JP2018178075A5 - - Google Patents

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JP2018178075A5
JP2018178075A5 JP2018016249A JP2018016249A JP2018178075A5 JP 2018178075 A5 JP2018178075 A5 JP 2018178075A5 JP 2018016249 A JP2018016249 A JP 2018016249A JP 2018016249 A JP2018016249 A JP 2018016249A JP 2018178075 A5 JP2018178075 A5 JP 2018178075A5
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Japan
Prior art keywords
polycarbonate resin
mass
resin composition
parts
molecular weight
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JP2018016249A
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Japanese (ja)
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JP6522818B2 (en
JP2018178075A (en
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Priority to CN201880024889.3A priority Critical patent/CN110546204B/en
Priority to KR1020197030465A priority patent/KR20190132421A/en
Priority to KR1020227028057A priority patent/KR102642651B1/en
Priority to PCT/JP2018/005648 priority patent/WO2018193702A1/en
Publication of JP2018178075A publication Critical patent/JP2018178075A/en
Publication of JP2018178075A5 publication Critical patent/JP2018178075A5/ja
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Publication of JP6522818B2 publication Critical patent/JP6522818B2/en
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Claims (5)

ポリカーボネート樹脂(A)100質量部に対し、ポリアルキレングリコール(B)を0.1〜4質量部、リン系安定剤(C)を0.005〜0.5質量部含有し、
ポリアルキレングリコール(B)は、テトラヒドロフランを溶媒としゲル浸透クロマトグラフィーによるポリスチレン換算で下記方法(i)により測定される分子量が400以下の成分の量が1.0質量%未満であり、かつ下記方法(ii)により末端水酸基価から求められる数平均分子量(Mn)が700〜2600であることを特徴とする光学部品用ポリカーボネート樹脂組成物。
方法(i):分子量が400以下の成分の割合(質量%)は、得られたGPCスペクトル曲線中の分子量が400以下の部分の面積を、スペクトル曲線全体の面積で除することで算出する。
方法(ii):Mnは、JIS K1577に準拠して測定され、末端水酸基価に基づいて算出する。
0.1-100 parts by mass of polyalkylene glycol (B) and 0.005-0.5 parts by mass of phosphorus stabilizer (C) with respect to 100 parts by mass of polycarbonate resin (A),
In the polyalkylene glycol (B), the amount of a component having a molecular weight of 400 or less measured by the following method (i) in terms of polystyrene by gel permeation chromatography using tetrahydrofuran as a solvent is less than 1.0% by mass, and the following method The number average molecular weight (Mn) calculated | required from a terminal hydroxyl value by (ii) is 700-2600, The polycarbonate resin composition for optical components characterized by the above-mentioned.
Method (i): The ratio (mass%) of the component having a molecular weight of 400 or less is calculated by dividing the area of the portion having a molecular weight of 400 or less in the obtained GPC spectrum curve by the area of the entire spectrum curve.
Method (ii): Mn is measured according to JIS K1577 and is calculated based on the terminal hydroxyl value. "
ポリアルキレングリコール(B)がテトラメチレンエーテル単位を有することを特徴とする請求項1に記載の光学部品用ポリカーボネート樹脂組成物。   The polycarbonate resin composition for optical parts according to claim 1, wherein the polyalkylene glycol (B) has a tetramethylene ether unit. ポリアルキレングリコール(B)のテトラメチレンエーテル単位のモル比率が50モル%以上であることを特徴とする請求項2に記載の光学部品用ポリカーボネート樹脂組成物。   The polycarbonate resin composition for an optical component according to claim 2, wherein the molar ratio of the tetramethylene ether units of the polyalkylene glycol (B) is 50 mol% or more. さらに、エポキシ化合物(D)を、ポリカーボネート樹脂(A)100質量部に対し、0.0005〜0.2質量部含有する請求項1〜3のいずれかに記載の光学部品用ポリカーボネート樹脂組成物。   Furthermore, the polycarbonate resin composition for optical components in any one of Claims 1-3 which contains 0.0005-0.2 mass part of epoxy compounds (D) with respect to 100 mass parts of polycarbonate resin (A). 請求項1〜4のいずれかに記載のポリカーボネート樹脂組成物を成形した光学部品。   The optical component which shape | molded the polycarbonate resin composition in any one of Claims 1-4.
JP2018016249A 2017-04-18 2018-02-01 Polycarbonate resin composition for optical parts and optical parts Active JP6522818B2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CN201880024889.3A CN110546204B (en) 2017-04-18 2018-02-19 Polycarbonate resin composition for optical member and optical member
KR1020197030465A KR20190132421A (en) 2017-04-18 2018-02-19 Polycarbonate Resin Compositions and Optical Components for Optical Components
KR1020227028057A KR102642651B1 (en) 2017-04-18 2018-02-19 Polycarbonate resin composition for optical component and optical component
PCT/JP2018/005648 WO2018193702A1 (en) 2017-04-18 2018-02-19 Polycarbonate resin composition for optical component and optical component

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2017082241 2017-04-18
JP2017082241 2017-04-18

Publications (3)

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JP2018178075A JP2018178075A (en) 2018-11-15
JP2018178075A5 true JP2018178075A5 (en) 2019-01-10
JP6522818B2 JP6522818B2 (en) 2019-05-29

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JP (1) JP6522818B2 (en)
KR (1) KR20190132421A (en)
CN (1) CN110546204B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114466896B (en) * 2019-09-25 2023-05-30 三菱工程塑料株式会社 Polycarbonate resin composition
JP2023528932A (en) * 2020-10-23 2023-07-06 エルジー・ケム・リミテッド Polycarbonate composition and molded article thereof

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5699188A (en) 1980-01-14 1981-08-10 Hitachi Ltd Step for man conveyor
CA1338226C (en) 1987-06-26 1996-04-02 Charles E. Lundy Gamma radiation resistant polycarbonate compositions
JPH09227785A (en) 1995-12-20 1997-09-02 Asahi Chem Ind Co Ltd Resin composition and formed material therefrom
JP4104707B2 (en) 1997-11-27 2008-06-18 出光興産株式会社 Polycarbonate resin composition and light guide plate
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JP4156163B2 (en) 2000-01-31 2008-09-24 出光興産株式会社 Light guide plate and manufacturing method thereof
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WO2015011994A1 (en) * 2013-07-26 2015-01-29 三菱エンジニアリングプラスチックス株式会社 Polycarbonate resin composition for thin optical component, and thin optical component
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