JPH0244282B2 - - Google Patents
Info
- Publication number
- JPH0244282B2 JPH0244282B2 JP56500931A JP50093181A JPH0244282B2 JP H0244282 B2 JPH0244282 B2 JP H0244282B2 JP 56500931 A JP56500931 A JP 56500931A JP 50093181 A JP50093181 A JP 50093181A JP H0244282 B2 JPH0244282 B2 JP H0244282B2
- Authority
- JP
- Japan
- Prior art keywords
- glass
- particles
- composites
- microns
- barium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 53
- 239000011521 glass Substances 0.000 description 38
- 239000002245 particle Substances 0.000 description 37
- 239000002131 composite material Substances 0.000 description 30
- 239000000945 filler Substances 0.000 description 23
- 230000002209 hydrophobic effect Effects 0.000 description 19
- 239000000377 silicon dioxide Substances 0.000 description 19
- 229910052788 barium Inorganic materials 0.000 description 16
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 16
- 239000000463 material Substances 0.000 description 16
- 239000011350 dental composite resin Substances 0.000 description 15
- HWSSEYVMGDIFMH-UHFFFAOYSA-N 2-[2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOCCOC(=O)C(C)=C HWSSEYVMGDIFMH-UHFFFAOYSA-N 0.000 description 11
- QUZSUMLPWDHKCJ-UHFFFAOYSA-N bisphenol A dimethacrylate Chemical class C1=CC(OC(=O)C(=C)C)=CC=C1C(C)(C)C1=CC=C(OC(=O)C(C)=C)C=C1 QUZSUMLPWDHKCJ-UHFFFAOYSA-N 0.000 description 9
- 238000001723 curing Methods 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 8
- 239000004342 Benzoyl peroxide Substances 0.000 description 7
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 7
- 235000019400 benzoyl peroxide Nutrition 0.000 description 7
- 125000005372 silanol group Chemical group 0.000 description 7
- YVJVQYNIANZFFM-UHFFFAOYSA-N 2-(4-methylanilino)ethanol Chemical compound CC1=CC=C(NCCO)C=C1 YVJVQYNIANZFFM-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 238000009826 distribution Methods 0.000 description 5
- DXGLGDHPHMLXJC-UHFFFAOYSA-N oxybenzone Chemical compound OC1=CC(OC)=CC=C1C(=O)C1=CC=CC=C1 DXGLGDHPHMLXJC-UHFFFAOYSA-N 0.000 description 5
- 238000001179 sorption measurement Methods 0.000 description 5
- 229910002012 Aerosil® Inorganic materials 0.000 description 4
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 4
- AMFGWXWBFGVCKG-UHFFFAOYSA-N Panavia opaque Chemical compound C1=CC(OCC(O)COC(=O)C(=C)C)=CC=C1C(C)(C)C1=CC=C(OCC(O)COC(=O)C(C)=C)C=C1 AMFGWXWBFGVCKG-UHFFFAOYSA-N 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000003963 antioxidant agent Substances 0.000 description 3
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 3
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 3
- 239000005351 kimble Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000011347 resin Substances 0.000 description 3
- 229920005989 resin Polymers 0.000 description 3
- 239000006097 ultraviolet radiation absorber Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 239000005046 Chlorosilane Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 230000003078 antioxidant effect Effects 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical compound Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 description 2
- LIKFHECYJZWXFJ-UHFFFAOYSA-N dimethyldichlorosilane Chemical compound C[Si](C)(Cl)Cl LIKFHECYJZWXFJ-UHFFFAOYSA-N 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- RZXMPPFPUUCRFN-UHFFFAOYSA-N p-toluidine Chemical compound CC1=CC=C(N)C=C1 RZXMPPFPUUCRFN-UHFFFAOYSA-N 0.000 description 2
- 229910052712 strontium Inorganic materials 0.000 description 2
- CIOAGBVUUVVLOB-UHFFFAOYSA-N strontium atom Chemical compound [Sr] CIOAGBVUUVVLOB-UHFFFAOYSA-N 0.000 description 2
