * | 2012-10-09 | 2014-04-17 | Linde Aktiengesellschaft | Verfahren zum messen eines temperaturprofils in einem adsorber |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4883078A (es) * | 1972-01-24 | 1973-11-06 |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB809168A (en) * | 1956-08-29 | 1959-02-18 | British Oxygen Co Ltd | Purification of argon |
| GB1449864A (en) * | 1973-10-24 | 1976-09-15 | Boc International Ltd | Adsorption system |
| US4144038A (en) * | 1976-12-20 | 1979-03-13 | Boc Limited | Gas separation |
-
1981
- 1981-11-05 DE DE19813144012 patent/DE3144012A1/de active Granted
-
1982
- 1982-11-01 JP JP57190905A patent/JPS5884020A/ja active Granted
- 1982-11-03 GB GB08231421A patent/GB2109266B/en not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4883078A (es) * | 1972-01-24 | 1973-11-06 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH06254336A (ja) * | 1992-11-16 | 1994-09-13 | Air Prod And Chem Inc | 真空スイング吸着方法によるガス成分の分離法 |
| JPH06254335A (ja) * | 1992-11-16 | 1994-09-13 | Air Prod And Chem Inc | 真空スイング吸着法によるガス成分の分離方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| GB2109266B (en) | 1985-12-18 |
| DE3144012C2 (es) | 1990-05-17 |
| GB2109266A (en) | 1983-06-02 |
| DE3144012A1 (de) | 1983-05-19 |
| JPS5884020A (ja) | 1983-05-20 |
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