JPH0228252B2 - - Google Patents

Info

Publication number
JPH0228252B2
JPH0228252B2 JP58081733A JP8173383A JPH0228252B2 JP H0228252 B2 JPH0228252 B2 JP H0228252B2 JP 58081733 A JP58081733 A JP 58081733A JP 8173383 A JP8173383 A JP 8173383A JP H0228252 B2 JPH0228252 B2 JP H0228252B2
Authority
JP
Japan
Prior art keywords
glass
film
pbo
melting point
manufacturing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP58081733A
Other languages
Japanese (ja)
Other versions
JPS59208729A (en
Inventor
Shigeru Honjo
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toshiba Corp
Original Assignee
Tokyo Shibaura Electric Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Tokyo Shibaura Electric Co Ltd filed Critical Tokyo Shibaura Electric Co Ltd
Priority to JP58081733A priority Critical patent/JPS59208729A/en
Publication of JPS59208729A publication Critical patent/JPS59208729A/en
Publication of JPH0228252B2 publication Critical patent/JPH0228252B2/ja
Granted legal-status Critical Current

Links

Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104Forming layers
    • H01L21/02107Forming insulating materials on a substrate

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Local Oxidation Of Silicon (AREA)
  • Formation Of Insulating Films (AREA)

Description

【発明の詳細な説明】 〔発明の技術分野〕 本発明は、半導体装置の製造方法に係り、特に
PbO系低融点ガラスで素子所定部分にパツシベー
シヨンを施したパワートランジスタ等の半導体装
置の製造方法に関するものである。
[Detailed Description of the Invention] [Technical Field of the Invention] The present invention relates to a method for manufacturing a semiconductor device, and particularly to a method for manufacturing a semiconductor device.
This invention relates to a method for manufacturing semiconductor devices such as power transistors in which predetermined portions of the device are passivated with PbO-based low melting point glass.

〔発明の技術的背景〕[Technical background of the invention]

パワートランジスタ等の半導体装置には低融点
ガラスのパツシベーシヨンが多用されているが、
低融点ガラスパツシベーシヨンの形成には、一般
にガラス粉末を電気泳動法により付着させこれを
焼成するという方法が採用されている。一方低融
点ガラスパツシベーシヨン以外の素子表面は、通
常酸化ケイ素(SiO2)膜によつて保護されてお
り、SiO2膜の上方をリンガラス化したPSG(ホス
ホシリケートガラス)パツシベーシヨン技術が多
用されている。
Low melting point glass passivation is often used in semiconductor devices such as power transistors.
In order to form a low-melting-point glass packaging, a method is generally employed in which glass powder is deposited by electrophoresis and then fired. On the other hand, the surface of the device other than the low-melting-point glass packaging is usually protected by a silicon oxide (SiO 2 ) film, and PSG (phosphosilicate glass) packaging technology, in which the upper part of the SiO 2 film is made into phosphor glass, is often used. has been done.

ところで低融点ガラスパツシベーシヨン用のガ
ラス種類としては、Zn系ガラスとPbO系ガラス
が使用されている。Zn系ガラスパツシベーシヨ
ンは、酸によつて侵され易いので、パツシベーシ
ヨン形成工程以後の製造工程でH2SO4、HCl、
HNO3等の酸処理が行われる場合には、パツシベ
ーシヨン部分をレジストやPSG膜でマスクをし
て酸処理をする必要があり、それだけ工程が繁雑
となつていた。また、マスクにピンホールがあり
完全でない場合には、ピンホールから酸が入り込
み、その結果素子に耐圧不良が多発していた。
By the way, Zn-based glass and PbO-based glass are used as types of glass for low-melting point glass partitions. Since Zn-based glass patties are easily attacked by acids, H 2 SO 4 , HCl,
When acid treatment such as HNO 3 is performed, it is necessary to mask the passivation area with a resist or PSG film before performing the acid treatment, making the process that much more complicated. Furthermore, if the mask had pinholes and was not perfect, acid would enter through the pinholes, resulting in frequent breakdown voltage failures in the device.

一方、PbO系低融点ガラスはZn系ガラスに比
較して酸によつて侵され難く、半導体製造の通常
酸処理工程では特別にマスクをして保護する必要
がないので、工程の短縮及び歩留向上を期待する
ことができるが、PbO系ガラスパツシベーシヨン
には下記のような問題点があり歩留の大幅な向上
は実現されていなかつたのである。
On the other hand, PbO-based low-melting glass is less susceptible to acid attack than Zn-based glass, and does not require special protection with a mask during the normal acid treatment process of semiconductor manufacturing, which shortens the process and improves yield. Although improvements can be expected, PbO-based glass percussion has the following problems, and a significant improvement in yield has not been achieved.

