JPH0245605B2 - - Google Patents
Info
- Publication number
- JPH0245605B2 JPH0245605B2 JP57073456A JP7345682A JPH0245605B2 JP H0245605 B2 JPH0245605 B2 JP H0245605B2 JP 57073456 A JP57073456 A JP 57073456A JP 7345682 A JP7345682 A JP 7345682A JP H0245605 B2 JPH0245605 B2 JP H0245605B2
- Authority
- JP
- Japan
- Prior art keywords
- zeolite
- catalyst
- mixture
- ruthenium
- manganese
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000010457 zeolite Substances 0.000 claims description 69
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 63
- 229910021536 Zeolite Inorganic materials 0.000 claims description 61
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 claims description 55
- 239000003054 catalyst Substances 0.000 claims description 52
- 239000000203 mixture Substances 0.000 claims description 44
- 230000015572 biosynthetic process Effects 0.000 claims description 30
- 238000003786 synthesis reaction Methods 0.000 claims description 30
- 229930195733 hydrocarbon Natural products 0.000 claims description 26
- 150000002430 hydrocarbons Chemical class 0.000 claims description 26
- 239000003502 gasoline Substances 0.000 claims description 22
- KJTLSVCANCCWHF-UHFFFAOYSA-N Ruthenium Chemical compound [Ru] KJTLSVCANCCWHF-UHFFFAOYSA-N 0.000 claims description 21
- 229910052707 ruthenium Inorganic materials 0.000 claims description 21
- 239000011572 manganese Substances 0.000 claims description 14
- 238000004519 manufacturing process Methods 0.000 claims description 6
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052748 manganese Inorganic materials 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 238000000034 method Methods 0.000 description 53
- 239000007789 gas Substances 0.000 description 35
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 23
- -1 nuclear power Substances 0.000 description 18
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 16
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 12
- 229910002091 carbon monoxide Inorganic materials 0.000 description 12
- 239000007864 aqueous solution Substances 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 11
- 239000000377 silicon dioxide Substances 0.000 description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
- 229910052739 hydrogen Inorganic materials 0.000 description 10
- 239000001257 hydrogen Substances 0.000 description 10
- 239000003921 oil Substances 0.000 description 10
- 239000011148 porous material Substances 0.000 description 10
- 239000000843 powder Substances 0.000 description 10
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 9
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 9
- YBCAZPLXEGKKFM-UHFFFAOYSA-K ruthenium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[Ru+3] YBCAZPLXEGKKFM-UHFFFAOYSA-K 0.000 description 9
- 239000000243 solution Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 229910001868 water Inorganic materials 0.000 description 9
- 229910052751 metal Inorganic materials 0.000 description 8
- 239000002184 metal Substances 0.000 description 8
- 239000004215 Carbon black (E152) Substances 0.000 description 7
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000003245 coal Substances 0.000 description 6
- 238000011282 treatment Methods 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 150000001336 alkenes Chemical class 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 5
- 239000003350 kerosene Substances 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 238000009835 boiling Methods 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 238000005470 impregnation Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical compound CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000001993 wax Substances 0.000 description 4
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000002309 gasification Methods 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- IPJKJLXEVHOKSE-UHFFFAOYSA-L manganese dihydroxide Chemical compound [OH-].[OH-].[Mn+2] IPJKJLXEVHOKSE-UHFFFAOYSA-L 0.000 description 3
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000003345 natural gas Substances 0.000 description 3
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910000314 transition metal oxide Inorganic materials 0.000 description 3
- GIAFURWZWWWBQT-UHFFFAOYSA-N 2-(2-aminoethoxy)ethanol Chemical compound NCCOCCO GIAFURWZWWWBQT-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 229910021193 La 2 O 3 Inorganic materials 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 229910000323 aluminium silicate Inorganic materials 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N ammonia Natural products N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000007580 dry-mixing Methods 0.000 description 2
- 238000010304 firing Methods 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000008240 homogeneous mixture Substances 0.000 description 2
- 239000000543 intermediate Substances 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical group O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000002243 precursor Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 150000003304 ruthenium compounds Chemical class 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- CYNYIHKIEHGYOZ-UHFFFAOYSA-N 1-bromopropane Chemical compound CCCBr CYNYIHKIEHGYOZ-UHFFFAOYSA-N 0.000 description 1
