JP6618829B2 - 2液混合型の第1,第2の液及びプリント配線板の製造方法 - Google Patents
2液混合型の第1,第2の液及びプリント配線板の製造方法 Download PDFInfo
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- JP6618829B2 JP6618829B2 JP2016033857A JP2016033857A JP6618829B2 JP 6618829 B2 JP6618829 B2 JP 6618829B2 JP 2016033857 A JP2016033857 A JP 2016033857A JP 2016033857 A JP2016033857 A JP 2016033857A JP 6618829 B2 JP6618829 B2 JP 6618829B2
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- titanium oxide
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- LLHWSBXZXJXVPL-UHFFFAOYSA-N 6-(2-methylphenyl)-1,3,5-triazine-2,4-diamine Chemical compound CC1=CC=CC=C1C1=NC(N)=NC(N)=N1 LLHWSBXZXJXVPL-UHFFFAOYSA-N 0.000 description 1
- ZNEHIUJFFLFDQP-UHFFFAOYSA-N 6-(3,4-dimethylphenyl)-1,3,5-triazine-2,4-diamine Chemical class C1=C(C)C(C)=CC=C1C1=NC(N)=NC(N)=N1 ZNEHIUJFFLFDQP-UHFFFAOYSA-N 0.000 description 1
- ZVVFVKJZNVSANF-UHFFFAOYSA-N 6-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]hexyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCCCCCCOC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 ZVVFVKJZNVSANF-UHFFFAOYSA-N 0.000 description 1
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- ADRNSOYXKABLGT-UHFFFAOYSA-N 8-methylnonyl diphenyl phosphite Chemical compound C=1C=CC=CC=1OP(OCCCCCCCC(C)C)OC1=CC=CC=C1 ADRNSOYXKABLGT-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 229910052582 BN Inorganic materials 0.000 description 1
- 239000005711 Benzoic acid Substances 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N Benzoic acid Natural products OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- MRABAEUHTLLEML-UHFFFAOYSA-N Butyl lactate Chemical compound CCCCOC(=O)C(C)O MRABAEUHTLLEML-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
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- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
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- IORUEKDKNHHQAL-UHFFFAOYSA-N [2-tert-butyl-6-[(3-tert-butyl-2-hydroxy-5-methylphenyl)methyl]-4-methylphenyl] prop-2-enoate Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)OC(=O)C=C)=C1O IORUEKDKNHHQAL-UHFFFAOYSA-N 0.000 description 1
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 description 1
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- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229940118662 aluminum carbonate Drugs 0.000 description 1
- OJMOMXZKOWKUTA-UHFFFAOYSA-N aluminum;borate Chemical compound [Al+3].[O-]B([O-])[O-] OJMOMXZKOWKUTA-UHFFFAOYSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 description 1
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- 229940121375 antifungal agent Drugs 0.000 description 1
- 229910000410 antimony oxide Inorganic materials 0.000 description 1
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- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 1
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- 235000010233 benzoic acid Nutrition 0.000 description 1
- RWCCWEUUXYIKHB-UHFFFAOYSA-N benzophenone Chemical compound C=1C=CC=CC=1C(=O)C1=CC=CC=C1 RWCCWEUUXYIKHB-UHFFFAOYSA-N 0.000 description 1