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910000497 Amalgam Inorganic materials 0.000 description 1
- 238000012935 Averaging Methods 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000006095 Cer-Vit Substances 0.000 description 1
- AFBPFSWMIHJQDM-UHFFFAOYSA-N N-methyl-N-phenylamine Natural products CNC1=CC=CC=C1 AFBPFSWMIHJQDM-UHFFFAOYSA-N 0.000 description 1
- 229910008051 Si-OH Inorganic materials 0.000 description 1
- 229910006358 Si—OH Inorganic materials 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- 150000001553 barium compounds Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000007767 bonding agent Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 210000004268 dentin Anatomy 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 229910001385 heavy metal Inorganic materials 0.000 description 1
- 210000004283 incisor Anatomy 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- QPJVMBTYPHYUOC-UHFFFAOYSA-N methyl benzoate Chemical compound COC(=O)C1=CC=CC=C1 QPJVMBTYPHYUOC-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000004626 scanning electron microscopy Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
Landscapes
- Health & Medical Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Plastic & Reconstructive Surgery (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Dental Preparations (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US06/120,119 US4297266A (en) | 1980-02-08 | 1980-02-08 | Microfilled dental composite and method using the same |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS57500150A JPS57500150A (en, 2012) | 1982-01-28 |
JPH0244282B2 true JPH0244282B2 (en, 2012) | 1990-10-03 |
Family
ID=22388379
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP56500931A Expired - Lifetime JPH0244282B2 (en, 2012) | 1980-02-08 | 1981-01-02 |
Country Status (6)
Country | Link |
---|---|
US (1) | US4297266A (en, 2012) |
EP (1) | EP0045793B2 (en, 2012) |
JP (1) | JPH0244282B2 (en, 2012) |
AU (1) | AU528332B2 (en, 2012) |
BR (1) | BR8106608A (en, 2012) |
WO (1) | WO1981002254A1 (en, 2012) |
Families Citing this family (57)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3034374A1 (de) * | 1980-09-12 | 1982-08-19 | DMG Dental-Material GmbH, 2000 Hamburg | Mineralische teilchen |
EP0049559A3 (en) * | 1980-09-29 | 1982-05-12 | Sybron Corporation | Dental restorative compositions |
EP0053442B2 (en) * | 1980-12-03 | 1993-05-19 | Imperial Chemical Industries Plc | Dental compositions |
ATE13808T1 (de) | 1981-03-24 | 1985-07-15 | Blendax Werke Schneider Co | Dentales fuellungsmaterial. |
NZ204975A (en) * | 1982-08-02 | 1985-10-11 | Johnson & Johnson Dental Prod | Polymerisable dental restorative compositions having improved mechanical properties and hydrolytic stability |
US4500657A (en) * | 1982-08-02 | 1985-02-19 | Johnson & Johnson Dental Products Company | Dental restorative compositions having improved mechanical properties and hydrolytic stability |
US4492777A (en) * | 1982-11-26 | 1985-01-08 | Johnson & Johnson Dental Products Co. | Heat treated barium or strontium glass |
GB2150141B (en) * | 1983-11-24 | 1987-04-29 | Glaverbel | Compositions incorporating glass beads and methods of preparing them |
DE3342601C1 (de) * | 1983-11-25 | 1985-03-14 | Blendax-Werke R. Schneider Gmbh & Co, 6500 Mainz | Verwendung von bromierten aromatischen Diacrylsaeure- bzw. Dimethacrylsaeureestern in dentalen Fuellungsmaterialien |
US4544359A (en) * | 1984-01-13 | 1985-10-01 | Pentron Corporation | Dental restorative material |
DE3403040A1 (de) * | 1984-01-30 | 1985-08-08 | Blendax-Werke R. Schneider Gmbh & Co, 6500 Mainz | Dentales fuellungsmaterial |
