JP6486901B2 - 電気化学デバイスのための共溶媒電解質 - Google Patents
電気化学デバイスのための共溶媒電解質 Download PDFInfo
- Publication number
- JP6486901B2 JP6486901B2 JP2016507559A JP2016507559A JP6486901B2 JP 6486901 B2 JP6486901 B2 JP 6486901B2 JP 2016507559 A JP2016507559 A JP 2016507559A JP 2016507559 A JP2016507559 A JP 2016507559A JP 6486901 B2 JP6486901 B2 JP 6486901B2
- Authority
- JP
- Japan
- Prior art keywords
- electrolyte
- electrochemical cell
- rechargeable electrochemical
- solvent
- electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000003792 electrolyte Substances 0.000 title claims description 163
- 239000006184 cosolvent Substances 0.000 title claims description 137
- WEVYAHXRMPXWCK-UHFFFAOYSA-N Acetonitrile Chemical compound CC#N WEVYAHXRMPXWCK-UHFFFAOYSA-N 0.000 claims description 98
- 239000002904 solvent Substances 0.000 claims description 89
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 88
- 238000006243 chemical reaction Methods 0.000 claims description 42
- 150000003839 salts Chemical class 0.000 claims description 30
- 150000001768 cations Chemical class 0.000 claims description 25
- 239000000463 material Substances 0.000 claims description 23
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 21
- -1 transition metal cyanide Chemical class 0.000 claims description 18
- 229910052723 transition metal Inorganic materials 0.000 claims description 16
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 14
- 239000000654 additive Substances 0.000 claims description 11
- 239000001257 hydrogen Substances 0.000 claims description 11
- 229910052739 hydrogen Inorganic materials 0.000 claims description 11
- 239000003446 ligand Substances 0.000 claims description 11
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 9
- 239000002184 metal Substances 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 7
- 239000000203 mixture Substances 0.000 claims description 7
- XFXPMWWXUTWYJX-UHFFFAOYSA-N Cyanide Chemical compound N#[C-] XFXPMWWXUTWYJX-UHFFFAOYSA-N 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 5
- 230000000996 additive effect Effects 0.000 claims description 5
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 claims description 5
- 239000003513 alkali Substances 0.000 claims description 4
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 claims description 4
- WOFDVDFSGLBFAC-UHFFFAOYSA-N lactonitrile Chemical compound CC(O)C#N WOFDVDFSGLBFAC-UHFFFAOYSA-N 0.000 claims description 4
- 150000002825 nitriles Chemical group 0.000 claims description 4
- MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical group O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 claims description 3
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000003586 protic polar solvent Substances 0.000 claims 3
- 239000003880 polar aprotic solvent Substances 0.000 claims 2
- 125000003158 alcohol group Chemical group 0.000 claims 1
- 229910002091 carbon monoxide Inorganic materials 0.000 claims 1
- 125000005587 carbonate group Chemical group 0.000 claims 1
- 125000000468 ketone group Chemical group 0.000 claims 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 39
- 238000002484 cyclic voltammetry Methods 0.000 description 34
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 23
- 239000011572 manganese Substances 0.000 description 20
- 239000012071 phase Substances 0.000 description 19
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical class [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 17
- 238000000034 method Methods 0.000 description 17
- 239000007864 aqueous solution Substances 0.000 description 16
- 239000013225 prussian blue Substances 0.000 description 16
- 229960003351 prussian blue Drugs 0.000 description 15
- 239000010949 copper Substances 0.000 description 12
- 238000004090 dissolution Methods 0.000 description 12
- 239000007772 electrode material Substances 0.000 description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 12
- 239000003960 organic solvent Substances 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- 230000007062 hydrolysis Effects 0.000 description 11
- 238000006460 hydrolysis reaction Methods 0.000 description 11
- 239000007788 liquid Substances 0.000 description 11
- 239000011244 liquid electrolyte Substances 0.000 description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- 230000008901 benefit Effects 0.000 description 9
- 239000011651 chromium Substances 0.000 description 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 8
- UETZVSHORCDDTH-UHFFFAOYSA-N iron(2+);hexacyanide Chemical compound [Fe+2].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] UETZVSHORCDDTH-UHFFFAOYSA-N 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 230000002441 reversible effect Effects 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 239000013078 crystal Substances 0.000 description 7
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- GAEKPEKOJKCEMS-UHFFFAOYSA-N gamma-valerolactone Chemical compound CC1CCC(=O)O1 GAEKPEKOJKCEMS-UHFFFAOYSA-N 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 5
- XFWPQJBAXJLHCP-UHFFFAOYSA-N [Mn+6].[O-][Mn](=O)(=O)C#N.[O-][Mn](=O)(=O)C#N.[O-][Mn](=O)(=O)C#N.[O-][Mn](=O)(=O)C#N.[O-][Mn](=O)(=O)C#N.[O-][Mn](=O)(=O)C#N Chemical compound [Mn+6].[O-][Mn](=O)(=O)C#N.[O-][Mn](=O)(=O)C#N.[O-][Mn](=O)(=O)C#N.[O-][Mn](=O)(=O)C#N.[O-][Mn](=O)(=O)C#N.[O-][Mn](=O)(=O)C#N XFWPQJBAXJLHCP-UHFFFAOYSA-N 0.000 description 5
- 230000008859 change Effects 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 238000000354 decomposition reaction Methods 0.000 description 5
- 230000007812 deficiency Effects 0.000 description 5
- 238000011161 development Methods 0.000 description 5
- 238000010586 diagram Methods 0.000 description 5
- 238000012986 modification Methods 0.000 description 5