- 239000012965 benzophenone Substances 0.000 description 1
- JRPRCOLKIYRSNH-UHFFFAOYSA-N bis(oxiran-2-ylmethyl) benzene-1,2-dicarboxylate Chemical compound C=1C=CC=C(C(=O)OCC2OC2)C=1C(=O)OCC1CO1 JRPRCOLKIYRSNH-UHFFFAOYSA-N 0.000 description 1
- 239000001191 butyl (2R)-2-hydroxypropanoate Substances 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 239000000378 calcium silicate Substances 0.000 description 1
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- 235000011132 calcium sulphate Nutrition 0.000 description 1
- AOWKSNWVBZGMTJ-UHFFFAOYSA-N calcium titanate Chemical compound [Ca+2].[O-][Ti]([O-])=O AOWKSNWVBZGMTJ-UHFFFAOYSA-N 0.000 description 1
- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
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- 239000004927 clay Substances 0.000 description 1
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- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
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- 229920001577 copolymer Polymers 0.000 description 1
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- 239000007822 coupling agent Substances 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
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- ZBCKWHYWPLHBOK-UHFFFAOYSA-N cyclohexylphosphane Chemical compound PC1CCCCC1 ZBCKWHYWPLHBOK-UHFFFAOYSA-N 0.000 description 1
- KOMDZQSPRDYARS-UHFFFAOYSA-N cyclopenta-1,3-diene titanium Chemical compound [Ti].C1C=CC=C1.C1C=CC=C1 KOMDZQSPRDYARS-UHFFFAOYSA-N 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- GYZLOYUZLJXAJU-UHFFFAOYSA-N diglycidyl ether Chemical compound C1OC1COCC1CO1 GYZLOYUZLJXAJU-UHFFFAOYSA-N 0.000 description 1
- QYMFNZIUDRQRSA-UHFFFAOYSA-N dimethyl butanedioate;dimethyl hexanedioate;dimethyl pentanedioate Chemical compound COC(=O)CCC(=O)OC.COC(=O)CCCC(=O)OC.COC(=O)CCCCC(=O)OC QYMFNZIUDRQRSA-UHFFFAOYSA-N 0.000 description 1
- NJLLQSBAHIKGKF-UHFFFAOYSA-N dipotassium dioxido(oxo)titanium Chemical compound [K+].[K+].[O-][Ti]([O-])=O NJLLQSBAHIKGKF-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- DBLVXHJTZIDGHE-UHFFFAOYSA-N ethyl acetate;2-(2-hydroxyethoxy)ethanol Chemical compound CCOC(C)=O.OCCOCCO DBLVXHJTZIDGHE-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
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- 125000000524 functional group Chemical group 0.000 description 1
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 1
- 229940015043 glyoxal Drugs 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- ACCCMOQWYVYDOT-UHFFFAOYSA-N hexane-1,1-diol Chemical compound CCCCCC(O)O ACCCMOQWYVYDOT-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- HCWCAKKEBCNQJP-UHFFFAOYSA-N magnesium orthosilicate Chemical compound [Mg+2].[Mg+2].[O-][Si]([O-])([O-])[O-] HCWCAKKEBCNQJP-UHFFFAOYSA-N 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- 239000000391 magnesium silicate Substances 0.000 description 1
- 229910052919 magnesium silicate Inorganic materials 0.000 description 1