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910052684 Cerium Inorganic materials 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 229910052776 Thorium Inorganic materials 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 238000005804 alkylation reaction Methods 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000010426 asphalt Substances 0.000 description 1
- GBDZMMXUOBAJMN-UHFFFAOYSA-K azane;ruthenium(3+);trichloride Chemical compound N.N.N.N.N.N.[Cl-].[Cl-].[Cl-].[Ru+3] GBDZMMXUOBAJMN-UHFFFAOYSA-K 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000005341 cation exchange Methods 0.000 description 1
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000002734 clay mineral Substances 0.000 description 1
- 239000003034 coal gas Substances 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 239000002283 diesel fuel Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 229910052675 erionite Inorganic materials 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229910001657 ferrierite group Inorganic materials 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 239000002737 fuel gas Substances 0.000 description 1
- 239000000295 fuel oil Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- GPRLSGONYQIRFK-UHFFFAOYSA-N hydron Chemical compound [H+] GPRLSGONYQIRFK-UHFFFAOYSA-N 0.000 description 1
- 238000001027 hydrothermal synthesis Methods 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- ICAKDTKJOYSXGC-UHFFFAOYSA-K lanthanum(iii) chloride Chemical compound Cl[La](Cl)Cl ICAKDTKJOYSXGC-UHFFFAOYSA-K 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 150000002697 manganese compounds Chemical class 0.000 description 1
- PPNAOCWZXJOHFK-UHFFFAOYSA-N manganese(2+);oxygen(2-) Chemical class [O-2].[Mn+2] PPNAOCWZXJOHFK-UHFFFAOYSA-N 0.000 description 1
- 150000002736 metal compounds Chemical class 0.000 description 1
- 229910052680 mordenite Inorganic materials 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000002006 petroleum coke Substances 0.000 description 1
- 238000004525 petroleum distillation Methods 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229910052703 rhodium Inorganic materials 0.000 description 1
- 239000010948 rhodium Substances 0.000 description 1
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 description 1
- 239000003079 shale oil Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 235000011121 sodium hydroxide Nutrition 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000011269 tar Substances 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- OSBSFAARYOCBHB-UHFFFAOYSA-N tetrapropylammonium Chemical class CCC[N+](CCC)(CCC)CCC OSBSFAARYOCBHB-UHFFFAOYSA-N 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Description
æ¬çºæã¯ãäžé
žåççŽ ãšæ°ŽçŽ ãšã®æ··åã¬ã¹ïŒä»¥äž
åæã¬ã¹ãšããïŒããå質ã®åªããã¬ãœãªã³æ²žç¹
ç¯å²ã®çåæ°ŽçŽ ãé«åçã§åŸãæ¹æ³ã«é¢ããç¹ã«
該æ¹æ³ã«äœ¿çšããã«é©ãã觊åªãæäŸãããšãã
ãã®ã§ããã çŸåšããšãã«ã®ãŒã®äžå¿ãå ããŠããç³æ²¹ãã
ããç°å¢ã¯éåžžã«äžå®å®ã§ããã1980幎代åŸåã
ã1990幎代ã«ãããŠã¯ç³æ²¹äžè¶³ãããšãã«ã®ãŒã®
è°·éãæ¥ãããšãææ ®ãããŠããããã®ããç³æ²¹
ã®æ¶è²»ã®ç¯çŽããããããšãšãã«ãç³çãåå
åãLNGãªã©ã®ç³æ²¹ä»£æ¿ãšãã«ã®ãŒã§å¯Ÿå¿ãã
ããšãèããããŠããããã®ãããããåœã§ã¯ã
ä»åŸçžå¯Ÿçã«é«ãéèŠã®äŒžã³ã瀺ããšäºæ³ãããŠ
ããã¬ãœãªã³ãç¯æ²¹ã軜油ãéæ²¹çã®äŸçµŠäžè¶³
ããç³æ²¹ä»¥å€ã®ççŽ æºãäŸãã°ç³çåã¯å€©ç¶ã¬ã¹
çãã補é ããæ°æè¡ã®éçºã«é¢å¿ãåããããŠ
ããããã®ãã¡ç³çããçåæ°ŽçŽ æ²¹ã補é ããæ¹
æ³ãšããŠã¯ãçŽæ¥æ³ã§ããç³çã®æ¶²ååã³éæ¥æ³
ã§ããåæã¬ã¹ãçµæ²¹ãã補é æ¹æ³ãç¥ãããŠã
ããåè ã¯æ«ã ç 究éçºéçšã«ãããçŸç¶ã§ã¯è£œ
åã®è³ªãå£ããšãšãã«çµæžæ§ãå£ããäžæ¹åŸè ã
ãã§ã«åã¢ããªã«SASOL瀟ã§ç³çã®ã¬ã¹åãã
ã»ã¹ãšãã€ãã·ã€ãŒã»ãããã·ãŠããã»ã¹ãçµå
ããSASOLæ³ã®å®çšé転ããªãããŠããã ãã®ããã«ç³çã倩ç¶ã¬ã¹åã¯ã¢ã¹ãã¢ã«ãç
ã®ã¬ãœãªã³ãç¯æ²¹ã軜油ãžã®çŽæ¥è»¢åãå°é£ãªç
çŽ å«æç©ãã¬ã¹åã«ãã€ãŠäžé žåççŽ ãšæ°ŽçŽ ãšã®
æ··åã¬ã¹ã«å®¹æã«è»¢åã§ããããšã¯å ¬ç¥ã§ããã
ãŸããã®æ··åã¬ã¹ãé©åœãªè§Šåªã®ååšäžã§æ¥è§Šã
ããããšã«ããçåæ°ŽçŽ æ··åç©ãžè»¢åã§ããããš
ãå ¬ç¥ã§ããã äŸãã°ããã€ãã·ã€ã»ãããã·ãŠæ³ã¯éãã³ã
ã«ããããã±ã«ãã«ãããŠã ãããªãŠã åã³ããž
ãŠã ã«åºã¥ã觊åªã®ååšäžã§åæã¬ã¹ããçåæ°Ž
çŽ æ··åç©ã補é ããããšã§ç¥ãããŠãããããã®
æ¹æ³ã§ã¯ãåå¿çæç©ãã¡ã¿ã³ããã¯ãã¯ã¹ã«è³
ãå¹ åºãçåæ°ŽçŽ æ··åç©ïŒãã©ãã€ã³ããªã¬ãã€
ã³ïŒãšåçš®ã®å«é žçŽ ååç©ïŒã¢ã«ã³ãŒã«ããšãŒã
ã«çïŒã§ããã䟡å€ã®ããç¹å®æ²žç¹ç¯å²ã®çæç©
ãéžæçã«åŸãããšã¯ã§ããããããã€ãŠãæã
䟡å€ã®é«ãã¬ãœãªã³çåã®åçã¯å åã§ãªãããŸ
ããã®ã¬ãœãªã³çåäžã«ã¯è³éŠæãé«åºŠã«æåã
ãããã©ãã€ã³åã¯ãªã¬ãã€ã³ãã»ãšãã©å«æã
ãªãããããªã¯ã¿ã³äŸ¡ãäœããèªåè»ã¬ãœãªã³ãš
ããŠã¯äŸ¡å€ãäœãã äžæ¹åæã¬ã¹ãäžé žåççŽ éå 觊åªãšæ¥è§Šã
ãã次ãã§çæç©ãå¥ã®åã¯åäžåå¿åšã§ç¹å®ã®
ã¿ã€ãã®ãŒãªã©ã€ã觊åªãšæ¥è§Šãããããšã«ã
ããåæã¬ã¹ãé«ãªã¯ã¿ã³äŸ¡ã®ã¬ãœãªã³çåãäž»
äœãšããçæç©ã«è»¢åããæ¹æ³ãæããã«ãããŠ
ãããããã§çšãããäžé žåççŽ éå 觊åªã¯ãã¡
ã¿ããŒã«åæ觊åªåã¯ãã€ãã·ã€ãŒã»ãããã·ãŠ
åæ觊åªã§ãããã¡ã¿ããŒã«åæ觊åªã§ã¯åæã¬
ã¹ãäžåºŠã¢ã«ã³ãŒã«çã®å«é žçŽ ååç©ã«è»¢åãã
åŸããŸããã€ãã·ã€ã»ãããã·ãŠåæ觊åªã§ã¯å
æã¬ã¹ãã¡ã¿ã³ããã¯ãã¯ã¹ãŸã§ã®å·Ÿåºãçåæ°Ž
çŽ æ··åç©åã³å«é žçŽ ååç©ãšã«è»¢åããåŸããã
ãã®çæç©ã次ã«ç¹å®ã®çŽ°ååŸãæãããŒãªã©ã€
ã觊åªãšæ¥è§Šãããé«ãªã¯ã¿ã³äŸ¡ã®ã¬ãœãªã³çå
ãåçãã補é ããïŒæ®µè»¢åæ¹æ³ã§ããã æè¿ãåæã¬ã¹ããïŒæ®µæ³ã§ç¹å®ã®æ²žç¹ç¯å²ã®
çåæ°ŽçŽ ãéžæçã«è£œé ããæ¹æ³ãèŠåºãããã
ãã®æ¹æ³ã®ïŒã€ã¯ïŒæ®µæ³ã§çšããäžé žåççŽ éå
觊åªãšç¹å®ãªãŒãªã©ã€ããšãæ©æ¢°çã«æ··åãã觊
åªãçšããæ¹æ³ã§ãããä»ã®ïŒã€ã¯ç¹å®ã®ãŒãªã©
ã€ãã«äžé žåççŽ éå éå±ïŒåã¯éå±é žåç©ïŒã
æ æããã觊åªãçšããæ¹æ³ã§ããã ãããã®æ¹æ³ã«ãããŠãçæç©ã¯è§Šåªãæ§æã
ãç¹å®ã®çŽ°åãæãããŒãªã©ã€ãã®åœ¢ç¶çå¶çŽã
åãã现ååŸãã倧ããªååãµã€ãºã®çæç©ã¯ã»
ãšãã©çæãããã¬ãœãªã³æ²žç¹ç¯å²ä»¥äžã®ååãµ
ã€ãºã®å°ããªçåæ°ŽçŽ ãéžæçã«è£œé ã§ãããšã