- 230000004048 modification Effects 0.000 description 5
- 239000002253 acid Substances 0.000 description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- 229910001416 lithium ion Inorganic materials 0.000 description 4
- 230000007246 mechanism Effects 0.000 description 4
- 239000005486 organic electrolyte Substances 0.000 description 4
- 229910052760 oxygen Inorganic materials 0.000 description 4
- 239000001301 oxygen Substances 0.000 description 4
- 238000007086 side reaction Methods 0.000 description 4
- 230000000087 stabilizing effect Effects 0.000 description 4
- WNXJIVFYUVYPPR-UHFFFAOYSA-N 1,3-dioxolane Chemical compound C1COCO1 WNXJIVFYUVYPPR-UHFFFAOYSA-N 0.000 description 3
- JOLQKTGDSGKSKJ-UHFFFAOYSA-N 1-ethoxypropan-2-ol Chemical compound CCOCC(C)O JOLQKTGDSGKSKJ-UHFFFAOYSA-N 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 3
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- 229910021607 Silver chloride Inorganic materials 0.000 description 3
- 230000002378 acidificating effect Effects 0.000 description 3
- 238000004458 analytical method Methods 0.000 description 3
- 239000011230 binding agent Substances 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 239000011262 electrochemically active material Substances 0.000 description 3
- 238000005868 electrolysis reaction Methods 0.000 description 3
- 238000004146 energy storage Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000037427 ion transport Effects 0.000 description 3
- 150000002500 ions Chemical class 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 229910052987 metal hydride Inorganic materials 0.000 description 3
- 150000004681 metal hydrides Chemical class 0.000 description 3
- 239000002105 nanoparticle Substances 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 229910000652 nickel hydride Inorganic materials 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 230000036961 partial effect Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 230000004044 response Effects 0.000 description 3
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- HXJUTPCZVOIRIF-UHFFFAOYSA-N sulfolane Chemical compound O=S1(=O)CCCC1 HXJUTPCZVOIRIF-UHFFFAOYSA-N 0.000 description 3
- 150000003624 transition metals Chemical class 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- 229920000557 Nafion® Polymers 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 238000004891 communication Methods 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 235000011187 glycerol Nutrition 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 238000002354 inductively-coupled plasma atomic emission spectroscopy Methods 0.000 description 2
- 238000003780 insertion Methods 0.000 description 2
- 230000037431 insertion Effects 0.000 description 2
- 238000009830 intercalation Methods 0.000 description 2
- 230000002687 intercalation Effects 0.000 description 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000012299 nitrogen atmosphere Substances 0.000 description 2
- 238000005191 phase separation Methods 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 2
- 239000002244 precipitate Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 229910001415 sodium ion Inorganic materials 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 241000894007 species Species 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- JGLMVXWAHNTPRF-CMDGGOBGSA-N CCN1N=C(C)C=C1C(=O)NC1=NC2=CC(=CC(OC)=C2N1C\C=C\CN1C(NC(=O)C2=CC(C)=NN2CC)=NC2=CC(=CC(OCCCN3CCOCC3)=C12)C(N)=O)C(N)=O Chemical compound CCN1N=C(C)C=C1C(=O)NC1=NC2=CC(=CC(OC)=C2N1C\C=C\CN1C(NC(=O)C2=CC(C)=NN2CC)=NC2=CC(=CC(OCCCN3CCOCC3)=C12)C(N)=O)C(N)=O JGLMVXWAHNTPRF-CMDGGOBGSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- NPYPAHLBTDXSSS-UHFFFAOYSA-N Potassium ion Chemical compound [K+] NPYPAHLBTDXSSS-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- FKNQFGJONOIPTF-UHFFFAOYSA-N Sodium cation Chemical compound [Na+] FKNQFGJONOIPTF-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- QIGXIDXEZVFOPY-UHFFFAOYSA-N [Cr+6].[O-][Cr](=O)(=O)C#N.[O-][Cr](=O)(=O)C#N.[O-][Cr](=O)(=O)C#N.[O-][Cr](=O)(=O)C#N.[O-][Cr](=O)(=O)C#N.[O-][Cr](=O)(=O)C#N Chemical compound [Cr+6].[O-][Cr](=O)(=O)C#N.[O-][Cr](=O)(=O)C#N.[O-][Cr](=O)(=O)C#N.[O-][Cr](=O)(=O)C#N.[O-][Cr](=O)(=O)C#N.[O-][Cr](=O)(=O)C#N QIGXIDXEZVFOPY-UHFFFAOYSA-N 0.000 description 1
- AGBIJHUURGOGBL-UHFFFAOYSA-N [Cr+6].[O-][Mn](=O)(=O)C#N.[O-][Mn](=O)(=O)C#N.[O-][Mn](=O)(=O)C#N.[O-][Mn](=O)(=O)C#N.[O-][Mn](=O)(=O)C#N.[O-][Mn](=O)(=O)C#N Chemical compound [Cr+6].[O-][Mn](=O)(=O)C#N.[O-][Mn](=O)(=O)C#N.[O-][Mn](=O)(=O)C#N.[O-][Mn](=O)(=O)C#N.[O-][Mn](=O)(=O)C#N.[O-][Mn](=O)(=O)C#N AGBIJHUURGOGBL-UHFFFAOYSA-N 0.000 description 1
- KVVDGOQPPSWVMN-UHFFFAOYSA-N [Mn](=O)(=O)([O-])C#N.[Mn](=O)(=O)([O-])C#N.[Mn](=O)(=O)([O-])C#N.[Mn](=O)(=O)([O-])C#N.[Mn](=O)(=O)([O-])C#N.[Mn](=O)(=O)([O-])C#N.[Zn+2].[Zn+2].[Zn+2] Chemical compound [Mn](=O)(=O)([O-])C#N.[Mn](=O)(=O)([O-])C#N.[Mn](=O)(=O)([O-])C#N.[Mn](=O)(=O)([O-])C#N.[Mn](=O)(=O)([O-])C#N.[Mn](=O)(=O)([O-])C#N.[Zn+2].[Zn+2].[Zn+2] KVVDGOQPPSWVMN-UHFFFAOYSA-N 0.000 description 1
- BNOODXBBXFZASF-UHFFFAOYSA-N [Na].[S] Chemical compound [Na].[S] BNOODXBBXFZASF-UHFFFAOYSA-N 0.000 description 1
- 239000003929 acidic solution Substances 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000010406 cathode material Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- UOUJSJZBMCDAEU-UHFFFAOYSA-N chromium(3+);oxygen(2-) Chemical class [O-2].[O-2].[O-2].[Cr+3].[Cr+3] UOUJSJZBMCDAEU-UHFFFAOYSA-N 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 229920001795 coordination polymer Polymers 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 229910001882 dioxygen Inorganic materials 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000002848 electrochemical method Methods 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 230000005518 electrochemistry Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 150000004677 hydrates Chemical class 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- LBSANEJBGMCTBH-UHFFFAOYSA-N manganate Chemical compound [O-][Mn]([O-])(=O)=O LBSANEJBGMCTBH-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000002572 peristaltic effect Effects 0.000 description 1
