JP7091552B2 - 有益剤カプセルを含む布地処理組成物 - Google Patents
有益剤カプセルを含む布地処理組成物 Download PDFInfo
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- JP7091552B2 JP7091552B2 JP2021507582A JP2021507582A JP7091552B2 JP 7091552 B2 JP7091552 B2 JP 7091552B2 JP 2021507582 A JP2021507582 A JP 2021507582A JP 2021507582 A JP2021507582 A JP 2021507582A JP 7091552 B2 JP7091552 B2 JP 7091552B2
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- 235000021286 stilbenes Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- WPLOVIFNBMNBPD-ATHMIXSHSA-N subtilin Chemical compound CC1SCC(NC2=O)C(=O)NC(CC(N)=O)C(=O)NC(C(=O)NC(CCCCN)C(=O)NC(C(C)CC)C(=O)NC(=C)C(=O)NC(CCCCN)C(O)=O)CSC(C)C2NC(=O)C(CC(C)C)NC(=O)C1NC(=O)C(CCC(N)=O)NC(=O)C(CC(C)C)NC(=O)C(NC(=O)C1NC(=O)C(=C/C)/NC(=O)C(CCC(N)=O)NC(=O)C(CC(C)C)NC(=O)C(C)NC(=O)CNC(=O)C(NC(=O)C(NC(=O)C2NC(=O)CNC(=O)C3CCCN3C(=O)C(NC(=O)C3NC(=O)C(CC(C)C)NC(=O)C(=C)NC(=O)C(CCC(O)=O)NC(=O)C(NC(=O)C(CCCCN)NC(=O)C(N)CC=4C5=CC=CC=C5NC=4)CSC3)C(C)SC2)C(C)C)C(C)SC1)CC1=CC=CC=C1 WPLOVIFNBMNBPD-ATHMIXSHSA-N 0.000 description 1
- DIORMHZUUKOISG-UHFFFAOYSA-N sulfoformic acid Chemical group OC(=O)S(O)(=O)=O DIORMHZUUKOISG-UHFFFAOYSA-N 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- DTXLBRAVKYTGFE-UHFFFAOYSA-J tetrasodium;2-(1,2-dicarboxylatoethylamino)-3-hydroxybutanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)C(O)C(C([O-])=O)NC(C([O-])=O)CC([O-])=O DTXLBRAVKYTGFE-UHFFFAOYSA-J 0.000 description 1
- OVTCUIZCVUGJHS-VQHVLOKHSA-N trans-dipyrrin Chemical compound C=1C=CNC=1/C=C1\C=CC=N1 OVTCUIZCVUGJHS-VQHVLOKHSA-N 0.000 description 1
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 1
- 150000004072 triols Chemical class 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000000341 volatile oil Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229940071104 xylenesulfonate Drugs 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/349—Organic compounds containing sulfur additionally containing nitrogen atoms, e.g. nitro, nitroso, amino, imino, nitrilo, nitrile groups containing compounds or their derivatives or thio urea