- 235000019792 magnesium silicate Nutrition 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 229910001507 metal halide Inorganic materials 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 125000005395 methacrylic acid group Chemical group 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
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- 239000006082 mold release agent Substances 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- MBAUOPQYSQVYJV-UHFFFAOYSA-N octyl 3-[4-hydroxy-3,5-di(propan-2-yl)phenyl]propanoate Chemical compound OC1=C(C=C(C=C1C(C)C)CCC(=O)OCCCCCCCC)C(C)C MBAUOPQYSQVYJV-UHFFFAOYSA-N 0.000 description 1
- 150000004866 oxadiazoles Chemical class 0.000 description 1
- 150000002923 oximes Chemical class 0.000 description 1
- RPQRDASANLAFCM-UHFFFAOYSA-N oxiran-2-ylmethyl prop-2-enoate Chemical compound C=CC(=O)OCC1CO1 RPQRDASANLAFCM-UHFFFAOYSA-N 0.000 description 1
- 125000000466 oxiranyl group Chemical group 0.000 description 1
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 description 1
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 125000000951 phenoxy group Chemical group [H]C1=C([H])C([H])=C(O*)C([H])=C1[H] 0.000 description 1
- 230000036211 photosensitivity Effects 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 1
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- 238000007650 screen-printing Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- VEALVRVVWBQVSL-UHFFFAOYSA-N strontium titanate Chemical compound [Sr+2].[O-][Ti]([O-])=O VEALVRVVWBQVSL-UHFFFAOYSA-N 0.000 description 1
- 239000012756 surface treatment agent Substances 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- JRMUNVKIHCOMHV-UHFFFAOYSA-M tetrabutylammonium bromide Chemical compound [Br-].CCCC[N+](CCCC)(CCCC)CCCC JRMUNVKIHCOMHV-UHFFFAOYSA-M 0.000 description 1
- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 description 1
- YRHRIQCWCFGUEQ-UHFFFAOYSA-N thioxanthen-9-one Chemical compound C1=CC=C2C(=O)C3=CC=CC=C3SC2=C1 YRHRIQCWCFGUEQ-UHFFFAOYSA-N 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229910001928 zirconium oxide Inorganic materials 0.000 description 1
Images
Landscapes
- Materials For Photolithography (AREA)
- Non-Metallic Protective Coatings For Printed Circuits (AREA)
Description
上記重合性重合体(A)はカルボキシル基を有する。カルボキシル基を有する重合性重合体(A)は重合性を有し、重合可能である。上記重合性重合体(A)がカルボキシル基を有することで、感光性組成物の現像性が良好になる。上記重合性重合体(A)としては、例えば、カルボキシル基を有するアクリル樹脂、カルボキシル基を有するエポキシ樹脂及びカルボキシル基を有するオレフィン樹脂が挙げられる。なお、「樹脂」は、固形樹脂に限定されず、液状樹脂及びオリゴマーも含む。
上記感光性組成物は、光重合開始剤(B)を含むので、光の照射により感光性組成物を硬化させることができる。光重合開始剤(B)は特に限定されない。光重合開始剤(B)は、1種のみが用いられてもよく、2種以上が併用されてもよい。
レジスト膜の切り出し加工性を高めることなどを目的として、上記感光性組成物は、環状エーテル基を有する化合物(C)を含む。また、上記環状エーテル基を有する化合物(C)の使用により、感光性組成物の硬化性も良好になる。
上記感光性組成物は、酸化チタン(D)を含むので、反射率が高いソルダーレジスト膜などのレジスト膜を形成できる。上記感光性組成物に含まれている酸化チタン(D)は特に限定されない。酸化チタン(D)は、1種のみが用いられてもよく、2種以上が併用されてもよい。
上記無機フィラー(E)は、酸化チタンとは異なる無機フィラーである。上記無機フィラー(E)は1種のみが用いられてもよく、2種以上が併用されてもよい。
上記感光性組成物は、有機溶剤(F)を含む。上記第1,第2の液を混合した感光性組成物は、有機溶剤(F)を含む。上記感光性組成物は、少なくとも2種の有機溶剤を含むことが好ましい。有機溶剤(F)は、1種のみが用いられてもよく、2種以上が併用されてもよい。
