JP6494924B2 - 乳化組成物 - Google Patents
乳化組成物 Download PDFInfo
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- JP6494924B2 JP6494924B2 JP2014107548A JP2014107548A JP6494924B2 JP 6494924 B2 JP6494924 B2 JP 6494924B2 JP 2014107548 A JP2014107548 A JP 2014107548A JP 2014107548 A JP2014107548 A JP 2014107548A JP 6494924 B2 JP6494924 B2 JP 6494924B2
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- polyoxyethylene
- fatty acid
- oil
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- 239000000203 mixture Substances 0.000 title claims description 22
- -1 sorbitan fatty acid Chemical class 0.000 claims description 44
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 22
- 239000000194 fatty acid Substances 0.000 claims description 22
- 229930195729 fatty acid Natural products 0.000 claims description 22
- 239000002202 Polyethylene glycol Substances 0.000 claims description 14
- 229920001223 polyethylene glycol Polymers 0.000 claims description 14
- 239000007764 o/w emulsion Substances 0.000 claims description 13
- 229920001214 Polysorbate 60 Polymers 0.000 claims description 10
- 239000010696 ester oil Substances 0.000 claims description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 229920001296 polysiloxane Polymers 0.000 claims description 2
- 150000005846 sugar alcohols Polymers 0.000 claims 1
- 230000014759 maintenance of location Effects 0.000 description 19
- 230000002123 temporal effect Effects 0.000 description 14
- 150000004665 fatty acids Chemical class 0.000 description 13
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 11
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 description 11
- ASKIVFGGGGIGKH-UHFFFAOYSA-N 2,3-dihydroxypropyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(O)CO ASKIVFGGGGIGKH-UHFFFAOYSA-N 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 9
- 238000011156 evaluation Methods 0.000 description 7
- 230000003020 moisturizing effect Effects 0.000 description 7
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 6
- RFVNOJDQRGSOEL-UHFFFAOYSA-N 2-hydroxyethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCO RFVNOJDQRGSOEL-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- 229940074052 glyceryl isostearate Drugs 0.000 description 5
- 229940100242 glycol stearate Drugs 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- RZRNAYUHWVFMIP-KTKRTIGZSA-N 1-oleoylglycerol Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(O)CO RZRNAYUHWVFMIP-KTKRTIGZSA-N 0.000 description 4
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000006071 cream Substances 0.000 description 4
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 4
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical group CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 4
- 229940058015 1,3-butylene glycol Drugs 0.000 description 3
- BGRXBNZMPMGLQI-UHFFFAOYSA-N 2-octyldodecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCCCC)CCCCCCCCCC BGRXBNZMPMGLQI-UHFFFAOYSA-N 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 235000019437 butane-1,3-diol Nutrition 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 229940073665 octyldodecyl myristate Drugs 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 2
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 2
- NCHJGQKLPRTMAO-XWVZOOPGSA-N [(2R)-2-[(2R,3R,4S)-3,4-dihydroxyoxolan-2-yl]-2-hydroxyethyl] 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NCHJGQKLPRTMAO-XWVZOOPGSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 229940074050 glyceryl myristate Drugs 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 235000011076 sorbitan monostearate Nutrition 0.000 description 2
- 239000001587 sorbitan monostearate Substances 0.000 description 2
- 229940035048 sorbitan monostearate Drugs 0.000 description 2
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- ZORQXIQZAOLNGE-UHFFFAOYSA-N 1,1-difluorocyclohexane Chemical compound FC1(F)CCCCC1 ZORQXIQZAOLNGE-UHFFFAOYSA-N 0.000 description 1
- LGEZTMRIZWCDLW-UHFFFAOYSA-N 14-methylpentadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCC(C)C LGEZTMRIZWCDLW-UHFFFAOYSA-N 0.000 description 1
- YICVJSOYNBZJAK-UHFFFAOYSA-N 14-methylpentadecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCC(C)C YICVJSOYNBZJAK-UHFFFAOYSA-N 0.000 description 1
- ABEXEQSGABRUHS-UHFFFAOYSA-N 16-methylheptadecyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCCOC(=O)CCCCCCCCCCCCCCC(C)C ABEXEQSGABRUHS-UHFFFAOYSA-N 0.000 description 1