US4503169A (en) * | 1984-04-19 | 1985-03-05 | Minnesota Mining And Manufacturing Company | Radiopaque, low visual opacity dental composites containing non-vitreous microparticles |
DE3421157A1 (de) * | 1984-06-07 | 1985-12-12 | Ernst Leitz Wetzlar Gmbh, 6330 Wetzlar | Verbundwerkstoff auf kunststoffbasis fuer prothetische zwecke |
AU595803B2 (en) * | 1985-06-07 | 1990-04-12 | Cheetham, Jeffrey James | Dental pit and fissure sealant |
JPH0791170B2 (ja) * | 1986-09-30 | 1995-10-04 | 株式会社クラレ | 歯科用複合材料 |
DE3708618A1 (de) * | 1987-03-17 | 1988-09-29 | Kulzer & Co Gmbh | Kunststoff-zahnersatzteil |
US4792577A (en) * | 1987-07-16 | 1988-12-20 | Johnson & Johnson Consumer Products, Inc. | Stain-resistant no-mix orthodontic adhesive |
US4859716A (en) * | 1987-11-06 | 1989-08-22 | Den-Mat Corporation | Microfilled dental composite and method for making it |
JPH0725648B2 (ja) * | 1988-08-02 | 1995-03-22 | クルツァ ゲーエムベーハー | プラスチック義歯部材 |
JP2719939B2 (ja) * | 1988-11-14 | 1998-02-25 | 三菱レイヨン株式会社 | 難燃性ポリフエニレンエーテル樹脂組成物 |
WO1990008799A1 (en) * | 1989-01-27 | 1990-08-09 | Neil Rex Hall | Reinforced composite resin |
US5266609A (en) * | 1989-01-27 | 1993-11-30 | Hall Neil R | Dental restorative adhesive having improved fracture toughness |
JP2701165B2 (ja) * | 1989-05-09 | 1998-01-21 | 株式会社モリタ製作所 | 接着性組成物、合成歯石用組成物および合成歯石用キット |
US5088927A (en) * | 1990-06-18 | 1992-02-18 | Lee Howard G | Radio opaque plastics and process of making |
ATE114241T1 (de) * | 1990-11-17 | 1994-12-15 | Heraeus Kulzer Gmbh | Polymerisierbares dentalmaterial. |
DE4100604C1 (en, 2012) * | 1991-01-11 | 1992-02-27 | Schott Glaswerke, 6500 Mainz, De | |
GB9110883D0 (en) * | 1991-05-20 | 1991-07-10 | Ici Plc | Highly filled,polymerisable compositions |
US5423680A (en) * | 1993-11-10 | 1995-06-13 | Jeneric/Pentron, Incorporated | Palladium, gallium and copper-free alloy having high thermal expansion coefficient |
US5462437A (en) * | 1993-11-10 | 1995-10-31 | Jeneric/Pentron Incorporated | Dental alloys for composite and porcelain overlays |
DE4412831C2 (de) * | 1994-04-14 | 1996-03-21 | Heraeus Kulzer Gmbh | Künstlicher Zahn |
US5547379A (en) | 1994-10-06 | 1996-08-20 | Hasel; Robert W. | Method of restoring a tooth |
DE4446033C2 (de) * | 1994-12-23 | 1996-11-07 | Heraeus Kulzer Gmbh | Polymerisierbares Dentalmaterial |
US6063830A (en) * | 1996-12-06 | 2000-05-16 | Kabushiki Kaisha Shofu | Dental curable composition and artificial tooth |
JPH10323353A (ja) * | 1997-05-26 | 1998-12-08 | G C:Kk | 歯科用レジン材料及びその作製方法 |
EP0969789B2 (en) | 1997-10-03 | 2015-08-19 | DENTSPLY International Inc. | Dental materials having a nanoscale filler |
US6693143B2 (en) | 1997-10-03 | 2004-02-17 | Dentsply Detrey Gmbh | Dental materials having a nanoscale filler |
US6362250B1 (en) | 1998-03-17 | 2002-03-26 | Jeneric/Pentron Incorporated | Dental bridges comprising fiber reinforced frameworks with fiber or particulate reinforced veneers |
WO2000002525A1 (en) * | 1998-07-10 | 2000-01-20 | New Age Biomaterials, Inc. | Composite veneered cast glass-ceramic dental construct |
EP1143915B1 (en) | 1999-01-08 | 2004-12-01 | 3M Innovative Properties Company | Dental mill blanks |
AU4206300A (en) * | 1999-04-07 | 2000-10-23 | Kimberly-Clark Worldwide, Inc. | Creping adhesive and products and process incorporating same |
US7001932B2 (en) * | 1999-04-12 | 2006-02-21 | Dentsply Detrey Gmbh | Dental composite restorative material and method of restoring a tooth |
EP1169009B1 (en) | 1999-04-12 | 2006-04-26 | Dentsply International, Inc. | Dental composite restorative material and method of restoring a tooth |
EP1101484B1 (en) | 1999-11-17 | 2007-01-10 | Kabushiki Kaisha Shofu | Dental fillers |