ãæ¹åããªãããã ïŒæ®µæ³ã¯ïŒæ®µæ³ã«ããã¹å·¥çšãç°¡ç¥åãããã
ããããçµæžçãªããã»ã¹ãšæãããããåèšã®
æ©æ¢°çæ··å觊åªãçšããïŒæ®µæ³ã¯ïŒæ®µæ³ã«æ¯èŒ
ããäžé žåççŽ ã®è»¢åçã¯äœããªããšãšãã«ãã¬
ãœãªã³åçãäœäžããäžæ¹çæã¬ã¹ãšããŠããè©
䟡ã§ããªãã¡ã¿ã³ãå€ãçæãããšãã觊åªæ§èœ
äžã®å€§ããªæ¬ ç¹ãããããŸãç¹å®ã®ãŒãªã©ã€ãã«
ãã€ãã·ã€ãŒãããã·ãŠæŽ»æ§ã瀺ãéå±ãæ æã
ã觊åªãçšããïŒæ®µæ³ãããããã®æ¹æ³ã¯åæã¬
ã¹ã觊åªçµæç©äžã®éå±æåã§ãã€ãã·ã€ãŒãã
ããã·ãŠåå¿ãè¡ãããã¡ã¿ã³ããã¯ãã¯ã¹ã«è³
ãå·Ÿåºãçåæ°ŽçŽ æ··åç©ãäžéäœãšããŠè£œé ãã
åŸã次ã«ã¯ãã¯ã¹ã®å解ã«æå¹ã§ããããšãç¥ã
ããŠãã圢ç¶éžææ§ãŒãªã©ã€ããããªãã¡ZSM
âïŒãŒãªã©ã€ãæåã§ããããçåæ°ŽçŽ ãã¬ãœãª
ã³ä»¥äžã®çåæ°ŽçŽ ã«è»¢åããããšãæå³ãããã®
ã§ããããã®çš®ã®è§ŠåªãšããŠã¯ç¹éæ50â142502
ã§ç€ºãããããã«ãZSMâïŒãŒãªã©ã€ãã«éå
ã¯ã«ãããŠã ãå«æµžã調補ãããã®ã§ããããã
ãåè ã®ZSMâïŒïŒé觊åªã§ã¯è»¢åçã¯æ¯èŒç
é«ãããäžé žåççŽ ã¯äºé žçåçŽ ã«è»¢åããå²å
ãå€ããšãšãã«ãçæããçåæ°ŽçŽ ã¯ã¡ã¿ã³ãäž»
ã§C5 +ã¬ãœãªã³çåã®åçã¯å£ãããŸãåŸè ã®
ZSMâïŒïŒã«ãããŠã 觊åªã¯ãåè ããC5 +ã¬ãœ
ãªã³çåã®åçã¯é«ãããçµæçã«æ¥éã«æŽ»æ§ã
äœäžããå®çšäžã®æ¬ ç¹ããããå ããŠ50KgïŒcm2以
äžã®é«ãåå¿å§åãå¿ èŠãšããããŸãé žåé°å²æ°
ã§å ç±ããããšã«ãã掻æ§ã倱ãããã觊åªåç
ãå°é£ã§ããã ããã§æ¬çºæè ãã¯ããããã®æ¬ ç¹ã解決ãã
ãããåèšåœ¢ç¶éžææ§ãæãããŒãªã©ã€ããšäžé ž
åççŽ ãæ°ŽçŽ åãã掻æ§éå±åã¯éå±ååç©ãšã®
çµåãã«ã€ããŠéæå®éšæ€èšãéããçµæããŒãª
ã©ã€ããšäŸ¡æ°ãïŒãïŒã®ãã³ã¬ã³ã®é žåç©ãããª
ãæ··åç©ã«ã«ãããŠã ãæ æãã觊åªçµæç©åã¯
ã«ãããŠã ãæ æãããã³ã¬ã³é žåç©ãšçµæ¶æ§ãŒ
ãªã©ã€ããšã®æ··åç©ãããªã觊åªçµæç©ããåæ
ã¬ã¹ããé«ãªã¯ã¿ã³äŸ¡ã¬ãœãªã³çåãåŸãã®ã«æ¥µ
ããŠæå¹ãªããšãèŠåºããæ¬çºæãå®æããã«è³
ã€ãã ããªãã¡ãæ¬çºæã¯ãåæã¬ã¹ããçåæ°ŽçŽ ã
補é ããæ¹æ³ã«ãããŠããã³ã¬ã³ã®äŸ¡æ°ãïŒãïŒ
ã®ç¯å²ã«ãããã³ã¬ã³ã®é žåç©ãšçµæ¶æ§ãŒãªã©ã€
ããšãããªãæ··åç©ã«ã«ãããŠã ãæ æãã觊åª
çµæç©åã¯ã«ãããŠã ãæ æããäžèšãã³ã¬ã³ã®
é žåç©ãšçµæ¶æ§ãŒãªã©ã€ããšã®æ··åç©ãããªã觊
åªçµæç©ã®ååšäžã§ãåæã¬ã¹ãå§å10ã100
KgïŒcm2ã枩床200ã400âã®æ¡ä»¶ã§æ¥è§Šãããç
æçåæ°ŽçŽ äžã®ççŽ æ°ïŒä»¥äžã®ã¬ãœãªã³çåã®å²
åã60ééïŒ ä»¥äžã®çåæ°ŽçŽ ã補é ããããšãç¹
城ãšããçåæ°ŽçŽ ã®è£œæ³ã§ããã 次ã«æ¬çºæã«ãã觊åªã®è£œé æ¹æ³åã³ããã觊
åªãšããŠäœ¿çšãã転åæ¹æ³ã«ã€ããŠèª¬æããã ããã§çšãããŒãªã©ã€ããšã¯çµæ¶æ§ã¢ã«ããã·
ãªã±ãŒãåã¯çµçµæ¶æ§ã¢ã«ããã·ãªã±ãŒãã®ã¢ã«
ãããŠã ã®äžéšåã¯å šéšãä»ã®éå±ãäŸãã°éã
ã¯ãã ããããžãŠã ããã¹ãã¹ãã©ã³ã¿ã³ãã»ãª
ãŠã ããã¿ã³çã®äžäŸ¡ã®éå±ã«æ¿ããŠåæããã
ãã®ããŸããã¢ã«ãããæ®ãã©å«æãã90ïŒ ä»¥äž
ãã·ãªã«ãããªãç©è³ªãå«ãããããã®ãŒãªã©ã€
ãã¯é垞倩ç¶ã«æ°å€ãååšããããåæã«ãã€ãŠ
ã補é ã§ãããäžè¬ã«è»¢ååå¿ã«çšãããŒãªã©ã€
ãã¯çŽ°ååŸãçŽïŒâ«ã®ãšãªãªãã€ãããªãã¬ã¿ã€
ããããšãªãšã©ã€ãã现ååŸãçŽïŒâ«ã®ããªãŒãž
ã€ãµã€ãåã®ïŒžåã¯ïŒ¹ãŒãªã©ã€ããšãã¢ã«ããã€
ãã®ã»ã现ååŸãïŒãïŒâ«ã®äžéç现åãæãã
ãã€ã·ãªã«å¯Ÿã¢ã«ããæ¯ã12以äžã®ZSMâïŒã·
ãªãŒãºã®ãŒãªã©ã€ããç¥ãããŠããããæ¬çºæã«
ãããŠã¯ããããã®ãŒãªã©ã€ãã䜿çšã§ããã 现ååŸãçŽïŒâ«ã®ãŒãªã©ã€ãã§ã¯çæããçå
æ°ŽçŽ ã¯ååãµã€ãºãçŽïŒâ«ä»¥äžã®çŽéã®ãã©ãã€
ã³ããªã¬ãã€ã³åã¯ççŽ æ°ãïŒä»¥äžã®è»œè³ªçåæ°Ž
çŽ ãšãªããããç³æ²¹ååŠåæãšããŠæçšãªããšã
ã¬ã³ããããã¬ã³ãããã¬ã³çã®äœçŽãªã¬ãã€ã³
ãåŸãå Žå奜ãŸãããŒãªã©ã€ããšãªãããããã¬
ãœãªã³çåã®åçãé«ããããã«ã¯ããããã®ç
æç©ãã¬ãœãªã³ã«è»¢åããããããªãµã€ã¯ã«ãè¡
ããåã¯å ¬ç¥ã®ã¢ã«ãã«ååå¿çã®åŠçã«äŸãã
ããã现ååŸãïŒâ«ä»¥äžã®ãŒãªã©ã€ãã§ã¯çæç©
ãã¬ãœãªã³çå以äžã®çåæ°ŽçŽ ã°ããã§ãªãç¯
æ²¹ã軜油çåããçæããã®ã§ç¯æ²¹ã軜油ã䜵ç£
ããå¿ èŠã®ããå Žåéžæãããã 现ååŸãïŒãïŒâ«ã®ãŒãªã©ã€ãã¯ã¬ãœãªã³çå
ãé«åçã§åŸãå Žåæã奜ãŸãããŒãªã©ã€ãã§ã
ãããã®çš®ã®ãŒãªã©ã€ããšããŠã¯ã·ãªã«å¯Ÿã¢ã«ã
ãã¢ã«æ¯ã12以äžã®ZSMâïŒïŒZSMâ11ïŒZSM
â12ïŒZSMâ21ãZSMâ35ïŒZSMâ38ãªã©ã®ã¢
ãŒãã«ãªã€ã«ç€Ÿã®éçºããZSMã·ãªãŒãºã®ãŒãª
ã©ã€ãã®ã»ããã·ãšã«ã»ã€ã³ã¿ãŒãã·ãšãã«ã»ãª
ãµãŒã瀟ã®éçºããã·ãªã«âéâã¢ã«ããããæ
ãZSMâïŒãšé¡äŒŒã®ïŒžç·ååãã¿ãŒã³ãäžãã
ãŒãªã©ã€ããããã«ã¯è£œé æ¹æ³ãç°ãªããç·å
æãã¿ãŒã³ãZSMâïŒãšåãã§ããZSMâïŒã¿
ã€ãã®çµæ¶æ§ãŒãªã©ã€ãããŸãäžèšãŒãªã©ã€ãã®
ã¢ã«ããã®äžéšåã¯å šéšãä»ã®äžäŸ¡ã®éå±ã§ä»£æ¿
ããããŒãªã©ã€ããå«ãŸããããã®çš®é¡ã§ã¯ããŒ
ãªã©ã€ãåææã«ã·ãªã«æºãã¢ã«ããæºãã¢ã«ã«
ãªæºã®ã»ãã«ææ©è©ŠéšãšããŠããã©ãããã«ã¢ã³
ã¢ããŠã å¡©ãææ©ã¢ãã³ãã¢ã«ã³ãŒã«ã¢ãã³åã¯
ãžã°ãªã³ãŒã«ã¢ãã³åã³ãããã®åé§ç©è³ªã®ååš
äžã§æ°Žç±åæåå¿ãè¡ã€ãŠåŸããããŒãªã©ã€ãã
奜ãŸãã䜿çšã§ããã çµæ¶æ§ãŒãªã©ã€ãã¯éåžžãéœã€ãªã³ãšããŠãã
ãªãŠã ãã«ãªãŠã ãåã¯ææ©çªçŽ éœã€ãªã³ãå«ã
ããæ¬çºæã®è»¢ååå¿ã«äœ¿çšããã«ã¯ããããã®
éœã€ãªã³ã®å°ãªããšã50ïŒ ä»¥äžãæ°ŽçŽ ã€ãªã³ãã¢
ã³ã¢ããŠã ã€ãªã³ãã¢ã«ã«ãªåé¡ã€ãªã³ãåžåé¡
ã€ãªã³ãé·ç§»éå±ã€ãªã³çã§äº€æãé žæ§ç¹ãçºçŸ
ãããã®ã奜ãŸãããéåžžãã®éœã€ãªã³äº€æåŠç
ã¯äº€æããéœã€ãªã³ãå«ã氎溶液ã§åŠçããå ¬ç¥
ã®ã€ãªã³äº€ææè¡ã§éæã§ãããåææ©çªçŽ éœã€
ãªã³ãå«ããã®ã§ã¯ç©ºæ°äžã§400ã700âã®ç¯å²ã§
å ç±ãææ©çªçŽ éœã€ãªã³ãå解ãçŒæããããšã«
ãã容æã«æ°ŽçŽ ã€ãªã³åã«ãªã掻æ§åãããã 次ã«ãŒãªã©ã€ããšäŸ¡æ°ãïŒãïŒã®ãã³ã¬ã³é žå
ç©ãšã®æ··åæ¹æ³ã§ãããããã®æ¹æ³ã¯éèŠãªæäœ
ã§ãããäž¡è ãåäžãªæ··åç©ãäœãããã«èª¿è£œã
ãªããã°ãªããªããæ¹æ³ãšããŠã¯å«æµžãã²ã«æ··å
åã¯ä¹ŸåŒæ··åãªã©ãå©çšã§ããã å«æµžæ³ã§ã¯ãã³ã¬ã³ã®æ°Žæº¶æ§ã®å¡©ãäŸãã°ç¡
é žãã³ã¬ã³ãå«æãã氎溶液ã«ãŒãªã©ã€ãã浞挬
ããéåžžã®å«æµžæ³ãå©çšã§ããåã²ã«æ··åæ³ã§
ã¯äºã調補ããæ°Žé žåãã³ã¬ã³ã®ã²ã«ããŒãªã©ã€
ãã®ç²æ«ãšæ··åããæ¹æ³ãååèšãã³ã¬ã³ã®æ°Ž
溶æ§ã®å¡©ãå«æãã氎溶液ã«ãŒãªã©ã€ãã®ç²æ«ã
ããã ããããããã«ã¢ã³ã¢ãã¢æ°Žçã®ã¢ã«ã«ãª
ãå ããã³ã¬ã³ãã²ã«åããäž¡è ã®åäžæ··åç©ã
åŸãæ¹æ³ããå也åŒæ··åã§ã¯åŸ®ç²æ«ç¶ã®ãã³ã¬
ã³é žåç©ãšãŒãªã©ã€ããšãããã€ã¶ããªããæ··å
ããæ¹æ³ã䜿çšã§ããã ãªãã以äžã®ããã«ããŠäœã€ããŒãªã©ã€ããšã
ã³ã¬ã³ã®ååç©ãšã®æ··åç©ïŒïŒã¯300ã600
âã§çŒæããããã®ãã®ã¯å¿ ããçŒæãèŠããª
ãããçŒæããŠãæªåœ±é¿ã¯ãªãã äžèšãã®ãã³ã¬ã³ã®é žåç©ã¯Mn2O3åã¯
MnO2ã§ãããMn2O3ïŒMnO2ã¯çŒææ¡ä»¶ïŒæž©åºŠïŒ
ã«ãã€ãŠæ±ºå®ãããã 以äžã®æ¹æ³ã§åŸããããŒãªã©ã€ããšäŸ¡æ°ãïŒã
ïŒã®ãã³ã¬ã³é žåç©ãšã®æ··åç©ã«çµã¿åãããã«
ãããŠã ã«ã€ããŠã§ããããé垞氎溶æ§ã®ããã²
ã³åç©åã¯ã¢ã³ãã³é¯å¡©ãšããŠå®¹æã«å ¥æã§ãã
ãã®ã䜿çšã§ããäŸãã°ãå¡©åã«ãããŠã ããã
ãµã¢ã³ãã³ã«ãããŠã âããªã¯ãã©ã€ããªã©ã䜿
çšã§ããã åãæ æã®æ¹æ³ãéåžžã®å«æµžæè¡ãå©çšã§ã
ããäŸãã°ããŒãªã©ã€ããšäŸ¡æ°ãïŒãïŒã®ãã³ã¬
ã³é žåç©ãšã®æ··åç©ãç²æ«ã®ãŸãŸããããã¯ãäž
æŠæ圢ãããããã«ãããŠã ååç©ã®æ°Žæº¶æ¶²åã¯
ã¢ã»ãã³ãªã©ã®æº¶å€ã«æº¶ãããé氎溶液äžã«æµžæŒ¬
ããå«æµžãæ æããæ¹æ³ãå©çšã§ããã ãã®å Žåã觊åªãæ圢ããéã«ãã·ãªã«ãã¢ã«