〔背景技術の問題点〕[Problems with background technology]

従来、電気泳動法によるPbO系低融点ガラスの
パツシベーシヨンは、第1図a〜dに示す工程で
行われていた。第1図a〜dはトランジスタの素
子断面で表されている。
Conventionally, the passivation of PbO-based low melting point glass by electrophoresis has been carried out in the steps shown in FIGS. 1a to 1d. 1A to 1D are cross-sectional views of transistor elements.

第1図aにおいて、素子1はコレクタN+層1
1、コレクタN-層12、ベース層13、エミツ
タ領域14からなり、その表面にSiO2膜2、
SiO2膜2の最上層にPSG膜3が形成されている。
そして基板はコレクタN-層12とベース層13
との間のPN接合に達する溝4が図示のごとくに
掘り込まれた状態で用意される。このようにガラ
スパツシベーシヨンする溝部4以外の素子表面が
SiO2膜2とPSG膜3でマスクした基板を、電気
泳動装置の電極と対向させてガラス粉末をアルコ
ール等の媒体に分散させたガラス液中に沈め、ガ
ラス粉末がプラスに帯電しているときは基板側に
マイナスの電圧を加えることにより、第1図bに
示すように、溝部4にガラス粉末41を泳動付着
させる。このときSiO2膜2、PSG膜3のマスク
にはピンホール等の欠陥が皆無というわけではな
いので、マスク欠陥部分にもボツ状のガラス5が
かならず付着してしまう。その後酢酸エチル等で
リンスして、溝部3以外に付着したガラスボツ5
を洗い流すが、ピンホール中に入つたガラス粉末
まで完全に除去することはできない。このような
状態で、O2雰囲気中800℃前後で数十分間熱処理
をしてガラス粉末を焼成すると、ガラスボツ5中
のPbとPSG膜3中のPとは異常反応を起こし、
焼成後第2図cに図示するように、溝部ガラス4
1をレジスト42でマスクしガラスボツ5をエツ
チング除去しても、PSG膜3のガラスボツ5が
異常反応した部分31は十分な絶縁性を保持する
ことができない。その後、第1図dのごとく電極
配線6を行つて素子を完成するが、ガラスボツ5
と異常反応31したPSG膜3は完成した素子に
特性上種々の不良を発生させる。
In FIG. 1a, element 1 has a collector N + layer 1
1. Consists of a collector N - layer 12, a base layer 13, and an emitter region 14, with a SiO 2 film 2 on its surface,
A PSG film 3 is formed on the top layer of the SiO 2 film 2.
And the substrate is collector N - layer 12 and base layer 13
A groove 4 reaching the PN junction between the two is prepared by being dug as shown in the figure. In this way, the surface of the element other than the groove 4 that undergoes glass percussion is
A substrate masked with SiO 2 film 2 and PSG film 3 is placed opposite the electrode of an electrophoresis device and immersed in a glass solution in which glass powder is dispersed in a medium such as alcohol, and when the glass powder is positively charged. By applying a negative voltage to the substrate side, the glass powder 41 is electrophoretically deposited in the groove 4, as shown in FIG. 1b. At this time, since the masks of the SiO 2 film 2 and the PSG film 3 are not completely free of defects such as pinholes, the glass spots 5 are inevitably attached to the defective portions of the masks. After that, rinse with ethyl acetate etc. to remove any glass bottles 5 that have adhered to areas other than the groove 3.
However, it is not possible to completely remove the glass powder that has entered the pinhole. When the glass powder is fired under such conditions by heat treatment at around 800°C for several tens of minutes in an O 2 atmosphere, an abnormal reaction occurs between Pb in the glass bottle 5 and P in the PSG film 3.
After firing, as shown in FIG. 2c, the groove glass 4
Even if the glass pots 5 are removed by etching while masking the PSG film 3 with the resist 42, the portion 31 of the PSG film 3 where the glass pots 5 have reacted abnormally cannot maintain sufficient insulation. Thereafter, as shown in FIG. 1d, the electrode wiring 6 is performed to complete the device.
The PSG film 3 that has undergone an abnormal reaction 31 causes various defects in characteristics in the completed device.

素子不良の例として、第2図素子平面図に示す
ように、エミツタ電極配線61直下にPSG膜の
異常反応部分31があると、エミツタ領域14と
ベース層13とが導通状態となり、IEBO(VEBO)シ
ヨート不良が発生する。
As an example of a device failure, as shown in the plan view of the device in FIG. 2, if there is an abnormally reactive portion 31 of the PSG film directly under the emitter electrode wiring 61, the emitter region 14 and the base layer 13 become electrically conductive, resulting in I EBO ( V EBO ) A shot defect occurs.

