JPH0249783B2 - - Google Patents
Info
- Publication number
- JPH0249783B2 JPH0249783B2 JP56144814A JP14481481A JPH0249783B2 JP H0249783 B2 JPH0249783 B2 JP H0249783B2 JP 56144814 A JP56144814 A JP 56144814A JP 14481481 A JP14481481 A JP 14481481A JP H0249783 B2 JPH0249783 B2 JP H0249783B2
- Authority
- JP
- Japan
- Prior art keywords
- catalyst
- pore volume
- pores
- alumina
- diameter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/882—Molybdenum and cobalt
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/613—10-100 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/633—Pore volume less than 0.5 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/63—Pore volume
- B01J35/635—0.5-1.0 ml/g
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/64—Pore diameter
- B01J35/647—2-50 nm
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
- C10G2300/10—Feedstock materials
- C10G2300/107—Atmospheric residues having a boiling point of at least about 538 °C
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
- Catalysts (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/187,685 US4328127A (en) | 1980-09-16 | 1980-09-16 | Residua demetalation/desulfurization catalyst |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS5781834A JPS5781834A (en) | 1982-05-22 |
JPH0249783B2 true JPH0249783B2 (en, 2012) | 1990-10-31 |
Family
ID=22690031
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP56144814A Granted JPS5781834A (en) | 1980-09-16 | 1981-09-16 | Hydrogenating de-metal desulfurizing catalyst and catalytic hydrogenating de-metal desulfurizing method for residual oil |
Country Status (3)
Country | Link |
---|---|
US (1) | US4328127A (en, 2012) |
JP (1) | JPS5781834A (en, 2012) |
CA (1) | CA1170246A (en, 2012) |
Families Citing this family (50)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4448677A (en) * | 1976-08-13 | 1984-05-15 | Mobil Oil Corporation | Catalyst and process for residua demetalation and desulfurization |
US4456700A (en) * | 1976-08-13 | 1984-06-26 | Mobil Oil Corporation | Catalyst for residua demetalation and desulfurization |
JPS601056B2 (ja) * | 1980-02-19 | 1985-01-11 | 千代田化工建設株式会社 | アスファルテンを含む重質炭化水素油の水素化処理 |
US4404097A (en) * | 1980-09-16 | 1983-09-13 | Mobil Oil Corporation | Residua demetalation/desulfurization catalyst and methods for its use |
US4431526A (en) * | 1982-07-06 | 1984-02-14 | Union Oil Company Of California | Multiple-stage hydroprocessing of hydrocarbon oil |
US4491639A (en) * | 1982-09-30 | 1985-01-01 | Gas Research Institute | Methods of making high activity transition metal catalysts |
US4460707A (en) * | 1982-12-28 | 1984-07-17 | Union Oil Company Of California | Hydroprocessing catalyst and method for preparing it |
US4548710A (en) * | 1982-12-28 | 1985-10-22 | Union Oil Company Of California | Hydrocarbon processing |
JPS59132945A (ja) * | 1983-01-21 | 1984-07-31 | Shokubai Kasei Kogyo Kk | 重質炭化水素油の水素化処理方法 |
CA1217756A (en) * | 1983-08-10 | 1987-02-10 | Hri, Inc. | Demetallization catalyst and process for metals- containing hydrocarbon feedstocks |
US4572778A (en) * | 1984-01-19 | 1986-02-25 | Union Oil Company Of California | Hydroprocessing with a large pore catalyst |
JPS59209649A (ja) * | 1984-04-20 | 1984-11-28 | Shokubai Kasei Kogyo Kk | 重質炭化水素の水素化脱メタル触媒 |
DE3581777D1 (de) * | 1984-09-12 | 1991-03-28 | Nippon Kokan Kk | Hydrierkatalysator fuer kohlenteer, methode zur hydrierung von kohlenteer mit dem katalysator, und methode zur herstellung von supernadelkoks aus dem hydrierungsprodukt von kohlenteer. |
US4657665A (en) * | 1985-12-20 | 1987-04-14 | Amoco Corporation | Process for demetallation and desulfurization of heavy hydrocarbons |
US4707466A (en) * | 1985-12-20 | 1987-11-17 | Amoco Corporation | Catalyst for demetallation and desulfurization of heavy hydrocarbons |
US4743572A (en) * | 1986-12-05 | 1988-05-10 | Mobil Oil Corporation | Magnesia-alumina-aluminum phosphate catalyst and catalyst product thereof |
US4729980A (en) * | 1987-04-27 | 1988-03-08 | Intevep, S.A. | Catalyst for the simultaneous hydrodemetallization and hydroconversion of heavy hydrocarbon feedstocks and process for preparing the catalyst |
US4810361A (en) * | 1987-05-18 | 1989-03-07 | Mobil Oil Corporation | Resid hydrotreating process using lanthana-alumina-aluminum phosphate catalyst |
US4880526A (en) * | 1987-09-24 | 1989-11-14 | Shell Oil Company | Hydrotreating catalysts prepared from hydrogels |
US4810684A (en) * | 1987-09-24 | 1989-03-07 | Shell Oil Company | Hydrotreating catalysts prepared from hydrogels |
US4880522A (en) * | 1987-09-24 | 1989-11-14 | Shell Oil Company | Process for hydrotreating hydrocarbon feeds |
US4880523A (en) * | 1987-09-24 | 1989-11-14 | Shell Oil Company | Process for hydrotreating hydrocarbon feeds |