ããããã³å€©ç¶ç²åé±ç©ãªã©ãæ·»å ããããšã¯è§Š
åªã®æ§èœãæãªããªããããã®éã§ããã°ããã€
ãããªãã ãŸãã«ãããŠã ãæ æãã䟡æ°ãïŒãïŒã®ãã³
ã¬ã³é žåç©ã«ãŒãªã©ã€ããæ··åãã觊åªã調補ã
ãå Žåã«ã¯ãå ã埮ç²æ«ç¶ã®äŸ¡æ°ãïŒãïŒã®ãã³
ã¬ã³é žåç©ãã«ãããŠã ååç©ã®æº¶æ¶²ãäŸãã°å¡©
åã«ãããŠã ããããµã¢ã³ãã³ã«ãããŠã ã¯ãã©
ã€ããªã©ãå«æãã氎溶液ã«æµžæŒ¬ãã也ç¥ãæ æ
ããåŸããŒãªã©ã€ãç²æ«ãšç©ççã«ãäŸãã°æ©æ¢°
çããã€ã¶ããŠãæ··åããæ¹æ³ãå©çšã§ããã 觊åªçµæäžã®ãŒãªã©ã€ããšäŸ¡æ°ãïŒãïŒã®ãã³
ã¬ã³é žåç©ãšã®å²åã¯éèŠã§ããã䟡æ°ãïŒãïŒ
ã®ãã³ã¬ã³é žåç©ãšããŠã®å²åã¯ããŒãªã©ã€ããš
䟡æ°ãïŒãïŒã®ãã³ã¬ã³é žåç©ã®åèšã«å¯ŸããïŒ
ã95ééïŒ ã奜é©ã«ã¯30ã70ééïŒ ã§ããããã
ã«æ æããã«ãããŠã ã¯éå±ãšããŠãåãããŒãª
ã©ã€ããšäŸ¡æ°ãïŒãïŒã®ãã³ã¬ã³é žåç©ã®åèšã«
察ããŠ0.05ã10ééïŒ ã奜ãŸããã¯0.5ãïŒéé
ïŒ ã§ããããã®å ŽåããŒãªã©ã€ãã®å²åãå°ãªã
ãšããªã¯ã¿ã³äŸ¡ã®é«ãå質ã®åªããã¬ãœãªã³ãã
ããã¯äœçŽãªã¬ãã€ã³ãç¯è»œæ²¹ãªã©ãææããç
åæ°ŽçŽ ãåŸãããšãå°é£ã«ãªããäžæ¹äŸ¡æ°ãïŒã
ïŒã®ãã³ã¬ã³é žåç©ãå°ãªããšãåæã¬ã¹ã®çå
æ°ŽçŽ ãžã®è»¢åçãäœäžããã åãæ¬çºæã®è§Šåªã¯ããŒãªã©ã€ããšäŸ¡æ°ãïŒã
ïŒã®ãã³ã¬ã³é žåç©åã³ã«ãããŠã ãããªãããš
ãç¹åŸŽãšããŠãããããã³ã¬ã³é žåç©ã®ã»ãã«
éãã³ãã«ãããããžãŠã ããã¿ã³ãªã©ã®é·ç§»é
å±é žåç©ãäžçš®åã¯äºçš®ä»¥äžäžç·ã«å«æãããŠã
ããããã®å Žåãé·ç§»éå±é žåç©ãå«æãããæ¹
æ³ã¯ãŒãªã©ã€ãã«äŸ¡æ°ãïŒãïŒã®ãã³ã¬ã³é žåç©
ãå«æãããåè¿°ã®æ¹æ³ãå©çšã§ããäŸãã°é·ç§»
éå±é žåç©ãšããŠé žåéã也åŒæ··åæ³ã«ããå«æ
ãããå Žåã¯ãŒãªã©ã€ãç²æ«ãšäŸ¡æ°ãïŒãïŒãã³
ã¬ã³é žåç©ã®ç²æ«åã³é žåéã®ç²æ«ãäžç·ã«æ··å
ããä¹³é¢ã§ããã€ã¶ããªããåäžã«æ··åããæ¹æ³
ã䜿çšã§ããã ãã®çºæã®æ¹æ³ã«ãããŠåæã¬ã¹ãšãªãåæã¬
ã¹ã¯ç³çã倩ç¶ã¬ã¹ãç³æ²¹ã³ãŒã¯ã¹ãé 岩油ãã¿
ãŒã«ãµã³ãåã¯ç³æ²¹èžçããã®æ®æž£æ²¹ãªã©ã®åç³
çæãå ¬ç¥ã®ã¬ã¹ååå¿ãäŸãã°éšåé žååå¿å
ã¯ã¹ããŒã ãªããªãŒãã³ã°åå¿ãªã©ã«ããä»»æã«
補é ããããååæã¬ã¹ã®åé§ç©è³ªã§ããäžé žå
ççŽ ãšã¹ããŒã ãšã®æ··åç©ãæãã¯äºé žåççŽ ãš
æ°ŽçŽ ãšã®æ··åç©ã䜿çšããããšãã§ãããæŽã«ã¯
çæç©äžã®æ¶²ç¶çåæ°ŽçŽ çåãé€å»ããæªåå¿ã¬
ã¹æ··åç©ãååæã¬ã¹ãšããŠäœ¿çšã§ãããåæã¬
ã¹äžã®æ°ŽçŽ ãšäžé žåççŽ ãšã®æ¯çã¯ã¬ã¹åããã
ççŽ æºã«ããå€åããããæ¬è»¢ååå¿ã®ããã«
ã¯ããã®æ¯çã¯0.2ã6.0ã®ç¯å²ã«ããããšã奜é©
ã§ããã åæã¬ã¹ã¯è§Šåªãš200ã400âã®æž©åºŠã10ã100
KgïŒcm2ã®å§ååã³è§Šåªäœç©åœãïŒæéæšæºæž©
床ãå§åã§çŽ100ã10000ã®åæã¬ã¬ã¹äœç©ã®
GHSVïŒã¬ã¹åºæºç©ºå¡é床ïŒã§æ¥è§Šåå¿ãè¡ãã ãŸããæ¬çºæã¯åºå®åºã¿ã€ãã ãã§ãªããæµå
åºã液çžã¹ã©ãªãŒã¿ã€ãã®ãªã¢ã¯ã¿ãŒã§è¡ãããš
ãã§ããã 次ã«æ¬çºæãå®æœäŸã«ããå ·äœçã«èª¬æããã
æ¬çºæã¯ãã®èŠæšãè¶ããªããããéå®ãããã
ã®ã§ã¯ãªãã ãå®æœäŸ ïŒã é«ã·ãªã«ãŒãªã©ã€ãã次ã®ããã«ããŠåæã
ãã ã³ãã€ãã«ã·ãªã«ãã¢ã«ãã³é žãœãŒããèæ§ãœ
ãŒãåã³æ°Žã10Na2Oã»Al2O3ã»80SiO2ã»
1300H2Oã®ã¢ã«æ¯ã«ãªãããã«èª¿åããããã«
ææ©è©Šè¬ãšããŠãžã°ãªã³ãŒã«ã¢ãã³ãã¢ã«ããã®
ã¢ã«æ°ã®18åå ãããæ··åããã®ã¡ãã¹ãã³ã¬ã¹
補3lãªãŒãã¯ã¬ãŒãã«åŒµèŸŒãã ãé»æ°ããŒã¿ã§
åŸã ã«æž©åºŠãäžããèªçå§åäž160âã®æž©åºŠã«é
ãããïŒç®éå ç±ãç¶ãããã®åŸèªç¶å·åŽããã
çæããçœè²åŸ®çŽ°çµæ¶ç©ãéããæŽæµæ°Žã®PHã
çŽïŒã«ãªããŸã§å åæ°ŽæŽãã次ã«30âã§ïŒæé也
ç¥ããããã®çµæ¶ç©è³ªã¯ååŠåæã®çµæããããª
ãŠã 1.8ééïŒ ãçªçŽ 0.8ééïŒ ãå«æããã·ãªã«
察ã¢ã«ããæ¯ã¯63ã§ãã€ãã ãŸãç·åæåæã«ããã°åæãã¿ãŒã³ã¯
ZSMâïŒãŒãªã©ã€ãã«é¡äŒŒããŠããã ãã®é«
ã·ãªã«ãŒãªã©ã€ãã¯ã次ã«é žåãŒãªã©ã€ããšãã
ãã以äžã®ã€ãªã³äº€æåŠçãè¡ã€ãã ãŒãªã©ã€ã500gã4Nã®å¡©åã¢ã³ã¢ããŠã 氎溶
液ïŒãšãšãã«ïŒæé沞ãšããããéãæ°ŽæŽ
åŸãæ°ããå¡©åã¢ã³ã¢ããŠã 氎溶液ã䜿çšããŠã
åã³åãåŠçãïŒåç¹°è¿ããŒãªã©ã€ãäžã®å€§éšå
ãã¢ã³ã¢ããŠã ã€ãªã³ã«äº€æãããããã130â
ã§ïŒæé也ç¥ã550âã§ïŒæéçŒæãããšã¢ã³ã¢
ããŠã ã€ãªã³ã¯æ°ŽçŽ ã€ãªã³ã«ããŸãææ©çªçŽ éœã€
ãªã³ã¯ççŒé€å»ãããæ°ŽçŽ ã€ãªã³ã«ããããå€æ
ãããçµæãšããŠãããªãŠã éã¯0.01ééïŒ ãŸã§
æžå°ããã ãã®ïŒšåé«ã·ãªã«ãŒãªã©ã€ã20gãç¡é žãã³ã¬
ã³80.8gãå«æãã氎溶液äžã«æ·»å ããããæ¹æ
ããªãã3Nã®ã¢ã³ã¢ãã¢æ°Žã溶液ã®PHã9.0ã«ãª
ããŸã§å ãæ°Žé žåãã³ã¬ã³ã®ã²ã«ã圢æãããã
ãã®æ··åã²ã«ã¯éåŸå åæ°ŽæŽãããã®åŸã130
âïŒæé也ç¥ç¶ããŠ500âã§ïŒæéçŒæãããã
ãã§åŸããããã®ã¯åæã®çµæ50ééïŒ ã®ãŒãªã©
ã€ããš50ééïŒ ã®ãã³ã¬ã³é žåç©ïŒMn2O3ïŒã
å«æããŠããããããæ··åç©ïŒãšãã¶ã ãŸããæ··åç©ïŒãšåãæ¹æ³ã§20ééïŒ ã®ãŒãªã©
ã€ããš80ééããŒã»ã³ãã®ãã³ã¬ã³é žåç©
ïŒMn2O3ïŒã®æ··åç©ïŒããŸãã80ééïŒ ã®ãŒãªã©
ã€ããš20ééããŒã»ã³ãã®ãã³ã¬ã³é žåç©
ïŒMn2O3ïŒã®æ··åç©ïŒã調補ããã 次ã«ãäžèšæ··åç©ïŒïŒïŒïŒïŒãããããã«ãã
ãŠå«æéãïŒééïŒ ã«ãªãéã®å¡©åã«ãããŠã æ°Ž
溶液ã«æµžæŒ¬ããåŸã130âã§ïŒæé也ç¥ããŠãã
ãã觊åªïŒïŒïŒïŒïŒãåŸãã ãŸããæ··åç©ïŒãæå®æ¿åºŠã®å¡©åã«ãããŠã æ°Ž
溶液ã«æµžæŒ¬ããåŸã130âã§ïŒæé也ç¥ããŠã«ã
ããŠã å«æéã0.5ééïŒ ã®è§ŠåªïŒåã³ã«ãããŠ
ã å«æéãïŒééïŒ ã®è§ŠåªïŒãåŸãã äžèšè§ŠåªïŒãïŒãããããïŒãïŒmmã®å€§ããã«
æ圢ãããã®ã10mlãªã¢ã¯ã¿ãŒã«å å¡«ããããã
ãã400âã§ïŒæéæ°ŽçŽ éå ããåŸãH2ïŒCOã¢
ã«æ¯ïŒã®åæã¬ã¹ãçšããŠ290âã®æž©åºŠã40KgïŒ
cm2ã®å§åãGHSV 500h-1ã®æ¡ä»¶ã§åå¿ããè¡š
ïŒã®ãããªçµæãåŸãã
åæã¬ã¹ãšããïŒããå質ã®åªããã¬ãœãªã³æ²žç¹
ç¯å²ã®çåæ°ŽçŽ ãé«åçã§åŸãæ¹æ³ã«é¢ããç¹ã«
該æ¹æ³ã«äœ¿çšããã«é©ãã觊åªãæäŸãããšãã
ãã®ã§ããã çŸåšããšãã«ã®ãŒã®äžå¿ãå ããŠããç³æ²¹ãã
ããç°å¢ã¯éåžžã«äžå®å®ã§ããã1980幎代åŸåã
ã1990幎代ã«ãããŠã¯ç³æ²¹äžè¶³ãããšãã«ã®ãŒã®
è°·éãæ¥ãããšãææ ®ãããŠããããã®ããç³æ²¹
ã®æ¶è²»ã®ç¯çŽããããããšãšãã«ãç³çãåå
åãLNGãªã©ã®ç³æ²¹ä»£æ¿ãšãã«ã®ãŒã§å¯Ÿå¿ãã
ããšãèããããŠããããã®ãããããåœã§ã¯ã
ä»åŸçžå¯Ÿçã«é«ãéèŠã®äŒžã³ã瀺ããšäºæ³ãããŠ
ããã¬ãœãªã³ãç¯æ²¹ã軜油ãéæ²¹çã®äŸçµŠäžè¶³
ããç³æ²¹ä»¥å€ã®ççŽ æºãäŸãã°ç³çåã¯å€©ç¶ã¬ã¹
çãã補é ããæ°æè¡ã®éçºã«é¢å¿ãåããããŠ
ããããã®ãã¡ç³çããçåæ°ŽçŽ æ²¹ã補é ããæ¹
æ³ãšããŠã¯ãçŽæ¥æ³ã§ããç³çã®æ¶²ååã³éæ¥æ³
ã§ããåæã¬ã¹ãçµæ²¹ãã補é æ¹æ³ãç¥ãããŠã
ããåè ã¯æ«ã ç 究éçºéçšã«ãããçŸç¶ã§ã¯è£œ
åã®è³ªãå£ããšãšãã«çµæžæ§ãå£ããäžæ¹åŸè ã
ãã§ã«åã¢ããªã«SASOL瀟ã§ç³çã®ã¬ã¹åãã
ã»ã¹ãšãã€ãã·ã€ãŒã»ãããã·ãŠããã»ã¹ãçµå
ããSASOLæ³ã®å®çšé転ããªãããŠããã ãã®ããã«ç³çã倩ç¶ã¬ã¹åã¯ã¢ã¹ãã¢ã«ãç
ã®ã¬ãœãªã³ãç¯æ²¹ã軜油ãžã®çŽæ¥è»¢åãå°é£ãªç
çŽ å«æç©ãã¬ã¹åã«ãã€ãŠäžé žåççŽ ãšæ°ŽçŽ ãšã®
æ··åã¬ã¹ã«å®¹æã«è»¢åã§ããããšã¯å ¬ç¥ã§ããã
ãŸããã®æ··åã¬ã¹ãé©åœãªè§Šåªã®ååšäžã§æ¥è§Šã
ããããšã«ããçåæ°ŽçŽ æ··åç©ãžè»¢åã§ããããš
ãå ¬ç¥ã§ããã äŸãã°ããã€ãã·ã€ã»ãããã·ãŠæ³ã¯éãã³ã
ã«ããããã±ã«ãã«ãããŠã ãããªãŠã åã³ããž
ãŠã ã«åºã¥ã觊åªã®ååšäžã§åæã¬ã¹ããçåæ°Ž
çŽ æ··åç©ã補é ããããšã§ç¥ãããŠãããããã®
æ¹æ³ã§ã¯ãåå¿çæç©ãã¡ã¿ã³ããã¯ãã¯ã¹ã«è³
