JP6522818B2 - Polycarbonate resin composition for optical parts and optical parts - Google Patents

Description

  TECHNICAL FIELD The present invention relates to a polycarbonate resin composition for optical parts and an optical part, and more particularly, a polycarbonate resin composition for optical parts having a good color and very little gas generation and mold contamination at the time of molding Related optical components.

  A planar light source device is incorporated in a liquid crystal display device used for a personal computer, a cellular phone or the like in order to meet the demand for thinning, weight saving, labor saving and high definition. The planar light source device has a wedge-shaped light guide plate or a flat plate shape having a uniform inclined surface for the purpose of guiding the incoming light uniformly and efficiently to the liquid crystal display side. A light guide plate is provided. There is also a type in which a concavo-convex pattern is formed on the surface of the light guide plate to provide a light scattering function.

  Such a light guide plate is obtained by injection molding of a thermoplastic resin, and the above-mentioned concavo-convex pattern is imparted by transfer of the concavo-convex part formed on the surface of the nested mold. Conventionally, the light guide plate has been molded from a resin material such as polymethyl methacrylate (PMMA), but recently, a display device for projecting a clearer image is required, and the heat generated in the vicinity of the light source raises the temperature inside the device It is being replaced by polycarbonate resin materials with higher heat resistance.

  A polycarbonate resin is excellent in mechanical properties, thermal properties, electrical properties, and weather resistance, but its light transmittance is lower than that of PMMA etc., so a surface light source is made of a light guide plate made of polycarbonate resin and a light source. When configured, there is a problem that the brightness is low. Further, recently, it has been required to reduce the difference in chromaticity between the light entrance portion of the light guide plate and a place away from the light entrance portion, but polycarbonate resins have a problem of being easily yellowed as compared with PMMA.

  Patent Document 1 discloses a method of improving light transmittance and luminance by adding an acrylic resin and an alicyclic epoxy compound, Patent Document 2 discloses that the terminal of a polycarbonate resin is modified to transfer the concavo-convex portion to a light guide plate. Patent Document 3 proposes a method of improving luminance by introducing a copolyester carbonate having an aliphatic segment to improve the above-mentioned transferability.

  However, according to the method of Patent Document 1, the addition of the acrylic resin makes the color good but the light transmittance and the brightness can not be increased because the white turbidity occurs, and the transmittance is increased by adding the alicyclic epoxy compound. Although there is a possibility of improvement, the improvement effect of the hue is not recognized. In the case of Patent Document 2 and Patent Document 3, although the effect of improving the fluidity and the transferability can be expected, there is a disadvantage that the heat resistance is lowered.

On the other hand, it is known to blend polyethylene glycol or poly (2-methyl) ethylene glycol etc. into a thermoplastic resin such as a polycarbonate resin, and Patent Document 4 contains a γ-ray-resistant polycarbonate resin containing it. Patent Document 5 describes a thermoplastic resin composition excellent in antistatic property and surface appearance blended in PMMA or the like.
And in patent document 6, the proposal which improves a transmittance | permeability and a hue is made | formed by mix | blending the polyalkylene glycol comprised with a linear alkyl group. By blending polytetramethylene ether glycol, the transmittance and the degree of yellowing (yellow index: YI) are improved.

  However, recently, in various portable terminals such as smartphones and tablet terminals, optical parts such as light guide plates are progressing at a rapid rate of thinning and increasing in size, and high temperature barrel temperatures And high speed injection is required. Along with this, the gas generated at the time of molding increases, and there is a problem that mold contamination is likely to progress. Therefore, not only excellent optical properties but also less mold contamination at the time of injection molding at high temperature is required for resin compositions used for these moldings.

JP-A-11-158364 JP 2001-208917 A JP 2001-215336 A Unexamined-Japanese-Patent No. 1-22959 Unexamined-Japanese-Patent No. 9-227785 Patent No. 5699188 gazette

  The present invention has been made in view of the above-described circumstances, and its object is to provide an optical device having a good color without causing any deterioration in the original characteristics of polycarbonate resin and having very little gas generation and mold contamination during molding. An object of the present invention is to provide a polycarbonate resin composition for parts and an optical part.

The inventors of the present invention have conducted intensive studies to achieve the above-mentioned problems, and as a result, a polyalkylene glycol having an amount of a component having a weight average molecular weight (Mw) of 400 or less is less than 1.0% by mass. In addition, it has been found that a polycarbonate resin composition for an optical component having a good color and very little gas generation and mold contamination at the time of molding can be obtained by blending the polycarbonate resin in a specific amount. We came to complete the invention.
The present invention relates to the following polycarbonate resin composition for optical parts and optical parts.

[1] 0.1 to 4 parts by mass of polyalkylene glycol (B) and 0.005 to 0.5 parts by mass of phosphorus stabilizer (C) with respect to 100 parts by mass of polycarbonate resin (A),
In the polyalkylene glycol (B), the amount of a component having a weight average molecular weight (Mw) of 400 or less measured in terms of polystyrene by gel permeation chromatography using tetrahydrofuran as a solvent is less than 1.0% by mass, and the terminal hydroxyl value The polycarbonate resin composition for optical parts characterized by having a number average molecular weight (Mn) of 700 to 2600 obtained from the above.
[2] The polycarbonate resin composition for optical parts as described in the above [1], wherein the polyalkylene glycol (B) has a tetramethylene ether unit.
[3] The polycarbonate resin composition for optical parts according to the above [2], wherein the molar ratio of tetramethylene ether units of the polyalkylene glycol (B) is 50 mol% or more.
[4] The optical component according to any one of the above [1] to [3], which further comprises an epoxy compound (D) in an amount of 0.0005 to 0.2 parts by mass with respect to 100 parts by mass of the polycarbonate resin (A) Polycarbonate resin composition.
[5] An optical component obtained by molding the polycarbonate resin composition according to any one of the above [1] to [4].

  The polycarbonate resin composition of the present invention can provide an optical component having a good hue, with little gas generation during molding, very little mold contamination, and without any loss of the original characteristics of the polycarbonate resin. .

FIG. 1 is a plan view of a drop mold used for evaluation of mold contamination in the example.

Hereinafter, the present invention will be described in detail with reference to embodiments and examples.
In addition, in this specification, unless there is particular notice, "-" is used by the meaning included as a lower limit and an upper limit with the numerical value described before and behind that.

The polycarbonate resin composition for optical parts of the present invention comprises 0.1 to 4 parts by mass of polyalkylene glycol (B) and 0.005 to phosphorus stabilizer (C) per 100 parts by mass of polycarbonate resin (A). 0.5 parts by mass,
In the polyalkylene glycol (B), the amount of a component having a weight average molecular weight (Mw) of 400 or less measured in terms of polystyrene by gel permeation chromatography using tetrahydrofuran as a solvent is less than 1.0% by mass, and the terminal hydroxyl value The number average molecular weight (Mn) calculated | required from these is 700-2600, It is characterized by the above-mentioned.
Hereinafter, each component which comprises the polycarbonate resin composition of this invention, an optical component etc. are demonstrated in detail.

[Polycarbonate resin (A)]
There is no restriction on the type of polycarbonate resin used in the present invention, and one type of polycarbonate resin may be used, or two or more types may be used in combination in an arbitrary ratio and an arbitrary ratio.

The polycarbonate resin is a polymer of a basic structure having a carbonic acid bond represented by the formula:-[-O-X-O-C (= O)-]-.
In the formula, X is generally a hydrocarbon, but a hetero atom or X having a hetero bond may be used for various properties.

  Further, polycarbonate resins can be classified into aromatic polycarbonate resins in which carbon directly bonded to carbonic bonds is aromatic carbon and aliphatic polycarbonate resins in which aliphatic carbon is directly bonded, but any of them can be used. Among them, aromatic polycarbonate resins are preferable from the viewpoint of heat resistance, mechanical physical properties, electrical properties and the like.

  Although there is no restriction | limiting in the specific kind of polycarbonate resin, For example, the polycarbonate polymer which makes a dihydroxy compound and a carbonate precursor react is mentioned. At this time, in addition to the dihydroxy compound and the carbonate precursor, a polyhydroxy compound or the like may be reacted. Alternatively, carbon dioxide may be reacted with cyclic ether as a carbonate precursor. The polycarbonate polymer may be linear or branched. Furthermore, the polycarbonate polymer may be a homopolymer comprising one kind of repeating unit, or may be a copolymer having two or more kinds of repeating units. At this time, as the copolymer, various copolymer forms such as a random copolymer and a block copolymer can be selected. In general, such polycarbonate polymers are thermoplastic resins.

