JP6929879B2 - ポリオレフィン触媒用の非フタレート型供与体 - Google Patents

ポリオレフィン触媒用の非フタレート型供与体 Download PDF

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JP6929879B2
JP6929879B2 JP2018561572A JP2018561572A JP6929879B2 JP 6929879 B2 JP6929879 B2 JP 6929879B2 JP 2018561572 A JP2018561572 A JP 2018561572A JP 2018561572 A JP2018561572 A JP 2018561572A JP 6929879 B2 JP6929879 B2 JP 6929879B2
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hydrocarbyl
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halogen
alkyl
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JP2019516852A (ja
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グエン,ビン・タイン
フェルナンデス,ジョナス・アウヴェス
マリン,ウラジーミル・ピー
パテール,ムシュタク・アハメド
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WR Grace and Co Conn
Braskem America Inc
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Braskem America Inc
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/04Monomers containing three or four carbon atoms
    • C08F10/06Propene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/04Monomers containing three or four carbon atoms
    • C08F110/06Propene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/122Metal aryl or alkyl compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/38Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of titanium, zirconium or hafnium
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/65Pretreating the metal or compound covered by group C08F4/64 before the final contacting with the metal or compound covered by group C08F4/44
    • C08F4/652Pretreating with metals or metal-containing compounds
    • C08F4/654Pretreating with metals or metal-containing compounds with magnesium or compounds thereof

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
JP2018561572A 2016-05-23 2016-05-26 ポリオレフィン触媒用の非フタレート型供与体 Active JP6929879B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662340347P 2016-05-23 2016-05-23
US62/340,347 2016-05-23
PCT/US2016/034431 WO2017204811A1 (en) 2016-05-23 2016-05-26 Non-phthalate donor for polyolefin catalysts

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JP2019516852A JP2019516852A (ja) 2019-06-20
JP6929879B2 true JP6929879B2 (ja) 2021-09-01

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US (2) US10662267B2 (es)
EP (1) EP3464391B1 (es)
JP (1) JP6929879B2 (es)
KR (1) KR102573618B1 (es)
CN (1) CN109790238B (es)
BR (2) BR112018074123B1 (es)
CA (1) CA3025263C (es)
MX (1) MX2018014356A (es)
WO (1) WO2017204811A1 (es)

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CA3025263C (en) * 2016-05-23 2024-01-09 W.R. Grace & Co. -Conn. Non-phthalate donor for polyolefin catalysts
WO2019036376A1 (en) 2017-08-14 2019-02-21 Braskem America, Inc. BORON-BASED ELECTRON DONORS FOR ZIEGLER-NATTA CATALYST SYSTEMS
WO2019094216A1 (en) * 2017-11-13 2019-05-16 W.R. Grace & Co.-Conn. Catalyst components for propylene polymerization
KR102467598B1 (ko) * 2017-11-28 2022-11-15 롯데케미칼 주식회사 올레핀 중합용 촉매 조성물, 이의 제조방법 및 이를 이용한 폴리올레핀의 제조방법
EP4031590A4 (en) * 2019-09-18 2023-10-11 W. R. Grace & Co.-Conn CATALYST COMPOSITION FOR POLYOLEFIN POLYMERS
CN112812205B (zh) * 2019-11-18 2023-05-09 中国石油化工股份有限公司 一种用于烯烃聚合反应的催化剂组分及其催化剂和其制法及应用
KR20220085198A (ko) * 2020-12-15 2022-06-22 주식회사 에이치엘클레무브 레이더 센서의 방해 검출 장치 및 방법과, 레이더 장치
CN118591567A (zh) * 2022-01-27 2024-09-03 英尼奥斯欧洲股份公司 催化剂组合物
KR20240135041A (ko) * 2022-01-31 2024-09-10 더블유.알. 그레이스 앤드 캄파니-콘. 마그네슘, 티타늄, 에폭시 화합물, 및 1,2-페닐렌 디벤조에이트 기반 화합물과 같은 내부 전자 공여체를 포함하는 올레핀 중합 촉매
WO2024204845A1 (ja) * 2023-03-30 2024-10-03 三井化学株式会社 固体状チタン触媒成分、オレフィン重合用触媒およびオレフィンの重合方法
WO2024204844A1 (ja) * 2023-03-31 2024-10-03 三井化学株式会社 固体状チタン触媒成分、オレフィン重合用触媒、オレフィンの重合方法

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US20200223958A1 (en) 2020-07-16
CA3025263C (en) 2024-01-09
US20190270831A1 (en) 2019-09-05
KR20190026678A (ko) 2019-03-13
BR112018074123B1 (pt) 2022-04-05
US10662267B2 (en) 2020-05-26
BR122020011705B1 (pt) 2022-04-12
BR112018074123A2 (pt) 2019-03-06
MX2018014356A (es) 2019-08-21
CN109790238A (zh) 2019-05-21
US11370854B2 (en) 2022-06-28
WO2017204811A1 (en) 2017-11-30
CN109790238B (zh) 2021-12-31
CA3025263A1 (en) 2017-11-30
KR102573618B1 (ko) 2023-08-31
EP3464391A1 (en) 2019-04-10
JP2019516852A (ja) 2019-06-20
EP3464391A4 (en) 2020-06-17
EP3464391B1 (en) 2024-01-03

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