硬化性をより一層高めるために、上記感光性組成物は、カルボキシル基を有する重合性重合体(A)とは異なる成分として、重合性単量体を含むことが好ましい。上記感光性組成物は、カルボキシル基を有する重合性重合体(A)と重合性単量体との双方を含むことが好ましい。上記重合性単量体は重合性を有し、重合可能である。上記重合性単量体は特に限定されない。上記重合性単量体は、1種のみが用いられてもよく、2種以上が併用されてもよい。
本発明に係る2液混合型の第1,第2の液は、LEDデバイスのレジスト膜を形成するために好適に用いられ、ソルダーレジスト膜を形成するためにより好適に用いられる。本発明に係る2液混合型の第1,第2の液は、レジスト組成物であることが好ましく、ソルダーレジスト組成物であることが好ましい。
(合成例1)
温度計、攪拌機、滴下ロート及び還流冷却器を備えたフラスコに、溶剤であるエチルカルビトールアセテートと、触媒であるアゾビスイソブチロニトリルとを入れ、窒素雰囲気下で80℃に加熱し、メタクリル酸とメチルメタクリレートとを30:70のモル比で混合したモノマーを2時間かけて滴下した。滴下後、1時間攪拌し、温度を120℃に上げた。その後、冷却した。得られた樹脂の全てのモノマー単位の総量のモル量に対するモル比が10となる量のグリシジルアクリレートを加え、触媒として臭化テトラブチルアンモニウムを用い100℃で30時間加熱して、グリシジルアクリレートとカルボキシル基とを付加反応させた。冷却後、フラスコから取り出して、固形分酸価60mgKOH/g、重量平均分子量15000、二重結合当量1000のカルボキシル基含有樹脂を50重量%(不揮発分)含む溶液を得た。以下、この溶液をアクリルポリマー1と呼ぶ。
3)828(ビスフェノールA型エポキシ樹脂、三菱化学社製)
4)TPO(光ラジカル発生剤である光重合開始剤、BASFジャパン社製)
5)CR−50(酸化チタン、石原産業社製、塩素法により製造されたルチル型酸化チタン)
6)FH105(タルク、富士タルク社製)
7)5X(シリカ、龍森社製)
8)KS−7710(コンパウンド型シリコーンオイル、ポリジメチルシロキサン、信越化学工業社製)
9)エチルカルビトールアセテート(ジエチレングリコールモノエチルエーテルアセテート、ダイセル社製)
10)ジプロピレングリコールモノメチルエーテル(日本乳化剤社製)
11)DBE(二塩基酸エステル、三協化学社製)
合成例1で得られたアクリルポリマー1を15gと、TPO(光ラジカル発生剤である光重合開始剤、BASFジャパン社製)2gと、CR−50(酸化チタン、石原産業社製)30gと、エチルカルビトールアセテート(ジエチレングリコールモノエチルエーテルアセテート、ダイセル社製)30gと、FH105(タルク、富士タルク社製)5gと、KS−7710(コンパウンド型シリコーンオイル、ポリジメチルシロキサン、信越化学工業社製)1gとを配合し、混合機(練太郎ARE−310、シンキー社製)にて3分間混合した後、3本ロールにて混合し、混合物を得た。その後、ARE−310を用いて、得られた混合物を3分間脱泡することにより、第1の液を得た。
第1の液及び第2の液で使用した材料の種類及び配合量を下記の表1に示すように変更したこと以外は、実施例1と同様にして、第1,第2の液を有する2液混合型の第1,第2の液(混合前の感光性組成物)を得た。
(1)保存安定性
上記のようにして得られた第1,第2の液をプラスチックス容器(近畿容器社製、BHR−150)に入れ、室温にて6ヶ月間静置、その後、第1,第2の液のそれぞれから、上澄み液と容器底部分の液をるつぼに2g採取し、550℃で2時間焼成を行ない、次式より灰分を計算した。
○:灰分の差が0.1%未満
△:灰分の差が0.1%以上0.5%未満
×:灰分の差が0.5%以上
測定サンプルの作製
第1の液と第2の液とを、1Lの丸型のプラスチックス容器(近畿容器社製、BHS−1200)に入れ、メッシュ社製自動インキ練機により、50rpmで10秒間攪拌したレジスト材料(混合後の感光性組成物)を作製した。
○:標準偏差σが0.5未満
△:標準偏差σが0.5以上1.0未満
×:標準偏差σが1.0以上
2…基板
2a…上面
3…レジスト膜
3a…上面
4a,4b…電極
7…LEDチップ
7a…下面
8a,8b…端子
9a,9b…はんだ
Claims (8)
- 混合物である感光性組成物を得るための2液混合型の第1,第2の液であり、該2液混合型の第1,第2の液は該第1,第2の液が混合される前の液であり、
前記第1,第2の液が混合された混合物である感光性組成物が全体で、カルボキシル基を有する重合性重合体と、光重合開始剤と、環状エーテル基を有する化合物と、酸化チタンと、酸化チタンとは異なる無機フィラーと、有機溶剤とを含み、
前記第1の液が、前記カルボキシル基を有する重合性重合体と、前記光重合開始剤と、前記酸化チタンと、前記無機フィラーと、前記有機溶剤とを含み、
前記第2の液が、前記環状エーテル基を有する化合物と、前記酸化チタンと、前記無機フィラーとを含み、
前記第2の液が、前記有機溶剤を含まないか、又は、前記有機溶剤を前記感光性組成物に含まれる前記有機溶剤の全体100重量%中の10重量%以下で含む、2液混合型の第1,第2の液。 - 前記第2の液が、前記有機溶剤を含まない、請求項1に記載の2液混合型の第1,第2の液。
- 前記感光性組成物に含まれる前記有機溶剤が、二塩基酸エステルを含む、請求項1又は2に記載の2液混合型の第1,第2の液。
- 前記無機フィラーの平均粒子径が0.1μm以上、10μm以下である、請求項1〜3のいずれか1項に記載の2液混合型の第1,第2の液。
- 前記第1の液中の前記酸化チタンの含有量と、前記第2の液中の前記酸化チタンの含有量とは、重量比で、20:80〜80:20であり、
前記第1の液中の前記無機フィラーの含有量と、前記第2の液中の前記無機フィラーの含有量とは、重量比で、20:80〜80:20である、請求項1〜4のいずれか1項に記載の2液混合型の第1,第2の液。 - 前記第1,第2の液が混合された混合物である感光性組成物が全体で、重合性単量体を含む、請求項1〜5のいずれか1項に記載の2液混合型の第1,第2の液。
- ソルダーレジスト膜を形成するために用いられる、請求項1〜6のいずれか1項に記載の2液混合型の第1,第2の液。
- 回路を表面に有するプリント配線板本体と、該プリント配線板本体の回路が設けられた表面に積層されたソルダーレジスト膜とを備えるプリント配線板の製造方法であって、
請求項1〜7のいずれか1項に記載の2液混合型の第1,第2の液を混合し、前記第1,第2の液が混合されたソルダーレジスト組成物である感光性組成物を得る工程と、
回路を表面に有するプリント配線板本体の回路が設けられた表面上に、前記第1,第2の液が混合されたソルダーレジスト組成物である感光性組成物を塗工して、前記プリント配線板本体の前記回路が設けられた表面に積層されたソルダーレジスト膜を形成する工程とを備える、プリント配線板の製造方法。
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