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
- C11D3/42—Brightening agents ; Blueing agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0008—Detergent materials or soaps characterised by their shape or physical properties aqueous liquid non soap compositions
- C11D17/0013—Liquid compositions with insoluble particles in suspension
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0039—Coated compositions or coated components in the compositions, (micro)capsules
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/50—Perfumes
- C11D3/502—Protected perfumes
- C11D3/505—Protected perfumes encapsulated or adsorbed on a carrier, e.g. zeolite or clay
-
- C11D2111/12—
Description
本発明で使用するとき、用語「布地処理組成物」は、特に指示がない限り、以下を含む洗浄及び処理組成物のサブセットである:顆粒又は粉末形態の汎用又は「ヘビーデューティ」洗浄剤、特に、洗浄洗剤;液体、ゲル、又はペースト形態の汎用洗浄剤、特にいわゆる強力液体タイプのもの;繊細な布地用の液体洗剤;液体洗浄及び消毒剤、布地コンディショニング製品(液体、固体及び/又は乾燥機シート形態であり得る柔軟剤及び/又はフレッシュニング剤を含む)に加えて、漂白添加剤及び「ステインスティック」又は前処理タイプなどの洗浄補助剤、乾燥機添加シート、乾燥及び湿潤のワイプ及びパッド、不織布基材、並びにスポンジなどの基材付き製品;加えて、スプレー及びミストを含む。適用可能なそのような製品は全て、標準形態、濃縮形態、あるいは、そのような製品が特定の態様では非水性であり得る程度まで高度に濃縮された形態であり得る。
本発明による布地処理組成物は有益剤カプセルを含み、有益剤カプセルは、コア材料を封入するシェル材料を含み、当該シェル材料は、ポリビニルアルコール及びシェル成分に由来し、当該シェル成分は、ポリアミン、メラミンホルムアルデヒド、ポリ尿素、ポリウレタン、多糖類、修飾多糖類、ホルムアルデヒドで架橋された尿素、グルタルアルデヒドで架橋された尿素、シリコーンジオキシド、ケイ酸ナトリウム、ポリエステル、ポリアクリルアミド、及びこれらの混合物からなるリストから選択され、当該コア材料は、有益剤を含む。布地処理組成物は、ジアミノスチルベン増白剤、及び好ましくは少なくとも1%の界面活性剤を更に含む。布地処理組成物は、固体又は液体であってよく、好ましくは、布地柔軟剤組成物は液体である。
本発明の布地処理組成物は、
布地処理組成物は、コア材料及び当該コア材料を封入するシェル材料を含む有益剤カプセルを含み、当該シェル材料は、ポリビニルアルコール及びシェル成分に由来し、当該シェル成分は、ポリアクリレート、ポリアミン、メラミンホルムアルデヒド、ポリ尿素、ポリウレタン、多糖類、修飾多糖類、ホルムアルデヒドで架橋された尿素、グルタルアルデヒドで架橋された尿素、シリコーンジオキシド、ケイ酸ナトリウム、ポリエステル、ポリアクリルアミド、及びこれらの混合物からなるリストから選択される。
(i)70%~99%、好ましくは75%~98%、より好ましくは80%~96%、より好ましくは82%~96%、最も好ましくは86%~94%の加水分解度、
(ii)20℃の4%水溶液において、2mPa.s~150mPa.s、好ましくは3mPa.s~70mPa.s、より好ましくは4mPa.s~60mPa.s、更により好ましくは5mPa.s~55mPa.sの粘度。
好ましい布地処理組成物では、組成物は、1重量%~70重量%、好ましくは10重量%~40重量%、より好ましくは15重量%~30重量%の濃度の界面活性剤を更に含む。