以上のように、従来の電気泳動法によるPbO系
低融点ガラスパツシベーシヨンの形成法では、素
子表面の絶縁膜上にもガラスが付着し、焼成時に
絶縁膜欠陥の発生を避けることができず、その結
果素子にとつてIEBOシヨート不良など、致命的な
不良原因となるという問題点があつた。
As described above, in the conventional electrophoresis method for forming PbO-based low-melting glass partitions, glass also adheres to the insulating film on the element surface, making it possible to avoid defects in the insulating film during firing. First, there was a problem in that this resulted in fatal defects such as IEBO shot defects for the device.

〔発明の目的〕[Purpose of the invention]

本発明の目的は、半導体素子のPbO系低融点ガ
ラスパツシベーシヨンを形成するにあたり、素子
表面の絶縁膜に欠陥を生ぜしめない半導体装置の
製造方法を提供することである。
An object of the present invention is to provide a method for manufacturing a semiconductor device that does not cause defects in the insulating film on the surface of the device when forming a PbO-based low melting point glass partition for the semiconductor device.

〔発明の概要〕[Summary of the invention]

本発明は、電気泳動法によるPbO系低融点ガラ
スパツシベーシヨン形成の場合に生ずる素子表面
の絶縁膜欠陥が、低融点ガラスに含有されるPbO
と絶縁膜に含有されるPとの反応によるものとの
知見を得てなされたものである。すなわち、本発
明の製造方法は、素子の所定部分に、PbOを含有
する低融点ガラスを電気泳動法により付着させた
後焼成したガラスパツシベーシヨンを有する半導
体装置を製造するにあたり、上記ガラスパツシベ
ーシヨン部分以外の素子表面保護膜の最上層に膜
厚2000Åを越えない窒化ケイ素膜を形成した後
に、上記PbOを含有する低融点ガラスの付着を行
うことを特徴とする。
The present invention aims to eliminate defects in the insulating film on the element surface that occur when forming a PbO-based low melting point glass partition by electrophoresis.
This was made based on the knowledge that this is due to a reaction between the P and P contained in the insulating film. In other words, the manufacturing method of the present invention provides a method for manufacturing a semiconductor device having a glass packaging in which a low-melting glass containing PbO is deposited on a predetermined portion of an element by electrophoresis and then fired. The method is characterized in that after a silicon nitride film with a thickness not exceeding 2000 Å is formed on the top layer of the element surface protection film other than the civation portion, the low melting point glass containing PbO is deposited.

電気泳動法によりガラス粉末を付着させるとき
は、所定部分以外にもガラスボツが付着するが、
本発明方法においては保護膜最上層に窒化ケイ素
膜が形成済みであるので、ガラス融点以上(例え
ば800℃)の焼成時にもガラスに含有される(例
えば50%程度)PbOと保護膜内層に含有されるP
との接触がなく異常反応を起こさず、その結果素
子表面保護膜の欠陥が防止できシヨート不良など
の製品の歩留りが改善できる。
When applying glass powder using electrophoresis, glass particles may adhere to areas other than the designated areas.
In the method of the present invention, a silicon nitride film has already been formed on the top layer of the protective film, so even during firing at temperatures above the glass melting point (e.g., 800°C), PbO, which is contained in the glass (for example, about 50%), is contained in the inner layer of the protective film. P to be
As a result, defects in the element surface protection film can be prevented and product yields such as shot defects can be improved.

本発明に適用できる窒化ケイ素膜は低圧CVD
(Chemical Vapor Deposition)法であつてもプ
ラズマCVD法であつてもよいことが確認されて
いる。窒化ケイ素膜の内層にはPを含有する
PSG膜が形成されていてもよいが、Pを含有し
ない保護膜とすることが望ましい。また泳動付着
したガラスボツをリンスする工程、さらに焼成し
たガラスボツをエツチング除去する工程を所望に
より付加することができる。
The silicon nitride film that can be applied to the present invention is produced by low-pressure CVD.
It has been confirmed that either the (Chemical Vapor Deposition) method or the plasma CVD method may be used. The inner layer of the silicon nitride film contains P.
Although a PSG film may be formed, it is preferable to use a protective film that does not contain P. Further, a step of rinsing the glass pots that have migrated thereon and a step of removing the fired glass pots by etching can be added as desired.