ãå¹ åºãçåæ°ŽçŽ æ··åç©ïŒãã©ãã€ã³ããªã¬ãã€
ã³ïŒãšåçš®ã®å«é žçŽ ååç©ïŒã¢ã«ã³ãŒã«ããšãŒã
ã«çïŒã§ããã䟡å€ã®ããç¹å®æ²žç¹ç¯å²ã®çæç©
ãéžæçã«åŸãããšã¯ã§ããããããã€ãŠãæã
䟡å€ã®é«ãã¬ãœãªã³çåã®åçã¯å åã§ãªãããŸ
ããã®ã¬ãœãªã³çåäžã«ã¯è³éŠæãé«åºŠã«æåã
ãããã©ãã€ã³åã¯ãªã¬ãã€ã³ãã»ãšãã©å«æã
ãªãããããªã¯ã¿ã³äŸ¡ãäœããèªåè»ã¬ãœãªã³ãš
ããŠã¯äŸ¡å€ãäœãã äžæ¹åæã¬ã¹ãäžé žåççŽ éå 觊åªãšæ¥è§Šã
ãã次ãã§çæç©ãå¥ã®åã¯åäžåå¿åšã§ç¹å®ã®
ã¿ã€ãã®ãŒãªã©ã€ã觊åªãšæ¥è§Šãããããšã«ã
ããåæã¬ã¹ãé«ãªã¯ã¿ã³äŸ¡ã®ã¬ãœãªã³çåãäž»
äœãšããçæç©ã«è»¢åããæ¹æ³ãæããã«ãããŠ
ãããããã§çšãããäžé žåççŽ éå 觊åªã¯ãã¡
ã¿ããŒã«åæ觊åªåã¯ãã€ãã·ã€ãŒã»ãããã·ãŠ
åæ觊åªã§ãããã¡ã¿ããŒã«åæ觊åªã§ã¯åæã¬
ã¹ãäžåºŠã¢ã«ã³ãŒã«çã®å«é žçŽ ååç©ã«è»¢åãã
åŸããŸããã€ãã·ã€ã»ãããã·ãŠåæ觊åªã§ã¯å
æã¬ã¹ãã¡ã¿ã³ããã¯ãã¯ã¹ãŸã§ã®å·Ÿåºãçåæ°Ž
çŽ æ··åç©åã³å«é žçŽ ååç©ãšã«è»¢åããåŸããã
ãã®çæç©ã次ã«ç¹å®ã®çŽ°ååŸãæãããŒãªã©ã€
ã觊åªãšæ¥è§Šãããé«ãªã¯ã¿ã³äŸ¡ã®ã¬ãœãªã³çå
ãåçãã補é ããïŒæ®µè»¢åæ¹æ³ã§ããã æè¿ãåæã¬ã¹ããïŒæ®µæ³ã§ç¹å®ã®æ²žç¹ç¯å²ã®
çåæ°ŽçŽ ãéžæçã«è£œé ããæ¹æ³ãèŠåºãããã
ãã®æ¹æ³ã®ïŒã€ã¯ïŒæ®µæ³ã§çšããäžé žåççŽ éå
觊åªãšç¹å®ãªãŒãªã©ã€ããšãæ©æ¢°çã«æ··åãã觊
åªãçšããæ¹æ³ã§ãããä»ã®ïŒã€ã¯ç¹å®ã®ãŒãªã©
ã€ãã«äžé žåççŽ éå éå±ïŒåã¯éå±é žåç©ïŒã
æ æããã觊åªãçšããæ¹æ³ã§ããã ãããã®æ¹æ³ã«ãããŠãçæç©ã¯è§Šåªãæ§æã
ãç¹å®ã®çŽ°åãæãããŒãªã©ã€ãã®åœ¢ç¶çå¶çŽã
åãã现ååŸãã倧ããªååãµã€ãºã®çæç©ã¯ã»
ãšãã©çæãããã¬ãœãªã³æ²žç¹ç¯å²ä»¥äžã®ååãµ
ã€ãºã®å°ããªçåæ°ŽçŽ ãéžæçã«è£œé ã§ãããšã
ãæ¹åããªãããã ïŒæ®µæ³ã¯ïŒæ®µæ³ã«ããã¹å·¥çšãç°¡ç¥åãããã
ããããçµæžçãªããã»ã¹ãšæãããããåèšã®
æ©æ¢°çæ··å觊åªãçšããïŒæ®µæ³ã¯ïŒæ®µæ³ã«æ¯èŒ
ããäžé žåççŽ ã®è»¢åçã¯äœããªããšãšãã«ãã¬
ãœãªã³åçãäœäžããäžæ¹çæã¬ã¹ãšããŠããè©
䟡ã§ããªãã¡ã¿ã³ãå€ãçæãããšãã觊åªæ§èœ
äžã®å€§ããªæ¬ ç¹ãããããŸãç¹å®ã®ãŒãªã©ã€ãã«
ãã€ãã·ã€ãŒãããã·ãŠæŽ»æ§ã瀺ãéå±ãæ æã
ã觊åªãçšããïŒæ®µæ³ãããããã®æ¹æ³ã¯åæã¬
ã¹ã觊åªçµæç©äžã®éå±æåã§ãã€ãã·ã€ãŒãã
ããã·ãŠåå¿ãè¡ãããã¡ã¿ã³ããã¯ãã¯ã¹ã«è³
ãå·Ÿåºãçåæ°ŽçŽ æ··åç©ãäžéäœãšããŠè£œé ãã
åŸã次ã«ã¯ãã¯ã¹ã®å解ã«æå¹ã§ããããšãç¥ã
ããŠãã圢ç¶éžææ§ãŒãªã©ã€ããããªãã¡ZSM
âïŒãŒãªã©ã€ãæåã§ããããçåæ°ŽçŽ ãã¬ãœãª
ã³ä»¥äžã®çåæ°ŽçŽ ã«è»¢åããããšãæå³ãããã®
ã§ããããã®çš®ã®è§ŠåªãšããŠã¯ç¹éæ50â142502
ã§ç€ºãããããã«ãZSMâïŒãŒãªã©ã€ãã«éå
ã¯ã«ãããŠã ãå«æµžã調補ãããã®ã§ããããã
ãåè ã®ZSMâïŒïŒé觊åªã§ã¯è»¢åçã¯æ¯èŒç
é«ãããäžé žåççŽ ã¯äºé žçåçŽ ã«è»¢åããå²å
ãå€ããšãšãã«ãçæããçåæ°ŽçŽ ã¯ã¡ã¿ã³ãäž»
ã§C5 +ã¬ãœãªã³çåã®åçã¯å£ãããŸãåŸè ã®
ZSMâïŒïŒã«ãããŠã 觊åªã¯ãåè ããC5 +ã¬ãœ
ãªã³çåã®åçã¯é«ãããçµæçã«æ¥éã«æŽ»æ§ã
äœäžããå®çšäžã®æ¬ ç¹ããããå ããŠ50KgïŒcm2以
äžã®é«ãåå¿å§åãå¿ èŠãšããããŸãé žåé°å²æ°
ã§å ç±ããããšã«ãã掻æ§ã倱ãããã觊åªåç
ãå°é£ã§ããã ããã§æ¬çºæè ãã¯ããããã®æ¬ ç¹ã解決ãã
ãããåèšåœ¢ç¶éžææ§ãæãããŒãªã©ã€ããšäžé ž
åççŽ ãæ°ŽçŽ åãã掻æ§éå±åã¯éå±ååç©ãšã®
çµåãã«ã€ããŠéæå®éšæ€èšãéããçµæããŒãª
ã©ã€ããšäŸ¡æ°ãïŒãïŒã®ãã³ã¬ã³ã®é žåç©ãããª
ãæ··åç©ã«ã«ãããŠã ãæ æãã觊åªçµæç©åã¯
ã«ãããŠã ãæ æãããã³ã¬ã³é žåç©ãšçµæ¶æ§ãŒ
ãªã©ã€ããšã®æ··åç©ãããªã觊åªçµæç©ããåæ
ã¬ã¹ããé«ãªã¯ã¿ã³äŸ¡ã¬ãœãªã³çåãåŸãã®ã«æ¥µ
ããŠæå¹ãªããšãèŠåºããæ¬çºæãå®æããã«è³
ã€ãã ããªãã¡ãæ¬çºæã¯ãåæã¬ã¹ããçåæ°ŽçŽ ã
補é ããæ¹æ³ã«ãããŠããã³ã¬ã³ã®äŸ¡æ°ãïŒãïŒ
ã®ç¯å²ã«ãããã³ã¬ã³ã®é žåç©ãšçµæ¶æ§ãŒãªã©ã€
ããšãããªãæ··åç©ã«ã«ãããŠã ãæ æãã觊åª
çµæç©åã¯ã«ãããŠã ãæ æããäžèšãã³ã¬ã³ã®
é žåç©ãšçµæ¶æ§ãŒãªã©ã€ããšã®æ··åç©ãããªã觊
åªçµæç©ã®ååšäžã§ãåæã¬ã¹ãå§å10ã100
KgïŒcm2ã枩床200ã400âã®æ¡ä»¶ã§æ¥è§Šãããç
æçåæ°ŽçŽ äžã®ççŽ æ°ïŒä»¥äžã®ã¬ãœãªã³çåã®å²
åã60ééïŒ ä»¥äžã®çåæ°ŽçŽ ã補é ããããšãç¹
城ãšããçåæ°ŽçŽ ã®è£œæ³ã§ããã 次ã«æ¬çºæã«ãã觊åªã®è£œé æ¹æ³åã³ããã觊
åªãšããŠäœ¿çšãã転åæ¹æ³ã«ã€ããŠèª¬æããã ããã§çšãããŒãªã©ã€ããšã¯çµæ¶æ§ã¢ã«ããã·
ãªã±ãŒãåã¯çµçµæ¶æ§ã¢ã«ããã·ãªã±ãŒãã®ã¢ã«
ãããŠã ã®äžéšåã¯å šéšãä»ã®éå±ãäŸãã°éã
ã¯ãã ããããžãŠã ããã¹ãã¹ãã©ã³ã¿ã³ãã»ãª
ãŠã ããã¿ã³çã®äžäŸ¡ã®éå±ã«æ¿ããŠåæããã
ãã®ããŸããã¢ã«ãããæ®ãã©å«æãã90ïŒ ä»¥äž
ãã·ãªã«ãããªãç©è³ªãå«ãããããã®ãŒãªã©ã€
ãã¯é垞倩ç¶ã«æ°å€ãååšããããåæã«ãã€ãŠ
ã補é ã§ãããäžè¬ã«è»¢ååå¿ã«çšãããŒãªã©ã€
ãã¯çŽ°ååŸãçŽïŒâ«ã®ãšãªãªãã€ãããªãã¬ã¿ã€
ããããšãªãšã©ã€ãã现ååŸãçŽïŒâ«ã®ããªãŒãž
ã€ãµã€ãåã®ïŒžåã¯ïŒ¹ãŒãªã©ã€ããšãã¢ã«ããã€
ãã®ã»ã现ååŸãïŒãïŒâ«ã®äžéç现åãæãã
ãã€ã·ãªã«å¯Ÿã¢ã«ããæ¯ã12以äžã®ZSMâïŒã·
ãªãŒãºã®ãŒãªã©ã€ããç¥ãããŠããããæ¬çºæã«
ãããŠã¯ããããã®ãŒãªã©ã€ãã䜿çšã§ããã 现ååŸãçŽïŒâ«ã®ãŒãªã©ã€ãã§ã¯çæããçå
æ°ŽçŽ ã¯ååãµã€ãºãçŽïŒâ«ä»¥äžã®çŽéã®ãã©ãã€
ã³ããªã¬ãã€ã³åã¯ççŽ æ°ãïŒä»¥äžã®è»œè³ªçåæ°Ž
çŽ ãšãªããããç³æ²¹ååŠåæãšããŠæçšãªããšã
ã¬ã³ããããã¬ã³ãããã¬ã³çã®äœçŽãªã¬ãã€ã³
ãåŸãå Žå奜ãŸãããŒãªã©ã€ããšãªãããããã¬
ãœãªã³çåã®åçãé«ããããã«ã¯ããããã®ç
æç©ãã¬ãœãªã³ã«è»¢åããããããªãµã€ã¯ã«ãè¡
ããåã¯å ¬ç¥ã®ã¢ã«ãã«ååå¿çã®åŠçã«äŸãã
ããã现ååŸãïŒâ«ä»¥äžã®ãŒãªã©ã€ãã§ã¯çæç©
ãã¬ãœãªã³çå以äžã®çåæ°ŽçŽ ã°ããã§ãªãç¯
æ²¹ã軜油çåããçæããã®ã§ç¯æ²¹ã軜油ã䜵ç£
ããå¿ èŠã®ããå Žåéžæãããã 现ååŸãïŒãïŒâ«ã®ãŒãªã©ã€ãã¯ã¬ãœãªã³çå
ãé«åçã§åŸãå Žåæã奜ãŸãããŒãªã©ã€ãã§ã
ãããã®çš®ã®ãŒãªã©ã€ããšããŠã¯ã·ãªã«å¯Ÿã¢ã«ã
ãã¢ã«æ¯ã12以äžã®ZSMâïŒïŒZSMâ11ïŒZSM
â12ïŒZSMâ21ãZSMâ35ïŒZSMâ38ãªã©ã®ã¢
ãŒãã«ãªã€ã«ç€Ÿã®éçºããZSMã·ãªãŒãºã®ãŒãª
ã©ã€ãã®ã»ããã·ãšã«ã»ã€ã³ã¿ãŒãã·ãšãã«ã»ãª
ãµãŒã瀟ã®éçºããã·ãªã«âéâã¢ã«ããããæ
ãZSMâïŒãšé¡äŒŒã®ïŒžç·ååãã¿ãŒã³ãäžãã
ãŒãªã©ã€ããããã«ã¯è£œé æ¹æ³ãç°ãªããç·å
æãã¿ãŒã³ãZSMâïŒãšåãã§ããZSMâïŒã¿
ã€ãã®çµæ¶æ§ãŒãªã©ã€ãããŸãäžèšãŒãªã©ã€ãã®
ã¢ã«ããã®äžéšåã¯å šéšãä»ã®äžäŸ¡ã®éå±ã§ä»£æ¿
ããããŒãªã©ã€ããå«ãŸããããã®çš®é¡ã§ã¯ããŒ
ãªã©ã€ãåææã«ã·ãªã«æºãã¢ã«ããæºãã¢ã«ã«
ãªæºã®ã»ãã«ææ©è©ŠéšãšããŠããã©ãããã«ã¢ã³
ã¢ããŠã å¡©ãææ©ã¢ãã³ãã¢ã«ã³ãŒã«ã¢ãã³åã¯
ãžã°ãªã³ãŒã«ã¢ãã³åã³ãããã®åé§ç©è³ªã®ååš
äžã§æ°Žç±åæåå¿ãè¡ã€ãŠåŸããããŒãªã©ã€ãã
奜ãŸãã䜿çšã§ããã çµæ¶æ§ãŒãªã©ã€ãã¯éåžžãéœã€ãªã³ãšããŠãã
ãªãŠã ãã«ãªãŠã ãåã¯ææ©çªçŽ éœã€ãªã³ãå«ã
ããæ¬çºæã®è»¢ååå¿ã«äœ¿çšããã«ã¯ããããã®
éœã€ãªã³ã®å°ãªããšã50ïŒ ä»¥äžãæ°ŽçŽ ã€ãªã³ãã¢
ã³ã¢ããŠã ã€ãªã³ãã¢ã«ã«ãªåé¡ã€ãªã³ãåžåé¡
ã€ãªã³ãé·ç§»éå±ã€ãªã³çã§äº€æãé žæ§ç¹ãçºçŸ
ãããã®ã奜ãŸãããéåžžãã®éœã€ãªã³äº€æåŠç
ã¯äº€æããéœã€ãªã³ãå«ã氎溶液ã§åŠçããå ¬ç¥
ã®ã€ãªã³äº€ææè¡ã§éæã§ãããåææ©çªçŽ éœã€
ãªã³ãå«ããã®ã§ã¯ç©ºæ°äžã§400ã700âã®ç¯å²ã§
å ç±ãææ©çªçŽ éœã€ãªã³ãå解ãçŒæããããšã«
