JPH0237540B2 - - Google Patents
Info
- Publication number
- JPH0237540B2 JPH0237540B2 JP57050265A JP5026582A JPH0237540B2 JP H0237540 B2 JPH0237540 B2 JP H0237540B2 JP 57050265 A JP57050265 A JP 57050265A JP 5026582 A JP5026582 A JP 5026582A JP H0237540 B2 JPH0237540 B2 JP H0237540B2
- Authority
- JP
- Japan
- Prior art keywords
- electrode
- platinum
- solid electrolyte
- detector
- silver
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 32
- 229910052697 platinum Inorganic materials 0.000 claims description 16
- 229910000510 noble metal Inorganic materials 0.000 claims description 13
- 229910052709 silver Inorganic materials 0.000 claims description 12
- 239000004332 silver Substances 0.000 claims description 12
- 239000007784 solid electrolyte Substances 0.000 claims description 12
- 239000007789 gas Substances 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 5
- 229910052760 oxygen Inorganic materials 0.000 claims description 5
- 239000001301 oxygen Substances 0.000 claims description 5
- 229910052703 rhodium Inorganic materials 0.000 claims description 5
- 239000010948 rhodium Substances 0.000 claims description 5
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims description 5
- MCMNRKCIXSYSNV-UHFFFAOYSA-N ZrO2 Inorganic materials O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 4
- 229910045601 alloy Inorganic materials 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 3
- YXTPWUNVHCYOSP-UHFFFAOYSA-N bis($l^{2}-silanylidene)molybdenum Chemical compound [Si]=[Mo]=[Si] YXTPWUNVHCYOSP-UHFFFAOYSA-N 0.000 claims description 3
- 229910021343 molybdenum disilicide Inorganic materials 0.000 claims description 3
- 239000010970 precious metal Substances 0.000 claims description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 3
- 229910000629 Rh alloy Inorganic materials 0.000 claims 2
- PXXKQOPKNFECSZ-UHFFFAOYSA-N platinum rhodium Chemical compound [Rh].[Pt] PXXKQOPKNFECSZ-UHFFFAOYSA-N 0.000 claims 2
- 239000010410 layer Substances 0.000 description 16
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 11
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 239000011247 coating layer Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000000725 suspension Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 150000002739 metals Chemical class 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 229910052596 spinel Inorganic materials 0.000 description 3
- 239000011029 spinel Substances 0.000 description 3
- 229910018921 CoO 3 Inorganic materials 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 230000010287 polarization Effects 0.000 description 2
- 229910021193 La 2 O 3 Inorganic materials 0.000 description 1
- 229910001252 Pd alloy Inorganic materials 0.000 description 1
- 229910001260 Pt alloy Inorganic materials 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 239000011532 electronic conductor Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 150000003057 platinum Chemical class 0.000 description 1
- 229910000923 precious metal alloy Inorganic materials 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- -1 silver or palladium Chemical class 0.000 description 1
- 238000005245 sintering Methods 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electrochemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/403—Cells and electrode assemblies
- G01N27/406—Cells and probes with solid electrolytes
- G01N27/407—Cells and probes with solid electrolytes for investigating or analysing gases
- G01N27/4075—Composition or fabrication of the electrodes and coatings thereon, e.g. catalysts
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B11/00—Electrodes; Manufacture thereof not otherwise provided for
- C25B11/04—Electrodes; Manufacture thereof not otherwise provided for characterised by the material
- C25B11/051—Electrodes formed of electrocatalysts on a substrate or carrier
- C25B11/073—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material
- C25B11/091—Electrodes formed of electrocatalysts on a substrate or carrier characterised by the electrocatalyst material consisting of at least one catalytic element and at least one catalytic compound; consisting of two or more catalytic elements or catalytic compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/10—Fuel cells with solid electrolytes
- H01M8/12—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte
- H01M8/1213—Fuel cells with solid electrolytes operating at high temperature, e.g. with stabilised ZrO2 electrolyte characterised by the electrode/electrolyte combination or the supporting material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
- H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9016—Oxides, hydroxides or oxygenated metallic salts
- H01M4/9025—Oxides specially used in fuel cell operating at high temperature, e.g. SOFC
- H01M4/9033—Complex oxides, optionally doped, of the type M1MeO3, M1 being an alkaline earth metal or a rare earth, Me being a metal, e.g. perovskites
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9041—Metals or alloys
- H01M4/905—Metals or alloys specially used in fuel cell operating at high temperature, e.g. SOFC
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- General Health & Medical Sciences (AREA)
- Metallurgy (AREA)