Among the monomers used as the raw material of the aromatic polycarbonate resin, to cite an example of the aromatic dihydroxy compound,
Dihydroxybenzenes such as 1,2-dihydroxybenzene, 1,3-dihydroxybenzene (that is, resorcinol), 1,4-dihydroxybenzene;
Dihydroxybiphenyls such as 2,5-dihydroxybiphenyl, 2,2'-dihydroxybiphenyl, 4,4'-dihydroxybiphenyl;

2,2'-dihydroxy-1,1'-binaphthyl, 1,2-dihydroxynaphthalene, 1,3-dihydroxynaphthalene, 2,3-dihydroxynaphthalene, 1,6-dihydroxynaphthalene, 2,6-dihydroxynaphthalene, 1 , Dihydroxynaphthalenes such as 7-dihydroxynaphthalene, 2,7-dihydroxynaphthalene;

2,2'-dihydroxydiphenyl ether, 3,3'-dihydroxydiphenyl ether, 4,4'-dihydroxydiphenyl ether, 4,4'-dihydroxy-3,3'-dimethyldiphenyl ether, 1,4-bis (3-hydroxyphenoxy) Dihydroxy diaryl ethers such as benzene and 1,3-bis (4-hydroxyphenoxy) benzene;

2,2-bis (4-hydroxyphenyl) propane (that is, bisphenol A),
1,1-bis (4-hydroxyphenyl) propane,
2,2-bis (3-methyl-4-hydroxyphenyl) propane,
2,2-bis (3-methoxy-4-hydroxyphenyl) propane,
2- (4-hydroxyphenyl) -2- (3-methoxy-4-hydroxyphenyl) propane,
1,1-bis (3-tert-butyl-4-hydroxyphenyl) propane,
2,2-bis (3,5-dimethyl-4-hydroxyphenyl) propane,
2,2-bis (3-cyclohexyl-4-hydroxyphenyl) propane,
2- (4-hydroxyphenyl) -2- (3-cyclohexyl-4-hydroxyphenyl) propane,
α, α'-bis (4-hydroxyphenyl) -1,4-diisopropylbenzene,
1,3-bis [2- (4-hydroxyphenyl) -2-propyl] benzene,
Bis (4-hydroxyphenyl) methane,
Bis (4-hydroxyphenyl) cyclohexylmethane,
Bis (4-hydroxyphenyl) phenylmethane,
Bis (4-hydroxyphenyl) (4-propenylphenyl) methane,
Bis (4-hydroxyphenyl) diphenylmethane,
Bis (4-hydroxyphenyl) naphthylmethane,
1,1-bis (4-hydroxyphenyl) ethane,
1,1-bis (4-hydroxyphenyl) -1-phenylethane,
1,1-bis (4-hydroxyphenyl) -1-naphthyl ethane,
1,1-bis (4-hydroxyphenyl) butane,
2,2-bis (4-hydroxyphenyl) butane,
2,2-bis (4-hydroxyphenyl) pentane,
1,1-bis (4-hydroxyphenyl) hexane,
2,2-bis (4-hydroxyphenyl) hexane,
1,1-bis (4-hydroxyphenyl) octane,
2,2-bis (4-hydroxyphenyl) octane,
4,4-bis (4-hydroxyphenyl) heptane,
2,2-bis (4-hydroxyphenyl) nonane,
1,1-bis (4-hydroxyphenyl) decane,
1,1-bis (4-hydroxyphenyl) dodecane,
Etc. bis (hydroxyaryl) alkanes such as

1,1-bis (4-hydroxyphenyl) cyclopentane,
1,1-bis (4-hydroxyphenyl) cyclohexane,
1,1-bis (4-hydroxyphenyl) -3,3-dimethylcyclohexane,
1,1-bis (4-hydroxyphenyl) -3,4-dimethylcyclohexane,
1,1-bis (4-hydroxyphenyl) -3,5-dimethylcyclohexane,
1,1-bis (4-hydroxyphenyl) -3,3,5-trimethylcyclohexane,
1,1-bis (4-hydroxy-3,5-dimethylphenyl) -3,3,5-trimethylcyclohexane,
1,1-bis (4-hydroxyphenyl) -3-propyl-5-methylcyclohexane, 1,1-bis (4-hydroxyphenyl) -3-tert-butyl-cyclohexane,
1,1-bis (4-hydroxyphenyl) -4-tert-butyl-cyclohexane,
1,1-bis (4-hydroxyphenyl) -3-phenylcyclohexane,
1,1-bis (4-hydroxyphenyl) -4-phenylcyclohexane,
Etc. bis (hydroxyaryl) cycloalkanes;

9,9-bis (4-hydroxyphenyl) fluorene,
Cardo-structure-containing bisphenols such as 9,9-bis (4-hydroxy-3-methylphenyl) fluorene;

4,4'-dihydroxydiphenyl sulfide,
Dihydroxy diaryl sulfides such as 4,4'-dihydroxy-3,3'-dimethyl diphenyl sulfide;

Dihydroxy diaryl sulfoxides such as 4,4'-dihydroxy diphenyl sulfoxide, 4,4'-dihydroxy-3,3'-dimethyl diphenyl sulfoxide;

4,4'-dihydroxydiphenyl sulfone,
Dihydroxy diaryl sulfones such as 4,4'-dihydroxy-3,3'-dimethyl diphenyl sulfone;
Etc.

Among these, bis (hydroxyaryl) alkanes are preferable, and in particular, bis (4-hydroxyphenyl) alkanes are preferable, and in particular, in view of impact resistance and heat resistance, 2,2-bis (4-hydroxyphenyl) propane ( That is, bisphenol A) is preferred.
In addition, 1 type may be used for an aromatic dihydroxy compound, and 2 or more types may be used together by arbitrary combinations and a ratio.

In addition, as an example of a monomer that is a raw material of aliphatic polycarbonate resin,
Ethane-1,2-diol, propane-1,2-diol, propane-1,3-diol, 2,2-dimethylpropane-1,3-diol, 2-methyl-2-propylpropane-1,3- Alkane diols such as diol, butane-1,4-diol, pentane-1,5-diol, hexane-1,6-diol and decane-1,10-diol;

  Cyclopentane-1,2-diol, cyclohexane-1,2-diol, cyclohexane-1,4-diol, 1,4-cyclohexanedimethanol, 4- (2-hydroxyethyl) cyclohexanol, 2,2,4,4, Cycloalkane diols such as 4-tetramethyl-cyclobutane-1,3-diol;

  Glycols such as ethylene glycol, 2,2'-oxydiethanol (ie, diethylene glycol), triethylene glycol, propylene glycol, spiro glycol and the like;

  1,2-benzenedimethanol, 1,3-benzenedimethanol, 1,4-benzenedimethanol, 1,4-benzenediethanol, 1,3-bis (2-hydroxyethoxy) benzene, 1,4-bis ( 2-hydroxyethoxy) benzene, 2,3-bis (hydroxymethyl) naphthalene, 1,6-bis (hydroxyethoxy) naphthalene, 4,4'-biphenyldimethanol, 4,4'-biphenyldiethanol, 1,4- Aralkyl diols such as bis (2-hydroxyethoxy) biphenyl, bisphenol A bis (2-hydroxyethyl) ether, bisphenol S bis (2-hydroxyethyl) ether;

  1,2-epoxyethane (ie ethylene oxide), 1,2-epoxypropane (ie propylene oxide), 1,2-epoxycyclopentane, 1,2-epoxycyclohexane, 1,4-epoxycyclohexane, 1-methyl -Cyclic ethers such as 1,2-epoxycyclohexane, 2,3-epoxy norbornane, and 1,3-epoxypropane; and the like.

  Among the monomers used as the raw materials of polycarbonate resins, carbonyl halides, carbonate esters and the like are used as examples of carbonate precursors. In addition, 1 type may be used for a carbonate precursor and it may use 2 or more types together by arbitrary combinations and a ratio.

  Specific examples of the carbonyl halide include phosgene; bischloroformates of dihydroxy compounds, haloformates such as monochloroformates of dihydroxy compounds, and the like.