ãã容æã«æ°ŽçŽ ã€ãªã³åã«ãªã掻æ§åãããã 次ã«ãŒãªã©ã€ããšäŸ¡æ°ãïŒãïŒã®ãã³ã¬ã³é žå
ç©ãšã®æ··åæ¹æ³ã§ãããããã®æ¹æ³ã¯éèŠãªæäœ
ã§ãããäž¡è ãåäžãªæ··åç©ãäœãããã«èª¿è£œã
ãªããã°ãªããªããæ¹æ³ãšããŠã¯å«æµžãã²ã«æ··å
åã¯ä¹ŸåŒæ··åãªã©ãå©çšã§ããã å«æµžæ³ã§ã¯ãã³ã¬ã³ã®æ°Žæº¶æ§ã®å¡©ãäŸãã°ç¡
é žãã³ã¬ã³ãå«æãã氎溶液ã«ãŒãªã©ã€ãã浞挬
ããéåžžã®å«æµžæ³ãå©çšã§ããåã²ã«æ··åæ³ã§
ã¯äºã調補ããæ°Žé žåãã³ã¬ã³ã®ã²ã«ããŒãªã©ã€
ãã®ç²æ«ãšæ··åããæ¹æ³ãååèšãã³ã¬ã³ã®æ°Ž
溶æ§ã®å¡©ãå«æãã氎溶液ã«ãŒãªã©ã€ãã®ç²æ«ã
ããã ããããããã«ã¢ã³ã¢ãã¢æ°Žçã®ã¢ã«ã«ãª
ãå ããã³ã¬ã³ãã²ã«åããäž¡è ã®åäžæ··åç©ã
åŸãæ¹æ³ããå也åŒæ··åã§ã¯åŸ®ç²æ«ç¶ã®ãã³ã¬
ã³é žåç©ãšãŒãªã©ã€ããšãããã€ã¶ããªããæ··å
ããæ¹æ³ã䜿çšã§ããã ãªãã以äžã®ããã«ããŠäœã€ããŒãªã©ã€ããšã
ã³ã¬ã³ã®ååç©ãšã®æ··åç©ïŒïŒã¯300ã600
âã§çŒæããããã®ãã®ã¯å¿ ããçŒæãèŠããª
ãããçŒæããŠãæªåœ±é¿ã¯ãªãã äžèšãã®ãã³ã¬ã³ã®é žåç©ã¯Mn2O3åã¯
MnO2ã§ãããMn2O3ïŒMnO2ã¯çŒææ¡ä»¶ïŒæž©åºŠïŒ
ã«ãã€ãŠæ±ºå®ãããã 以äžã®æ¹æ³ã§åŸããããŒãªã©ã€ããšäŸ¡æ°ãïŒã
ïŒã®ãã³ã¬ã³é žåç©ãšã®æ··åç©ã«çµã¿åãããã«
ãããŠã ã«ã€ããŠã§ããããé垞氎溶æ§ã®ããã²
ã³åç©åã¯ã¢ã³ãã³é¯å¡©ãšããŠå®¹æã«å ¥æã§ãã
ãã®ã䜿çšã§ããäŸãã°ãå¡©åã«ãããŠã ããã
ãµã¢ã³ãã³ã«ãããŠã âããªã¯ãã©ã€ããªã©ã䜿
çšã§ããã åãæ æã®æ¹æ³ãéåžžã®å«æµžæè¡ãå©çšã§ã
ããäŸãã°ããŒãªã©ã€ããšäŸ¡æ°ãïŒãïŒã®ãã³ã¬
ã³é žåç©ãšã®æ··åç©ãç²æ«ã®ãŸãŸããããã¯ãäž
æŠæ圢ãããããã«ãããŠã ååç©ã®æ°Žæº¶æ¶²åã¯
ã¢ã»ãã³ãªã©ã®æº¶å€ã«æº¶ãããé氎溶液äžã«æµžæŒ¬
ããå«æµžãæ æããæ¹æ³ãå©çšã§ããã ãã®å Žåã觊åªãæ圢ããéã«ãã·ãªã«ãã¢ã«
ããããã³å€©ç¶ç²åé±ç©ãªã©ãæ·»å ããããšã¯è§Š
åªã®æ§èœãæãªããªããããã®éã§ããã°ããã€
ãããªãã ãŸãã«ãããŠã ãæ æãã䟡æ°ãïŒãïŒã®ãã³
ã¬ã³é žåç©ã«ãŒãªã©ã€ããæ··åãã觊åªã調補ã
ãå Žåã«ã¯ãå ã埮ç²æ«ç¶ã®äŸ¡æ°ãïŒãïŒã®ãã³
ã¬ã³é žåç©ãã«ãããŠã ååç©ã®æº¶æ¶²ãäŸãã°å¡©
åã«ãããŠã ããããµã¢ã³ãã³ã«ãããŠã ã¯ãã©
ã€ããªã©ãå«æãã氎溶液ã«æµžæŒ¬ãã也ç¥ãæ æ
ããåŸããŒãªã©ã€ãç²æ«ãšç©ççã«ãäŸãã°æ©æ¢°
çããã€ã¶ããŠãæ··åããæ¹æ³ãå©çšã§ããã 觊åªçµæäžã®ãŒãªã©ã€ããšäŸ¡æ°ãïŒãïŒã®ãã³
ã¬ã³é žåç©ãšã®å²åã¯éèŠã§ããã䟡æ°ãïŒãïŒ
ã®ãã³ã¬ã³é žåç©ãšããŠã®å²åã¯ããŒãªã©ã€ããš
䟡æ°ãïŒãïŒã®ãã³ã¬ã³é žåç©ã®åèšã«å¯ŸããïŒ
ã95ééïŒ ã奜é©ã«ã¯30ã70ééïŒ ã§ããããã
ã«æ æããã«ãããŠã ã¯éå±ãšããŠãåãããŒãª
ã©ã€ããšäŸ¡æ°ãïŒãïŒã®ãã³ã¬ã³é žåç©ã®åèšã«
察ããŠ0.05ã10ééïŒ ã奜ãŸããã¯0.5ãïŒéé
ïŒ ã§ããããã®å ŽåããŒãªã©ã€ãã®å²åãå°ãªã
ãšããªã¯ã¿ã³äŸ¡ã®é«ãå質ã®åªããã¬ãœãªã³ãã
ããã¯äœçŽãªã¬ãã€ã³ãç¯è»œæ²¹ãªã©ãææããç
åæ°ŽçŽ ãåŸãããšãå°é£ã«ãªããäžæ¹äŸ¡æ°ãïŒã
ïŒã®ãã³ã¬ã³é žåç©ãå°ãªããšãåæã¬ã¹ã®çå
æ°ŽçŽ ãžã®è»¢åçãäœäžããã åãæ¬çºæã®è§Šåªã¯ããŒãªã©ã€ããšäŸ¡æ°ãïŒã
ïŒã®ãã³ã¬ã³é žåç©åã³ã«ãããŠã ãããªãããš
ãç¹åŸŽãšããŠãããããã³ã¬ã³é žåç©ã®ã»ãã«
éãã³ãã«ãããããžãŠã ããã¿ã³ãªã©ã®é·ç§»é
å±é žåç©ãäžçš®åã¯äºçš®ä»¥äžäžç·ã«å«æãããŠã
ããããã®å Žåãé·ç§»éå±é žåç©ãå«æãããæ¹
æ³ã¯ãŒãªã©ã€ãã«äŸ¡æ°ãïŒãïŒã®ãã³ã¬ã³é žåç©
ãå«æãããåè¿°ã®æ¹æ³ãå©çšã§ããäŸãã°é·ç§»
éå±é žåç©ãšããŠé žåéã也åŒæ··åæ³ã«ããå«æ
ãããå Žåã¯ãŒãªã©ã€ãç²æ«ãšäŸ¡æ°ãïŒãïŒãã³
ã¬ã³é žåç©ã®ç²æ«åã³é žåéã®ç²æ«ãäžç·ã«æ··å
ããä¹³é¢ã§ããã€ã¶ããªããåäžã«æ··åããæ¹æ³
ã䜿çšã§ããã ãã®çºæã®æ¹æ³ã«ãããŠåæã¬ã¹ãšãªãåæã¬
ã¹ã¯ç³çã倩ç¶ã¬ã¹ãç³æ²¹ã³ãŒã¯ã¹ãé 岩油ãã¿
ãŒã«ãµã³ãåã¯ç³æ²¹èžçããã®æ®æž£æ²¹ãªã©ã®åç³
çæãå ¬ç¥ã®ã¬ã¹ååå¿ãäŸãã°éšåé žååå¿å
ã¯ã¹ããŒã ãªããªãŒãã³ã°åå¿ãªã©ã«ããä»»æã«
補é ããããååæã¬ã¹ã®åé§ç©è³ªã§ããäžé žå
ççŽ ãšã¹ããŒã ãšã®æ··åç©ãæãã¯äºé žåççŽ ãš
æ°ŽçŽ ãšã®æ··åç©ã䜿çšããããšãã§ãããæŽã«ã¯
çæç©äžã®æ¶²ç¶çåæ°ŽçŽ çåãé€å»ããæªåå¿ã¬
ã¹æ··åç©ãååæã¬ã¹ãšããŠäœ¿çšã§ãããåæã¬
ã¹äžã®æ°ŽçŽ ãšäžé žåççŽ ãšã®æ¯çã¯ã¬ã¹åããã
ççŽ æºã«ããå€åããããæ¬è»¢ååå¿ã®ããã«
ã¯ããã®æ¯çã¯0.2ã6.0ã®ç¯å²ã«ããããšã奜é©
ã§ããã åæã¬ã¹ã¯è§Šåªãš200ã400âã®æž©åºŠã10ã100
KgïŒcm2ã®å§ååã³è§Šåªäœç©åœãïŒæéæšæºæž©
床ãå§åã§çŽ100ã10000ã®åæã¬ã¬ã¹äœç©ã®
GHSVïŒã¬ã¹åºæºç©ºå¡é床ïŒã§æ¥è§Šåå¿ãè¡ãã ãŸããæ¬çºæã¯åºå®åºã¿ã€ãã ãã§ãªããæµå
åºã液çžã¹ã©ãªãŒã¿ã€ãã®ãªã¢ã¯ã¿ãŒã§è¡ãããš
ãã§ããã 次ã«æ¬çºæãå®æœäŸã«ããå ·äœçã«èª¬æããã
æ¬çºæã¯ãã®èŠæšãè¶ããªããããéå®ãããã
ã®ã§ã¯ãªãã ãå®æœäŸ ïŒã é«ã·ãªã«ãŒãªã©ã€ãã次ã®ããã«ããŠåæã
ãã ã³ãã€ãã«ã·ãªã«ãã¢ã«ãã³é žãœãŒããèæ§ãœ
ãŒãåã³æ°Žã10Na2Oã»Al2O3ã»80SiO2ã»
1300H2Oã®ã¢ã«æ¯ã«ãªãããã«èª¿åããããã«
ææ©è©Šè¬ãšããŠãžã°ãªã³ãŒã«ã¢ãã³ãã¢ã«ããã®
ã¢ã«æ°ã®18åå ãããæ··åããã®ã¡ãã¹ãã³ã¬ã¹
補3lãªãŒãã¯ã¬ãŒãã«åŒµèŸŒãã ãé»æ°ããŒã¿ã§
åŸã ã«æž©åºŠãäžããèªçå§åäž160âã®æž©åºŠã«é
ãããïŒç®éå ç±ãç¶ãããã®åŸèªç¶å·åŽããã
çæããçœè²åŸ®çŽ°çµæ¶ç©ãéããæŽæµæ°Žã®PHã
çŽïŒã«ãªããŸã§å åæ°ŽæŽãã次ã«30âã§ïŒæé也
ç¥ããããã®çµæ¶ç©è³ªã¯ååŠåæã®çµæããããª
ãŠã 1.8ééïŒ ãçªçŽ 0.8ééïŒ ãå«æããã·ãªã«
察ã¢ã«ããæ¯ã¯63ã§ãã€ãã ãŸãç·åæåæã«ããã°åæãã¿ãŒã³ã¯
ZSMâïŒãŒãªã©ã€ãã«é¡äŒŒããŠããã ãã®é«
ã·ãªã«ãŒãªã©ã€ãã¯ã次ã«é žåãŒãªã©ã€ããšãã
ãã以äžã®ã€ãªã³äº€æåŠçãè¡ã€ãã ãŒãªã©ã€ã500gã4Nã®å¡©åã¢ã³ã¢ããŠã 氎溶
液ïŒãšãšãã«ïŒæé沞ãšããããéãæ°ŽæŽ
åŸãæ°ããå¡©åã¢ã³ã¢ããŠã 氎溶液ã䜿çšããŠã
åã³åãåŠçãïŒåç¹°è¿ããŒãªã©ã€ãäžã®å€§éšå
ãã¢ã³ã¢ããŠã ã€ãªã³ã«äº€æãããããã130â
ã§ïŒæé也ç¥ã550âã§ïŒæéçŒæãããšã¢ã³ã¢
ããŠã ã€ãªã³ã¯æ°ŽçŽ ã€ãªã³ã«ããŸãææ©çªçŽ éœã€
ãªã³ã¯ççŒé€å»ãããæ°ŽçŽ ã€ãªã³ã«ããããå€æ
ãããçµæãšããŠãããªãŠã éã¯0.01ééïŒ ãŸã§
æžå°ããã ãã®ïŒšåé«ã·ãªã«ãŒãªã©ã€ã20gãç¡é žãã³ã¬
ã³80.8gãå«æãã氎溶液äžã«æ·»å ããããæ¹æ
ããªãã3Nã®ã¢ã³ã¢ãã¢æ°Žã溶液ã®PHã9.0ã«ãª
ããŸã§å ãæ°Žé žåãã³ã¬ã³ã®ã²ã«ã圢æãããã
ãã®æ··åã²ã«ã¯éåŸå åæ°ŽæŽãããã®åŸã130
âïŒæé也ç¥ç¶ããŠ500âã§ïŒæéçŒæãããã
ãã§åŸããããã®ã¯åæã®çµæ50ééïŒ ã®ãŒãªã©
ã€ããš50ééïŒ ã®ãã³ã¬ã³é žåç©ïŒMn2O3ïŒã
å«æããŠããããããæ··åç©ïŒãšãã¶ã ãŸããæ··åç©ïŒãšåãæ¹æ³ã§20ééïŒ ã®ãŒãªã©
ã€ããš80ééããŒã»ã³ãã®ãã³ã¬ã³é žåç©
ïŒMn2O3ïŒã®æ··åç©ïŒããŸãã80ééïŒ ã®ãŒãªã©
ã€ããš20ééããŒã»ã³ãã®ãã³ã¬ã³é žåç©
ïŒMn2O3ïŒã®æ··åç©ïŒã調補ããã 次ã«ãäžèšæ··åç©ïŒïŒïŒïŒïŒãããããã«ãã
ãŠå«æéãïŒééïŒ ã«ãªãéã®å¡©åã«ãããŠã æ°Ž
溶液ã«æµžæŒ¬ããåŸã130âã§ïŒæé也ç¥ããŠãã
ãã觊åªïŒïŒïŒïŒïŒãåŸãã ãŸããæ··åç©ïŒãæå®æ¿åºŠã®å¡©åã«ãããŠã æ°Ž
溶液ã«æµžæŒ¬ããåŸã130âã§ïŒæé也ç¥ããŠã«ã
ããŠã å«æéã0.5ééïŒ ã®è§ŠåªïŒåã³ã«ãããŠ
ã å«æéãïŒééïŒ ã®è§ŠåªïŒãåŸãã äžèšè§ŠåªïŒãïŒãããããïŒãïŒmmã®å€§ããã«
æ圢ãããã®ã10mlãªã¢ã¯ã¿ãŒã«å å¡«ããããã
ãã400âã§ïŒæéæ°ŽçŽ éå ããåŸãH2ïŒCOã¢
ã«æ¯ïŒã®åæã¬ã¹ãçšããŠ290âã®æž©åºŠã40KgïŒ