- 238000010587 phase diagram Methods 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 235000010333 potassium nitrate Nutrition 0.000 description 1
- 239000004323 potassium nitrate Substances 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 239000002243 precursor Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 230000001681 protective effect Effects 0.000 description 1
- 238000012552 review Methods 0.000 description 1
- 229910052701 rubidium Inorganic materials 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 description 1
- 229910001488 sodium perchlorate Inorganic materials 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- 238000007614 solvation Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 238000003419 tautomerization reaction Methods 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 230000035899 viability Effects 0.000 description 1
- 229910009112 xH2O Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0569—Liquid materials characterised by the solvents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
- H01M10/0568—Liquid materials characterised by the solutes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/06—Lead-acid accumulators
- H01M10/08—Selection of materials as electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/34—Gastight accumulators
- H01M10/345—Gastight metal hydride accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/36—Accumulators not provided for in groups H01M10/05-H01M10/34
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/485—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of mixed oxides or hydroxides for inserting or intercalating light metals, e.g. LiTi2O4 or LiTi2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/60—Selection of substances as active materials, active masses, active liquids of organic compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
- H01M4/90—Selection of catalytic material
- H01M4/9008—Organic or organo-metallic compounds
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/18—Regenerative fuel cells, e.g. redox flow batteries or secondary fuel cells
- H01M8/184—Regeneration by electrochemical means
- H01M8/188—Regeneration by electrochemical means by recharging of redox couples containing fluids; Redox flow type batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
- H01M2004/027—Negative electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/10—Batteries in stationary systems, e.g. emergency power source in plant
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2220/00—Batteries for particular applications
- H01M2220/20—Batteries in motive systems, e.g. vehicle, ship, plane
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
- H01M2250/10—Fuel cells in stationary systems, e.g. emergency power source in plant
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2250/00—Fuel cells for particular applications; Specific features of fuel cell system
- H01M2250/20—Fuel cells in motive systems, e.g. vehicle, ship, plane
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0002—Aqueous electrolytes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
- H01M2300/0028—Organic electrolyte characterised by the solvent
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
- H01M2300/0028—Organic electrolyte characterised by the solvent
- H01M2300/0037—Mixture of solvents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0017—Non-aqueous electrolytes
- H01M2300/0025—Organic electrolyte
- H01M2300/0028—Organic electrolyte characterised by the solvent
- H01M2300/0037—Mixture of solvents
- H01M2300/004—Three solvents
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M2300/00—Electrolytes
- H01M2300/0088—Composites
- H01M2300/0091—Composites in the form of mixtures
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02B—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
- Y02B90/00—Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02B90/10—Applications of fuel cells in buildings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T90/00—Enabling technologies or technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02T90/40—Application of hydrogen technology to transportation, e.g. using fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Secondary Cells (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)
Description
本出願は、2014年3月31日に出願された米国特許出願第14/231,571号および2013年4月10日に出願された米国特許出願第61/810,684号の両方の恩典を主張するものであり、なお、当該特許出願の内容はすべて、すべての目的のために参照によりその全体が明確に本明細書に組み入れられる。
本発明は、DOEによって付与されたARPA−E Award No.DEAR000300の下、政府支援によって為された。政府は、本発明においてある特定の権利を有する。
本発明は、概して、電気化学デバイスに関し、より詳細には、しかし非排他的に、共溶媒ベースの液体電解質セルに関する。
本発明の実施形態は、溶解および/または加水分解に対して電極を安定化させるためのシステムおよび方法を提供する。以下の説明は、当業者がこの発明を実施および使用することを可能にするために提示されるのであって、特許出願およびその要件との関連において提供される。
AxPy[R(CN)6−jLj]z・nH2O
[式中、
Aは、一価のカチオン(例えば、Na+、K+、Li+、またはNH4 +など)または二価のカチオン(例えば、Mg2+またはCa2+など)であり;
Pは、遷移金属カチオン(例えば、Ti3+、Ti4+、V2+、V3+、Cr2+、Cr3+、Mn2+、Mn3+、Fe2+、Fe3+、Co2+、Co3+、Ni2+、Cu+、Cu2+、またはZn2+など)または別の金属カチオン(例えば、Al3+、Sn2+、In3+、またはPb2+など)であり;
Rは、遷移金属カチオン(例えば、V2+、V3+、Cr2+、Cr3+、Mn+、Mn2+、Mn3+、Fe2+、Fe3+、Co2+、Co3+、Ru2+、Ru3+、Os2+、Os3+、Ir2+、Ir3+、Pt2+、またはPt3+など)であり;
Lは、CN−配位子の位置において置換され得る配位子(例えば、CO(カルボニル)、NO(ニトロシル)、またはCl−など)であり;
0≦x≦2であり;
0<y≦4であり;
0<z≦1であり;
0≦j≦6であり;ならびに
0≦n≦5である]によって与えられる。
参考文献1. Rastler, D.著 Electricity Energy Storage Technology Options, Electric Power Research Institute, 1020676 (2010).
