JP6434747B2 - 洗浄剤組成物 - Google Patents
洗浄剤組成物 Download PDFInfo
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- JP6434747B2 JP6434747B2 JP2014176284A JP2014176284A JP6434747B2 JP 6434747 B2 JP6434747 B2 JP 6434747B2 JP 2014176284 A JP2014176284 A JP 2014176284A JP 2014176284 A JP2014176284 A JP 2014176284A JP 6434747 B2 JP6434747 B2 JP 6434747B2
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- 239000001866 hydroxypropyl methyl cellulose Substances 0.000 description 1
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- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 1
- UFVKGYZPFZQRLF-UHFFFAOYSA-N hydroxypropyl methyl cellulose Chemical compound OC1C(O)C(OC)OC(CO)C1OC1C(O)C(O)C(OC2C(C(O)C(OC3C(C(O)C(O)C(CO)O3)O)C(CO)O2)O)C(CO)O1 UFVKGYZPFZQRLF-UHFFFAOYSA-N 0.000 description 1
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Description
(A)アニオン界面活性剤の1種又は2種以上と、
(B)下記一般式(1)又は(2)
(RCOはイソステアリン酸残基、R1、R2はそれぞれ独立して水素原子、−CH2COOM又は−CH2CH2COOMを表す。但し、R1、R2は同時に水素原子となることはなく、ここでMは水素原子、アルカリ金属、有機アミン類を表す。)
(RCOはイソステアリン酸残基、R3、R4はそれぞれ独立して水素原子、−CH2COOM又は−CH2CH2COOMを表す。但し、R3、R4は同時に水素原子となることはなく、ここでMは水素原子、アルカリ金属、有機アミン類を表す。)で表されるイミダゾリン系両性界面活性剤と(C)(B)成分以外の両性界面活性剤を含有することにより、上記要件を満たす洗浄剤組成物が得られることを見出し、本発明を完成させた。
本発明に使用される(A)成分のアニオン界面活性剤としては、硫酸エステル系アニオン界面活性剤、アミノ酸系アニオン界面活性剤、リン酸エステル系アニオン界面活性剤、カルボン酸系アニオン界面活性剤、スルホン酸系アニオン界面活性剤が挙げられ、具体的には、アルキル硫酸塩(ラウリル硫酸塩等)、ポリオキシアルキレンアルキルエーテル硫酸塩(ポリオキシエチレン(3)ラウリルエーテル硫酸塩等)、ポリオキシアルキレンアルキルモノアルキロールアミド硫酸塩(ポリオキシエチレン(3)ヤシ脂肪酸モノエタノールアミド硫酸塩等)、アシルグリシネート(ラウロイルグリシン塩等)、アシルサルコシンネート(ココイルサルコシン塩等)、アシルアラニネート(ラウロイルアラニン塩等)、アシルメチルアラニネート(ココイルメチルアラニン塩等)、アシルタウレート(ココイルタウリン塩等)、アシルメチルタウレート(ココイルメチルタウリン塩等)、アシルグルタメート(ココイルグルタミン酸塩等)、アルキルリン酸エステル塩(ラウリルリン酸塩等)、ポリオキシアルキレンアルキルエーテルリン酸エステル塩(ポリオキシエチレン(4)ラウリルエーテルリン酸塩等)、高級脂肪酸塩(ラウリン酸塩等)、ポリオキシエチレンアルキルエーテルカルボン酸塩(ポリオキシエチレン(4)ラウリルエーテル酢酸塩等)、オレフィン(C14−16)スルホン酸塩、アルキルスルホコハク酸塩(スルホコハク酸ラウリル塩等)、ポリオキシエチレンスルホコハク酸アルキル塩(ポリオキシエチレン(3)スルホコハク酸ラウリル塩等)、アルキルエチルエステルスルホン酸塩(ココイルイセチオン酸塩等)などが挙げられ、炭素数8〜18のアルキル基、特に炭素数10〜16のアルキル基が好ましく、これらの中でもポリオキシエチレン(3)ラウリルエーテル硫酸塩、ココイルメチルタウリン塩、ココイルグルタミン酸塩、高級脂肪酸塩が特に好適に用いられる。本発明では、これらのアニオン界面活性剤の中から1種又は2種以上を任意に用いることができる。
健康黒髪にブリーチ処理を30分行った損傷毛髪束(20g×20cm)用いて、毛髪洗浄剤1.0gを塗布し、30秒間泡立て、その後すすいでタオルドライ後ドライヤーで乾燥した時の洗浄時の使用感(泡立ち、泡質(細かさ)、すべり性)、すすぎ時の使用感(きしみ感の無さ)と乾燥後の感触(滑らかさ)及び乾燥翌日の感触(しっとり感)を10名の専門パネラーにて、官能的に比較し、下記基準で評価した。
◎:良いと答えた人が9人以上の場合
○:良いと答えた人が6〜8人の場合
△:良いと答えた人が3〜5人の場合
×:良いと答えた人が2人以下の場合
上記評価(洗浄時、すすぎ時の使用感と乾燥後、乾燥翌日の感触)の結果をポイント制(◎:3ポイント、○:2ポイント、△:1ポイント、×:0ポイント)にしてその合計より、下記基準で評価した。ポイントの多いものが良い総合評価となる。
◎:14ポイント以上
○:10〜13ポイント
△:5〜9ポイント
×:4ポイント以下
両手を水で濡らした後、洗浄剤組成物1mlを手に採って10秒間両手を擦り合わせて、洗浄時の使用感(泡立ちの良さ)、続けて、流水で手指に付いて泡や洗液をすすぎ流し、すすぎ時の使用感(滑らかさ)を、タオルドライ後、手肌の感触から乾燥後の感触(しっとり感)を10名の専門パネラーにて、官能的に下記基準で評価した。
◎:良いと答えた人が9人以上の場合
○:良いと答えた人が6〜8人の場合
△:良いと答えた人が3〜5人の場合
×:良いと答えた人が2人以下の場合
上記評価(泡立ちの良さ、すすぎ時の滑らかさ、洗浄後のしっとり感)の結果をポイント制(◎:3ポイント、○:2ポイント、△:1ポイント、×:0ポイント)にしてその合計より、下記基準で評価した。
ポイントの多いものが良い総合評価となる。
◎:8ポイント以上
○:6〜7ポイント
△:3〜5ポイント
×:2ポイント以下
Claims (4)
- (A)アニオン界面活性剤の1種又は2種以上、
(B)下記一般式(1)又は(2)
(RCOはイソステアリン酸残基、R1、R2はそれぞれ独立して水素原子、−CH2COOM又は−CH2CH2COOMを表す。但し、R1、R2は同時に水素原子となることはなく、ここでMは水素原子、アルカリ金属、有機アミン類を表す。)
(RCOはイソステアリン酸残基、R3、R4はそれぞれ独立して水素原子、−CH2COOM又は−CH2CH2COOMを表す。但し、R3、R4は同時に水素原子となることはなく、ここでMは水素原子、アルカリ金属、有機アミン類を表す。)で表されるイミダゾリン系両性界面活性剤の1種又は2種以上、および
(C)(B)成分以外の両性界面活性剤、を含有してなる洗浄剤組成物。 - 洗浄剤組成物全量中に、前記(A)成分を1〜30質量%、(B)成分を1〜20質量%および(C)成分を0.1〜10質量%含有してなる請求項1記載の洗浄剤組成物。
- 更に、(D)非イオン界面活性剤を含有してなる請求項1又は2に記載の洗浄剤組成物。
- 更に、(E)多価アルコールを含有してなる請求項1〜3のいずれかに記載の洗浄剤組成物。
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