- NCLNAHJFXIKYBY-UHFFFAOYSA-N 2-hexyldecyl 16-methylheptadecanoate Chemical compound CCCCCCCCC(CCCCCC)COC(=O)CCCCCCCCCCCCCCC(C)C NCLNAHJFXIKYBY-UHFFFAOYSA-N 0.000 description 1
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
- 239000004909 Moisturizer Substances 0.000 description 1
- 239000005642 Oleic acid Substances 0.000 description 1
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 1
- 229920001219 Polysorbate 40 Polymers 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 238000004378 air conditioning Methods 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- GHVNFZFCNZKVNT-UHFFFAOYSA-M decanoate Chemical compound CCCCCCCCCC([O-])=O GHVNFZFCNZKVNT-UHFFFAOYSA-M 0.000 description 1
- SZXQTJUDPRGNJN-UHFFFAOYSA-N dipropylene glycol Chemical compound OCCCOCCCO SZXQTJUDPRGNJN-UHFFFAOYSA-N 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000003827 glycol group Chemical group 0.000 description 1
- 229940078568 isocetyl myristate Drugs 0.000 description 1
- 229940078545 isocetyl stearate Drugs 0.000 description 1
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 1
- 229940060384 isostearyl isostearate Drugs 0.000 description 1
- 239000002649 leather substitute Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000001333 moisturizer Effects 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002884 skin cream Substances 0.000 description 1
- 235000011069 sorbitan monooleate Nutrition 0.000 description 1
- 239000001593 sorbitan monooleate Substances 0.000 description 1
- 229940035049 sorbitan monooleate Drugs 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Landscapes
- Cosmetics (AREA)
Description
なお、本発明において他の成分についての含有量を示す%数は、特段の断りがない限り質量%数とする。
試料を40℃、3カ月放置後の外観を目視にて観察し、下記評価基準により判定した。
<評価基準>
◎:外観の変化がなく、初期と比較して粘度または硬度の低下・上昇は10%未満である。
○:外観の変化がなく、初期と比較して粘度または硬度の低下・上昇は25%未満である。
△:気液界面での若干の油浮きや、25%以上50%未満の粘度または硬度の低下・上昇が見られる。
×:分離や、50%以上の粘度または硬度の低下・上昇が見られる。
実施例、比較例に示した水中油型乳化組成物を被験者20名に2週間使用させ、以下の評価基準に従って評価した。
<評価基準>
◎:とても良好 15名以上がべたつかないと評価した。
○:良好 10名〜14名がべたつかないと評価した。
△:普通 5名〜9名がべたつかないと評価した。
×:悪い 4名以下がべたつかないと評価した。
実施例、比較例に示した水中油型乳化組成物を被験者20名に2週間使用させ、以下の評価基準に従って評価した。
<評価基準>
◎:とても良好 15名以上が保湿性があると評価した。
○:良好 10名〜14名が保湿性があると評価した。
△:普通 5名〜9名が保湿性があると評価した。
×:悪い 4名以下が保湿性があると評価した。
実施例1〜31、比較例1〜9に示した乳化組成物を調製し、経時安定性、べたつき感のなさ、保湿性について評価し、その結果を表1〜4に示した。
a相およびb相を80℃以上に熱し、a相にb相を加え均一に混合する。次いでc相を加え均一に混合し、撹拌しながら30℃まで冷却する。なお、c相の含有量はpHが6.3程度になるように適宜調整する。
Claims (1)
- (A)エステル油
(B)ソルビタン脂肪酸モノエステル
(C)ポリオキシエチレンソルビタン脂肪酸エステル、ポリエチレングリコール脂肪酸エステル、ポリオキシエチレングリセリン脂肪酸エステルから選ばれる1種
(D)重合度が80〜300であるメチルポリシロキサン
(E)多価アルコール
を含有し、前記(A)成分のMIU(平均摩擦係数)が0.35〜0.45でありかつ分子量が450〜550であり、
前記(D)成分と前記(E)成分の合計含有量が17.0質量%以下であり、前記(D)成分と前記(E)成分の配合比が、(E)/(D)=5〜25である、水中油型乳化組成物。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014107548A JP6494924B2 (ja) | 2014-05-23 | 2014-05-23 | 乳化組成物 |
Applications Claiming Priority (1)
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JP2014107548A JP6494924B2 (ja) | 2014-05-23 | 2014-05-23 | 乳化組成物 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2015221774A JP2015221774A (ja) | 2015-12-10 |
JP6494924B2 true JP6494924B2 (ja) | 2019-04-03 |
Family
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JP2014107548A Active JP6494924B2 (ja) | 2014-05-23 | 2014-05-23 | 乳化組成物 |
Country Status (1)
Country | Link |
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JP (1) | JP6494924B2 (ja) |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2529571B2 (ja) * | 1987-05-12 | 1996-08-28 | 株式会社ヤクルト本社 | 皮膚刺激感抑制剤及びこれを配合してなる化粧料 |
FR2760365B1 (fr) * | 1997-03-07 | 2000-12-22 | Roc Sa | Composition pharmaceutique ou cosmetologique contenant au moins un retinoide, et methode de traitement cosmetique des modifications liees au vieillissement de la peau et/ou des phaneres |
JPH11106328A (ja) * | 1997-10-01 | 1999-04-20 | Lion Corp | 皮膚外用組成物 |
JP4311064B2 (ja) * | 2003-03-31 | 2009-08-12 | スズキ株式会社 | 放電加工皮膜およびその加工方法 |
JP2007055989A (ja) * | 2005-08-25 | 2007-03-08 | Estate Chemical Kk | ヘアリンス剤組成物 |
JP5819643B2 (ja) * | 2010-06-04 | 2015-11-24 | ロート製薬株式会社 | 外用組成物 |
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2014
- 2014-05-23 JP JP2014107548A patent/JP6494924B2/ja active Active
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JP2015221774A (ja) | 2015-12-10 |
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