参考文献2. Wessells, C. D.など著 Copper hexacyanoferrate battery electrodes with long cycle life and high power. Nature Comm., 2, 550 (2011).
参考文献3. Wessells, C. D.など著 Nickel Hexacyanoferrate Nanoparticle Electrodes for Aqueous Sodium and Potassium Ion Batteries. Nano Lett., 11, 5421 (2011).
参考文献4. Wessells, C. D.など著 The Effect of Insertion Species on Nanostructured Open Framework Hexacyanoferrate Battery Electrodes. J. Electrochem. Soc., 159, A98 (2012).
参考文献5. Wessells, C. D. など著 Tunable Reaction Potentials in Open Framework Nanoparticle Battery Electrodes for Grid-Scale Energy Storage. ACS Nano, 6, 1688 (2012).
参考文献6. Pasta, M. など著 A high-rate and long cycle life aqueous electrolyte battery for grid-scale energy storage. Nature Comm., 3, 1149 (2012).
参考文献7. Wessells, C. D. など著 High Rate, Long Cycle Life Battery Electrode Materials With An Open Framework Structure. US Patent Application US 2012/0328936 A1.
参考文献8. Scholz, F. など著 The Formal Potentials of Solid Metal Hexacyanometalates. Angew. Chem. Int. Ed. Engl., 34, 2685 (1995).
参考文献9. Lopez-Cueto, G. など著 Fast disproportionation of hexacyanomanganate(III) in acidic solution. Formation of hexacyanomanganate(IV) and kinetics of its decomposition. Can. J. Chem., 64, 2301 (1986).
参考文献10. Buser, H. J. など著 The Crystal Structure of Prussian Blue: Fe4[Fe(CN)6]3・xH2O. Inorg. Chem., 16, 2704 (1977).
参考文献11. Itaya, K. など著 Electrochemistry of Polynuclear Transition Metal Cyanides: Prussian Blue and Its Analogues. Acc. Chem. Res., 19, 162 (1986).
参考文献12. Messina, R., Perichon, J., and Broussely, M. 著 Mecanismes de la reduction electrochimique en milieu non aqueux de materiaux cathodiques utilizes dans les piles au lithium. IV. Reduction d’electrodes membranaires d’hexacyanoferrates (II et III) d’argent dans le melange carbonate de propylene-1,2-dimethoxyethane. J. Appl. Electrochem., 9, 677 (1979).
参考文献13. Messina, R., and Perichon, J.著 Mecanisme de la reduction electrochimique en milieu non aqueux de materiaux cathodiques utilizes dan les piles au lithium. V. Utilisation des hexacyanoferrates de fer (II et III) comme materiaux cathodiques reversibles. J. Appl. Electrochem., 10, 655 (1980).
参考文献14. Neff, V. D.著 Some Performance Characteristics of a Prussian Blue Battery. J. Electrochem. Soc., 132, 1382 (1985).
参考文献15. Honda, K. and Hayashi, H.著 Prussian Blue Containing Nafion Composite Film as Rechareable Battery. J. Electrochem. Soc., 134, 1339 (1987).
参考文献16. Grabner, E. W., and Kalwellis-Mohn, S. 著 Hexacyanoferrate layers as electrodes for secondary cells. J. Appl. Electrochem., 17, 653 (1987).
参考文献17. Kaneko, M., and Okada, T.著 A secondary battery composed of multilayer Prussian Blue and its reaction characteristics. J. Electroanal. Chem., 255, 45 (1988).
参考文献18. Kalwellis-Mohn, S., and Grabner, E. W.著 A Secondary Cell Based on Thin Film Layers of Zeolite-Like Nickel Hexacyanometallates. Electrochim. Acta., 34, 1265 (1989).
参考文献19. Jayalakshmi, M., and Scholz, F.著 Charge-discharge characteristics of a solid-state Prussian blue secondary cell. J. Power Sources, 87, 212 (2000).
参考文献20. Jayalakshmi, M., and Sholz, F. 著 Performance characteristics of zinc hexacyanoferrate/Prussian blue and copper hexacyanoferrate/Prussian blue soid state secondary cells. J. Power Sources, 91, 217 (2000).
参考文献21. Itaya, K.など著 European Patent Application EP 0086555A1 (January 13, 1983).
参考文献22. Eftekhari, A. 著 Fabrication of all-solid-state thin-film secondary cells using hexacyanometalate-based electrode materials. J. Power Sources, 132, 291 (2004).
参考文献23. Okubo, M.など著 Switching Redox-Active Sites by Valence Tautomerism in Prussian Blue Analaogues AxMny[Fe(CN)6]・nH2O (A: K, Rb): Robust Frameworks for Reversible Li Storage. J. Phys. Chem. Lett., 1, 2063 (2010).
参考文献24. Asakura, D.など著 Fabrication of a Cyanide-Bridged Coordination Polymer Electrode for Enhanced Electrochemical Ion Storage Ability. J. Phys. Chem. C, 116, 8364 (2012).
