JP6491792B2 - プロピレン−エチレン−1−ブテンターポリマーを含む組成物 - Google Patents
プロピレン−エチレン−1−ブテンターポリマーを含む組成物 Download PDFInfo
- Publication number
- JP6491792B2 JP6491792B2 JP2018506284A JP2018506284A JP6491792B2 JP 6491792 B2 JP6491792 B2 JP 6491792B2 JP 2018506284 A JP2018506284 A JP 2018506284A JP 2018506284 A JP2018506284 A JP 2018506284A JP 6491792 B2 JP6491792 B2 JP 6491792B2
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- Prior art keywords
- ethylene
- polyolefin composition
- weight
- butene
- propylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000000203 mixture Substances 0.000 title claims description 36
- -1 propylene-ethylene-1-butene Chemical class 0.000 title claims description 15
- 229920001897 terpolymer Polymers 0.000 title claims description 12
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 claims description 41
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 30
- 239000005977 Ethylene Substances 0.000 claims description 30
- 229920000098 polyolefin Polymers 0.000 claims description 29
- 150000001875 compounds Chemical class 0.000 claims description 22
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 claims description 15
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 claims description 13
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 11
- 238000002844 melting Methods 0.000 claims description 10
- 230000008018 melting Effects 0.000 claims description 10
- 125000000217 alkyl group Chemical group 0.000 claims description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 9
- 125000004122 cyclic group Chemical group 0.000 claims description 9
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 9
- 239000008096 xylene Substances 0.000 claims description 9
- IYYGCUZHHGZXGJ-UHFFFAOYSA-N but-1-ene;ethene;prop-1-ene Chemical compound C=C.CC=C.CCC=C IYYGCUZHHGZXGJ-UHFFFAOYSA-N 0.000 claims description 7
- 125000005842 heteroatom Chemical group 0.000 claims description 7
- 229920005653 propylene-ethylene copolymer Polymers 0.000 claims description 7
- 239000011949 solid catalyst Substances 0.000 claims description 7
- 125000003118 aryl group Chemical group 0.000 claims description 6
- 239000011127 biaxially oriented polypropylene Substances 0.000 claims description 5
- 229920006378 biaxially oriented polypropylene Polymers 0.000 claims description 5
- 238000009826 distribution Methods 0.000 claims description 5
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 4
- 229910052799 carbon Inorganic materials 0.000 claims description 4
- 239000003054 catalyst Substances 0.000 claims description 4
- 125000001424 substituent group Chemical group 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 3
- 230000000977 initiatory effect Effects 0.000 claims description 3
- 229910052757 nitrogen Inorganic materials 0.000 claims description 3
- 230000000379 polymerizing effect Effects 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 2
- 239000007795 chemical reaction product Substances 0.000 claims description 2
