JP7583730B2 - 酸化物、固体電解質、および全固体リチウムイオン二次電池 - Google Patents
酸化物、固体電解質、および全固体リチウムイオン二次電池 Download PDFInfo
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- JP7583730B2 JP7583730B2 JP2021548753A JP2021548753A JP7583730B2 JP 7583730 B2 JP7583730 B2 JP 7583730B2 JP 2021548753 A JP2021548753 A JP 2021548753A JP 2021548753 A JP2021548753 A JP 2021548753A JP 7583730 B2 JP7583730 B2 JP 7583730B2
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- 229910001416 lithium ion Inorganic materials 0.000 title claims description 27
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 title claims description 25
- 239000007784 solid electrolyte Substances 0.000 title claims description 22
- 238000006467 substitution reaction Methods 0.000 claims description 57
- 239000000203 mixture Substances 0.000 claims description 17
- 229910052744 lithium Inorganic materials 0.000 claims description 12
- 229910052760 oxygen Inorganic materials 0.000 claims description 10
- 239000000470 constituent Substances 0.000 claims description 9
- 229910052725 zinc Inorganic materials 0.000 claims description 9
- 229910052746 lanthanum Inorganic materials 0.000 claims description 6
- 229910052726 zirconium Inorganic materials 0.000 claims description 6
- 229910052758 niobium Inorganic materials 0.000 claims description 5
- 229910052797 bismuth Inorganic materials 0.000 claims description 4
- 229910052735 hafnium Inorganic materials 0.000 claims description 3
- 239000000956 alloy Substances 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 description 37
- 239000010955 niobium Substances 0.000 description 25
- 238000002441 X-ray diffraction Methods 0.000 description 15
- 239000013078 crystal Substances 0.000 description 13
- 238000000034 method Methods 0.000 description 12
- 230000007423 decrease Effects 0.000 description 9
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- 238000010304 firing Methods 0.000 description 8
- 239000012298 atmosphere Substances 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 238000005245 sintering Methods 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- 239000011149 active material Substances 0.000 description 6
- 238000002156 mixing Methods 0.000 description 6
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 5
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 5
- 238000009792 diffusion process Methods 0.000 description 5
- 239000001301 oxygen Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
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- 239000000843 powder Substances 0.000 description 4
- 238000001878 scanning electron micrograph Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 239000007858 starting material Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- -1 LiSn Chemical compound 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 238000001354 calcination Methods 0.000 description 2
- 239000002134 carbon nanofiber Substances 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 230000001747 exhibiting effect Effects 0.000 description 2
- 229910052732 germanium Inorganic materials 0.000 description 2
- 238000002847 impedance measurement Methods 0.000 description 2
- 229910052738 indium Inorganic materials 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 229910052720 vanadium Inorganic materials 0.000 description 2
- 229910052692 Dysprosium Inorganic materials 0.000 description 1
- 229910052691 Erbium Inorganic materials 0.000 description 1
- 229910052688 Gadolinium Inorganic materials 0.000 description 1
- 229910052689 Holmium Inorganic materials 0.000 description 1
- 206010021143 Hypoxia Diseases 0.000 description 1
- 229910000733 Li alloy Inorganic materials 0.000 description 1
- 229910008088 Li-Mn Inorganic materials 0.000 description 1
- 229910002984 Li7La3Zr2O12 Inorganic materials 0.000 description 1
- 229910010199 LiAl Inorganic materials 0.000 description 1
- 229910012794 LiCoN Inorganic materials 0.000 description 1
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 1
- 229910014689 LiMnO Inorganic materials 0.000 description 1
- 229910013716 LiNi Inorganic materials 0.000 description 1
- 229910012096 LiSb Inorganic materials 0.000 description 1