1605 負極
1610 正極
1615 電解質
1620 負電流コレクタ
1625 正電流コレクタ
Claims (28)
- 陽極と、
陰極と、
総電解質体積Vの第一の分率V1を占める第一の量の水、および、該総電解質体積Vの第二の分率V2を一緒に占める第二の量の1種もしくは複数種の有機共溶媒を含む、該総電解体積Vを有する電解質と、を含み、
V1/V>0.02であり、
V2>V1であり、
前記電極の特定の一方の電極が、遷移金属シアニド配位化合物(TMCCC)材料を含み、
前記電解質が単相であることを特徴とする再充電可能な電気化学電池。 - 前記TMCCC材料が、一般化学式AxPy[R(CN)6−jLj]z・nH2Oを有する組成物を含み、
Aは、1つまたは複数のカチオンを含み、
Pは、1つまたは複数の金属カチオンを含み、
Rは、1つまたは複数の遷移金属カチオンを含み、ならびに、
Lは、CN−配位子の位置において置換された配位子であり、
0≦x≦2であり、
0<y≦4であり、
0<z≦1であり、
0≦j≦6であり、ならびに
0≦n≦5である、請求項1に記載の再充電可能な電気化学電池。 - 前記Aカチオンが、Na+、K+、Li+、NH4+、Mg2+、Ca2+、およびそれらの組み合わせからなる群より選択される1つまたは複数のカチオンを含み、
前記P金属カチオンが、Ti3+、Ti4+、V2+、V3+、Cr2+、Cr3+、Mn2+、Mn3+、Fe2+、Fe3+、Co2+、Co3+、Ni2+、Cu+、Cu2+、Zn2+、Al3+、Sn2+、In3+、もしくはPb2+、およびそれらの組み合わせからなる群より選択される1つまたは複数の金属カチオンを含み、
前記R遷移金属カチオンが、V2+、V3+、Cr2+、Cr3+、Mn+、Mn2+、Mn3+、Fe2+、Fe3+、Co2+、Co3+、Ru2+、Ru3+、Os2+、Os3+、Ir2+、Ir3+、Pt2+、Pt3+、およびそれらの組み合わせからなる群より選択される1つまたは複数の遷移金属カチオンを含み、
前記L配位子が、CO(カルボニル)、NO(ニトロシル)、Cl−、およびそれらの組み合わせからなる群より選択される1つまたは複数の配位子を含む、請求項2に記載の再充電可能な電気化学電池。 - 前記電解質が、塩濃度を有する塩を含み、
前記特定の1つの電極が、前記電解質に配置された場合に第一の寿命を有し、
前記特定の1つの電極が、V1/V=1.00および前記塩濃度での前記塩を有する第二の電解質に配置された場合に第二の寿命を有し、該第一の寿命が該第二の寿命よりも長い、請求項1に記載の再充電可能な電気化学電池。 - 前記電解質が、アルカリカチオン、アルカリ土類カチオン、アンモニウムカチオン、およびそれらの組み合わせからなる群より選択される1つまたは複数の塩を含む、請求項1に記載の再充電可能な電気化学電池。
- 前記電解質が、0.1Mを超える電解質中の前記複数のカチオンの総濃度を生じる、再充電可能な電気化学電池。
- 前記総濃度が1.0Mを超える、請求項6に記載の再充電可能な電気化学電池。
- 前記総濃度が1.4Mを超える、請求項7に記載の再充電可能な電気化学電池。
- 前記電解質が添加剤を含み、前記特定の1つの電極が前記電解質に配置された場合に第一の寿命を有し、前記特定の1つの電極が、該添加剤を含まない前記電解質に配置された場合に第二の寿命を有し、該第一の寿命が該第二の寿命よりも長い、請求項1に記載の再充電可能な電気化学電池。
- 前記電解質が1種または複数種の極性非プロトン性溶媒を含む、請求項1に記載の再充電可能な電気化学電池。
- 前記1種または複数種の極性非プロトン性溶媒が、1種または複数種の有機極性非プロトン共溶媒を含む、請求項10に記載の再充電可能な電気化学電池。
- 前記1種または複数種の有機極性非プロトン性共溶媒が、1つまたは複数のシアニド基を有する特定の共溶媒を含む、請求項11に記載の再充電可能な電気化学電池。
- 前記特定の共溶媒がアセトニトリルを含む、請求項12に記載の再充電可能な電気化学電池。
- 前記1種または複数種の有機極性非プロトン性共溶媒が、1つまたは複数のカーボネート基を有する特定の共溶媒を含む、請求項11に記載の再充電可能な電気化学電池。
- 前記特定の共溶媒が、エチレンカーボネート、プロピレンカーボネート、ジメチルカーボネート、およびそれらの組み合わせからなる群より選択される、請求項14に記載の再充電可能な電気化学電池。
- 前記1種または複数種の有機極性非プロトン性共溶媒が、1つまたは複数のケトン基を有する特定の共溶媒を含む、請求項11に記載の再充電可能な電気化学電池。
- 前記特定の共溶媒がアセトンを含む、請求項16に記載の再充電可能な電気化学電池。
- 前記電解質が、1種または複数種の有機極性プロトン性溶媒を含む、請求項1に記載の再充電可能な電気化学電池。
- 前記1種または複数種の有機極性プロトン性溶媒が、1つまたは複数のアルコール基を有する特定の溶媒を含む、請求項18に記載の再充電可能な電気化学電池。
- 前記特定の溶媒が、メタノール、エチレングリコール、グリセロール、ヒドロキシプロピオニトリル、およびそれらの組み合わせからなる群より選択される、請求項20に記載の再充電可能な電気化学電池。
- 前記電解質が、1種または複数種の有機極性プロトン性溶媒を含む、請求項10に記載の再充電可能な電気化学電池。
- V1/V≦30%およびV2/V≧70%である、請求項1に記載の再充電可能な電気化学電池。
- V1/V≦10%およびV2/V≧90%である、請求項22に記載の再充電可能な電気化学電池。
- 前記電解質が、シアニド含有共溶媒およびカーボネート含有共溶媒の両方を含む、請求項1に記載の再充電可能な電気化学電池。
- 50%充電状態で1Vを超える全電池電圧を有する、請求項1に記載の再充電可能な電気化学電池。
- 前記電極の1つが、標準水素電極に対する−0.5Vを下回る電位を中心とする反応電位を有する陽極として構成される、請求項1に記載の再充電可能な電気化学電池。
- 前記電極の1つが、標準水素電極に対する0.7Vを超える電位を中心とする反応電位を有する陰極として構成される、請求項1に記載の再充電可能な電気化学電池。
- 陽極と、
陰極と、
総電解質重量Wの第一の分率W1を占める第一の量の水および該総電解質重量Wの第二の分率W2を一緒に占める第二の量の1種もしくは複数種の有機共溶媒を含む、該総電解質重量Wを有する電解質と、
を含み、
W1/W>0.02であり、
W2>W1であり、
該電極の特定の一方の電極が、遷移金属シアニド配位化合物(TMCCC)材料を含み、
該電解質が単相である、再充電可能な電気化学電池。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201361810684P | 2013-04-10 | 2013-04-10 | |
US61/810,684 | 2013-04-10 | ||
PCT/US2014/032430 WO2014168778A2 (en) | 2013-04-10 | 2014-03-31 | Cosolvent electrolytes for electrochemical devices |
US14/231,571 US9287589B2 (en) | 2013-04-10 | 2014-03-31 | Cosolvent electrolytes for electrochemical devices |
US14/231,571 | 2014-03-31 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2016519842A JP2016519842A (ja) | 2016-07-07 |
JP6486901B2 true JP6486901B2 (ja) | 2019-03-20 |
Family
ID=51687004
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016507559A Active JP6486901B2 (ja) | 2013-04-10 | 2014-03-31 | 電気化学デバイスのための共溶媒電解質 |
Country Status (7)
Country | Link |
---|---|
US (5) | US9287589B2 (ja) |
EP (1) | EP2997615B1 (ja) |
JP (1) | JP6486901B2 (ja) |
KR (1) | KR102196785B1 (ja) |
CN (1) | CN105122518B (ja) |
AU (1) | AU2014251301B2 (ja) |
WO (1) | WO2014168778A2 (ja) |