cm2ã®å§åãGHSV 500h-1ã®æ¡ä»¶ã§åå¿ããè¡š
ïŒã®ãããªçµæãåŸãã
ç¡é
žãã³ã¬ã³ãå«æãã氎溶液ã®PHã9.0ã«ãª
ããŸã§ã¢ã³ã¢ãã¢æ°Žãå ããŠæ°Žé žåãã³ã¬ã³ã®ã²
ã«ãäœã€ãåŸããããéæŽæµãã130âã§ïŒæ
é也ç¥ãç¶ããŠ500âã§ïŒæéçŒæããŠãã³ã¬ã³
é žåç©ïŒMn2O3ïŒã®åŸ®ç²æ«ãåŸãã ãã®ãã³ã¬ã³é žåç©ïŒMn2O3ïŒãšå®æœäŸïŒã§
åŸãåé«ã·ãªã«ãŒãªã©ã€ããšã®ïŒïŒïŒã®ééæ¯
ã®æ··åç©ã«ã«ãããŠã å«æéãïŒééïŒ ã«ãªãé
ã®å¡©åã«ãããŠã 氎溶液ã«æµžæŒ¬ããåŸã130âã§
ïŒæé也ç¥ããŠè§ŠåªïŒãåŸãããããå®æœäŸïŒãš
åãæ¹æ³ãæ¡ä»¶ã§åæã¬ã¹ã®è»¢ååå¿ãè¡ããã
ãšãããè¡šïŒã®ãããªçµæãåŸãããã
ããŸã§ã¢ã³ã¢ãã¢æ°Žãå ããŠæ°Žé žåãã³ã¬ã³ã®ã²
ã«ãäœã€ãåŸããããéæŽæµãã130âã§ïŒæ
é也ç¥ãç¶ããŠ500âã§ïŒæéçŒæããŠãã³ã¬ã³
é žåç©ïŒMn2O3ïŒã®åŸ®ç²æ«ãåŸãã ãã®ãã³ã¬ã³é žåç©ïŒMn2O3ïŒãšå®æœäŸïŒã§
åŸãåé«ã·ãªã«ãŒãªã©ã€ããšã®ïŒïŒïŒã®ééæ¯
ã®æ··åç©ã«ã«ãããŠã å«æéãïŒééïŒ ã«ãªãé
ã®å¡©åã«ãããŠã 氎溶液ã«æµžæŒ¬ããåŸã130âã§
ïŒæé也ç¥ããŠè§ŠåªïŒãåŸãããããå®æœäŸïŒãš
åãæ¹æ³ãæ¡ä»¶ã§åæã¬ã¹ã®è»¢ååå¿ãè¡ããã
ãšãããè¡šïŒã®ãããªçµæãåŸãããã
å®æœäŸïŒã§åŸãåé«ã·ãªã«ãŒãªã©ã€ãã«ã«ã
ããŠã å«æéãïŒééïŒ ã«ãªãéã®å¡©åã«ãããŠ
ã 氎溶液ã«æµžæŒ¬ããåŸã130âã§ïŒæé也ç¥ããŠ
觊åªïŒãåŸãããããå®æœäŸïŒãšåãæ¹æ³ãæ¡ä»¶
ã§åæã¬ã¹ã®è»¢ååå¿ãè¡ããããšãããè¡šïŒã®
ãããªçµæãåŸãããã
ããŠã å«æéãïŒééïŒ ã«ãªãéã®å¡©åã«ãããŠ
ã 氎溶液ã«æµžæŒ¬ããåŸã130âã§ïŒæé也ç¥ããŠ
觊åªïŒãåŸãããããå®æœäŸïŒãšåãæ¹æ³ãæ¡ä»¶
ã§åæã¬ã¹ã®è»¢ååå¿ãè¡ããããšãããè¡šïŒã®
ãããªçµæãåŸãããã
å®æœäŸïŒåã³æ¯èŒäŸã«ãããŠåæã¬ã¹ã®è»¢åå
å¿ãè¡ããããè©ŠéšåŸã®è§ŠåªïŒãšè§ŠåªïŒãããã
ã空æ°æµäž550âã§ãïŒæéå ç±åŠçããããã®
觊åªãå床å®æœäŸïŒãšåãæ¹æ³ã§ãæ°ŽçŽ éå ãäž
èšæ¡ä»¶ã§åæã¬ã¹ã®è»¢ååå¿ãè¡ããããšããã
è¡šïŒã®ãããªçµæãåŸãããã
å¿ãè¡ããããè©ŠéšåŸã®è§ŠåªïŒãšè§ŠåªïŒãããã
ã空æ°æµäž550âã§ãïŒæéå ç±åŠçããããã®
觊åªãå床å®æœäŸïŒãšåãæ¹æ³ã§ãæ°ŽçŽ éå ãäž
èšæ¡ä»¶ã§åæã¬ã¹ã®è»¢ååå¿ãè¡ããããšããã
è¡šïŒã®ãããªçµæãåŸãããã
ãã®äŸã¯å¥ã®ãŒãªã©ã€ããçšããå Žåã®å®æœäŸ
ã§ããããŸãçµæ¶æ§ã·ãªã±ãŒãã次ã®æ¹æ³ã§åæ
ããã æ°Žã¬ã©ã¹ãå¡©åã©ã³ã¿ã³ãæ°Žã36Na2Oã»
La2O3ã»80SiO2ã»1600H2Oã®ã¢ã«æ¯ã«ãªãããã«
調åããããã«å¡©é žãé©åœéæ·»å ããäžèšæ··åç©
ã®PHãïŒååŸã«ãªãããã«ããåŸãææ©ååç©ãš
ããŠãããã«ã¢ãã³ãèåãããã«ãLa2O3ã®ã¢
ã«æ°ã®20åå ããããæ··åãã500c.c.ã®ã¹ãã³ã¬
ã¹è£œãªãŒãã¯ã¬ãŒãã«åŒµèŸŒãã ã äžèšæ··åç©ãçŽ500rpmã«ãŠæ¹æããªãã60â
ã§ïŒæ¥éãåå¿ããããå·åŽåŸãåºåœ¢åãé
ããæŽæµæ°Žã®PHãçŽïŒã«ãªããŸã§å åæ°ŽæŽã110
âã§12æé也ç¥ãã550âã§ïŒæéçŒæãããã
ã®çæç©ã®çµæ¶ç²åŸã¯1ÎŒååŸã§ãããææ©åå
ç©ãåŸå€ããçµæã¯è±æ°Žã®åœ¢æ ã§è¡šãããŠ
0.4Na2Oã»La2O3ã»80SiO2ïŒä»¥äžãçµæ¶æ§ã·ãªã±
ãŒããšç¥ç§°ããïŒã§ãã€ãã ãã®çµæ¶æ§ã·ãªã±ãŒãã¯æ¬¡ã«é žåãšãããã以
äžã®ã€ãªã³äº€æåŠçãè¡ã€ãã çµæ¶æ§ã·ãªã±ãŒã50gã1Nã®å¡©é žæº¶æ¶²500c.c.ãš
ãšãã«80âã§ïŒé±éåŠçãçµæ¶æ§ã·ãªã±ãŒãäžã®
ãããªãŠã ã€ãªã³ã®å€§éšåãæ°ŽçŽ ã€ãªã³ã«äº€æã
ãããããäžæŠéãæ°ŽæŽãã130âã§ïŒæé也
ç¥åŸ500âã§ïŒæéçŒæãåã®çµæ¶æ§ã·ãªã±ãŒ
ããåŸãã ãã®ïŒšåçµæ¶æ§ã·ãªã±ãŒããšå®æœäŸïŒã§äœã€ã
ãã³ã¬ã³é žåç©ïŒMn2O3ïŒãšã®ïŒïŒïŒã®ééæ¯
ã®æ··åç©ã«ã«ãããŠã å«æéãïŒééïŒ ã«ãªãé
ã®å¡©åã«ãããŠã 氎溶液ã«æµžæŒ¬ããåŸã130âã§
ïŒæé也ç¥ããŠè§ŠåªïŒãåŸãã 次ã«ããŸãå®æœäŸïŒã§äœã€ããã³ã¬ã³é žåç©
ïŒMn2O3ïŒã«ã«ãããŠã å«æéãïŒééïŒ ã«ãªã
éã®å¡©åã«ãããŠã 氎溶液ã«æµžæŒ¬ããåŸãäžèšã®
åçµæ¶æ§ã·ãªã±ãŒãåã¯ïŒ¹åãŒãªã©ã€ãïŒãŠã
ãªã³ã»ã«ãŒãã€ã瀟補ã®Skâ41ãšåŒã°ããNH4
âåãŒãªã©ã€ãã300âã§çŒæãããã®ïŒãç
ééæ··åããåã 觊åªïŒïŒ10ãåŸãã ãããã®è§ŠåªïŒïŒïŒïŒ10ãå®æœäŸïŒãšåãæ¹
æ³ãæ¡ä»¶ã§åæã¬ã¹ã®è»¢ååå¿ãè¡ããããšãã
è¡šã®ãããªçµæãåŸãããã
ã§ããããŸãçµæ¶æ§ã·ãªã±ãŒãã次ã®æ¹æ³ã§åæ
ããã æ°Žã¬ã©ã¹ãå¡©åã©ã³ã¿ã³ãæ°Žã36Na2Oã»
La2O3ã»80SiO2ã»1600H2Oã®ã¢ã«æ¯ã«ãªãããã«
調åããããã«å¡©é žãé©åœéæ·»å ããäžèšæ··åç©
ã®PHãïŒååŸã«ãªãããã«ããåŸãææ©ååç©ãš
ããŠãããã«ã¢ãã³ãèåãããã«ãLa2O3ã®ã¢
ã«æ°ã®20åå ããããæ··åãã500c.c.ã®ã¹ãã³ã¬
ã¹è£œãªãŒãã¯ã¬ãŒãã«åŒµèŸŒãã ã äžèšæ··åç©ãçŽ500rpmã«ãŠæ¹æããªãã60â
ã§ïŒæ¥éãåå¿ããããå·åŽåŸãåºåœ¢åãé
ããæŽæµæ°Žã®PHãçŽïŒã«ãªããŸã§å åæ°ŽæŽã110
âã§12æé也ç¥ãã550âã§ïŒæéçŒæãããã
ã®çæç©ã®çµæ¶ç²åŸã¯1ÎŒååŸã§ãããææ©åå
ç©ãåŸå€ããçµæã¯è±æ°Žã®åœ¢æ ã§è¡šãããŠ
0.4Na2Oã»La2O3ã»80SiO2ïŒä»¥äžãçµæ¶æ§ã·ãªã±
ãŒããšç¥ç§°ããïŒã§ãã€ãã ãã®çµæ¶æ§ã·ãªã±ãŒãã¯æ¬¡ã«é žåãšãããã以
äžã®ã€ãªã³äº€æåŠçãè¡ã€ãã çµæ¶æ§ã·ãªã±ãŒã50gã1Nã®å¡©é žæº¶æ¶²500c.c.ãš
ãšãã«80âã§ïŒé±éåŠçãçµæ¶æ§ã·ãªã±ãŒãäžã®
ãããªãŠã ã€ãªã³ã®å€§éšåãæ°ŽçŽ ã€ãªã³ã«äº€æã
ãããããäžæŠéãæ°ŽæŽãã130âã§ïŒæé也
ç¥åŸ500âã§ïŒæéçŒæãåã®çµæ¶æ§ã·ãªã±ãŒ
ããåŸãã ãã®ïŒšåçµæ¶æ§ã·ãªã±ãŒããšå®æœäŸïŒã§äœã€ã
ãã³ã¬ã³é žåç©ïŒMn2O3ïŒãšã®ïŒïŒïŒã®ééæ¯
ã®æ··åç©ã«ã«ãããŠã å«æéãïŒééïŒ ã«ãªãé
ã®å¡©åã«ãããŠã 氎溶液ã«æµžæŒ¬ããåŸã130âã§
ïŒæé也ç¥ããŠè§ŠåªïŒãåŸãã 次ã«ããŸãå®æœäŸïŒã§äœã€ããã³ã¬ã³é žåç©
ïŒMn2O3ïŒã«ã«ãããŠã å«æéãïŒééïŒ ã«ãªã
éã®å¡©åã«ãããŠã 氎溶液ã«æµžæŒ¬ããåŸãäžèšã®
åçµæ¶æ§ã·ãªã±ãŒãåã¯ïŒ¹åãŒãªã©ã€ãïŒãŠã
ãªã³ã»ã«ãŒãã€ã瀟補ã®Skâ41ãšåŒã°ããNH4
âåãŒãªã©ã€ãã300âã§çŒæãããã®ïŒãç
ééæ··åããåã 觊åªïŒïŒ10ãåŸãã ãããã®è§ŠåªïŒïŒïŒïŒ10ãå®æœäŸïŒãšåãæ¹
æ³ãæ¡ä»¶ã§åæã¬ã¹ã®è»¢ååå¿ãè¡ããããšãã
è¡šã®ãããªçµæãåŸãããã
åžè²©ã®é
žåãã³ã¬ã³ïŒMnO3ïŒç²æ«ãšå®æœäŸïŒ
ã§åŸãåã®çµæ¶æ§ã·ãªã±ãŒããšã®ïŒïŒïŒã®éé
æ¯ã®æ··åç©ã«ã«ãããŠã å«æéãïŒééïŒ ã«ãªã
éã®å¡©åã«ãããŠã 氎溶液ã«æµžæŒ¬ããåŸã130â
ã§ïŒæé也ç¥ããŠè§Šåª11ãåŸãã ãã®è§Šåª11ãå®æœäŸïŒãšåãæ¹æ³ãæ¡ä»¶ã§åæ
ã¬ã¹ã®è»¢ååå¿ãè¡ããããšããäžèšè¡šã®ãããª
çµæãåŸãããã
ã§åŸãåã®çµæ¶æ§ã·ãªã±ãŒããšã®ïŒïŒïŒã®éé
æ¯ã®æ··åç©ã«ã«ãããŠã å«æéãïŒééïŒ ã«ãªã
éã®å¡©åã«ãããŠã 氎溶液ã«æµžæŒ¬ããåŸã130â
ã§ïŒæé也ç¥ããŠè§Šåª11ãåŸãã ãã®è§Šåª11ãå®æœäŸïŒãšåãæ¹æ³ãæ¡ä»¶ã§åæ
ã¬ã¹ã®è»¢ååå¿ãè¡ããããšããäžèšè¡šã®ãããª
çµæãåŸãããã
ãè¡šã
以äžå®æœäŸã§ç€ºããããšããæ¬çºæã«ããããŒ
ãªã©ã€ããšäŸ¡æ°ãïŒãïŒã®ãã³ã¬ã³é žåç©ã®æ··å
ç©ã«ã«ãããŠã ãæ æãã觊åªãçšããããšã«ã
ããåæã¬ã¹ãããã®ãŸãŸã¬ãœãªã³ãšããŠå©çšã§
ããçåæ°ŽçŽ ãé«éžæçã§åŸãããã
ãªã©ã€ããšäŸ¡æ°ãïŒãïŒã®ãã³ã¬ã³é žåç©ã®æ··å
ç©ã«ã«ãããŠã ãæ æãã觊åªãçšããããšã«ã
ããåæã¬ã¹ãããã®ãŸãŸã¬ãœãªã³ãšããŠå©çšã§
ããçåæ°ŽçŽ ãé«éžæçã§åŸãããã
Claims (1)
- ïŒ åæã¬ã¹ããçåæ°ŽçŽ ã補é ããæ¹æ³ã«ãã
ãŠããã³ã¬ã³ã®äŸ¡æ°ãïŒãïŒã®ç¯å²ã«ãããã³ã¬
ã³ã®é žåç©ãšçµæ¶æ§ãŒãªã©ã€ããšãããªãæ··åç©
ã«ã«ãããŠã ãæ æãã觊åªçµæç©åã¯ã«ãããŠ
ã ãæ æããäžèšãã³ã¬ã³ã®é žåç©ãšçµæ¶æ§ãŒãª
ã©ã€ããšã®æ··åç©ãããªã觊åªçµæç©ã®ååšäž