- 229910052736 halogen Inorganic materials 0.000 claims description 2
- 150000002367 halogens Chemical class 0.000 claims description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 125000003367 polycyclic group Chemical group 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 229910052717 sulfur Inorganic materials 0.000 claims description 2
- 125000002877 alkyl aryl group Chemical group 0.000 claims 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 1
- 238000000034 method Methods 0.000 description 24
- 229920000642 polymer Polymers 0.000 description 15
- 239000000523 sample Substances 0.000 description 14
- 238000006116 polymerization reaction Methods 0.000 description 10
- 238000011084 recovery Methods 0.000 description 10
- 238000005259 measurement Methods 0.000 description 9
- 239000010936 titanium Substances 0.000 description 8
- 229920001296 polysiloxane Polymers 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical compound ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 5
- 239000002245 particle Substances 0.000 description 5
- 238000001228 spectrum Methods 0.000 description 5
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 238000012512 characterization method Methods 0.000 description 4
- 238000003851 corona treatment Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 229920005604 random copolymer Polymers 0.000 description 4
- 238000007789 sealing Methods 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000011282 treatment Methods 0.000 description 4
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 238000000113 differential scanning calorimetry Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 3
- RKMGAJGJIURJSJ-UHFFFAOYSA-N 2,2,6,6-tetramethylpiperidine Chemical compound CC1(C)CCCC(C)(C)N1 RKMGAJGJIURJSJ-UHFFFAOYSA-N 0.000 description 2
- ZWINORFLMHROGF-UHFFFAOYSA-N 9,9-bis(methoxymethyl)fluorene Chemical compound C1=CC=C2C(COC)(COC)C3=CC=CC=C3C2=C1 ZWINORFLMHROGF-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000005840 aryl radicals Chemical class 0.000 description 2
- 238000012662 bulk polymerization Methods 0.000 description 2
- 238000011088 calibration curve Methods 0.000 description 2
- JWCYDYZLEAQGJJ-UHFFFAOYSA-N dicyclopentyl(dimethoxy)silane Chemical compound C1CCCC1[Si](OC)(OC)C1CCCC1 JWCYDYZLEAQGJJ-UHFFFAOYSA-N 0.000 description 2
- MGWAVDBGNNKXQV-UHFFFAOYSA-N diisobutyl phthalate Chemical compound CC(C)COC(=O)C1=CC=CC=C1C(=O)OCC(C)C MGWAVDBGNNKXQV-UHFFFAOYSA-N 0.000 description 2
- 150000002170 ethers Chemical class 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 150000002430 hydrocarbons Chemical class 0.000 description 2
- 238000012417 linear regression Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920001384 propylene homopolymer Polymers 0.000 description 2
- 239000012488 sample solution Substances 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000003595 spectral effect Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- PJSFQEVODHCOOF-UHFFFAOYSA-N (2-ethylpiperidin-1-yl)-dimethoxy-(3,3,3-trifluoropropyl)silane Chemical compound CCC1CCCCN1[Si](CCC(F)(F)F)(OC)OC PJSFQEVODHCOOF-UHFFFAOYSA-N 0.000 description 1
