JP7817036B2 - 不飽和アルデヒド及び/又は不飽和カルボン酸の製造方法 - Google Patents

不飽和アルデヒド及び/又は不飽和カルボン酸の製造方法

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Publication number
JP7817036B2
JP7817036B2 JP2022047929A JP2022047929A JP7817036B2 JP 7817036 B2 JP7817036 B2 JP 7817036B2 JP 2022047929 A JP2022047929 A JP 2022047929A JP 2022047929 A JP2022047929 A JP 2022047929A JP 7817036 B2 JP7817036 B2 JP 7817036B2
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Prior art keywords
catalyst
mass
methacrylic acid
parts
raw material
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JP2022047929A
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English (en)
Japanese (ja)
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JP2023141552A (ja
Inventor
圭介 重森
良太 平岡
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Kayaku Co Ltd
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Nippon Kayaku Co Ltd
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Priority to JP2022047929A priority Critical patent/JP7817036B2/ja
Priority to KR1020230033376A priority patent/KR20230140472A/ko
Priority to CN202310291434.0A priority patent/CN116803968A/zh
Publication of JP2023141552A publication Critical patent/JP2023141552A/ja
Priority to JP2025200504A priority patent/JP2026015556A/ja
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Publication of JP7817036B2 publication Critical patent/JP7817036B2/ja
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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/27Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation
    • C07C45/32Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen
    • C07C45/33Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties
    • C07C45/34Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds
    • C07C45/35Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by oxidation with molecular oxygen of CHx-moieties in unsaturated compounds in propene or isobutene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/78Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with alkali- or alkaline earth metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/80Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with zinc, cadmium or mercury
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/88Molybdenum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/30Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
    • B01J35/31Density
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/40Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02Impregnation, coating or precipitation
    • B01J37/024Multiple impregnation or coating
    • B01J37/0244Coatings comprising several layers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/001Controlling catalytic processes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C47/00Compounds having —CHO groups
    • C07C47/20Unsaturated compounds having —CHO groups bound to acyclic carbon atoms
    • C07C47/21Unsaturated compounds having —CHO groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C47/22Acryaldehyde; Methacryaldehyde
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C57/00Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
    • C07C57/02Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms with only carbon-to-carbon double bonds as unsaturation
    • C07C57/03Monocarboxylic acids
    • C07C57/04Acrylic acid; Methacrylic acid

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
JP2022047929A 2022-03-24 2022-03-24 不飽和アルデヒド及び/又は不飽和カルボン酸の製造方法 Active JP7817036B2 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2022047929A JP7817036B2 (ja) 2022-03-24 2022-03-24 不飽和アルデヒド及び/又は不飽和カルボン酸の製造方法
KR1020230033376A KR20230140472A (ko) 2022-03-24 2023-03-14 불포화 알데히드 및/또는 불포화 카본산의 제조 방법
CN202310291434.0A CN116803968A (zh) 2022-03-24 2023-03-23 不饱和醛和/或不饱和羧酸的制造方法
JP2025200504A JP2026015556A (ja) 2022-03-24 2025-11-20 不飽和アルデヒド及び/又は不飽和カルボン酸の製造方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2022047929A JP7817036B2 (ja) 2022-03-24 2022-03-24 不飽和アルデヒド及び/又は不飽和カルボン酸の製造方法

Related Child Applications (1)

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JP2025200504A Division JP2026015556A (ja) 2022-03-24 2025-11-20 不飽和アルデヒド及び/又は不飽和カルボン酸の製造方法

Publications (2)

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JP2023141552A JP2023141552A (ja) 2023-10-05
JP7817036B2 true JP7817036B2 (ja) 2026-02-18

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JP2022047929A Active JP7817036B2 (ja) 2022-03-24 2022-03-24 不飽和アルデヒド及び/又は不飽和カルボン酸の製造方法
JP2025200504A Pending JP2026015556A (ja) 2022-03-24 2025-11-20 不飽和アルデヒド及び/又は不飽和カルボン酸の製造方法

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JP2025200504A Pending JP2026015556A (ja) 2022-03-24 2025-11-20 不飽和アルデヒド及び/又は不飽和カルボン酸の製造方法

Country Status (3)

Country Link
JP (2) JP7817036B2 (https=)
KR (1) KR20230140472A (https=)
CN (1) CN116803968A (https=)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001011010A (ja) 1999-04-27 2001-01-16 Nippon Shokubai Co Ltd メタクリル酸の製造方法
JP2004002209A (ja) 2002-03-29 2004-01-08 Nippon Shokubai Co Ltd 不飽和アルデヒドの製造方法
JP2020073581A (ja) 2018-04-10 2020-05-14 日本化薬株式会社 不飽和アルデヒド及び不飽和カルボン酸の少なくとも一方の製造方法並びに不飽和アルデヒド及び不飽和カルボン酸の少なくとも一方の製造用触媒

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4710614U (https=) 1971-03-09 1972-10-07
JPS50126605A (https=) 1974-03-23 1975-10-04
JPS61221149A (ja) 1985-03-26 1986-10-01 Nippon Shokubai Kagaku Kogyo Co Ltd メタクリル酸の製造方法
JP3804875B2 (ja) * 1996-06-05 2006-08-02 旭化成ケミカルズ株式会社 メタクロレインの製造方法
JP3775872B2 (ja) 1996-12-03 2006-05-17 日本化薬株式会社 アクロレイン及びアクリル酸の製造方法
KR100569632B1 (ko) * 1999-05-13 2006-04-10 가부시키가이샤 닛폰 쇼쿠바이 불포화 알데히드 및 불포화 카르복실산을 제조하기 위한촉매 및 이 촉매를 사용하여 불포화 알데히드 및 불포화카르복실산을 제조하기 위한 방법
KR101686189B1 (ko) 2015-05-21 2016-12-13 김몽필 분쇄기 공급장치
JP6205044B2 (ja) 2016-10-24 2017-09-27 旭化成株式会社 酸化物触媒の製造方法
JP7418252B2 (ja) * 2019-03-25 2024-01-19 日本化薬株式会社 触媒前駆体、それを用いた触媒、及びその製造方法
JP7209578B2 (ja) 2019-04-15 2023-01-20 日本化薬株式会社 触媒およびその製造方法
JP6932293B1 (ja) * 2020-01-10 2021-09-08 日本化薬株式会社 触媒、それを用いた化合物の製造方法及び化合物

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2001011010A (ja) 1999-04-27 2001-01-16 Nippon Shokubai Co Ltd メタクリル酸の製造方法
JP2004002209A (ja) 2002-03-29 2004-01-08 Nippon Shokubai Co Ltd 不飽和アルデヒドの製造方法
JP2020073581A (ja) 2018-04-10 2020-05-14 日本化薬株式会社 不飽和アルデヒド及び不飽和カルボン酸の少なくとも一方の製造方法並びに不飽和アルデヒド及び不飽和カルボン酸の少なくとも一方の製造用触媒

Also Published As

Publication number Publication date
CN116803968A (zh) 2023-09-26
KR20230140472A (ko) 2023-10-06
JP2023141552A (ja) 2023-10-05
JP2026015556A (ja) 2026-01-29

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