US8026295B2 (en) * | 2000-02-17 | 2011-09-27 | Dentsply International, Inc. | Dental composition with improved light stability |
US20040225029A1 (en) * | 2000-02-17 | 2004-11-11 | Uwe Walz | Dental composition with improved light stability |
US20030225182A1 (en) * | 2001-01-04 | 2003-12-04 | Dentsply Detrey Gmbh | Dental composition with improved light stability |
WO2002013767A2 (en) | 2000-08-11 | 2002-02-21 | Dentsply International Inc. | Polyaminoester and their application in dental compositions |
US20030069327A1 (en) * | 2001-08-09 | 2003-04-10 | Uwe Walz | Dental compostions comprising bisacrylamides and use thereof |
US20040171716A1 (en) * | 2002-12-03 | 2004-09-02 | Uwe Walz | Dental compositions comprising bisacrylamides and use thereof |
DE60206933T2 (de) * | 2001-08-13 | 2006-07-27 | Dentsply International Inc. | Konus zur Füllung von Zahnwurzelkanälen |
EP1290997A1 (en) * | 2001-09-05 | 2003-03-12 | Degussa AG | Homogeneous microfilled dental composite material and method of preparation |
US20040209990A1 (en) * | 2003-04-15 | 2004-10-21 | Uwe Walz | Low shrinking polymerizable dental material |
US20060115783A1 (en) * | 2004-12-01 | 2006-06-01 | Mclaren Edwin C | Apparatus and method for curing a light curable adhesive |
CA2619755A1 (en) * | 2005-09-14 | 2007-03-22 | Danville Materials, Inc. | Composite paste for dental prostheses |
DE102005061965A1 (de) * | 2005-12-23 | 2007-07-05 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Oxidische Agglomeratpartikel, Verfahren zur Herstellung von Nanokompositen sowie deren Verwendung |
JP5943672B2 (ja) * | 2012-03-28 | 2016-07-05 | クラレノリタケデンタル株式会社 | 歯科用複合化無機充填材 |
DE102017105841A1 (de) * | 2017-03-17 | 2018-09-20 | Voco Gmbh | Fräsrohling zur Herstellung einer indirekten dentalen Restauration, entsprechende Verwendungen und Verfahren |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA878004A (en) * | 1968-06-14 | 1971-08-10 | Ii Henry L. Lee | Dental filling package |
AU477135B2 (en) * | 1972-11-14 | 1974-05-15 | The B. F. Goodrich Company | Fabric cutting |
US3770811A (en) * | 1973-03-23 | 1973-11-06 | H Lee | Diacrylate esters of hydrogenated bis-phenol and tolylene |
US4032504A (en) * | 1973-09-28 | 1977-06-28 | Lee Pharmaceuticals | X-ray opaque filler useful in dental and medical restorative compounds |
DE2462271A1 (de) * | 1974-01-23 | 1976-09-09 | Dentaire Ivoclar Ets | Dentale formkoerper |
FR2272638B1 (en, 2012) * | 1974-01-23 | 1982-06-25 | Perdent Gmbh | |
JPS50116581A (en, 2012) * | 1974-02-13 | 1975-09-11 | ||
US4150012A (en) * | 1977-01-21 | 1979-04-17 | Minnesota Mining And Manufacturing Company | Discernible dental sealant |
US4220582A (en) * | 1979-01-03 | 1980-09-02 | Lee Pharmaceuticals | Dental restorative compositions of improved X-ray opacity |
-
1980
- 1980-02-08 US US06/120,119 patent/US4297266A/en not_active Expired - Lifetime
-
1981
- 1981-01-02 WO PCT/US1981/000031 patent/WO1981002254A1/en active IP Right Grant
- 1981-01-02 EP EP81900703A patent/EP0045793B2/en not_active Expired
- 1981-01-02 AU AU69216/81A patent/AU528332B2/en not_active Ceased
- 1981-01-02 BR BR8106608A patent/BR8106608A/pt unknown
- 1981-01-02 JP JP56500931A patent/JPH0244282B2/ja not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPS57500150A (en, 2012) | 1982-01-28 |
EP0045793A4 (en) | 1982-03-29 |
WO1981002254A1 (en) | 1981-08-20 |
AU6921681A (en) | 1981-08-31 |
AU528332B2 (en) | 1983-04-21 |
US4297266A (en) | 1981-10-27 |
EP0045793A1 (en) | 1982-02-17 |
EP0045793B2 (en) | 1988-04-06 |
BR8106608A (pt) | 1981-12-22 |
EP0045793B1 (en) | 1985-09-18 |
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