- 125000000008 (C1-C10) alkyl group Chemical group 0.000 description 1
- OUPPKRIDJAMCCA-UHFFFAOYSA-N 1-methoxy-2-(methoxymethyl)-2,3-dimethylbutane Chemical compound COCC(C)(C(C)C)COC OUPPKRIDJAMCCA-UHFFFAOYSA-N 0.000 description 1
- BHPDSAAGSUWVMP-UHFFFAOYSA-N 3,3-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(C(C)C)(COC)CCC(C)C BHPDSAAGSUWVMP-UHFFFAOYSA-N 0.000 description 1
- PVWCLOAAEFMTLH-UHFFFAOYSA-N 4,4-bis(methoxymethyl)-2,6-dimethylheptane Chemical compound COCC(COC)(CC(C)C)CC(C)C PVWCLOAAEFMTLH-UHFFFAOYSA-N 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- DTEPJAROXANKQG-UHFFFAOYSA-N C(C)C1N(CCCC1)CO[Si](OC)(CC)CC Chemical compound C(C)C1N(CCCC1)CO[Si](OC)(CC)CC DTEPJAROXANKQG-UHFFFAOYSA-N 0.000 description 1
- 101100223811 Caenorhabditis elegans dsc-1 gene Proteins 0.000 description 1
- 241000282994 Cervidae Species 0.000 description 1
- 238000004566 IR spectroscopy Methods 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- XMYDKOZNENQEHO-UHFFFAOYSA-N [1-methoxy-2-(methoxymethyl)-3-methylbutan-2-yl]cyclopentane Chemical compound COCC(COC)(C(C)C)C1CCCC1 XMYDKOZNENQEHO-UHFFFAOYSA-N 0.000 description 1
- 238000002835 absorbance Methods 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 125000005234 alkyl aluminium group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- LMHUKLLZJMVJQZ-UHFFFAOYSA-N but-1-ene;prop-1-ene Chemical group CC=C.CCC=C LMHUKLLZJMVJQZ-UHFFFAOYSA-N 0.000 description 1
- IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- OEYIOHPDSNJKLS-UHFFFAOYSA-N choline Chemical compound C[N+](C)(C)CCO OEYIOHPDSNJKLS-UHFFFAOYSA-N 0.000 description 1
- 229960001231 choline Drugs 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000013065 commercial product Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- MEWFSXFFGFDHGV-UHFFFAOYSA-N cyclohexyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C1CCCCC1 MEWFSXFFGFDHGV-UHFFFAOYSA-N 0.000 description 1
- SJJCABYOVIHNPZ-UHFFFAOYSA-N cyclohexyl-dimethoxy-methylsilane Chemical compound CO[Si](C)(OC)C1CCCCC1 SJJCABYOVIHNPZ-UHFFFAOYSA-N 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 1
- VHPUZTHRFWIGAW-UHFFFAOYSA-N dimethoxy-di(propan-2-yl)silane Chemical compound CO[Si](OC)(C(C)C)C(C)C VHPUZTHRFWIGAW-UHFFFAOYSA-N 0.000 description 1
- DIJRHOZMLZRNLM-UHFFFAOYSA-N dimethoxy-methyl-(3,3,3-trifluoropropyl)silane Chemical compound CO[Si](C)(OC)CCC(F)(F)F DIJRHOZMLZRNLM-UHFFFAOYSA-N 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 238000012685 gas phase polymerization Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- APFVFJFRJDLVQX-UHFFFAOYSA-N indium atom Chemical compound [In] APFVFJFRJDLVQX-UHFFFAOYSA-N 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Natural products C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229940078552 o-xylene Drugs 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 229920006280 packaging film Polymers 0.000 description 1