布地処理組成物は、有機非アミノ官能性溶媒を含み得る。存在する場合、有機非アミノ官能性溶媒は、好ましくは、有機非アミノ官能性溶媒の40重量%未満、より好ましくは15重量%未満、より好ましくは1重量%~10重量%、より好ましくは1.2重量%~7.5重量%、最も好ましくは1.2重量%~5.0重量%の濃度で存在する。本明細書で使用するとき、「非アミノ官能性有機溶媒」は、アミノ官能基を不含で、更には窒素も不含の任意の溶媒を指す。非アミノ官能性溶媒としては、例えば、メタノール、エタノール及び/若しくはプロパノールなどのC1~C5アルカノール、並びに/又は1-エトキシペンタノール;C2~C6ジオール;C3~C8アルキレングリコール;C3~C8アルキレングリコールモノ低級アルキルエーテル;グリコールジアルキルエーテル;低分子量ポリエチレングリコール;グリセロールなどのC3~C9トリオール;並びにこれらの混合物が挙げられる。より具体的には、非アミノ官能性溶媒は、周囲温度及び圧力(すなわち、21℃及び1気圧)で液体であり、炭素、水素、及び酸素を含む。
好適な布地処理組成物は、ヒドロトロープを含み得る。存在する場合、ヒドロトロープは、好ましくは、液体組成物の1重量%未満、より好ましくは0.1重量%~0.5重量%の濃度で存在する。好適なヒドロトロープとしては、米国特許第3,915,903号に開示されているような、アニオン型のヒドロトロープ、特にキシレンスルホン酸ナトリウム、キシレンスルホン酸カリウム、及びキシレンスルホン酸アンモニウム、トルエンスルホン酸ナトリウム、トルエンスルホン酸カリウム及びトルエンスルホン酸アンモニウム、クメンスルホン酸ナトリウム、クメンスルホン酸カリウム及びクメンスルホン酸アンモニウム、並びにこれらの混合物が挙げられる。誤解を避けるために、双性イオンでもあるヒドロトロープは、本発明の組成物では双性イオンであるとみなされる。
布地処理組成物は、炭酸ナトリウム、炭酸水素ナトリウム(重炭酸ナトリウム)、塩化マグネシウム、エチレンジアミン四酢酸(EDTA)、ジエチレントリアミン五酢酸(DTPA)、ヒドロキシエタンジホスホン酸(HEDP)、クエン酸ナトリウム、塩化ナトリウム、クエン酸、塩化カルシウム、ギ酸ナトリウム、ジエチレントリアミンペンタメチレンホスホン酸、及びこれらの混合物からなる群から選択される非界面活性剤塩を含み得る。そのような非界面活性剤塩を使用して、存在する液晶相、特にラメラ相の量を増加させることができる。布地処理組成物中に1.5重量%~10重量%、より好ましくは2.5重量%~7重量%、最も好ましくは3重量%~5重量%の濃度の非界面活性剤塩を提供するように、非界面活性剤塩を添加してよい。
布地処理組成物は、ポリマー付着助剤、有機ビルダー及び/又はキレート剤、酵素、酵素安定剤、色相染料、微粒子材料、洗浄ポリマー、外部構造化剤、並びにこれらの混合物からなる群から選択されるものなどの追加成分を含み得る。
出願人らは、驚くべきことに、本発明による布地処理組成物中のジアミノスチルベン増白剤が、有益剤カプセルの付着を改善することを見出した。理論に束縛されるものではないが、出願人らは、ジアミノスチルベン増白剤と有益剤カプセルのポリビニルアルコールとの間の相互作用によって、付着、特に綿布に対する親和性が改善されると考えている。
有益剤カプセルの付着を測定する方法
蛍光カプセルは、Ind.Eng.Chem.Res.(2012),51,16741に記載の通り、少量の蛍光染料、Sigma Aldrich製のピロメテン546(PM546)と組み合わせて香油を封入することによって調製されている。蛍光染料を抽出するために、蛍光カプセルで処理した布地を60Cのエタノールに浸漬した。エタノール溶液から少量のアリコートを採取し、その蛍光強度(励起=495nm、発光=505nm、スリット幅=5mm)を蛍光光度計(Perkin Elmer LS50)で測定した。蛍光強度は、布地上に付着した蛍光カプセルの量に比例する。
粘度は、4.00%+/-0.05%固体で、Brookfield LVシリーズ粘度計又はそれに相当する装置を使用して測定する。
500mLビーカー及び撹拌機を秤量する。重量を記録する。16.00+/-0.01グラムのポリビニルアルコールサンプルをビーカーに添加する。約350~375mLの脱イオン水をビーカーに添加し、溶液を撹拌する。カバープレートを有する温水浴にビーカーを入れる。中程度の速度で45分間~1時間、又はポリビニルアルコールが完全に溶解するまで撹拌する。撹拌機をオフにする。ビーカーを約20℃に冷却する。
ビーカーの最終重量を以下のように計算する。
最終重量=(空ビーカー及び撹拌機の重量)+(小数点×400とした固体%)