- 229910012506 LiSi Inorganic materials 0.000 description 1
- 229910012381 LiSn Inorganic materials 0.000 description 1
- 229910001228 Li[Ni1/3Co1/3Mn1/3]O2 (NCM 111) Inorganic materials 0.000 description 1
- 229910006327 Li—Mn Inorganic materials 0.000 description 1
- 229910052765 Lutetium Inorganic materials 0.000 description 1
- 229910019021 Mg 2 Sn Inorganic materials 0.000 description 1
- 229910052779 Neodymium Inorganic materials 0.000 description 1
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- 229910019142 PO4 Inorganic materials 0.000 description 1
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- 229910052777 Praseodymium Inorganic materials 0.000 description 1
- 229910052772 Samarium Inorganic materials 0.000 description 1
- 229910004298 SiO 2 Inorganic materials 0.000 description 1
- 229910004283 SiO 4 Inorganic materials 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 229910052771 Terbium Inorganic materials 0.000 description 1
- 229910052775 Thulium Inorganic materials 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
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- 230000002159 abnormal effect Effects 0.000 description 1
- 239000006230 acetylene black Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
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- 239000012300 argon atmosphere Substances 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910000416 bismuth oxide Inorganic materials 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 229910021393 carbon nanotube Inorganic materials 0.000 description 1
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- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
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- 238000009694 cold isostatic pressing Methods 0.000 description 1
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- TYIXMATWDRGMPF-UHFFFAOYSA-N dibismuth;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Bi+3].[Bi+3] TYIXMATWDRGMPF-UHFFFAOYSA-N 0.000 description 1
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- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000003966 growth inhibitor Substances 0.000 description 1
- 229910000449 hafnium oxide Inorganic materials 0.000 description 1
- WIHZLLGSGQNAGK-UHFFFAOYSA-N hafnium(4+);oxygen(2-) Chemical compound [O-2].[O-2].[Hf+4] WIHZLLGSGQNAGK-UHFFFAOYSA-N 0.000 description 1
- 229910021385 hard carbon Inorganic materials 0.000 description 1
- 238000001513 hot isostatic pressing Methods 0.000 description 1
- 238000007731 hot pressing Methods 0.000 description 1
- 150000004679 hydroxides Chemical class 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910000765 intermetallic Inorganic materials 0.000 description 1
- 239000003273 ketjen black Substances 0.000 description 1
- 239000011244 liquid electrolyte Substances 0.000 description 1
- 239000001989 lithium alloy Substances 0.000 description 1
- FUJCRWPEOMXPAD-UHFFFAOYSA-N lithium oxide Chemical compound [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 description 1
- 229910001947 lithium oxide Inorganic materials 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 239000007773 negative electrode material Substances 0.000 description 1
- 229910000484 niobium oxide Inorganic materials 0.000 description 1
- URLJKFSTXLNXLG-UHFFFAOYSA-N niobium(5+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Nb+5].[Nb+5] URLJKFSTXLNXLG-UHFFFAOYSA-N 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
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- 150000003891 oxalate salts Chemical class 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
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- 239000007774 positive electrode material Substances 0.000 description 1
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- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
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- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 229910000314 transition metal oxide Inorganic materials 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
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- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6567—Treatment time