- 239000012785 packaging film Substances 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000010926 purge Methods 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 239000013074 reference sample Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 239000012748 slip agent Substances 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000012798 spherical particle Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- TXLMBPWQZULYHP-UHFFFAOYSA-N tert-butyl(dimethoxy)silane Chemical compound CO[SiH](OC)C(C)(C)C TXLMBPWQZULYHP-UHFFFAOYSA-N 0.000 description 1
- HXLWJGIPGJFBEZ-UHFFFAOYSA-N tert-butyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C(C)(C)C HXLWJGIPGJFBEZ-UHFFFAOYSA-N 0.000 description 1
- 150000003609 titanium compounds Chemical group 0.000 description 1
- SQBBHCOIQXKPHL-UHFFFAOYSA-N tributylalumane Chemical compound CCCC[Al](CCCC)CCCC SQBBHCOIQXKPHL-UHFFFAOYSA-N 0.000 description 1
- ORYGRKHDLWYTKX-UHFFFAOYSA-N trihexylalumane Chemical compound CCCCCC[Al](CCCCCC)CCCCCC ORYGRKHDLWYTKX-UHFFFAOYSA-N 0.000 description 1
- MCULRUJILOGHCJ-UHFFFAOYSA-N triisobutylaluminium Chemical compound CC(C)C[Al](CC(C)C)CC(C)C MCULRUJILOGHCJ-UHFFFAOYSA-N 0.000 description 1
- LFXVBWRMVZPLFK-UHFFFAOYSA-N trioctylalumane Chemical compound CCCCCCCC[Al](CCCCCCCC)CCCCCCCC LFXVBWRMVZPLFK-UHFFFAOYSA-N 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/14—Copolymers of propene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/07—Flat, e.g. panels
- B29C48/08—Flat, e.g. panels flexible, e.g. films
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
- B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
- B29C55/10—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial
- B29C55/12—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/16—Layered products comprising a layer of synthetic resin specially treated, e.g. irradiated
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
- C08F4/6421—Titanium tetrahalides with organo-aluminium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/647—Catalysts containing a specific non-metal or metal-free compound
- C08F4/649—Catalysts containing a specific non-metal or metal-free compound organic
- C08F4/6491—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon
- C08F4/6492—Catalysts containing a specific non-metal or metal-free compound organic hydrocarbon containing aliphatic unsaturation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
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- C—CHEMISTRY; METALLURGY
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Description
A)1.5重量%〜6.0重量%の範囲のエチレン誘導単位含量を有するプロピレンエチレンコポリマー19重量%〜50重量%;
B)1.5重量%〜6.0重量%の範囲のエチレン誘導単位含量及び4.8重量%〜12.4重量%の1−ブテン誘導単位含量を有するプロピレンエチレン1−ブテンターポリマー50重量%〜81重量%を含むポリオレフィン組成物であって;
成分A)及びB)の合計が100であり;
前記組成物が下記の要件を特徴とし:
−C2重量%/C4重量%の比が0.22〜3.0であり、C2重量%はエチレン誘導単位の重量%であり、C4重量%は1−ブテン誘導単位の重量%であり;
−25℃でのキシレン可溶性分画の含量が2〜15重量%であり;
−Mw/Mnに関して表される、分子量分布(MWD)が4.0超過であり;
