JP6516753B2 - 難燃性ポリエステル - Google Patents
難燃性ポリエステル Download PDFInfo
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- JP6516753B2 JP6516753B2 JP2016541859A JP2016541859A JP6516753B2 JP 6516753 B2 JP6516753 B2 JP 6516753B2 JP 2016541859 A JP2016541859 A JP 2016541859A JP 2016541859 A JP2016541859 A JP 2016541859A JP 6516753 B2 JP6516753 B2 JP 6516753B2
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- thermoplastic molding
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- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 150000004668 long chain fatty acids Chemical class 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 239000001095 magnesium carbonate Substances 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000005226 mechanical processes and functions Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000012170 montan wax Substances 0.000 description 1
- 238000010137 moulding (plastic) Methods 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
- 125000004123 n-propyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- HYBLFDUGSBOMPI-UHFFFAOYSA-N octa-1,4-diene Chemical compound CCCC=CCC=C HYBLFDUGSBOMPI-UHFFFAOYSA-N 0.000 description 1
- 230000005693 optoelectronics Effects 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- QYZLKGVUSQXAMU-UHFFFAOYSA-N penta-1,4-diene Chemical compound C=CCC=C QYZLKGVUSQXAMU-UHFFFAOYSA-N 0.000 description 1
- 150000002989 phenols Chemical class 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229940094537 polyester-10 Drugs 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- PNXMTCDJUBJHQJ-UHFFFAOYSA-N propyl prop-2-enoate Chemical compound CCCOC(=O)C=C PNXMTCDJUBJHQJ-UHFFFAOYSA-N 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229960001755 resorcinol Drugs 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 150000003873 salicylate salts Chemical class 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 235000014214 soft drink Nutrition 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- 229910052717 sulfur Chemical group 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 1
- 150000003509 tertiary alcohols Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 238000012719 thermal polymerization Methods 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- 239000006163 transport media Substances 0.000 description 1
- 238000009966 trimming Methods 0.000 description 1
- 238000000214 vapour pressure osmometry Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
- 239000010456 wollastonite Substances 0.000 description 1