US4810687A (en) * | 1987-09-24 | 1989-03-07 | Shell Oil Company | Hydrotreating catalysts prepared from hydrogels |
US4810686A (en) * | 1987-09-24 | 1989-03-07 | Shell Oil Company | Hydrotreating catalysts prepared from hydrogels |
US4820680A (en) * | 1987-09-24 | 1989-04-11 | Shell Oil Company | Hydrotreating catalysts prepared from hydrogels |
US4880525A (en) * | 1987-09-24 | 1989-11-14 | Shell Oil Company | Process for hydrotreating hydrocarbon feeds |
US4941964A (en) * | 1988-03-14 | 1990-07-17 | Texaco Inc. | Hydrotreatment process employing catalyst with specified pore size distribution |
US5266300A (en) * | 1989-08-02 | 1993-11-30 | Texaco Inc. | Method of making porous alumina |
US5192734A (en) * | 1991-10-25 | 1993-03-09 | W. R. Grace & Co.- Conn. | Hydroprocessing catalyst composition |
US5223472A (en) * | 1992-04-14 | 1993-06-29 | Union Oil Company Of California | Demetallation catalyst |
JP2996423B2 (ja) * | 1992-07-14 | 1999-12-27 | 株式会社コスモ総合研究所 | 炭化水素油の水素化処理用触媒 |
JP3955096B2 (ja) * | 1996-02-02 | 2007-08-08 | エクソンモービル リサーチ アンド エンジニアリング カンパニー | 選択的水素化脱硫触媒及び方法 |
CN1054393C (zh) * | 1997-07-22 | 2000-07-12 | 中国石油化工总公司 | 一种渣油加氢脱金属催化剂 |
US6387248B2 (en) | 1997-11-06 | 2002-05-14 | Texaco Inc. | Method of preparing a catalyst for use in the hydrotreating of high boiling hydrocarbon feedstocks |
US6197718B1 (en) * | 1999-03-03 | 2001-03-06 | Exxon Research And Engineering Company | Catalyst activation method for selective cat naphtha hydrodesulfurization |
US6589418B2 (en) * | 1999-03-03 | 2003-07-08 | Exxonmobil Research And Engineering Company | Method for selective cat naphtha hydrodesulfurization |
BRPI0601787B1 (pt) * | 2006-05-17 | 2016-06-07 | Petroleo Brasileiro Sa | processo de hidrodessulfurização seletiva de nafta |
MX2007009504A (es) * | 2007-08-07 | 2009-02-06 | Mexicano Inst Petrol | Catalizador para la primera etapa de hidrodesmetalizacion en un sistema de hidro procesamiento con reactores multiples para el mejoramiento de crudos pesados y extra-pesados. |
MX2009002359A (es) * | 2009-03-03 | 2010-10-01 | Mexicano Inst Petrol | Catalizador soportado en carbon para la desmetalizacion de crudos pesados y residuos. |
US8058203B2 (en) * | 2009-04-29 | 2011-11-15 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalyst and method for making thereof |
US7964524B2 (en) * | 2009-04-29 | 2011-06-21 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalyst and method for making thereof |
US7964526B2 (en) * | 2009-04-29 | 2011-06-21 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalyst and method for making thereof |
US8080492B2 (en) * | 2009-04-29 | 2011-12-20 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalyst and method for making thereof |
US7964525B2 (en) * | 2009-04-29 | 2011-06-21 | Chevron U.S.A. Inc. | Hydroconversion multi-metallic catalyst and method for making thereof |
CA2754870C (en) * | 2010-10-13 | 2019-11-05 | China Petroleum & Chemical Corporation | Ebullated bed hydrotreating process of heavy crude oil |
US9873797B2 (en) | 2011-10-24 | 2018-01-23 | Aditya Birla Nuvo Limited | Process for the production of carbon black |
MX350307B (es) | 2012-03-30 | 2017-09-04 | Aditya Birla Science And Tech Company Ltd | Proceso de obtención de polvo de negro de carbón con contenido de azufre reducido. |
RU2610525C1 (ru) * | 2015-12-09 | 2017-02-13 | Федеральное государственное бюджетное учреждение науки Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук | Способ деасфальтизации и деметаллизации тяжелого нефтяного сырья |
RU2699354C1 (ru) * | 2018-11-27 | 2019-09-05 | Федеральное государственное бюджетное учреждение науки "Федеральный исследовательский центр "Институт катализа им. Г.К. Борескова Сибирского отделения Российской академии наук" (ИК СО РАН) | Катализатор защитного слоя для переработки тяжелого нефтяного сырья и способ его приготовления |
RU2691069C1 (ru) * | 2018-12-27 | 2019-06-10 | Акционерное общество "Всероссийский научно-исследовательский институт по переработке нефти" (АО "ВНИИ НП") | Способ получения катализатора деметаллизации нефтяных фракций |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4082695A (en) * | 1975-01-20 | 1978-04-04 | Mobil Oil Corporation | Catalyst for residua demetalation and desulfurization |
JPS5423096A (en) * | 1977-07-22 | 1979-02-21 | Exxon Research Engineering Co | Hydrotreating catalyst and method of using it |
-
1980
- 1980-09-16 US US06/187,685 patent/US4328127A/en not_active Expired - Lifetime
-
1981
- 1981-07-22 CA CA000382275A patent/CA1170246A/en not_active Expired
- 1981-09-16 JP JP56144814A patent/JPS5781834A/ja active Granted
Also Published As
Publication number | Publication date |
---|---|
CA1170246A (en) | 1984-07-03 |
US4328127A (en) | 1982-05-04 |
JPS5781834A (en) | 1982-05-22 |
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