−特徴化セクションで報告された手続きに従って200℃で測定した回復可能なコンプライアンスは、800〜1200秒の間の最大値65×10−5Pa−1未満であるものである、ポリオレフィン組成物に関するものである。
A)1.5重量%〜6.0重量%、好ましくは2.6重量%〜5.2重量%、より好ましくは3.1重量%〜4.3重量%の範囲のエチレン誘導単位含量を有するプロピレンエチレンコポリマー19重量%〜50重量%、好ましくは25重量%〜42重量%;より好ましくは31重量%〜38重量%;
B)1.5重量%〜6.0重量%、好ましくは1.9重量%〜4.8重量%、より好ましくは2.1重量%〜3.7重量%の範囲のエチレン誘導単位含量、及び4.8重量%〜12.4重量%、好ましくは5.1重量%〜10.5重量%、より好ましくは6.8重量%〜10.0重量%の1−ブテン誘導単位含量を有するプロピレンエチレン1−ブテンターポリマー50重量%〜81重量%好ましくは58重量%〜75重量%、より好ましくは62重量%〜69重量%を含む;
成分A)及びB)の合計は100であり;
前記組成物は下記の要件を特徴とし:
−C2重量%/C4重量%の比率が0.22〜3.0、好ましくは0.30〜2.3、より好ましくは0.35〜1.3であり、C2重量%はエチレン誘導単位の重量%であり、C4重量%は1−ブテン誘導単位の重量%であり;
−25℃でのキシレン可溶性分画が2〜15重量%、好ましくは5〜13重量%、より好ましくは7〜11.5重量%含まれ、
−Mw/Mnに関して表される、分子量分布(MWD)が4.0超過、好ましくは10.0未満であり;
−特徴化セクションで報告された手続きに従って200℃で測定した回復可能なコンプライアンスは、800〜1200秒の間の最大値65×10−5Pa−1未満を有する。
(i)Ti、Mg、Cl及び電子供与体化合物(内部供与体)を含む固体触媒成分;
(ii)アルキルアルミニウム化合物及び、
(iii)電子−供与体化合物(外部供与体)。
2.5gのポリマー及び250mLのo−キシレンを冷蔵庫及び磁気撹拌機を備えたガラスフラスコに導入する。温度を溶媒の30分内に沸点まで上昇させる。次いで、このようにして得られた溶液を還流下に維持させ、さらに30分間撹拌する。次いで、密閉されたフラスコを氷と水のバス中に30分間維持させ、25℃の恒温水槽に30分間さらに維持させる。このようにして得られた固体を急速濾過紙で濾過し、100mlの濾過液をあらかじめ秤量したアルミニウム容器に注き、これを窒素気流下で加熱板で加熱して蒸発によって溶媒を除去する。次いで、一定の重量が得られるまで容器を80℃のオーブンで真空下に維持させる。残留物は、秤量してキシレン可溶性重合体の百分率を測定する。
分子量及び分子量分布は、13μmの粒子サイズを有する4つの混床式カラムPLgel Olexisが備えられたWaters Alliance GPCV/2000装備を使用して150℃で測定した。カラムの寸法は、300×7.8mmであった。使用された移動相は、真空蒸溜された1、2、4−卜リクロロベンゼン(TCB)であり、流量は1.0ml/分に維持した。サンプル溶液を1〜2時間TCBで150℃で撹拌しながらサンプルを加熱して製造した。濃度は1mg/mlであった。分解を防ぐために、0.1g/lの2、6−ジーtert−ブチル−p−クレゾールを添加した。300μl(公称値)の溶液をカラムセットに注入した。580〜7 500 000Da範囲の分子量を有する10個のポリスチレン標準サンプル(アジレント社のEasiCalキット)を使用して較正曲線を得た。Mark−Houwink関係式のK値は、次の通りであると仮定した:
K=1.21×10−4dl/g及びα=0.706ポリスチレン標準物質の場合、
K=1.90×10−4dl/g及びα=0.725実験サンプルの場合。
三次多項式フィットを、実験データを補間し、較正曲線を得るために使用した。データ取得及び処理は、GPCオプションを使用してWaters Empowers 3 クロマトグラフィーデータソフトウェアを使用して行った。
ポリマー組成物の溶融流量MFRは、ISO 1133(230℃、2.16Kg)に従って測定した。
コモノマー含量は、フーリエ変換赤外線分光器(FTIR)を使用してサンプル対空気バックグラウンドのIRスペクトルを収集することによって赤外線分光法によって測定した;装備データ取得パラメーターは、次の通りである:
−パージ時間:最小30秒
−収集時間:最小3分
−アポディゼーション:Happ−Genzel
−解像度:2cm−1。
サンプル製造:
−膜厚さの分光標準化に使用される4482〜3950cm−1の組み合わせ吸収帯の面積(At)。
−アイソタクチック非添加的(isotactic non additivate)ポリプロピレンスペクトルの2つの適切な連続的な分光学的減算の以後に750〜700cm−1の間の吸収帯の面積及び次いで800〜690cm−1の範囲の1−ブテン−プロピレンランダムコポリマーの基準スペクトルの面積である、AC2。
−アイソタクチック非添加的ポリプロピレンスペクトルの2つの適切な連続的な分光学的減算の以後に769cm−1(最大値)における吸収帯の高さ及び次いで800〜690cm−1の範囲のエチレン−プロピレンランダムコポリマーの基準スペクトルの高さである、DC4。
AC2/At対エチレンモルパーセント(%C2m)をフロットすることによって較正直線(GC2)を得る。GC2の勾配は、線形回帰から計算する。
DC4/At対1−ブテンモルパーセント(%C4m)をフロットすることによって較正直線(GC4)を得る。GC4の勾配は、線形回帰から計算する。
知られないサンプルのスペクトルを記録した後、知られないサンプルの(At)、(AC2)及び(DC4)を計算する。サンプルのエチレン含量(%モル分率C2m)は、次のように計算する:
ポリマーの溶融温度(Tm)は、インジウム溶融点に対してあらかじめ較正したパーキンエルマー社製DSC−1熱量計上で、示差走査熱量法(D.S.C.)で、20℃/分でISO 11357−1,2009及び11357−3,2011に従って測定した。すべてのDSCるつぼ内のサンプルの重量は、6.0±0.5mgに維持した。
各試験組成物を単軸スクリューコリン押出機(スクリュー1:25の長さ/直径比)で7m/分のフィルム延伸速度及び210〜250℃の溶融温度で押出して製造された約5×5cm 50μm厚さのフィルム試片を使用した。ヘイズ値は、ヘーズメーター(Hazemeter)タイプUX−10またはフィルター“C”と共にG.E.1209光源を有する同等の装備に連結されたガードナー(Gardner)測光単位を使用して測定した。既知のヘイズの基準サンプルは、装備を較正するのに使用した。
表面張力の測定は、ASTM D2578−09に従って測定する。
フィルム試片の製作