Families Citing this family (26)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9130234B2 (en) | 2011-06-22 | 2015-09-08 | Alveo Energy, Inc. | Stabilization of battery electrodes |
US9478798B2 (en) | 2012-03-28 | 2016-10-25 | Sharp Laboratories Of America, Inc. | Prussian blue analogue electrodes without zeolitic water content |
US20180191033A1 (en) | 2012-11-02 | 2018-07-05 | Natron Energy, Inc. | Electrolyte additives for electrochemical devices |
US9287589B2 (en) | 2013-04-10 | 2016-03-15 | Alveo Energy, Inc. | Cosolvent electrolytes for electrochemical devices |
US9099740B1 (en) * | 2014-10-24 | 2015-08-04 | Alveo Energy, Inc. | Homometallic cyanide-containing inorganic polymers and related compounds |
WO2016141013A1 (en) * | 2015-03-03 | 2016-09-09 | Ut-Battelle Llc | Electrolytes for supercapacitors |
US11198614B2 (en) | 2015-06-30 | 2021-12-14 | Natron Energy, Inc. | Transition metal cyanide coordination compounds having multiple reactions |
US9299981B1 (en) | 2015-06-30 | 2016-03-29 | Alveo Energy, Inc. | Surface-modified cyanide-based transition metal compounds |
KR20180084131A (ko) * | 2016-01-07 | 2018-07-24 | 케이디 이노베이션 리미티드 | 전기의 직접 생성 및 열 펌핑을 위한 전기화학 시스템 |
US11289700B2 (en) | 2016-06-28 | 2022-03-29 | The Research Foundation For The State University Of New York | KVOPO4 cathode for sodium ion batteries |
WO2018001430A1 (en) * | 2016-06-29 | 2018-01-04 | Science Ventures Denmark A/S | A supercapacitor and a method for expanding the voltage range of an aqueous electrolyte supercapacitor |
US10707531B1 (en) | 2016-09-27 | 2020-07-07 | New Dominion Enterprises Inc. | All-inorganic solvents for electrolytes |
JP6677193B2 (ja) * | 2017-02-24 | 2020-04-08 | トヨタ自動車株式会社 | 燃料電池電極用触媒インクに使用する溶媒の選定方法 |
US20180269538A1 (en) * | 2017-03-17 | 2018-09-20 | Kabushiki Kaisha Toshiba | Secondary battery, battery pack and vehicle |
FI130182B (en) * | 2017-03-17 | 2023-03-31 | Broadbit Batteries Oy | Electrolyte for use in super capacitor and high power battery |
US11431035B2 (en) | 2017-03-17 | 2022-08-30 | Kabushiki Kaisha Toshiba | Secondary battery, battery pack and vehicle |
EP3376583A1 (en) * | 2017-03-17 | 2018-09-19 | Kabushiki Kaisha Toshiba | Secondary battery, battery pack and vehicle |
JP6759173B2 (ja) * | 2017-09-20 | 2020-09-23 | 株式会社東芝 | 二次電池、電池パック及び車両 |
CN110034340B (zh) * | 2019-04-22 | 2021-11-02 | 中国科学院宁波材料技术与工程研究所 | 一种水系电解液及水系金属离子电池 |
US10529987B1 (en) | 2019-05-21 | 2020-01-07 | Natron Energy, Inc. | Transition metal cyanide coordination compounds having enhanced reaction potential |
US11283109B1 (en) * | 2020-06-11 | 2022-03-22 | Natron Energy, Inc. | Electrochemical cell with TMCCC electrodes in an acetonitrile solvent including a dinitrile additive |
CN113113674A (zh) * | 2021-04-10 | 2021-07-13 | 南开大学 | 一种抑制水系电池析氢反应的电解液添加剂 |
US20230299286A1 (en) * | 2022-03-15 | 2023-09-21 | Natron Energy, Inc. | Tmccc electrode |
US11522229B1 (en) * | 2022-04-01 | 2022-12-06 | Natron Energy, Inc. | Hierachical structure of transition metal cyanide coordination compounds |
US20230318047A1 (en) * | 2022-04-01 | 2023-10-05 | Natron Energy, Inc. | Hierachical structure of transition metal cyanide coordination compounds |
CN116885276A (zh) * | 2022-10-13 | 2023-10-13 | 太仓中科赛诺新能源科技有限公司 | 一种适用于普鲁士蓝类似物的共溶性电解液 |
Family Cites Families (29)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2445034A1 (fr) * | 1978-12-20 | 1980-07-18 | Accumulateurs Fixes | Matiere active positive reversible pour generateur electrochimique secondaire a electrolyte non aqueux |
JPS58121559A (ja) | 1982-01-14 | 1983-07-19 | Seiko Instr & Electronics Ltd | 電池 |
JPS603862A (ja) | 1983-06-22 | 1985-01-10 | Seiko Instr & Electronics Ltd | 二次電池 |
JPS6215770A (ja) * | 1985-07-11 | 1987-01-24 | Yamaguchi Univ | レドックス二次電池 |
JPS6324556A (ja) * | 1986-07-17 | 1988-02-01 | Tdk Corp | 2次電池 |
US5869207A (en) | 1996-12-09 | 1999-02-09 | Valence Technology, Inc. | Stabilized electrochemical cell |