  Specific examples of the carbonate ester include diaryl carbonates such as diphenyl carbonate and ditolyl carbonate; dialkyl carbonates such as dimethyl carbonate and diethyl carbonate; biscarbonates of dihydroxy compounds; monocarbonates of dihydroxy compounds; cyclic carbonates And carbonates of dihydroxy compounds such as

Method for Producing Polycarbonate Resin The method for producing polycarbonate resin is not particularly limited, and any method can be adopted. Examples thereof include an interfacial polymerization method, a melt transesterification method, a pyridine method, a ring opening polymerization method of a cyclic carbonate compound, and a solid phase transesterification method of a prepolymer.
Among these methods, particularly preferred ones will be specifically described below.

Interfacial Polymerization Method First, the case of producing a polycarbonate resin by an interfacial polymerization method will be described.
In the interfacial polymerization method, after the dihydroxy compound is reacted with a carbonate precursor (preferably phosgene) in the presence of an organic solvent inert to the reaction and an alkaline aqueous solution, the pH is usually maintained at 9 or more. The polycarbonate resin is obtained by performing interfacial polymerization in the presence. In addition, in the reaction system, a molecular weight modifier (end stopper) may be present if necessary, and an antioxidant may be present to prevent oxidation of the dihydroxy compound.

  The dihydroxy compound and the carbonate precursor are as described above. Among the carbonate precursors, it is preferable to use phosgene, and a method using phosgene is particularly called phosgene method.

  Examples of the organic solvent inert to the reaction include chlorinated hydrocarbons such as dichloromethane, 1,2-dichloroethane, chloroform, monochlorobenzene, and dichlorobenzene; and aromatic hydrocarbons such as benzene, toluene, and xylene; Be In addition, an organic solvent may use 1 type and may use 2 or more types together by arbitrary combinations and a ratio.

  Examples of the alkali compound contained in the aqueous alkali solution include alkali metal compounds such as sodium hydroxide, potassium hydroxide, lithium hydroxide and sodium hydrogencarbonate and alkaline earth metal compounds, among which sodium hydroxide and water Potassium oxide is preferred. In addition, an alkali compound may use 1 type and may use 2 or more types together by arbitrary combinations and a ratio.

  Although the concentration of the alkali compound in the aqueous alkali solution is not limited, it is usually used at 5 to 10% by mass in order to control the pH in the aqueous alkali solution of the reaction to 10 to 12. For example, when blowing in phosgene, the molar ratio of the bisphenol compound to the alkali compound is usually 1: 1.9 or more in order to control the pH of the aqueous phase to be 10 to 12, preferably 10 to 11. It is preferable to set it as 1: 2.0 or more, usually 1: 3.2 or less, and in particular 1: 2.5 or less.

  Examples of the polymerization catalyst include aliphatic tertiary amines such as trimethylamine, triethylamine, tributylamine, tripropylamine and trihexylamine; and alicyclic resins such as N, N'-dimethylcyclohexylamine and N, N'-diethylcyclohexylamine Aromatic amines such as tertiary amines; N, N'-dimethylaniline, N, N'-diethylaniline; quaternary ammonium salts such as trimethylbenzyl ammonium chloride, tetramethyl ammonium chloride, triethyl benzyl ammonium chloride, etc. Pyridine; guanine; salts of guanidine; and the like. The polymerization catalyst may be used alone, or two or more may be used in any combination and ratio.

  Examples of the molecular weight modifier include aromatic phenols having a monohydric phenolic hydroxyl group; aliphatic alcohols such as methanol and butanol; mercaptan; phthalimide and the like, among which aromatic phenols are preferable. Specific examples of such aromatic phenols include alkyl groups such as m-methylphenol, p-methylphenol, m-propylphenol, p-propylphenol, p-tert-butylphenol, and p-long-chain alkyl-substituted phenols. Examples thereof include substituted phenols; vinyl group-containing phenols such as isopropanyl phenol; epoxy group-containing phenols; carboxyl group-containing phenols such as o-hydroxybenzoic acid and 2-methyl-6-hydroxyphenylacetic acid; In addition, a molecular weight modifier may be used 1 type and may use 2 or more types together by arbitrary combinations and a ratio.

  The amount of the molecular weight modifier used is usually 0.5 mol or more, preferably 1 mol or more, and usually 50 mol or less, preferably 30 mol or less, per 100 mol of the dihydroxy compound. By making the usage-amount of a molecular weight modifier into this range, the thermal stability and hydrolysis resistance of a resin composition can be improved.

In the reaction, the order of mixing the reaction substrate, reaction medium, catalyst, additive and the like is arbitrary as long as a desired polycarbonate resin can be obtained, and the appropriate order may be arbitrarily set. For example, when phosgene is used as the carbonate precursor, the molecular weight modifier can be mixed at any time between the time of the reaction between the dihydroxy compound and phosgene (phosgenation) and the time of the polymerization reaction start.
The reaction temperature is usually 0 to 40 ° C., and the reaction time is usually several minutes (eg, 10 minutes) to several hours (eg, 6 hours).

Melt Transesterification Method Next, the case of producing a polycarbonate resin by a melt transesterification method will be described.
In the melt transesterification method, for example, a transesterification reaction of carbonic acid diester with a dihydroxy compound is performed.

The dihydroxy compound is as described above.
On the other hand, as a carbonic diester, for example, dialkyl carbonate compounds such as dimethyl carbonate, diethyl carbonate, di-tert-butyl carbonate and the like; diphenyl carbonate; substituted diphenyl carbonates such as ditolyl carbonate and the like can be mentioned. Among them, diphenyl carbonate and substituted diphenyl carbonate are preferable, and particularly diphenyl carbonate is more preferable. One carbonic diester may be used, or two or more carbonic diesters may be used in any combination and ratio.

  The ratio between the dihydroxy compound and the carbonic diester is arbitrary as long as the desired polycarbonate resin can be obtained, but it is preferable to use an equal molar amount or more of the carbonic diester with respect to 1 mol of the dihydroxy compound, and more preferably 1.01 mol or more Is more preferred. The upper limit is usually 1.30 moles or less. By setting it as such a range, the amount of terminal hydroxyl groups can be adjusted to a suitable range.

  In polycarbonate resins, the amount of terminal hydroxyl groups tends to greatly affect the thermal stability, hydrolysis stability, color tone and the like. Therefore, the amount of terminal hydroxyl groups may be adjusted as necessary by any known method. In the transesterification reaction, a polycarbonate resin in which the amount of terminal hydroxyl groups is adjusted can usually be obtained by adjusting the mixing ratio of the carbonic diester and the aromatic dihydroxy compound; the degree of pressure reduction at the time of the transesterification reaction. In addition, the molecular weight of the polycarbonate resin usually obtained can also be adjusted by this operation.

When adjusting the mixing ratio of carbonic diester and dihydroxy compound to adjust the amount of terminal hydroxyl groups, the mixing ratio is as described above.
Further, as a more positive adjustment method, a method of mixing an end terminator separately at the time of reaction may be mentioned. Examples of the terminal stopper at this time include monohydric phenols, monohydric carboxylic acids, carbonic diesters and the like. In addition, 1 type may be used for end terminator and 2 or more types may be used together by arbitrary combinations and a ratio.

  In the production of a polycarbonate resin by a melt transesterification method, a transesterification catalyst is usually used. Any transesterification catalyst can be used. Among them, it is preferable to use, for example, an alkali metal compound and / or an alkaline earth metal compound. In addition, for example, basic compounds such as basic boron compounds, basic phosphorus compounds, basic ammonium compounds and amine compounds may be used in combination. In addition, 1 type may be used for a transesterification catalyst, and 2 or more types may be used together by arbitrary combinations and a ratio.

  In the melt transesterification method, the reaction temperature is usually 100 to 320 ° C. Moreover, the pressure at the time of reaction is usually a reduced pressure condition of 2 mmHg or less. As a specific operation, a melt polycondensation reaction may be carried out while removing by-products such as aromatic hydroxy compounds under the above conditions.

  The melt polycondensation reaction can be carried out either batchwise or continuously. When carrying out by a batch system, the order which mixes a reaction substrate, a reaction medium, a catalyst, an additive etc. is arbitrary as long as a desired aromatic polycarbonate resin is obtained, and what is necessary is just to set an appropriate order arbitrarily. However, in consideration of the stability of the polycarbonate resin, it is preferable to carry out the melt polycondensation reaction continuously.