本開始のポリオレフィン組成物は、A/B/C多層フィルムを製造するのに使用されており、ここで、A層は実施例1のポリマーであり、B層はLyondellbasellによって販売されているプロピレンホモポリマーMOPLEN HP522Hであり、C層は比較例2のポリマーである。工程パラメタは表1に報告する。
それぞれの試験のために2つの前記試片を、隣接した層が特定試験組成物の層になるように整列して重ね合わせた。重ね合わされた試片をBrugger Feinmechanik Sealer、モデルHSG−ETK 745を用いて2cm側面の一方に沿って密封した。密封時間は、0.1N/mm2の圧力で5秒である。密封温度は、各シールに対して1℃を増加させて、試験組成物の溶融温度よりも約30℃未満の温度から始めた。密封されたサンプルを冷却した後、この密封されていない端部をインストロン機械に取り付け、これらを50mm/分の牽引速度(traction speed)で試験した。
回復可能なコンプライアンスは、25mm半径の円錐板形状及び上部に円錐板を有する1.992゜等級の測定円錐角度を有するPhysica MCR301 レオメーターを使用してクリープ及び回復測定によって、測定された。試験温度は200℃である。
複素粘度は、5%の一定の歪みで100rad/s〜0.01rad/sの周波数掃引試験において測定し、0.01rad/sの周波数での値を選択してクリープ時間を計算した(プロファイルにおける時間設定なし)。クリープ時間は、次の式を使用して計算した:
クリープ時間=複素粘度@0.01rad/s/100; [1]
ここで、100は印加された応力パスカルである。
回復時間は、次の式に従って計算した:
回復時間=クリープ時間*7 [2]
a)クリープ
クリープは、[1]で計算されたクリープ時間に従って最大秒間1秒に1回測定した。印加されたせん断応力は100Paである;
b)回復
回復は、[2]で計算された回復時間に従って最大秒間1秒に1回測定した。印加されたせん断応力は0Paである。
球状付加物の製造のための手続き
マイクロ楕円体MgCl2.2.1C2H5OH付加物は、ヨーロッパ特許出願第728769号の実施例1に従って製造した。
固体触媒成分は、ヨーロッパ特許出願第728769号の実施例1に従って製造した。
前述の固体触媒成分を重合反応器内に注入する前に、トリエチルアルミニウム(TEAL)及びジシクロペンチルジメトキシシラン(DCPMS、D供与体)と表2に報告された比率で接触させた。
第1の気相重合反応器に、予備重合された触媒システム、水素(分子量調節剤として使用した場合)プロピレン及びエチレンを気体状態で連続的且つ一定の流れで供給することによって、プロピレンエチレンコポリマーを生成する。
Claims (11)
- A)1.5重量%〜6.0重量%の範囲のエチレン誘導単位含量を有するプロピレンエチレンコポリマー19重量%〜50重量%;
B)1.5重量%〜6.0重量%の範囲のエチレン誘導単位含量及び4.8重量%〜12.4重量%の1−ブテン誘導単位含量を有するプロピレンエチレン1−ブテンターポリマー50重量%〜81重量%を含むポリオレフィン組成物であって;
成分A)及びB)の合計が100重量%であり
以下の要件:
−C2重量%/C4重量%の比が0.22〜3.0であり、C2重量%はエチレン誘導単位の重量%であり、C4重量%は1−ブテン誘導単位の重量%であり;
−25℃でのキシレン可溶性分画の含量が2〜15重量%であり;
−Mw/Mnに関して表される分子量分布(MWD)が4.0超過であり;
−200℃で測定した回復可能なコンプライアンスは、800〜1200秒の間の最大値65×10−5Pa−1未満を有する
により特徴づけられるとともに、
(i)Ti、Mg、Cl及び電子供与体化合物(内部供与体)を含む固体触媒成分;
(ii)アルキルアルミニウム化合物及び、
(iii)電子−供与体化合物(外部供与体)
の反応生成物を含む触媒の存在下で、プロピレンをエチレンと重合させ、プロピレンをエチレン及び1−ブテンと重合させる段階を含む方法によって製造され、
前記内部供与体が、下記式
- 成分A)が25重量%〜42重量%の範囲であり、成分B)が58重量%〜75重量%の範囲である、請求項1に記載のポリオレフィン組成物。
- 成分A)中のエチレン誘導単位含量が2.6重量%〜5.2重量%の範囲である、請求項1に記載のポリオレフィン組成物。
- 成分B)中のエチレン誘導単位含量が1.9重量%〜4.8重量%の範囲であり、1−ブテン誘導単位含量が5.1重量%〜10.5重量%の範囲である、請求項1に記載のポリオレフィン組成物。
- 200℃で回復可能なコンプライアンスは、800〜1200秒の間の最大値60×10−5Pa−1未満を有する、請求項1に記載のポリオレフィン組成物。
- エチレン誘導単位含量が2.5重量%〜3.9重量%の範囲である、請求項1に記載のポリオレフィン組成物。
- 1−ブテン誘導単位含量が5.3重量%〜6.9重量%の範囲である、請求項1に記載のポリオレフィン組成物。
- 溶融温度が136.8℃未満である、請求項1に記載のポリオレフィン組成物。
- シール開始温度(SIT)が90〜109℃に含まれる、請求項1に記載のポリオレフィン組成物。
- 請求項1〜9のいずれか一項に記載のポリオレフィン組成物を含む、フィルム。
- 請求項1〜9のいずれか一項に記載のポリオレフィン組成物を含む、2軸配向(BOPP)フィルム。
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EP15180040 | 2015-08-06 | ||
EP15180040.6 | 2015-08-06 | ||
PCT/EP2016/067144 WO2017021138A1 (en) | 2015-08-06 | 2016-07-19 | Composition comprising propylene-ethylene-1-butene terpolymers |
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EP (1) | EP3331703B1 (ja) |
JP (1) | JP6491792B2 (ja) |
KR (1) | KR101917069B1 (ja) |
CN (1) | CN107921764B (ja) |
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KR102173594B1 (ko) * | 2020-07-16 | 2020-11-04 | 최용제 | 단열 및 차열성능이 우수한 비닐 하우스용 시트 |
US20240124693A1 (en) * | 2020-12-09 | 2024-04-18 | Basell Poliolefine Italia S.R.L. | Propylene polymer composition |