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/658—Atmosphere during thermal treatment
- C04B2235/6587—Influencing the atmosphere by vaporising a solid material, e.g. by using a burying of sacrificial powder
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/74—Physical characteristics
- C04B2235/76—Crystal structural characteristics, e.g. symmetry
- C04B2235/762—Cubic symmetry, e.g. beta-SiC
- C04B2235/764—Garnet structure A3B2(CO4)3
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0065—Solid electrolytes
- H01M2300/0068—Solid electrolytes inorganic
- H01M2300/0071—Oxides
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
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| JP2019177871 | 2019-09-27 | ||
| JP2019177871 | 2019-09-27 | ||
| PCT/JP2020/033751 WO2021059939A1 (ja) | 2019-09-27 | 2020-09-07 | 酸化物、固体電解質、および全固体リチウムイオン二次電池 |
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| JPWO2021059939A1 JPWO2021059939A1 (https=) | 2021-04-01 |
| JPWO2021059939A5 JPWO2021059939A5 (https=) | 2023-07-25 |
| JP7583730B2 true JP7583730B2 (ja) | 2024-11-14 |
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| WO2021200486A1 (ja) * | 2020-03-31 | 2021-10-07 | デンカ株式会社 | 炭素含有アルミナ粉末、樹脂組成物、放熱部品、及び炭素含有アルミナ粉末の製造方法 |
| CN117263701B (zh) * | 2022-06-15 | 2025-08-12 | 中国科学院上海硅酸盐研究所 | 一种锂石榴石型电解质烧结用埋粉和使用该埋粉制备锂石榴石型电解质的方法 |
| CN115458800A (zh) * | 2022-08-30 | 2022-12-09 | 淄博火炬能源有限责任公司 | 石榴石型固态电解质压片工艺 |
Citations (7)
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| JP2013243111A (ja) | 2012-05-17 | 2013-12-05 | Ngk Insulators Ltd | 正極−固体電解質複合体の製造方法 |
| US20160064785A1 (en) | 2014-08-27 | 2016-03-03 | Samsung Electronics Co., Ltd. | Lithium air battery and method of preparing the same |
| JP2016171068A (ja) | 2015-03-10 | 2016-09-23 | Tdk株式会社 | ガーネット型リチウムイオン伝導性酸化物 |
| WO2017135461A1 (ja) | 2016-02-05 | 2017-08-10 | 株式会社村田製作所 | 固体電解質及び全固体電池 |
| WO2018085847A1 (en) | 2016-11-07 | 2018-05-11 | University Of Maryland, College Park | Lithium solid state electrolyte interface treatment |
| WO2019032514A1 (en) | 2017-08-07 | 2019-02-14 | The Regents Of The University Of Michigan | IONIC AND ELECTRONIC MIXED DRIVER FOR SOLID BATTERY |
| CN109888374A (zh) | 2019-01-22 | 2019-06-14 | 华南理工大学 | 一种多掺杂的石榴石型固体电解质材料及其制备方法 |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP5132639B2 (ja) | 2008-08-21 | 2013-01-30 | 日本碍子株式会社 | セラミックス材料及びその製造方法 |
| JP5525388B2 (ja) | 2009-09-03 | 2014-06-18 | 日本碍子株式会社 | セラミックス材料及びその製造方法 |
| US9991556B2 (en) | 2015-03-10 | 2018-06-05 | Tdk Corporation | Garnet-type li-ion conductive oxide |
-
2020
- 2020-09-07 WO PCT/JP2020/033751 patent/WO2021059939A1/ja not_active Ceased
- 2020-09-07 CN CN202080067464.8A patent/CN114466822B/zh active Active
- 2020-09-07 JP JP2021548753A patent/JP7583730B2/ja active Active
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013243111A (ja) | 2012-05-17 | 2013-12-05 | Ngk Insulators Ltd | 正極−固体電解質複合体の製造方法 |
| US20160064785A1 (en) | 2014-08-27 | 2016-03-03 | Samsung Electronics Co., Ltd. | Lithium air battery and method of preparing the same |
| JP2016171068A (ja) | 2015-03-10 | 2016-09-23 | Tdk株式会社 | ガーネット型リチウムイオン伝導性酸化物 |
| WO2017135461A1 (ja) | 2016-02-05 | 2017-08-10 | 株式会社村田製作所 | 固体電解質及び全固体電池 |
| WO2018085847A1 (en) | 2016-11-07 | 2018-05-11 | University Of Maryland, College Park | Lithium solid state electrolyte interface treatment |
| WO2019032514A1 (en) | 2017-08-07 | 2019-02-14 | The Regents Of The University Of Michigan | IONIC AND ELECTRONIC MIXED DRIVER FOR SOLID BATTERY |
| CN109888374A (zh) | 2019-01-22 | 2019-06-14 | 华南理工大学 | 一种多掺杂的石榴石型固体电解质材料及其制备方法 |
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| YAN Chen et al.,Origin of High Li+ Conduction in Doped Li7La3Zr2O1,CHEM. MATER.,2015年,Vol.27,p.5491-5494,P.5491左欄、図1b |
| YUE Jiang et al.,Investigation of Mg2+ Sc3+ and Zn2+ doping effect,SOLID STATE IONICS,2017年02月,Volume 300,Pages 73-77,抄録、2.図5c |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2021059939A1 (ja) | 2021-04-01 |
| JPWO2021059939A1 (https=) | 2021-04-01 |
| CN114466822B (zh) | 2024-07-09 |
| CN114466822A (zh) | 2022-05-10 |
| US20220216510A1 (en) | 2022-07-07 |
| US12249686B2 (en) | 2025-03-11 |
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