- 229910052882 wollastonite Inorganic materials 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K3/2279—Oxides; Hydroxides of metals of antimony
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/02—Halogenated hydrocarbons
- C08K5/03—Halogenated hydrocarbons aromatic, e.g. C6H5-CH2-Cl
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
- C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
- C08L33/16—Homopolymers or copolymers of esters containing halogen atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2367/00—Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Derivatives of such polymers
- C08J2367/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0875—Antimony
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/62—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyesters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Description
B) 式
xは1〜3であり、
mは1〜9であり、
nは2〜3であり、
Mは、アルカリ土類金属、Ni、Ce、Fe、In、Ga、Al、Pb、Y、Zn、Hgを表す]のジカルボン酸塩0.5〜30質量%
C) 次の
C1) B)とは異なるハロゲン含有の難燃剤、
C2) 酸化アンチモン
からなる難燃剤の組み合わせ1〜30質量%
D) 他の添加剤0〜50質量%
を有し、ここで、成分A)〜D)の質量パーセントの合計は、100%となる、熱可塑性成形材料。
特に、カルボキシル末端基含有量が、ポリエステル1kg当たり100mvalまで、好ましくはポリエステル1kg当たり50mvalまで、特にポリエステル1kg当たり40mvalまでであるポリエステルが好ましい。この種のポリエステルは、例えばDE−A 44 01 055の方法により製造することができる。このカルボキシル末端基含有量は、通常では滴定法(例えば電位差法)により決定される。
1) いわゆる産業廃棄物リサイクル物(Post industrial Rezyklat):これは重縮合の際又は加工の際の製造くず、例えば射出成形加工時のスプール、射出成形加工又は押出加工時の始動くず、もしくは押し出されたプレート又はシートのトリミングくずである。
ジヒドロキシジフェニル、
ジ−(ヒドロキシフェニル)アルカン、
ジ−(ヒドロキシフェニル)シクロアルカン、
ジ−(ヒドロキシフェニル)スルフィド、
ジ−(ヒドロキシフェニル)エーテル、
ジ−(ヒドロキシフェニル)ケトン、
ジ−(ヒドロキシフェニル)スルホキシド、
α,α’−ジ−(ヒドロキシフェニル)−ジアルキルベンゼン、
ジ−(ヒドロキシフェニル)スルホン、ジ−(ヒドロキシベンゾイル)ベンゼン
レゾルシン及びヒドロキノン、並びにこれらの環アルキル化又は環ハロゲン化誘導体が挙げられる。
4,4’−ジヒドロキシジフェニル、
2,4−ジ−(4’−ヒドロキシフェニル)−2−メチルブタン、
α,α’−ジ−(4−ヒドロキシフェニル)−p−ジイソプロピルベンゼン、
2,2−ジ−(3’−メチル−4’−ヒドロキシフェニル)プロパン及び
2,2−ジ−(3’−クロロ−4’−ヒドロキシフェニル)プロパン、
並びに特に
2,2−ジ−(4’−ヒドロキシフェニル)プロパン、
2,2−ジ−(3’,5−ジクロロジヒドロキシフェニル)プロパン、
1,1−ジ−(4’−ヒドロキシフェニル)シクロヘキサン、
3,4’−ジヒドロキシベンゾフェノン、
4,4’−ジヒドロキシジフェニルスルホン及び
2,2−ジ(3’,5’−ジメチル−4’−ヒドロキシフェニル)プロパン
又はこれらの混合物が好ましい。
この式の好ましいジフェノールは、例えば、ヒドロキノン、レゾルシン、4,4’−ジヒドロキシジフェニル、2,2−ビス−(4−ヒドロキシフェニル)−プロパン、2,4−ビス−(4−ヒドロキシフェニル)−2−メチルブタン、1,1−ビス−(4−ヒドロキシフェニル)−シクロヘキサンである。特に、2,2−ビス−(4−ヒドロキシフェニル)−プロパン及び1,1−ビス−(4−ヒドロキシフェニル)−シクロヘキサン、並びに1,1−ビス−(4−ヒドロキシフェニル)−3,3,5−トリメチルシクロヘキサンが好ましい。
R1〜R4は、互いに無関係に、ハロゲン又は水素を表し、ただし、基R1〜R4の少なくとも1つはハロゲンを表し、
Xは、1〜3、好ましくは1、2であり、
mは、1〜9、好ましくは1〜3、6、9、特に1〜3であり、
nは、2〜3であり、
Mは、アルカリ土類金属、Ni、Ce、Fe、In、Ga、Al、Pb、Y、Zn、Hgである]のジカルボン酸塩を、A)〜D)を基準として、0.5〜30質量%、好ましくは1〜25質量%、特に5〜25質量%含む。
C1) B)とは異なる、ハロゲン含有の難燃剤20〜99質量%、好ましくは50〜85質量%
C2) 酸化アンチモン1〜80質量%、好ましくは15〜50質量%