  In the melt transesterification method, if necessary, a catalyst deactivator may be used. As the catalyst deactivator, a compound that neutralizes the transesterification catalyst can be optionally used. Examples thereof include sulfur-containing acidic compounds and derivatives thereof. The catalyst deactivator may be used alone or in combination of two or more at any ratio and ratio.

  The amount of catalyst deactivator used is usually 0.5 equivalents or more, preferably 1 equivalent or more, and usually 10 equivalents or less, with respect to the alkali metal or alkaline earth metal contained in the above-mentioned transesterification catalyst. Preferably, it is 5 equivalents or less. Furthermore, it is usually 1 ppm or more, and usually 100 ppm or less, preferably 20 ppm or less, relative to the polycarbonate resin.

The molecular weight of the polycarbonate resin (A) is preferably 10,000 to 26,000 as a viscosity average molecular weight (Mv) calculated from the solution viscosity measured at a temperature of 25 ° C. using methylene chloride as a solvent. Preferably, it is 10,500 or more, more preferably 11,000 or more, in particular 11,500 or more, most preferably 12,000 or more, more preferably 24,000 or less, still more preferably 20,000 or less. is there. By setting the viscosity average molecular weight to the lower limit value or more of the above range, the mechanical strength of the polycarbonate resin composition of the present invention can be further improved, and by setting the viscosity average molecular weight to the upper limit value or less of the above range The flowability of the polycarbonate resin composition of the present invention can be suppressed and improved, and the molding processability can be enhanced to facilitate thin-wall molding.
In addition, you may mix and use 2 or more types of polycarbonate resin from which a viscosity average molecular weight differs, and in this case, you may mix the polycarbonate resin whose viscosity average molecular weight is out of said preferable range.

In addition, with viscosity average molecular weight [Mv], using methylene chloride as a solvent, the intrinsic viscosity [ロ ー] (unit dl / g) at a temperature of 20 ° C. is determined using a Ubbelohde viscometer, and Schnell's viscosity formula, ie, , = 1 = 1.23 × 10 ⁻⁴ Mv ^0.83 . In addition, the intrinsic viscosity [η] is a value calculated by measuring the specific viscosity [で_sp ] at each solution concentration [C] (g / dl) according to the following equation.

  The terminal hydroxyl group concentration of the polycarbonate resin is arbitrary and may be appropriately selected and determined, but is usually 1,000 ppm or less, preferably 800 ppm or less, more preferably 600 ppm or less. This can further improve the retention heat stability and color tone of the polycarbonate resin. The lower limit is usually 10 ppm or more, preferably 30 ppm or more, and more preferably 40 ppm or more, particularly for polycarbonate resins produced by the melt transesterification method. Thereby, the fall of molecular weight can be suppressed and the mechanical property of a resin composition can be improved more.

  In addition, the unit of terminal hydroxyl group concentration represents the mass of terminal hydroxyl group to ppm with respect to the mass of polycarbonate resin. The measurement method is the colorimetric determination by the titanium tetrachloride / acetic acid method (the method described in Macromol. Chem. 88 215 (1965)).

  Polycarbonate resin is not limited to an embodiment including polycarbonate resin alone (polycarbonate resin alone is not limited to one including only one kind of polycarbonate resin, for example, it is used in a sense including an embodiment including plural kinds of polycarbonate resins different in monomer composition and molecular weight from each other) And may be used in combination with alloys (mixtures) of polycarbonate resins and other thermoplastic resins. Furthermore, for example, in order to further enhance flame retardancy and impact resistance, polycarbonate resin is copolymerized with an oligomer or polymer having a siloxane structure; phosphorus atom for the purpose of further enhancing thermal oxidation stability and flame retardancy Copolymers with monomers, oligomers or polymers having the following; copolymers with monomers, oligomers or polymers having the dihydroxyanthraquinone structure for the purpose of improving the thermal oxidation stability; polystyrenes and the like to improve the optical properties Copolymer with an oligomer or polymer having an olefin structure; copolymer with a polyester resin oligomer or polymer for the purpose of improving chemical resistance; or even a copolymer based on a polycarbonate resin Good.

  The polycarbonate resin may contain a polycarbonate oligomer in order to improve the appearance and fluidity of the molded article. The viscosity average molecular weight [Mv] of this polycarbonate oligomer is usually 1,500 or more, preferably 2,000 or more, and usually 9,500 or less, preferably 9,000 or less. Furthermore, the content of the polycarbonate oligomer is preferably 30% by mass or less of the polycarbonate resin (including the polycarbonate oligomer).

Furthermore, the polycarbonate resin may be not only a virgin raw material but also a polycarbonate resin regenerated from a used product (so-called material recycled polycarbonate resin).
However, it is preferable that it is 80 mass% or less among polycarbonate resin, and it is more preferable that it is 50 mass% or less among regenerated polycarbonate resin. Since the recycled polycarbonate resin is highly likely to be degraded due to thermal degradation, aging degradation, etc., when such polycarbonate resin is used more than the above range, it is possible to lower the hue and mechanical properties. It is because there is sex.

[Polyalkylene glycol (B)]
The polycarbonate resin composition for optical parts of the present invention has a weight-average molecular weight (Mw) of 400 or less as measured by polystyrene conversion by gel permeation chromatography using tetrahydrofuran as a solvent and the amount of the component is less than 1.0% by mass. And the polyalkylene glycol (B) whose number average molecular weight (Mn) calculated | required from the terminal hydroxyl value is 700-2600 is contained.
By containing such a polyalkylene glycol (B), it is possible to obtain an optical component having a good color and extremely low gas generation and mold contamination at the time of molding. When the amount of the component having a weight average molecular weight (Mw) of 400 or less is 1.0% by mass or more, mold deposit during injection molding increases and clogging such as gas vent occurs. The amount of the component having a weight average molecular weight (Mw) of 400 or less is preferably less than 0.8% by mass, more preferably less than 0.6% by mass, and further preferably less than 0.5% by mass .

  The weight average molecular weight (Mw) of the polyalkylene glycol (B) is determined by gel permeation chromatography (GPC), using tetrahydrofuran as a solvent, and determined by conversion relative to a calibration curve with standard polystyrene. And the amount (% by mass) of the component having Mw of 400 or less is defined as a ratio calculated by dividing the area of the portion having Mw of 400 or less in the obtained GPC spectrum curve by the area of the entire spectrum curve. Be done. Specific details of the GPC measurement are as described in the examples.

  The polyalkylene glycol (B) in which the amount of components having a weight average molecular weight (Mw) of 400 or less is less than 1.0% by mass is removed by washing the components with Mw of 400 or less by washing with water or alcohol. Alternatively, it can be obtained by selectively extracting low molecular weight components by adding an aqueous solution containing sulfuric acid. Moreover, it is also possible by selecting and using it out of a commercial item.

The number average molecular weight (Mn) of the polyalkylene glycol (B) is 700 to 2,600 in number average molecular weight determined from the terminal hydroxyl value as described above, preferably 800 or more, more preferably 900 or more. Preferably, it is 2,200 or less, more preferably 2,000 or less, still more preferably 1,800 or less, particularly preferably 1,600 or less. If the upper limit of the above range is exceeded, the compatibility is lowered, which is not preferable. If the lower limit of the above range is not reached, gas is generated during molding, which is not preferable.
Here, the number average molecular weight (Mn) of the polyalkylene glycol (B) is measured according to JIS K1577, and is a number average molecular weight calculated based on the terminal hydroxyl value.

  As the polyalkylene glycol (B), various polyalkylene glycols can be used. For example, a branched polyalkylene glycol represented by the following general formula (1) or a straight chain type poly represented by the following general formula (2) Alkylene glycols are mentioned as being preferred. The branched polyalkylene glycol represented by the following general formula (1) or the linear polyalkylene glycol represented by the following general formula (2) may be a copolymer with another copolymer component. Although it is good, it is preferable that it is a homopolymer.

(Wherein R represents an alkyl group having 1 to 3 carbon atoms, and X and Y each independently represent a hydrogen atom, an aliphatic acyl group having 1 to 23 carbon atoms, an alkyl group having 1 to 23 carbon atoms, carbon It represents an aryl group of 6 to 22 or an aralkyl group having 7 to 23 carbon atoms, and m represents an integer of 10 to 400.)
The branched polyalkylene glycol represented by the above general formula (1) may be a homopolymer consisting of one kind of R or a copolymer consisting of different R.