US6277525B1 (en) | 1997-09-25 | 2001-08-21 | Canon Kabushiki Kaisha | Method for producing electrolyte and method for producing secondary battery |
JP3815087B2 (ja) * | 1998-10-26 | 2006-08-30 | 宇部興産株式会社 | 非水電解液及びそれを用いたリチウム二次電池 |
JP3860937B2 (ja) * | 1999-08-04 | 2006-12-20 | トヨタ自動車株式会社 | ヘキサシアノ鉄錯体およびそれを正極活物質として用いたリチウム二次電池 |
JP3565777B2 (ja) | 2000-10-25 | 2004-09-15 | Necトーキン株式会社 | ポリマー電池 |
US6924061B1 (en) * | 2001-02-13 | 2005-08-02 | The United States Of America As Represented By The Secretary Of Army | Nonflammable non-aqueous electrolyte and non-aqueous electrolyte cells comprising the same |
US7968235B2 (en) * | 2003-07-17 | 2011-06-28 | Uchicago Argonne Llc | Long life lithium batteries with stabilized electrodes |
JP4635473B2 (ja) * | 2004-05-13 | 2011-02-23 | ソニー株式会社 | 光電変換素子の製造方法及び半導体電極の製造方法 |
US7927742B2 (en) | 2004-10-29 | 2011-04-19 | Medtronic, Inc. | Negative-limited lithium-ion battery |
US8652692B2 (en) * | 2005-11-23 | 2014-02-18 | Polyplus Battery Company | Li/Air non-aqueous batteries |
CA2552282A1 (fr) | 2006-07-18 | 2008-01-18 | Hydro Quebec | Materiau multi-couches a base de lithium vif, procedes de preparation et applications dans les generateurs electrochimiques |
FR2920255B1 (fr) | 2007-08-24 | 2009-11-13 | Commissariat Energie Atomique | Generateur electrochimique au lithium fonctionnant avec un electrolyte aqueux. |
JP4453049B2 (ja) * | 2007-10-12 | 2010-04-21 | トヨタ自動車株式会社 | 二次電池の製造方法 |
CN101855770A (zh) | 2007-10-25 | 2010-10-06 | 应用材料股份有限公司 | 大量制造薄膜电池的方法 |
US20100221596A1 (en) | 2009-02-06 | 2010-09-02 | Huggins Robert A | Systems, methods of manufacture and use involving lithium and/or hydrogen for energy-storage applications |
US8308971B1 (en) | 2011-06-09 | 2012-11-13 | Wildcat Discovery Technologies, Inc. | Materials for battery electrolytes and methods for use |
US9130234B2 (en) | 2011-06-22 | 2015-09-08 | Alveo Energy, Inc. | Stabilization of battery electrodes |
US8951673B2 (en) | 2011-06-22 | 2015-02-10 | The Board Of Trustees Of The Leland Stanford Junior University | High rate, long cycle life battery electrode materials with an open framework structure |
US9029015B2 (en) | 2011-08-31 | 2015-05-12 | The Board Of Trustees Of The Leland Stanford Junior University | High rate, long cycle life electrochemical energy storage devices |
US9379368B2 (en) * | 2011-07-11 | 2016-06-28 | California Institute Of Technology | Electrochemical systems with electronically conductive layers |
CN102522553A (zh) | 2011-12-31 | 2012-06-27 | 武汉大学 | 一类钠离子电池正极材料 |
US9559358B2 (en) | 2012-03-28 | 2017-01-31 | Sharp Laboratories Of America, Inc. | Alkali and alkaline-earth ion batteries with hexacyanometallate cathode and non-metal anode |
WO2013157660A1 (en) | 2012-04-17 | 2013-10-24 | Sharp Kabushiki Kaisha | Alkali and alkaline-earth ion batteries with hexacyanometallate cathode and non-metal anode |
US9287589B2 (en) | 2013-04-10 | 2016-03-15 | Alveo Energy, Inc. | Cosolvent electrolytes for electrochemical devices |
-
2014
- 2014-03-31 US US14/231,571 patent/US9287589B2/en active Active
- 2014-03-31 WO PCT/US2014/032430 patent/WO2014168778A2/en active Application Filing
- 2014-03-31 CN CN201480020748.6A patent/CN105122518B/zh active Active
- 2014-03-31 EP EP14783421.2A patent/EP2997615B1/en active Active
- 2014-03-31 KR KR1020157032222A patent/KR102196785B1/ko active IP Right Grant
- 2014-03-31 JP JP2016507559A patent/JP6486901B2/ja active Active
- 2014-03-31 AU AU2014251301A patent/AU2014251301B2/en active Active
-
2016
- 2016-02-02 US US15/013,922 patent/US9876255B2/en active Active
- 2016-03-06 US US15/062,177 patent/US20160233551A1/en not_active Abandoned
- 2016-03-06 US US15/062,184 patent/US9893382B2/en active Active
- 2016-03-06 US US15/062,171 patent/US9972867B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
US20160233551A1 (en) | 2016-08-11 |