の難燃剤組み合わせを、1〜30質量%、好ましくは2〜25質量%、特に5〜20質量%含む。
エチレン50〜98質量%、特に55〜95質量%、
グリシジルアクリラート、及び/又はグリシジルメタクリラート、(メタ)アクリル酸及び/又は無水マレイン酸0.1〜40質量%、特に0.3〜20質量%、及び
n−ブチルアクリラート及び/又は2−エチルヘキシルアクリラート1〜45質量%、特に10〜40質量%からなる共重合体が好ましい。
R10は、水素又はC1〜C4−アルキル基であり、
R11は、水素、C1〜C8−アルキル基又はアリール基、特にフェニル基であり、
R12は、水素、C1〜C10−アルキル基、C6〜C12−アリール基又は−OR13であり、
R13は、C1〜C8−アルキル基又はC6〜C12−アリール基であり、これらの基は場合によりO含有基又はN含有基で置換されていてもよく、
Xは、化学結合、C1〜C10−アルキレン基又はC6〜C12−アリール基、又は
Yは、O−Z又はNH−Zであり、
Zは、C1〜C10−アルキレン基又はC6〜C12−アリーレン基である。
(X−(CH2)n)k−Si−(O−CmH2m+1)4−k
のシラン化合物であり、
ここでは、置換基は次の意味を有する:
Xは、NH2−、
nは2〜10、好ましくは3〜4の整数であり、
mは1〜5、好ましくは1〜2の整数であり、
kは1〜3の整数、好ましくは1である。
好ましいシラン化合物は、アミノプロピルトリメトキシシラン、アミノブチルトリメトキシシラン、アミノプロピルトリエトキシシラン、アミノブチルトリエトキシシラン及び置換基Xとしてグリシジル基を有する相応するシランである。
成分A:
130ml/gの粘度数VZ及び34mval/kgのカルボキシ末端基含有率を有するポリブチレンテレフタラート(BASF SE社のUltradur(登録商標)B 4500)(VZは、DIN53728/ISOにより25℃でフェノール/o−ジクロロベンゼンの1:1混合物からなる0.5質量%の溶液中で測定)。
テトラブロモフタルアルミナート(CAS:13654−74−5)
[Al2(TBrPA)3]又は2/3 Al・C8H2Br4O4
成分B/2:
テトラブロモフタル酸(「TBrPA」)の亜鉛塩(CAS:13654−76−7)
[ZnC8H2Br4O4]
成分B/3:
TBrPAのカルシウム塩(CAS:13899−13−3)
[CaC8H2Br4O4]
成分B/4:
TBrPAの鉄塩(CAS:13810−83−8)
2/3Fe・C8Br4O4H2又は[Fe2(TBrPA)3]
平均太さ10μmのポリエステル用の標準チョップドガラス繊維。
配合による相応するプラスチック成形材料を製造した。このために、個々の成分を押出機中で約250〜270℃のフラットな温度プロフィールで混合し、ストランドとして搬出し、顆粒化できるまで冷却し、顆粒化した。試験体を、Arburg 420C型の射出成形機で、約260℃の材料温度及び約80℃の金型温度で射出成形した。
炭化残量(TGA)を、TA Instrument TGA Q5000で測定した。秤量は、それぞれ4.5〜5mgであった。窒素雰囲気下で10℃/minで測定した。パージ率は65ml/minであった。残量(炭化残量)は600℃で決定した。
Claims (11)
- A) 熱可塑性ポリエステル 35〜80質量%
B) 式:
xは、1〜3であり、
mは、1〜9であり、
nは、2〜3であり、
Mは、アルカリ土類金属、Ni、Ce、Fe、In、Ga、Al、Pb、Y、Zn又はHgを表す]のジカルボン酸塩 5〜25質量%
C) 次の
C1) B)とは異なる、臭素化された化合物からなる群から選択される難燃剤 20〜99質量%、及び
C2) 酸化アンチモン 1〜80質量%
からなる難燃剤の組み合わせ 5〜20質量%、並びに
D) 他の添加剤 0〜50質量%
を含み、
成分C1)は、式:
ここで、成分A)〜D)の質量パーセントの合計は100%となる、熱可塑性成形材料。 - 成分A)は、2〜6個の炭素原子を有するアルカンジオールから誘導されたポリアルキレンテレフタラートである、請求項1に記載の熱可塑性成形材料。
- 成分B)の前記基R1〜R4は、互いに無関係に、Cl、Br又は水素を表す、請求項1又は2に記載の熱可塑性成形材料。
- 成分B)の前記基R1〜R4は、互いに無関係に、Cl又はBrを表す、請求項3に記載の熱可塑性成形材料。
- 成分B)の金属Mは、Be、Mg、Ca、Sr、Ba、Al、Zn又はFeを表す、請求項1から4までのいずれか1項に記載の熱可塑性成形材料。
- 成分C)は、
C1) 50〜85質量%及び
C2) 15〜50質量%
から構成されている、請求項1から5までのいずれか1項に記載の熱可塑性成形材料。 - 成分C2)は、Sb2O3、Sb2O5又はアンチモン酸ナトリウム又はこれらの混合物から構成されている、請求項1から6までのいずれか1項に記載の熱可塑性成形材料。
- 成分D)を0〜45質量%までの量で含む、請求項1から7までのいずれか1項に記載の熱可塑性成形材料。
- 成分D)が繊維状の充填剤を0〜35質量%までの量で含む、請求項8に記載の熱可塑性成形材料。
- 繊維、シート又は成形品を製造するための、請求項1から9までのいずれか1項に記載のポリエステル成形材料の使用。
- 請求項1から9までのいずれか1項に記載のポリエステル成形材料から得られる繊維、シート又は成形品。
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PCT/EP2014/067508 WO2015032607A1 (de) | 2013-09-09 | 2014-08-15 | Flammgeschützte polyester |
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