〔発明の実施例〕[Embodiments of the invention]

以下本発明製造方法の一実施例を第3図a〜g
の工程図に従つて説明する。第3図a〜gにおい
て第1図a〜dと同一符号で表示した部分は第1
図における部分と同じであるのでその説明を省略
する。
An example of the manufacturing method of the present invention is shown below in Figures 3a to 3g.
This will be explained according to the process diagram. In Figures 3a to 3g, parts indicated by the same symbols as in Figures 1a to d are
Since the parts are the same as those in the figure, their explanation will be omitted.

第3図aにおいて、ベース層13、SiO2膜2
およびエミツタ領域14を形成済みのトランジス
タ1が用意される。
In FIG. 3a, the base layer 13, the SiO 2 film 2
A transistor 1 with an emitter region 14 already formed is prepared.

第3図bにおいて、トランジスタ1の表面全体
にSi3N4膜7を低圧CVD(LP−CVD)法で1500〜
2000Åの膜厚で均一に形成する。
In Fig. 3b, a Si 3 N 4 film 7 is deposited over the entire surface of the transistor 1 using a low pressure CVD (LP-CVD) method.
Form a uniform film with a thickness of 2000 Å.

次に第3図cにおいて、コレクタN-層12と
ベース層13間のPN接合をガラスパツシベーシ
ヨンするために、先ず溝部4のSi3N4膜7とSiO2
2の一部をプラズマエツチング又はリン酸煮沸・
NH4Fエツチングにより除去する。この場合溝部
4以外の部分はレジストでマスクしておく。
Next, in FIG. 3c, in order to glass bond the PN junction between the collector N - layer 12 and the base layer 13, the Si 3 N 4 film 7 in the groove 4 and the SiO 2
A part of 2 is plasma etched or boiled in phosphoric acid.
Remove by NH 4 F etching. In this case, portions other than the groove portion 4 are masked with resist.

次に第3図dにおいて、基板1はHF:HAc
(酢酸):HNO3:=1:2:3のエツチング液等
によりコレクタベース接合に達する溝部4を形成
する。
Next, in FIG. 3d, the substrate 1 is HF:HAc
A groove 4 reaching the collector-base junction is formed using an etching solution of (acetic acid):HNO 3 :=1:2:3.

次に第3図eにおいて、例えばPbOガラス100
g、アルコール600c.c.、泳動浴用添加液20c.c.を混
合して十分均一にした電気泳動装置の電着液中に
基板を沈め、泳動装置の電極と基板との間に
100Vの電圧を2分間印加し、溝部4へガラス粉
末41を付着させる。付着させた基板は酢酸エチ
ル等のリンス液でリンスし、溝部4以外に付着し
たガラス粉末を洗い流す。しかし完全に洗浄する
ことはできず、素子表面にはガラスボツ5がかな
らず残る。そしてO2雰囲気中800℃で30分間ガラ
スの焼成を行う。
Next, in Figure 3e, for example, PbO glass 100
Submerge the substrate in the electrodeposition solution of the electrophoresis device, which has been made sufficiently uniform by mixing 600 c.c. of alcohol, and 20 c.c. of the additive liquid for the electrophoresis device, and place it between the electrode of the electrophoresis device and the substrate.
A voltage of 100 V is applied for 2 minutes to adhere the glass powder 41 to the groove 4. The adhered substrate is rinsed with a rinsing liquid such as ethyl acetate to wash away glass powder adhered to areas other than the grooves 4. However, it cannot be completely cleaned, and glass pots 5 always remain on the surface of the element. Then, the glass is fired at 800 °C for 30 minutes in an O2 atmosphere.

次に第3図fにおいて、焼成した溝部ガラス4
1の表面をレジスト42で保護し、HF:HCl=
1:9のエツチング液に基板を浸漬し、ガラスボ
ツ5をエツチング除去する。除去したあとの
Si3N4膜7には欠陥がみられなかつた。
Next, in FIG. 3 f, the fired groove glass 4
The surface of 1 was protected with resist 42, and HF:HCl=
The substrate is immersed in a 1:9 etching solution, and the glass pots 5 are etched away. after removing
No defects were observed in the Si 3 N 4 film 7.

次に第3図gにおいて周知の方法により電極穴
をあけ、電極6を形成し、PbO系低融点ガラスパ
ツシベーシヨンのパワートランジスタのペレツト
が完成する。
Next, as shown in FIG. 3g, electrode holes are made by a well-known method to form electrodes 6, thereby completing a power transistor pellet made of PbO-based low melting point glass packaging.