EP2997615B1 (en) | 2017-09-27 |
US20160190588A1 (en) | 2016-06-30 |
US20140308544A1 (en) | 2014-10-16 |
JP2016519842A (ja) | 2016-07-07 |
KR20150143635A (ko) | 2015-12-23 |
WO2014168778A2 (en) | 2014-10-16 |
AU2014251301A1 (en) | 2015-10-29 |
US20160156023A1 (en) | 2016-06-02 |
US9972867B2 (en) | 2018-05-15 |
KR102196785B1 (ko) | 2020-12-31 |
US9876255B2 (en) | 2018-01-23 |
AU2014251301B2 (en) | 2018-12-13 |
US20160190629A1 (en) | 2016-06-30 |
EP2997615A2 (en) | 2016-03-23 |
CN105122518B (zh) | 2018-10-26 |
WO2014168778A3 (en) | 2015-08-06 |
US9893382B2 (en) | 2018-02-13 |
US9287589B2 (en) | 2016-03-15 |
CN105122518A (zh) | 2015-12-02 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6486901B2 (ja) | 電気化学デバイスのための共溶媒電解質 | |
Blanc et al. | Scientific challenges for the implementation of Zn-ion batteries | |
Huang et al. | Recent progress of rechargeable batteries using mild aqueous electrolytes | |
Deng et al. | The current state of aqueous Zn-based rechargeable batteries | |
Shin et al. | A review on mechanistic understanding of MnO2 in aqueous electrolyte for electrical energy storage systems | |
Kasiri et al. | Mixed copper-zinc hexacyanoferrates as cathode materials for aqueous zinc-ion batteries | |
Ming et al. | Zinc-ion batteries: Materials, mechanisms, and applications | |
Fang et al. | Recent advances in aqueous zinc-ion batteries | |
Zhang et al. | Rechargeable aqueous Zn–V2O5 battery with high energy density and long cycle life | |
Fernández-Ropero et al. | Electrochemical characterization of NaFe2 (CN) 6 Prussian blue as positive electrode for aqueous sodium-ion batteries | |
US8951673B2 (en) | High rate, long cycle life battery electrode materials with an open framework structure | |
EP2752925B1 (en) | Use of a positive electrode material in a sodium battery, and sodium battery comprising said positive electrode active material | |
US9466853B2 (en) | High energy density aluminum battery | |
CN103703602B (zh) | 电化学能存储装置和用于该装置的活性物质及其制造方法 | |
US20140220392A1 (en) | Prussian Blue Analogue Anodes for Aqueous Electrolyte Batteries | |
US10862168B2 (en) | Electrolyte additives for electrochemical devices | |
KR101765941B1 (ko) | 침전법을 이용한 산화망간/탄소 복합체의 제조방법, 상기 방법으로 제조된 산화망간/탄소 복합체 및 상기 복합체를 포함하는 리튬/공기 이차전지 | |
US20140076730A1 (en) | Method and apparatus for extracting energy and metal from seawater electrodes | |
Li et al. | Metal–air batteries: a review on current status and future applications | |
JP5215146B2 (ja) | リチウム空気二次電池及びリチウム空気二次電池の製造方法 | |
Vardhini et al. | Polyimide-Based Aqueous Potassium Energy Storage Systems Using Concentrated WiSE Electrolyte | |
Zhang et al. | Aqueous organic anode//iodine cascadable battery with ultra-long lifespan, high energy and power density | |
WO2024031134A1 (en) | Aqueous electrochemical devices and preparation method thereof | |
Wang et al. | Aqueous Electrolytic Zinc-Manganese Dioxide Batteries | |
De Luna et al. | 2d Dioxonium Vanadium Oxide: A Novel and Highly Stable Cathode Material for Aqueous Rechargeable Zinc-Ion Batteries |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20170331 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20180221 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20180313 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20180613 |
|
A601 | Written request for extension of time |
Free format text: JAPANESE INTERMEDIATE CODE: A601 Effective date: 20180810 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20180913 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20190122 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20190220 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6486901 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
S533 | Written request for registration of change of name |
Free format text: JAPANESE INTERMEDIATE CODE: R313533 |
|
R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |