JP7413083B2

JP7413083B2 - 感熱記録体

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Publication number: JP7413083B2
Authority: JP; Japan
Prior art keywords: sensitive recording; heat; meth; copolymer; group
Prior art date: 2020-03-02
Legal status : Active

Application number

JP2020034863A

Other languages

English (en)

Japanese (ja)

Other versions

JP2021137977A5 (enExample

JP2021137977A (ja

Inventor

健二平井

賢太郎川▲崎▼

佳美緑川

佑香村田

Current Assignee

Nippon Paper Industries Co Ltd

Original Assignee

Nippon Paper Industries Co Ltd

Priority date

2020-03-02

Filing date

2020-03-02

Publication date

2024-01-15

2020-03-02 Application filed by Nippon Paper Industries Co Ltd filed Critical Nippon Paper Industries Co Ltd

2020-03-02 Priority to JP2020034863A priority Critical patent/JP7413083B2/ja

2020-12-08 Priority to CN202080085525.3A priority patent/CN114786957B/zh

2020-12-08 Priority to US17/784,584 priority patent/US12053997B2/en

2020-12-08 Priority to PCT/JP2020/045602 priority patent/WO2021117702A1/ja

2020-12-08 Priority to EP20900008.2A priority patent/EP4056605A4/en

2021-09-16 Publication of JP2021137977A publication Critical patent/JP2021137977A/ja

2022-01-14 Publication of JP2021137977A5 publication Critical patent/JP2021137977A5/ja

2024-01-15 Application granted granted Critical

2024-01-15 Publication of JP7413083B2 publication Critical patent/JP7413083B2/ja

Status Active legal-status Critical Current

2040-03-02 Anticipated expiration legal-status Critical

Links

239000000463 material Substances 0.000 title claims description 43
239000000178 monomer Substances 0.000 claims description 99
239000004925 Acrylic resin Substances 0.000 claims description 55
229920000178 Acrylic resin Polymers 0.000 claims description 55
-1 polyoxyethylene chain Polymers 0.000 claims description 53
239000000839 emulsion Substances 0.000 claims description 50
239000011241 protective layer Substances 0.000 claims description 46
239000010410 layer Substances 0.000 claims description 38
229920001577 copolymer Polymers 0.000 claims description 32
NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 27
CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 25
239000011258 core-shell material Substances 0.000 claims description 20
125000005370 alkoxysilyl group Chemical group 0.000 claims description 19
125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims description 16
230000009477 glass transition Effects 0.000 claims description 12
PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical group C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 11
QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 11
239000004094 surface-active agent Substances 0.000 claims description 9
230000000379 polymerizing effect Effects 0.000 claims description 8
125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 6
239000002245 particle Substances 0.000 claims description 6
NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 34
238000000576 coating method Methods 0.000 description 32
239000011248 coating agent Substances 0.000 description 30
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LEQAOMBKQFMDFZ-UHFFFAOYSA-N glyoxal Chemical compound O=CC=O LEQAOMBKQFMDFZ-UHFFFAOYSA-N 0.000 description 4
239000000314 lubricant Substances 0.000 description 4
238000004519 manufacturing process Methods 0.000 description 4
239000011259 mixed solution Substances 0.000 description 4
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CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 4
235000019698 starch Nutrition 0.000 description 4
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XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 3
229920000298 Cellophane Polymers 0.000 description 3
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235000010724 Wisteria floribunda Nutrition 0.000 description 3
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125000000217 alkyl group Chemical group 0.000 description 3
229910001870 ammonium persulfate Inorganic materials 0.000 description 3
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 3
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238000009472 formulation Methods 0.000 description 3
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USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 3
238000001454 recorded image Methods 0.000 description 3
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XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 3
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239000000654 additive Substances 0.000 description 2
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125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 2
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235000013305 food Nutrition 0.000 description 2
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125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 2
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UGRMITBWUVWUEB-UHFFFAOYSA-N 1-$l^{1}-oxidanyl-3-methylbenzene Chemical group CC1=CC=CC([O])=C1 UGRMITBWUVWUEB-UHFFFAOYSA-N 0.000 description 1
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NNORAMKREOSIBW-UHFFFAOYSA-N 1-methyl-3-[(4-phenylphenyl)methoxy]benzene Chemical group CC1=CC=CC(OCC=2C=CC(=CC=2)C=2C=CC=CC=2)=C1 NNORAMKREOSIBW-UHFFFAOYSA-N 0.000 description 1
HUOKHAMXPNSWBJ-UHFFFAOYSA-N 2'-chloro-6'-(diethylamino)-3'-methylspiro[2-benzofuran-3,9'-xanthene]-1-one Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC(Cl)=C(C)C=C1OC1=CC(N(CC)CC)=CC=C21 HUOKHAMXPNSWBJ-UHFFFAOYSA-N 0.000 description 1
OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
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