〔発明の効果〕〔Effect of the invention〕

本発明の製造方法によれば、素子表面の保護膜
最上層に窒化ケイ素膜を形成した後に、電気泳動
法によりPbOを含有する低融点ガラスを付着させ
次いで焼成するから、保護膜がPbOと異常反応す
ることがなく、その結果シヨート不良などの製品
特性不良を生じない。そのため、PbO系低融点ガ
ラスパツシベーシヨンの本来の利点(すなわちパ
ツシベーシヨン形成後の酸処理工程において低融
点ガラスをマスクして保護する必要がない)をも
ち、半導体装置製造工程の短縮及び歩留りの向上
が実現される。
According to the manufacturing method of the present invention, after forming a silicon nitride film on the top layer of the protective film on the element surface, low-melting glass containing PbO is attached by electrophoresis and then baked, so that the protective film is abnormally contaminated with PbO. There is no reaction, and as a result, there are no defects in product characteristics such as shot defects. Therefore, it has the inherent advantage of PbO-based low melting point glass passivation (that is, there is no need to mask and protect the low melting point glass in the acid treatment process after forming the passivation), shortens the semiconductor device manufacturing process, and improves yield. Improvements are realized.

【図面の簡単な説明】[Brief explanation of drawings]

第1図a〜dは従来のPbO系ガラスパツシベー
シヨン形成工程を説明するための素子断面図、第
2図は第1図a〜dの工程で製造された素子の製
品不良を説明するための素子平面図、第3図a〜
gは本発明製造方法の工程を説明するための素子
断面図である。 1……素子、2……保護膜(SiO2膜)、3……
保護膜(PSG膜)、31……保護膜欠陥、4……
溝部、41……PbO系低融点ガラス、5……ガラ
スボツ、6,61……電極配線、7……Si3N4
膜。
Figures 1 a to d are cross-sectional views of the device to explain the conventional PbO-based glass partition formation process, and Figure 2 illustrates product defects of the element manufactured by the process of Figures 1 a to d. Element plan view for Figure 3 a~
g is a cross-sectional view of an element for explaining the steps of the manufacturing method of the present invention. 1...Element, 2...Protective film (SiO 2 film), 3...
Protective film (PSG film), 31... Protective film defect, 4...
Groove, 41... PbO-based low melting point glass, 5... Glass pot, 6, 61... Electrode wiring, 7... Si 3 N 4
film.

Claims (1)

【特許請求の範囲】[Claims] 1 素子の所定部分に、PbOを含有する低融点ガ
ラスを電気泳動法により付着させた後焼成したガ
ラスパツシベーシヨンを有する半導体装置を製造
するにあたり、上記ガラスパツシベーシヨン部分
以外の素子表面保護膜の最上層に膜厚2000Åを超
えない窒化ケイ素膜を形成した後に、上記PbOを
含有する低融点ガラスの付着を行うことを特徴と
する半導体装置の製造方法。
1. When manufacturing a semiconductor device having a glass patency, which is obtained by attaching a low melting point glass containing PbO to a predetermined portion of the device by electrophoresis and then firing it, the surface of the device other than the glass patties is 1. A method for manufacturing a semiconductor device, comprising forming a silicon nitride film with a thickness not exceeding 2000 Å as the uppermost layer of a protective film, and then depositing the low melting point glass containing PbO.
JP58081733A 1983-05-12 1983-05-12 Manufacture of semiconductor device Granted JPS59208729A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP58081733A JPS59208729A (en) 1983-05-12 1983-05-12 Manufacture of semiconductor device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP58081733A JPS59208729A (en) 1983-05-12 1983-05-12 Manufacture of semiconductor device

Publications (2)

Publication Number Publication Date
JPS59208729A JPS59208729A (en) 1984-11-27
JPH0228252B2 true JPH0228252B2 (en) 1990-06-22

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JP58081733A Granted JPS59208729A (en) 1983-05-12 1983-05-12 Manufacture of semiconductor device

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JP (1) JPS59208729A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5453395A (en) * 1994-03-21 1995-09-26 United Microelectronics Corp. Isolation technology using liquid phase deposition
US5445989A (en) * 1994-08-23 1995-08-29 United Microelectronics Corp. Method of forming device isolation regions
CN1302523C (en) * 2004-12-21 2007-02-28 天津中环半导体股份有限公司 Glass deactivating forming process for table top rectifier

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5632735A (en) * 1979-08-27 1981-04-02 Toshiba Corp Manufacture of mesa type semiconductor device

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5632735A (en) * 1979-08-27 1981-04-02 Toshiba Corp Manufacture of mesa type semiconductor device

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Publication number Publication date
JPS59208729A (en) 1984-11-27

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