- Molecular Biology (AREA)
- Materials Engineering (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- Organic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Manufacturing & Machinery (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- General Chemical & Material Sciences (AREA)
- Measuring Oxygen Concentration In Cells (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19813112739 DE3112739A1 (de) | 1981-03-31 | 1981-03-31 | "strukturstabile elektrode fuer festelektrolyte fuer elektrochemische anwendungen sowie verwendung einer solchen elektrode in elektrochemischen messfuehlern zur bestimmung des sauerstoffgehaltes in gasen" |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57175251A JPS57175251A (en) | 1982-10-28 |
| JPH0237540B2 true JPH0237540B2 (enrdf_load_stackoverflow) | 1990-08-24 |
Family
ID=6128828
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP57050265A Granted JPS57175251A (en) | 1981-03-31 | 1982-03-30 | Structurally stable electrode for solid electrolyte and electrochemical detector |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JPS57175251A (enrdf_load_stackoverflow) |
| DE (1) | DE3112739A1 (enrdf_load_stackoverflow) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2541530B2 (ja) * | 1985-10-29 | 1996-10-09 | コモンウェルス、サイエンティフィク、エンド、インダストリアル、リサ−チ、オ−ガナイゼ−ション | 固体電解質装置及びその製造方法 |
| US5134042A (en) * | 1986-11-26 | 1992-07-28 | Sri International | Solid compositions for fuel cells, sensors and catalysts |
| US4851303A (en) * | 1986-11-26 | 1989-07-25 | Sri-International | Solid compositions for fuel cells, sensors and catalysts |
| DE3910037A1 (de) * | 1989-03-28 | 1991-04-25 | Gyulai Maria Dobosne | Elektrochemische sauerstoffanordnung |
| DE4009747A1 (de) * | 1989-03-28 | 1991-10-02 | Gyulai Maria Dobosne | Elektrochemische sauerstoffanordnung (elektrochemische sauerstoff-messanordnung) |
| DE3935311A1 (de) * | 1989-10-24 | 1991-04-25 | Asea Brown Boveri | Brennstoffzellenanordnung |
| DE4021929C2 (de) * | 1990-07-10 | 1998-04-30 | Abb Patent Gmbh | Sensor |
| DE4225775C2 (de) † | 1992-08-04 | 2002-09-19 | Heraeus Electro Nite Int | Anordnung zum kontinuierlichen Überwachen der Konzentration von NO in Gasgemischen |
| DE4424539C2 (de) * | 1993-07-12 | 1998-04-30 | Unisia Jecs Corp | Element zur Erfassung eines Luft-Kraftstoff-Verhältnisses |
| JP2545050B2 (ja) * | 1995-05-26 | 1996-10-16 | 日本特殊陶業株式会社 | 酸素センサ素子 |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DD87024A (enrdf_load_stackoverflow) * | ||||
| GB1201806A (en) * | 1967-11-23 | 1970-08-12 | Kent Ltd G | Improvements in or relating to electrode assemblies |
| GB1249300A (en) * | 1967-12-27 | 1971-10-13 | Ici Ltd | Electrodes for electrochemical processes |
| US3616446A (en) * | 1969-03-28 | 1971-10-26 | Ppg Industries Inc | Method of coating an electrode |
| CA967508A (en) * | 1970-11-02 | 1975-05-13 | Paul P. Anthony | Electrodes |
| NL7204743A (en) * | 1972-04-08 | 1973-06-25 | Electrochemical electrode - consisting of electrochemically resistant double metal oxide | |
| FR2230402B1 (enrdf_load_stackoverflow) * | 1973-03-30 | 1975-10-31 | Anvar | |
| US4042483A (en) * | 1973-07-20 | 1977-08-16 | Rhone-Progil | Electrolysis cell electrode and method of preparation |
| JPS5334077B2 (enrdf_load_stackoverflow) * | 1973-08-29 | 1978-09-19 | ||
| IN143553B (enrdf_load_stackoverflow) * | 1973-10-26 | 1977-12-24 | Ici Ltd | |
| GB1524195A (en) * | 1974-12-09 | 1978-09-06 | Kent Ltd | Bonding of metals to solid electrolytes |
| GB1524520A (en) * | 1974-12-09 | 1978-09-13 | Kent Ltd G | Bonding of metals to solid electrolytes |
| FR2312573A1 (fr) * | 1975-05-30 | 1976-12-24 | Rhone Poulenc Ind | Nouvelle electrode pour cellule d'electrolyse |
| US4146438A (en) * | 1976-03-31 | 1979-03-27 | Diamond Shamrock Technologies S.A. | Sintered electrodes with electrocatalytic coating |
| DD131568A5 (de) * | 1976-05-17 | 1978-07-05 | Diamond Shamrock Techn | Elektrode |
| US4075070A (en) * | 1976-06-09 | 1978-02-21 | Ppg Industries, Inc. | Electrode material |
| DE2747467C2 (de) * | 1977-10-22 | 1979-10-11 | Dornier System Gmbh, 7990 Friedrichshafen | Cermet-Elektroden für Festelektrolytzellen und Verfahren zu ihrer Herstellung |
| BR7902625A (pt) * | 1978-05-04 | 1979-11-27 | Du Pont | Aperfeicoamento em sensor de concentracao de oxigenio |
| DE2837118C2 (de) * | 1978-08-25 | 1982-05-19 | Dornier System Gmbh, 7990 Friedrichshafen | Poröse Oxidelektroden für elektrochemische Hochtemperaturzellen |
| DE2852638C2 (de) * | 1978-12-06 | 1986-01-16 | Robert Bosch Gmbh, 7000 Stuttgart | Gassensor mit Cermet- Elektroden |
| DE2922131A1 (de) * | 1979-05-31 | 1980-12-18 | Bosch Gmbh Robert | Polarographischer messfuehler fuer die bestimmung des sauerstoffgehaltes in gasen, insbesondere in abgasen von verbrennungsmotoren |
| JPS5692447A (en) * | 1979-12-26 | 1981-07-27 | Nissan Motor Co Ltd | Production of film-structure oxygen sensor element |
-
1981
- 1981-03-31 DE DE19813112739 patent/DE3112739A1/de active Granted
-
1982
- 1982-03-30 JP JP57050265A patent/JPS57175251A/ja active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| DE3112739A1 (de) | 1982-10-07 |
| JPS57175251A (en) | 1982-10-28 |
| DE3112739C2 (enrdf_load_stackoverflow) | 1990-10-18 |
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