WO2024028042A1 (en) * | 2022-08-03 | 2024-02-08 | Basell Poliolefine Italia S.R.L. | Polypropylene composition for heat sealable films |
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DE2735550A1 (de) | 1977-08-06 | 1979-02-08 | Guenther O Prof Dr Schenck | Mehrkammer-photoreaktor |
IT1096661B (it) | 1978-06-13 | 1985-08-26 | Montedison Spa | Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente |
IT1098272B (it) | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
JPS61115940A (ja) | 1984-11-09 | 1986-06-03 | Mitsubishi Yuka Badische Kk | ポリプロピレン発泡体粒子 |
JPS61248740A (ja) | 1985-04-26 | 1986-11-06 | 住友化学工業株式会社 | ポリプロピレン多層フイルム |
IT1227260B (it) | 1988-09-30 | 1991-03-28 | Himont Inc | Dieteri utilizzabili nella preparazione di catalizzatori ziegler-natta |
IT1269914B (it) | 1994-03-24 | 1997-04-16 | Himonty Inc | Composizioni verniciabili di copolimeri cristallini del propilene aventi bassa temperatura di saldabilita' |
IL117114A (en) | 1995-02-21 | 2000-02-17 | Montell North America Inc | Components and catalysts for the polymerization ofolefins |
US7049377B1 (en) | 1995-02-21 | 2006-05-23 | Basell Poliolefine Italia S.R.L. | 1,3-diethers and components and catalysts for the polymerization of olefins, containing said diethers |
DE19722569A1 (de) | 1997-05-28 | 1998-12-03 | Basf Ag | Statistische Propylencopolymerisate |
US6455602B1 (en) | 2000-10-24 | 2002-09-24 | Union Carbide Chemicals & Plastics Technology Corporation | High-speed processable cellular insulation material with enhanced foamability |
US7351478B2 (en) * | 2001-03-16 | 2008-04-01 | Fina Technology, Inc. | Heat-seal films and method of manufacture |
WO2009019169A1 (en) | 2007-08-03 | 2009-02-12 | Basell Poliolefine Italia S.R.L. | Process for producing propylene terpolymers |
BRPI0822601B1 (pt) | 2008-04-24 | 2020-12-01 | Borealis Ag | copolímeros de polipropileno heterofásico com elevada pureza, seu processo de produção, e artigo |
EP2666793A1 (en) | 2012-05-21 | 2013-11-27 | Basell Poliolefine Italia S.r.l. | Propylene based terpolymer |
EP2743307A1 (en) | 2012-12-12 | 2014-06-18 | Basell Poliolefine Italia S.r.l. | Polyolefin composition |
KR101349929B1 (ko) | 2013-05-14 | 2014-01-14 | 두지산업 주식회사 | 리본형 직물 |
EP2810773A1 (en) * | 2013-06-05 | 2014-12-10 | Basell Poliolefine Italia S.r.l. | Butene-1 copolymer tie layer in multilayer film structures having a low seal temperature and improved hot tack |
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CN107921764A (zh) | 2018-04-17 |
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CN107921764B (zh) | 2019-07-26 |
JP2018525488A (ja) | 2018-09-06 |
KR101917069B1 (ko) | 2018-11-08 |
BR112018002393A2 (pt) | 2018-09-18 |
EP3331703B1 (en) | 2019-05-29 |
PL3331703T3 (pl) | 2019-11-29 |
US10577492B2 (en) | 2020-03-03 |
KR20180025974A (ko) | 2018-03-09 |
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RU2679259C1 (ru) | 2019-02-06 |
TR201910968T4 (tr) | 2019-08-21 |
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