ã§ãåæã¬ã¹ãå§åïŒã100KgïŒcm2G.枩床200ã
400âã®æ¡ä»¶ã§æ¥è§Šãããçæçåæ°ŽçŽ äžã®ççŽ
æ°ïŒä»¥äžã®ã¬ãœãªã³çåã®å²åã60ééïŒ ä»¥äžã®
åæ°ŽçŽ ã補é ããããšãç¹åŸŽãšããçåæ°ŽçŽ ã®è£œ
æ³ã
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57073456A JPS58192834A (ja) | 1982-05-04 | 1982-05-04 | çåæ°ŽçŽ ã®è£œé æ¹æ³ |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP57073456A JPS58192834A (ja) | 1982-05-04 | 1982-05-04 | çåæ°ŽçŽ ã®è£œé æ¹æ³ |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS58192834A JPS58192834A (ja) | 1983-11-10 |
| JPH0245605B2 true JPH0245605B2 (ja) | 1990-10-11 |
Family
ID=13518757
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57073456A Granted JPS58192834A (ja) | 1982-05-04 | 1982-05-04 | çåæ°ŽçŽ ã®è£œé æ¹æ³ |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS58192834A (ja) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS621783A (ja) * | 1985-06-28 | 1987-01-07 | Res Assoc Petroleum Alternat Dev<Rapad> | çåæ°ŽçŽ ã®è£œé æ¹æ³ |
| JPS62109888A (ja) * | 1985-11-06 | 1987-05-21 | Res Assoc Petroleum Alternat Dev<Rapad> | çåæ°ŽçŽ ã®è£œé æ³ |
| US4874732A (en) * | 1987-07-13 | 1989-10-17 | Uop | Cobalt Fischer-Tropsch catalysts having improved selectivity |
| JP5483045B2 (ja) * | 2008-06-20 | 2014-05-07 | ç¬ç«è¡æ¿æ³äººç£æ¥æè¡ç·åç 究æ | äžé žåççŽ ãšæ°ŽçŽ ããã®çåæ°ŽçŽ ã®è£œé æ¹æ³ |
| US7943674B1 (en) * | 2009-11-20 | 2011-05-17 | Chevron U.S.A. Inc. | Zeolite supported cobalt hybrid fischer-tropsch catalyst |
| JP5482709B2 (ja) * | 2011-03-31 | 2014-05-07 | ã³ã¹ã¢ç³æ²¹æ ªåŒäŒç€Ÿ | ã¬ãœãªã³åºæãåã³ã¬ãœãªã³åºæã®è£œé æ¹æ³ |
| JP5482708B2 (ja) * | 2011-03-31 | 2014-05-07 | ã³ã¹ã¢ç³æ²¹æ ªåŒäŒç€Ÿ | ã¬ãœãªã³åºæãåã³ã¬ãœãªã³åºæã®è£œé æ¹æ³ |
| JP5683015B2 (ja) * | 2011-06-17 | 2015-03-11 | ã³ã¹ã¢ç³æ²¹æ ªåŒäŒç€Ÿ | ã¬ãœãªã³çµæç©åã³ã¬ãœãªã³çµæç©ã®è£œé æ¹æ³ |
| JP5683012B2 (ja) * | 2011-06-17 | 2015-03-11 | ã³ã¹ã¢ç³æ²¹æ ªåŒäŒç€Ÿ | ã¬ãœãªã³çµæç©åã³ã¬ãœãªã³çµæç©ã®è£œé æ¹æ³ |
| JP5683013B2 (ja) * | 2011-06-17 | 2015-03-11 | ã³ã¹ã¢ç³æ²¹æ ªåŒäŒç€Ÿ | ã¬ãœãªã³çµæç©åã³ã¬ãœãªã³çµæç©ã®è£œé æ¹æ³ |
| JP5683014B2 (ja) * | 2011-06-17 | 2015-03-11 | ã³ã¹ã¢ç³æ²¹æ ªåŒäŒç€Ÿ | ã¬ãœãªã³çµæç©åã³ã¬ãœãªã³çµæç©ã®è£œé æ¹æ³ |
| JP5683011B2 (ja) * | 2011-06-17 | 2015-03-11 | ã³ã¹ã¢ç³æ²¹æ ªåŒäŒç€Ÿ | ã¬ãœãªã³çµæç©åã³ã¬ãœãªã³çµæç©ã®è£œé æ¹æ³ |
| JP5683016B2 (ja) * | 2011-06-17 | 2015-03-11 | ã³ã¹ã¢ç³æ²¹æ ªåŒäŒç€Ÿ | ã¬ãœãªã³çµæç©åã³ã¬ãœãªã³çµæç©ã®è£œé æ¹æ³ |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50142502A (ja) * | 1974-04-24 | 1975-11-17 | ||
| US4206134A (en) * | 1979-03-12 | 1980-06-03 | Exxon Research & Engineering Co. | Ruthenium supported on manganese oxide as hydrocarbon synthesis catalysts in CO/H2 reactions |
| JPS56136890A (en) * | 1980-03-24 | 1981-10-26 | Mobil Oil Corp | Conversion of synthetic gas to hydrocarbon rich in straight chain alpha olefin |
-
1982
- 1982-05-04 JP JP57073456A patent/JPS58192834A/ja active Granted
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS50142502A (ja) * | 1974-04-24 | 1975-11-17 | ||
| US4206134A (en) * | 1979-03-12 | 1980-06-03 | Exxon Research & Engineering Co. | Ruthenium supported on manganese oxide as hydrocarbon synthesis catalysts in CO/H2 reactions |
| JPS56136890A (en) * | 1980-03-24 | 1981-10-26 | Mobil Oil Corp | Conversion of synthetic gas to hydrocarbon rich in straight chain alpha olefin |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS58192834A (ja) | 1983-11-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4622308A (en) | Catalyst for the production of hydrocarbons from the synthesis gas | |
| CA1196617A (en) | Catalyst composition, method for its production and its use in the production of hydrocarbons from synthesis gas | |
| US4556645A (en) | Enhanced catalyst for conversion of syngas to liquid motor fuels | |
| US4172843A (en) | Conversion of synthesis gas to high octane predominantly olefinic naphtha | |
| JPH0245605B2 (ja) | ||
| US4371628A (en) | Process for the preparation of aromatic hydrocarbons using crystalline silicates as catalyst | |
| JPH0118013B2 (ja) | ||
| JPS59219388A (ja) | äžéçåºæ²¹ã®è£œé æ¹æ³ | |
| US4698449A (en) | Crystalline silicates, and processes for the production or use thereof | |
| US4617320A (en) | Enhanced conversion of syngas to liquid motor fuels | |
| US4292410A (en) | Process for the preparation of hydrocarbons from synthesis gas | |
| US4361503A (en) | Catalyst for converting synthesis gas to high octane predominantly olefinic naphtha | |
| EP0018683B1 (en) | Process for the preparation of hydrocarbons, and hydrocarbons so prepared | |
| US4463101A (en) | Catalyst for converting synthesis gas to high octane predominantly olefinic naphtha | |
| JPH0528278B2 (ja) | ||
| CA1128964A (en) | Process for the preparation of hydrocarbons | |
| EP0192289B1 (en) | Process for the preparation of an aromatic hydrocarbons-containing mixture | |
| JPH028776B2 (ja) | ||
| EP0133591B1 (en) | Process for the preparation of an aromatic hydrocarbon mixture | |
| JPH0528279B2 (ja) | ||
| RU2242279C2 (ru) | ÐаÑалОзаÑÐŸÑ ÐŽÐ»Ñ Ð¿ÑевÑаÑÐµÐœÐžÑ Ð¿Ð°ÑаÑОМПвÑÑ ÑглевПЎПÑПЎПв Ñ2-Ñ5, ÑпПÑПб егП пПлÑÑÐµÐœÐžÑ Ðž ÑпПÑПб пÑевÑаÑÐµÐœÐžÑ Ð¿Ð°ÑаÑОМПвÑÑ ÑглевПЎПÑПЎПв Ñ2-Ñ5 в МОзÑОе ПлеÑÐžÐœÑ | |
| EP0012534B1 (en) | Conversion of synthesis gas with iron-containing catalyst | |
| JPH0261518B2 (ja) | ||
| JPH0212452B2 (ja) | ||
| JPS59199791A (ja) | çåæ°ŽçŽ ã®è£œé æ¹æ³ |