例:空ビーカー及び撹拌機の重量=125.0グラム
(サンプルの)ポリビニルアルコールの固形分%=97.50%又は小数としては0.9750
最終重量=125.0+(0.9750×400)=515.0グラム
上載せ式天秤をゼロに合わせ、プロペラを備えるポリビニルアルコール溶液のビーカーをその上に置く。脱イオン水を添加して、重量を計算された最終重量515.0グラムにする。
サンプルの固形分含有量は、粘度を測定するためには4.00+0.05%でなければならない。
4%ポリビニルアルコール溶液のサンプルを粘度計のチャンバ内に分注し、スピンドルを挿入してそれを粘度計に取り付ける。チャンバSC4-13RPYを有するサンプルアダプタ(SSA)、Ultralowアダプタ。スピンドルはSC4-18及び00である。20℃の温度でサンプルを平衡化させる。粘度計を開始し、定常状態の粘度値を記録する。
粘度<13cPを0.01cP単位で、13~100cPを0.1cP単位で記録し、100cPを超える粘度を1cP単位で記録する。
計算された溶液固体含有量が4.00±0.05%である場合、測定された粘度に対する補正は必要ない。そうでなければ、以下の等式を使用して、測定された粘度を溶液固体の偏差に関して補正する。
ランドロメーター(Launderometer)と呼ばれる小規模洗濯機シミュレータを使用した。ランドロメーターのジャーに3gのパイル生地4片を装填した。2.5gの布地処理組成物を1Lの水道水に添加した。350mLのこの溶液(水道水+布地処理組成物)をランドロメーターのジャー内で布地に添加した。ランドロメーターのサイクル時間を7分に設定し、温度を25Cに設定する。ランドロメーターのサイクル後、布地をMiele WMに移し、1200rpmで7分間遠心分離した。次いで、布地を60℃のオーブン内で30分間乾燥させた。乾燥した布地を有益剤カプセルの付着について分析する(方法を参照)。
各試験につき、ランドロメーターのジャーに3gのパイル生地4片を装填した。以下のように布地処理組成物を調製し、2gの布地処理組成物を1Lの水道水に添加した。350mLのこの溶液(水道水+布地処理組成物)をランドロメーターのジャー内で布地に添加した。ランドロメーターのサイクル時間を9分に設定し、温度を30℃に設定する。ランドロメーターのサイクル後、布地をMiele WMに移し、1200rpmで7分間遠心分離する。次いで、布地を60℃のオーブン内で30分間乾燥させる。乾燥した布地を、「有益剤カプセルの付着を測定する方法」に記載されるように、有益剤カプセルの付着について分析する。
Claims (15)
- 前記ジアミノスチルベン増白剤の合計濃度が、前記布地処理組成物の0.01重量%~2重量%である、請求項1~3のいずれか一項に記載の布地処理組成物。
- 前記ポリビニルアルコールが、70%~99%の加水分解度を有する、請求項1~4のいずれか一項に記載の布地処理組成物。
- 前記ポリビニルアルコールが、4重量%水溶液として、2mPa.s~150mPa.sの粘度を有する、請求項1~5のいずれか一項に記載の布地処理組成物。
- ポリビニルアルコールの増白剤に対する重量比が、1/1~1/5000である、請求項1~6のいずれか一項に記載の布地処理組成物。
- ジアミノスチルベン増白剤の有益剤カプセルに対する重量比が、50/1~1/500である、請求項1~7のいずれか一項に記載の布地処理組成物。
- 前記ポリビニルアルコールの濃度が、前記有益剤カプセルの0.01~20重量%である、請求項1~8のいずれか一項に記載の布地処理組成物。
- 非イオン性、アニオン性、カチオン性、双性イオン性界面活性剤、及びこれらの組み合わせから選択される界面活性剤を更に含む、請求項1~9のいずれか一項に記載の布地処理組成物。
- 前記界面活性剤の濃度が、前記布地処理組成物の1重量%~70重量%である、請求項10に記載の布地処理組成物。
- 前記有益剤カプセルの濃度が、前記布地処理組成物の0.01重量%~10重量%である、請求項1~11のいずれか一項に記載の布地処理組成物。
- 請求項1~12のいずれか一項に記載の布地処理組成物を含む洗浄水であって、前記ジアミノスチルベン増白剤の濃度が、前記洗浄水の0.1~50重量ppmである、洗浄水。
- 布地上への有益剤カプセルの付着を増加させるための、請求項1~12のいずれか一項に記載の組成物におけるジアミノスチルベン増白剤の使用。
- 綿布への有益剤カプセルの付着を増加させるための、請求項1~12のいずれか一項に記載の組成物の使用。
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