(Wherein, X and Y each independently represent a hydrogen atom, an aliphatic acyl group having 2 to 23 carbon atoms, an alkyl group having 1 to 23 carbon atoms, an aryl group having 6 to 22 carbon atoms, or 7 to 23 carbon atoms P represents an integer of 2 to 6, and r represents an integer of 6 to 100.
The linear polyalkylene glycol represented by the above general formula (2) may be a homopolymer of one kind of p or a copolymer of different p.

  As the branched polyalkylene glycol, in the general formula (1), (2-methyl) ethylene glycol in which X and Y are a hydrogen atom and R is a methyl group, and (2-ethyl) ethylene glycol in which an ethyl group is used are preferable. .

  Examples of linear polyalkylene glycols include polyethylene glycols in which X and Y in the general formula (2) are hydrogen atoms and p is 2; polytrimethylene glycols in which p is 3; polytetramethylenes in which p is 4 Glycol, polypentamethylene glycol in which p is 5 and polyhexamethylene glycol in which p is 6 are preferably mentioned, and more preferably polytrimethylene glycol and polytetramethylene glycol.

  The polyalkylene glycol (B) is selected from a linear alkylene ether unit (P1) represented by the following general formula (3) and a unit represented by the following general formulas (4-1) to (4-4) A polyalkylene glycol copolymer having a branched alkylene ether unit (P2) is also mentioned as a preferable one.

(In the formula (3), p represents an integer of 2 to 6.)
As a linear alkylene ether unit represented by General formula (3), even if it is a single unit which consists of 1 type of p, several units which consist of different p may be mixed.

In formulas (4-1) to (4-4), R ^{1 to} R ¹⁰ each independently represent a hydrogen atom or an alkyl group having 1 to 3 carbon atoms, and each of formulas (4-1) to (4- In 4), at least one of R ^{1 to} R ¹⁰ is an alkyl group having 1 to 3 carbon atoms.)

  The branched alkylene ether unit represented by any one of the general formulas (4-1) to (4-4) is a branched alkylene ether unit represented by any one of the general formulas (4-1) to (4-4) Or a copolymer composed of branched alkylene ether units having a plurality of structures.

  When the linear alkylene ether unit (P1) represented by the above general formula (3) is described as a glycol, ethylene glycol whose p is 2; trimethylene glycol whose p is 3; Methylene glycol, pentamethylene glycol of p 5 and hexamethylene glycol of p 6 may be mentioned, and these may be mixed, preferably trimethylene glycol and tetramethylene glycol, with tetramethylene glycol being particularly preferred.

  Trimethylene glycol is industrially obtained by hydroformylation of ethylene oxide to obtain 3-hydroxypropionaldehyde, which is hydrogenated, or 3-hydroxypropionaldehyde obtained by hydration of acrolein is hydrogenated with Ni catalyst Manufactured in a manner. In recent years, it has also been carried out to produce trimethylene glycol by reducing glycerol, glucose, starch and the like to microorganisms by a bio method.

  When this is described as a glycol as a branched alkylene ether unit shown by said general formula (4-1), (2-methyl) ethylene glycol, (2-ethyl) ethylene glycol, (2, 2- dimethyl) ethylene glycol etc. These may be mixed, preferably (2-methyl) ethylene glycol, (2-ethyl) ethylene glycol.

  When this is described as a glycol as a branched alkylene ether unit shown by said general formula (4-2), (2-methyl) trimethylene glycol, (3-methyl) trimethylene glycol, (2-ethyl) trimethylene glycol , (3-ethyl) triethylene glycol, (2,2-dimethyl) trimethylene glycol, (2,2-methylethyl) trimethylene glycol, (2,2-diethyl) trimethylene glycol (ie neopentyl glycol) And (3,3-dimethyl) trimethylene glycol, (3,3-methylethyl) trimethylene glycol, (3,3-diethyl) trimethylene glycol and the like, and these may be mixed.

  When this is described as a glycol as a branched alkylene ether unit shown by said general formula (4-3), (3-methyl) tetramethylene glycol, (4-methyl) tetramethylene glycol, (3-ethyl) tetramethylene glycol , (4-ethyl) tetramethylene glycol, (3,3-dimethyl) tetramethylene glycol, (3,3-methylethyl) tetramethylene glycol, (3,3-diethyl) tetramethylene glycol, (4,4-dimethyl) And tetramethylene glycol, (4,4-methylethyl) tetramethylene glycol, (4,4-diethyl) tetramethylene glycol and the like, and these may be mixed, and (3-methyl) tetramethylene glycol is preferable.

  When this is described as a glycol as a branched alkylene ether unit shown by said general formula (4-4), (3-methyl) pentamethylene glycol, (4-methyl) pentamethylene glycol, (5-methyl) pentamethylene glycol , (3-ethyl) pentamethylene glycol, (4-ethyl) pentamethylene glycol, (5-ethyl) pentamethylene glycol, (3,3-dimethyl) pentamethylene glycol, (3,3-methylethyl) pentamethylene glycol , (3,3-diethyl) pentamethylene glycol, (4,4-dimethyl) pentamethylene glycol, (4,4-methylethyl) pentamethylene glycol, (4,4-diethyl) pentamethylene glycol, (5,5 -Dimethyl) pentamethylene glycol (5,5-methylethyl) pentamethylene glycol, (5,5-diethyl) such as pentamethylene glycol, and the like, it may also be these mixtures.

  As mentioned above, although the unit represented by General Formula (4-1)-(4-4) which comprises a branched alkylene ether unit was described for convenience as glycol as an example, not only these glycols, but these alkylene oxides Or polyether-forming derivatives thereof.

  When a preferable thing is mentioned as a polyalkylene glycol copolymer, the copolymer which consists of a unit represented by a tetramethylene ether unit and the said General formula (4-3) is preferable, and a tetramethylene ether unit and 3-methyl tetramethylene are especially preferable. Copolymers comprising ether units are more preferred. Further, a copolymer comprising a tetramethylene ether unit and a unit represented by the above general formula (4-1) is also preferable, and in particular, a copolymer comprising a tetramethylene ether unit and a 2-methyl ethylene ether unit, and a tetramethylene ether The copolymer which consists of a unit and 2-ethyl ethylene ether unit is more preferable. Furthermore, a copolymer comprising a tetramethylene ether unit and the above general formula (4-2) is also preferable, and a copolymer comprising a 2,2-dimethyltrimethylene ether unit, that is, a neopentyl glycol ether unit is also preferable.

  The polyalkylene glycol copolymer may be a random copolymer or a block copolymer.

Linear alkylene ether unit (P1) represented by the general formula (3) of polyalkylene glycol copolymer and branched alkylene ether unit (P2) represented by the general formulas (4-1) to (4-4) The copolymerization ratio of (P1) / (P2) is preferably 95/5 to 5/95, more preferably 93/7 to 40/60, still more preferably 90/10. It is -65/35, and it is more preferable that a linear alkylene ether unit (P1) is rich.
The mole fraction is measured using ¹ H-NMR measurement apparatus with deuterated chloroform as a solvent.

  Also, as polyalkylene glycol (B), even if one end or both ends are blocked with a fatty acid or alcohol, there is no influence on the performance expression, and fatty acid esterified or etherified can be used similarly, And X and / or Y in the general formulas (1) and (2) may be an aliphatic acyl group having 1 to 23 carbon atoms or an alkyl group.

  The esterified product or etherified product of the polyalkylene glycol does not necessarily have to be entirely esterified or etherified, and is preferably a partially esterified product or an etherified product.

As the fatty acid esterified product, any of linear or branched fatty acid esters can be used, and the fatty acid constituting the fatty acid ester may be a saturated fatty acid or an unsaturated fatty acid. Also, those in which a part of hydrogen atoms are substituted by a substituent such as a hydroxyl group can be used.
The fatty acid constituting the fatty acid ester is a monovalent or divalent fatty acid having 1 to 23 carbon atoms, for example, a monovalent saturated fatty acid, specifically, formic acid, acetic acid, propionic acid, butyric acid, valeric acid, caproic acid Enanthate, caprylic acid, caprylic acid, lauric acid, myristic acid, pentadecylic acid, palmitic acid, heptadecylic acid, stearic acid, nonadecanoic acid, arachidic acid, behenic acid, and monovalent unsaturated fatty acids, specifically, Unsaturated fatty acids such as oleic acid, elaidic acid, linoleic acid, linolenic acid, arachidonic acid, and divalent fatty acids having 10 or more carbon atoms, specifically, sebacic acid, undecanedioic acid, dodecanedioic acid, tetradecanedioic acid , Tapsia acid and decenoic acid, undecenoic acid and dodecenoic acid.
These fatty acids can be used alone or in combination of two or more. The fatty acids also include fatty acids having one or more hydroxyl groups in the molecule.

  Preferred specific examples of fatty acid esters of polyalkylene glycols are polypropylene glycol stearates in which R is a methyl group, and X and Y are aliphatic acyl groups having 18 carbon atoms in general formula (I-1), R is a methyl group And polypropylene glycol behenate in which X and Y each represent a C22 aliphatic acyl group. Preferred specific examples of fatty acid esters of polyalkylene glycols include polyalkylene glycol monopalmitate, polyalkylene glycol dipalmitate, polyalkylene glycol monostearate, polyalkylene glycol distearate, polyalkylene glycol (monopalmitin Examples include acid / monostearic acid) esters, polyalkylene glycol behenates and the like.

  The alkyl group constituting the alkyl ether of the polyalkylene glycol may be linear or branched, and has, for example, a carbon number such as methyl group, ethyl group, propyl group, butyl group, octyl group, lauryl group and stearyl group. Examples of such polyalkylene glycols include alkyl methyl ether of polyalkylene glycol, ethyl ether, butyl ether, lauryl ether and stearyl ether.

  As said polyalkylene glycol (B), the structure derived from polyols, such as a 1, 4- butanediol, glycerol, sorbitol, benzenediol, bisphenol A, a cyclohexanediol, spiro glycol, may be contained in a structure. These organic groups can be provided in the main chain by adding these polyols during the polymerization of polyalkylene glycols. Particularly preferred are glycerol, sorbitol, bisphenol A and the like.

  Examples of polyalkylene glycols containing an organic group in the structure include polyethylene glycol glyceryl ether, poly (2-methyl) ethylene glycol glyceryl ether, poly (2-ethyl) ethylene glycol glyceryl ether, polytetramethylene glycol glyceryl ether, Polyethylene glycol-poly (2-methyl) ethylene glycol glyceryl ether, polytetramethylene glycol-poly (2-methyl) ethylene glycol glyceryl ether, polytetramethylene glycol-poly (2-ethyl) polyethylene glycol glyceryl ether, polyethylene glycol sorbityl Ether, poly (2-methyl) ethylene glycol sorbityl ether, poly (2-ethyl) ethylene glycol sorbitic Ether, polytetramethylene glycol sorbityl ether, polyethylene glycol-poly (2-methyl) ethylene glycol sorbityl ether, polytetramethylene glycol-poly (2-methyl) ethylene glycol sorbityl ether, polytetramethylene glycol-poly (2 -Ethyl) ethylene glycol sorbityl ether, bisphenol A-bis (polyethylene glycol) ether, bisphenol A-bis (poly (2-methyl) ethylene glycol) ether, bisphenol A-bis (poly (2-ethyl) ethylene glycol) ether , Bisphenol A-bis (polytetramethylene glycol) ether, bisphenol A-bis (polyethylene glycol-poly (2-methyl) ethylene glycol) ether And bisphenol A-bis (polytetramethylene glycol-poly (2-methyl) ethylene glycol) ether, bisphenol A-bis (polytetramethylene glycol-poly (2-ethyl) polyethylene glycol) ether, etc. are mentioned as preferred. .

  The polyalkylene glycol (B) may be used alone or in combination of two or more.

  The content of the polyalkylene glycol (B) is 0.1 to 4 parts by mass with respect to 100 parts by mass of the polycarbonate resin (A). The preferred content is 0.15 parts by mass or more, more preferably 0.2 parts by mass or more, preferably 3.5 parts by mass or less, more preferably 3 parts by mass or less, still more preferably 2.5 parts by mass or less Particularly preferably, it is 2 parts by mass or less. When the content is less than 0.1 part by mass, the improvement of the hue and yellowing is not sufficient, and when it exceeds 4 parts by mass, the transmittance of the polycarbonate resin is reduced due to the clouding of the polycarbonate resin, and melt kneading by the extruder is performed. And breakage of strands frequently occur, making it difficult to make resin composition pellets.

[Phosphorus based stabilizer (C)]
The polycarbonate resin composition of the present invention contains a phosphorus-based stabilizer. By containing a phosphorus-based stabilizer, the hue of the polycarbonate resin composition of the present invention becomes good, and the heat discoloration resistance further improves.
Any known phosphorus-based stabilizer can be used. Specific examples thereof include phosphorus oxo acids such as phosphoric acid, phosphonic acid, phosphorous acid, phosphinic acid and polyphosphoric acid; acid pyrophosphate metal salts such as sodium acid pyrophosphate, potassium acid pyrophosphate and calcium acid pyrophosphate; phosphoric acid Examples thereof include phosphates of Group 1 or 2B metals such as potassium, sodium phosphate, cesium phosphate and zinc phosphate; phosphate compounds, phosphite compounds, phosphonite compounds and the like, with phosphite compounds being particularly preferable. By selecting the phosphite compound, a polycarbonate resin composition having higher color fastness and continuous productivity can be obtained.

Here, the phosphite compound is a trivalent phosphorus compound represented by the general formula: P (OR) ₃ and R represents a monovalent or divalent organic group.
As such a phosphite compound, for example, triphenyl phosphite, tris (monononylphenyl) phosphite, tris (monononyl / dinonyl phenyl) phosphite, tris (2,4-di-tert-butylphenyl) phosphite Phyto, monooctyl diphenyl phosphite, dioctyl monophenyl phosphite, monodecyl diphenyl phosphite, didecyl monophenyl phosphite, tridecyl phosphite, trilauryl phosphite, tristearyl phosphite, distearyl pentaerythritol diphosphite, Bis (2,4-di-tert-butyl-4-methylphenyl) pentaerythritol phosphite, bis (2,6-di-tert-butylphenyl) octyl phosphite, 2,2-methylene (4,6-di-tert-butylphenyl) octyl phosphite, tetrakis (2,4-di-tert-butylphenyl) -4,4'-biphenylene-diphosphite, 6- [3- (3-tert- Butyl-hydroxy-5-methylphenyl) propoxy] -2,4,8,10-tetra-tert-butyldibenzo [d, f] [1,3,2] -dioxaphosphepin and the like can be mentioned.

  Among such phosphite compounds, an aromatic phosphite compound represented by the following formula (1) or (2) is more preferable because the heat-resistant color-changing property of the polycarbonate resin composition of the present invention is effectively enhanced. .

[In Formula (1), R ¹ , R ² and R ³ may be the same or different, and represent an aryl group having 6 to 30 carbon atoms]. ]

[In Formula (2), R ⁴ and R ⁵ may be the same as or different from each other, and represent an aryl group having 6 to 30 carbon atoms. ]

  Among the phosphite compounds represented by the above formula (1), triphenyl phosphite, tris (monononylphenyl) phosphite, tris (2,4-di-tert-butylphenyl) phosphite and the like are preferable among them, among which More preferred is tris (2,4-di-tert-butylphenyl) phosphite. As such an organic phosphite compound, specifically, for example, "ADEKA Stub 1178" manufactured by ADEKA, "Sumilyzer TNP" manufactured by Sumitomo Chemical, "JP-351" manufactured by Johoku Kagaku Kogyo, "ADEKA Stub" manufactured by ADEKA 2112 "," IRGAFOS 168 "manufactured by BASF," JP-650 "manufactured by Johoku Chemical Industry, and the like.

  Among the phosphite compounds represented by the above formula (2), bis (2,4-di-tert-butyl-4-methylphenyl) pentaerythritol diphosphite, bis (2,6-di-tert-butyl), among others Particularly preferred are those having a pentaerythritol diphosphite structure such as -4-methylphenyl) pentaerythritol diphosphite and bis (2,4-dicumylphenyl) pentaerythritol diphosphite. Specific examples of such organic phosphite compounds preferably include “Adekastab PEP-24G”, “Adekastab PEP-36” manufactured by Adeka, and “Doverphos S-9228” manufactured by Doverchemical.

Among the phosphite compounds, the aromatic phosphite compound represented by the above formula (2) is more preferable because the hue is more excellent.
In addition, 1 type may contain phosphorus stabilizer and 2 types or more may be contained by arbitrary combinations and ratios.

  The content of the phosphorus-based stabilizer (C) is 0.005 to 0.5 parts by mass, preferably 0.007 parts by mass or more, and more preferably 0.2 parts by mass with respect to 100 parts by mass of the polycarbonate resin (A). 008 parts by mass or more, particularly preferably 0.01 parts by mass or more, preferably 0.4 parts by mass or less, more preferably 0.3 parts by mass or less, still more preferably 0.2 parts by mass or less, particularly 0 .1 part by mass or less. When the content of the phosphorus-based stabilizer (C) is less than 0.005 parts by mass in the above range, the hue and the heat discoloration resistance become insufficient, and the content of the phosphorus-based stabilizer (C) is 0.5 parts by mass Not only does the heat discoloration resistance deteriorate, but also the wet heat stability decreases.

[Epoxy Compound (D)]
It is also preferable that the resin composition of the present invention contains an epoxy compound (D). By containing the epoxy compound (D) together with the polyalkylene glycol (B), the heat discoloration resistance can be further improved.

  As the epoxy compound (D), a compound having one or more epoxy groups in one molecule is used. Specifically, phenyl glycidyl ether, allyl glycidyl ether, t-butylphenyl glycidyl ether, 3,4-epoxycyclohexylmethyl-3 ', 4'-epoxycyclohexyl carboxylate, 3,4-epoxy-6-methylcyclohexylmethyl -3 ', 4'-Epoxy-6'-methylcyclohexylcarboxylate, 2,3-epoxycyclohexylmethyl-3', 4'-epoxycyclohexylcarboxylate, 4- (3,4-epoxy-5-methylcyclohexyl) Butyl-3 ', 4'-epoxycyclohexylcarboxylate, 3,4-epoxycyclohexylethylene oxide, cyclohexylmethyl 3,4-epoxycyclohexylcarboxylate, 3,4-epoxy-6-methylcyclohexyl Methyl-6'-Methylcylohexyl Carboxylate, Bisphenol-A diglycidyl ether, Tetrabromobisphenol-A glycidyl ether, Diglycidyl ester of phthalic acid, Diglycidyl ester of hexahydrophthalic acid, Bis-epoxydicyclopentadienyl Ether, bis-epoxy ethylene glycol, bis-epoxy cyclohexyl adipate, butadiene diepoxide, tetraphenyl ethylene epoxide, octyl epoxy tartrate, epoxidized polybutadiene, 3,4-dimethyl-1,2-epoxy cyclohexane, 3,5- dimethyl -1,2-epoxycyclohexane, 3-methyl-5-t-butyl-1,2-epoxycyclohexane, octadecyl-2,2-dimethyl-3,4-epoxycyclohexene Carboxylate, N-butyl-2,2-dimethyl-3,4-epoxycyclohexyl carboxylate, cyclohexyl-2-methyl-3,4-epoxycyclohexyl carboxylate, N-butyl-2-isopropyl-3,4- Epoxy-5-methylcyclohexylcarboxylate, octadecyl-3,4-epoxycyclohexylcarboxylate, 2-ethylhexyl-3 ', 4'-epoxycyclohexylcarboxylate, 4,6-dimethyl-2,3-epoxycyclohexyl-3' 4,4'-epoxycyclohexylcarboxylate, 4,5-epoxytetrahydrophthalic anhydride, 3-t-butyl-4,5-epoxytetrahydrophthalic anhydride, diethyl 4,5-epoxy-cis-1,2-cyclohexyldiethyl Carboxy And di-n-butyl-3-t-butyl-4,5-epoxy-cis-1,2-cyclohexyldicarboxylate, epoxidized soybean oil, epoxidized linseed oil and the like can be preferably exemplified.

  Among these, alicyclic epoxy compounds are preferably used, and in particular, 3,4-epoxycyclohexylmethyl-3 ', 4'-epoxycyclohexyl carboxylate is preferable.

  In addition, polyalkylene glycol derivatives having an epoxy group at one or both ends can also be preferably used. In particular, polyalkylene glycols having epoxy groups at both ends are preferred.

  Examples of polyalkylene glycol derivatives containing an epoxy group in the structure include polyethylene glycol diglycidyl ether, poly (2-methyl) ethylene glycol diglycidyl ether, poly (2-ethyl) ethylene glycol diglycidyl ether, polytetramethylene Glycol diglycidyl ether, polyethylene glycol-poly (2-methyl) ethylene glycol diglycidyl ether, polytetramethylene glycol-poly (2-methyl) ethylene glycol diglycidyl ether, polytetramethylene glycol-poly (2-ethyl) ethylene glycol Polyalkylene glycol derivatives such as diglycidyl ether are mentioned as preferred.

  The epoxy compounds may be used alone or in combination of two or more.

  The preferable content of the epoxy compound (D) is 0.0005 to 0.2 parts by mass, more preferably 0.001 parts by mass or more, still more preferably 0. 05 to 0.2 parts by mass with respect to 100 parts by mass of the polycarbonate resin (A). The content is 003 parts by mass or more, particularly preferably 0.005 parts by mass or more, more preferably 0.15 parts by mass or less, still more preferably 0.1 parts by mass or less, and particularly preferably 0.05 parts by mass or less. When the content of the epoxy compound (D) is less than 0.0005 parts by mass, the hue and the heat discoloration resistance tend to be insufficient, and when the content exceeds 0.2 parts by mass, the heat discoloration resistance is apt to deteriorate. The hue and moist heat stability are also likely to decrease.

[Additives, etc.]
The polycarbonate resin composition of the present invention may contain other additives than those described above, for example, antioxidants, mold release agents, UV absorbers, fluorescent brighteners, pigments, dyes, polymers other than polycarbonate resins, Additives such as flame retardants, impact modifiers, antistatic agents, plasticizers, compatibilizers can be included. These additives may be used alone or in combination of two or more.
However, the content in the case of containing other polymers other than polycarbonate resin is preferably 20 parts by mass or less, more preferably 10 parts by mass or less, further preferably 5 parts by mass with respect to 100 parts by mass of polycarbonate resin (A). It is preferable to set it as the mass part or less, especially 3 mass parts or less.

[Method of producing polycarbonate resin composition]
There is no restriction on the method for producing the polycarbonate resin composition of the present invention, and any known method for producing the polycarbonate resin composition can be widely adopted, and the polycarbonate resin (A), the polyalkylene glycol (B) and the phosphorus stabilizer (C) In addition, after mixing in advance other components to be blended if necessary using various mixers such as tumblers and Henschel mixers, for example, Banbury mixers, rolls, brabenders, single-screw kneading extruders, twin-screw kneading extruders And melt kneading using a mixer such as a kneader. The melt-kneading temperature is not particularly limited, but is usually in the range of 240 to 320 ° C.

[Optical parts]
The polycarbonate resin composition for optical parts of the present invention can manufacture optical parts by molding pellets obtained by pelletizing the polycarbonate resin composition described above by various molding methods. Alternatively, the resin melt-kneaded by an extruder may be directly molded into an optical component without passing through pellets.

The polycarbonate resin composition of the present invention is excellent in fluidity and color, and has very little gas generation during molding and mold contamination, so it is an optical component, particularly a thin-walled optical component that is prone to mold contamination by injection molding. It is particularly suitably used to form Particularly in the case of thin-walled molded articles, it is preferable to mold the resin temperature at a resin temperature higher than 260 to 300 ° C., which is a temperature generally applied to the injection molding of polycarbonate resin. Resin temperatures of ̃400 ° C. are preferred. The resin temperature is more preferably 310 ° C. or more, further preferably 315 ° C. or more, particularly preferably 320 ° C. or more, and more preferably 390 ° C. or less. When a conventional polycarbonate resin composition is used, there is also a problem that when the resin temperature during molding is increased to mold a thin-walled molded product, yellowing of the molded product tends to occur, but the resin of the present invention The use of the composition makes it possible to produce molded articles having good hue, in particular thin-walled optical components, even in the above temperature range.
In addition, with resin temperature, when it is difficult to measure directly, it is grasped as barrel preset temperature.

  Here, the thin-walled molded article refers to a molded article having a plate-like portion having a thickness of usually 1 mm or less, preferably 0.8 mm or less, more preferably 0.6 mm or less. Here, the plate-like portion may be a flat plate or a curved plate, or may be a flat surface or may have irregularities or the like on the surface, and the cross section has an inclined surface. Or it may be a bowl-shaped cross section or the like.

Examples of optical components include parts of devices and appliances that directly or indirectly use light sources such as LEDs, organic EL, incandescent lamps, fluorescent lamps, and cathode tubes, and light guide plates and members for surface light emitters are typical. It is illustrated as a thing.
The light guide plate is for guiding the light of a light source such as an LED in a liquid crystal backlight unit, various display devices, and lighting devices, and the light introduced from the side surface or the back surface is usually provided on the front surface Diffuse by the asperity, and give out uniform light. The shape is usually flat and may or may not have asperities on the surface.
The formation of the light guide plate is usually performed preferably by an injection molding method, an ultra-high speed injection molding method, an injection compression molding method, a melt extrusion molding method (for example, a T-die molding method) or the like.
A light guide plate molded using the resin composition of the present invention has no clouding and no decrease in transmittance, has a good hue, and has few molding defects due to mold contamination.

  The light guide plate using the polycarbonate resin composition of the present invention can be suitably used in the field of liquid crystal backlight units, various display devices, and lighting devices. Examples of such devices include mobile phones, mobile notebooks, netbooks, slate PCs, tablet PCs, smartphones, various types of portable terminals such as tablet terminals, cameras, watches, notebook computers, various displays, lighting devices, etc. Be

  Moreover, the shape as an optical component may be a film or a sheet, and as a specific example thereof, for example, a light guide film etc. may be mentioned.

  Further, as an optical component, a light guide or a lens or the like for guiding light from a light source such as an LED is suitable for a vehicle headlamp (head lamp) such as an automobile or a motorcycle, a rear lamp, a fog lamp, etc. It can also be used suitably.

  The light guide plate using the polycarbonate resin composition of the present invention can be suitably used in the field of liquid crystal backlight units, various display devices, and lighting devices. Examples of such devices include mobile phones, mobile notebooks, netbooks, slate PCs, tablet PCs, smartphones, various types of portable terminals such as tablet terminals, cameras, watches, notebook computers, various displays, lighting devices, etc. Be

Hereinafter, the present invention will be more specifically described with reference to examples. However, the present invention is not construed as being limited to the following examples.
Raw materials and evaluation methods used in the following examples and comparative examples are as follows. In addition, the measuring method of the viscosity average molecular weight of polycarbonate resin (A) is as having mentioned above.

The measurement of the weight average molecular weight (Mw) of polyalkylene glycol by gel permeation chromatography was specifically performed as follows.
In the gel permeation chromatography apparatus, HLC-8320 (manufactured by Tosoh Corp.) was used, and TSKgel Multipore Hxl-M (7.8 mm ID × 30 cmL × 2, manufactured by Tosoh Corp.) was used as a column. The column temperature was 40.degree. The detector used was an HLC-8320 RI detector. Tetrahydrofuran was used as an eluent, and a calibration curve was prepared using standard polystyrene (manufactured by Tosoh Corporation).
The proportion (% by mass) of the component having a Mw of 400 or less was calculated by dividing the area of the portion having a Mw of 400 or less in the GPC spectrum curve obtained above by the area of the entire spectrum curve.

In addition, the water washing process goods of the said polyalkylene glycol (B1) and (B3) were obtained by the following water washing processes.
That is, 100 g of the raw material polyalkylene glycol described above is added to 500 ml of pure water having a temperature of 40 to 50 ° C. and stirred for 5 minutes, and then the stirring is stopped and left to stand to separate the polyalkylene glycol layer and the aqueous layer. The alkylene glycol layer was separated. This operation was repeated twice, and the obtained polyalkylene glycol was heated at 120 ° C. for 10 hours to remove water, to obtain poly (alkylene glycol) (B1) and (B3).

(Examples 1 to 10, Comparative Examples 1 to 3)
[Production of Resin Composition Pellets]
The components described above are compounded in proportions (parts by mass) described in Table 2 below, mixed with a tumbler for 20 minutes, and then a vented single-screw extruder with a screw diameter of 40 mm ("VS-" manufactured by Tanabe Plastic Machinery Co., Ltd. According to 40 "), the cylinder temperature was melt-kneaded at 240 ° C, and pellets were obtained by strand cutting.

[Measurement of hue (YI)]
The obtained pellets are dried at 120 ° C. for 5 to 7 hours with a hot air circulating drier, and then the resin temperature is 340 ° C. and the mold temperature is 80 ° C. by an injection molding machine (“EC100SX-2A” manufactured by Toshiba Machine Co., Ltd.) A long optical path molded product (300 mm × 7 mm × 4 mm) was molded.
For this long-path molded product, YI (degree of yellowing) was measured at a light path length of 300 mm. For measurement, a long path spectral transmission colorimeter (“ASA 1” manufactured by Nippon Denshoku Kogyo Co., Ltd., C light source, 2 ° visual field) was used.

[Mold pollution evaluation (mold adhesion)]
Contamination evaluation in injection molding (mold dirt)
The pellets obtained above are dried at 120 ° C. for 5 hours, and then using an injection molding machine (“SE8M” manufactured by Sumitomo Heavy Industries, Ltd.), a cylinder as shown in FIG. 200 shot injection molding was performed under the conditions of temperature of 340 ° C., molding cycle of 10 seconds, and mold temperature of 40 ° C., and the condition of the stain due to white deposits generated on the metal mirror surface on the mold fixing side after completion Evaluation was judged visually by the following criteria compared with 1.
A: The mold deposit is extremely less than the state after 200 shot molding of Comparative Example 1, and the mold contamination resistance is extremely good.
B: The mold deposit is less than the state after 200 shot molding of Comparative Example 1, but some mold contamination resistance is observed.
C: The mold deposit is at the same level as the state after 200 shot molding in Comparative Example 1.
D: The mold deposit is more than the state after 200 shot molding of Comparative Example 1, and the mold contamination is remarkably observed.

The drop mold shown in FIG. 1 is a mold designed such that the resin composition is introduced from the gate G and the generated gas is easily accumulated in the tip P portion. The gate G has a width of 1 mm and a thickness of 1 mm. In FIG. 1, the width h1 is 14.5 mm, the length h2 is 7 mm, the length h3 is 27 mm, and the thickness of the formed portion is 3 mm.
The above evaluation results are shown in Table 2 below.

  The polycarbonate resin composition of the present invention has a good color and has very little gas generation and mold contamination during molding, so it can be used extremely suitably for optical parts.

Claims (5)

0.1 to 4 parts by mass of polyalkylene glycol (B) and 0.005 to 0.5 parts by mass of phosphorus stabilizer (C) with respect to 100 parts by mass of polycarbonate resin (A),
In the polyalkylene glycol (B), the amount of a component having a molecular weight of 400 or less is less than 1.0% by mass, which is measured by the following method (i) in terms of polystyrene by gel permeation chromatography using tetrahydrofuran as a solvent The polycarbonate resin composition for optical parts, wherein the number average molecular weight (Mn) determined from the terminal hydroxyl value by (ii) is 700 to 2600.
Method (i): The proportion (mass%) of the component having a molecular weight of 400 or less is calculated by dividing the area of the portion having a molecular weight of 400 or less in the obtained GPC spectrum curve by the area of the entire spectrum curve.
Method (ii): Mn is measured in accordance with JIS K1577 and calculated based on the terminal hydroxyl value .   The polycarbonate resin composition for optical parts according to claim 1, wherein the polyalkylene glycol (B) has a tetramethylene ether unit.   The polycarbonate resin composition for optical parts according to claim 2, wherein a molar ratio of tetramethylene ether units of the polyalkylene glycol (B) is 50 mol% or more.   The polycarbonate resin composition for optical parts according to any one of claims 1 to 3, further comprising 0.0005 to 0.2 parts by mass of an epoxy compound (D) with respect to 100 parts by mass of the polycarbonate resin (A).   The optical component which shape | molded the polycarbonate resin composition in any one of Claims 1-4.