JP6421248B2 - 帯電防止剤の存在下での重合方法 - Google Patents
帯電防止剤の存在下での重合方法 Download PDFInfo
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- JP6421248B2 JP6421248B2 JP2017546978A JP2017546978A JP6421248B2 JP 6421248 B2 JP6421248 B2 JP 6421248B2 JP 2017546978 A JP2017546978 A JP 2017546978A JP 2017546978 A JP2017546978 A JP 2017546978A JP 6421248 B2 JP6421248 B2 JP 6421248B2
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- B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
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- C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
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- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/07—High density, i.e. > 0.95 g/cm3
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- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
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- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/18—Bulk density
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- C08K2201/00—Specific properties of additives
- C08K2201/017—Additives being an antistatic agent
Description
密度は、2mm厚さの圧縮成形プラークを利用してDIN EN ISO 1183−1:2004、方法A(イマージョン(Immersion))に従って決定した。圧縮成形プラークは、規定された熱履歴で製造した:8分間180℃、20MPaで圧着後、30分間沸騰水で結晶化される。
−非常に悪い操作性:通常、2時間周期内に回避できない停止を誘導する、非常に不安定な反応器の挙動。
−悪い操作性:通常、12時間周期内に回避できない停止を誘導する、不安定な反応器の挙動。
−中度の操作性:依然として不安定な反応器の挙動であるが、通常、停止は必要ではない。
−優れた操作性:わずかな変動のみを有した安定した反応器の挙動。
−非常に優れた操作性:変動ない安定した反応器の挙動。
ポリエチレンを図1に示したように、2つの相互連結された反応ゾーンを有したマルチゾーン循環反応器及び流動床反応器のカスケードで製造した。
比較例Aで使用された流動床反応器及びマルチゾーン循環反応器のカスケードで、比較例Aの組成と組成の異なるポリエチレン等級を製造し、第1重合反応器で得られたポリエチレンは、比較例Aの第1重合反応器で得られたポリエチレンより低い溶融流量を有した。
比較例Bの重合を繰り返したが、100ppmのポリグリコール(Polyglykol)PE K 270(3:1のエチレンオキシド/プロピレンオキシド比を有し、ドイツフランクフルトのクラリアントエスイ(Clariant SE)のジオルによって開始された線状ランダムエチレンオキシド/プロピレンオキシドコポリマー)を80ppmのAtmer 163の代わりに帯電防止剤として第1反応器に供給した。5kg/hの流量の液体プロパンを第1反応器内にポリグリコール PE−K 270を導入するめの供給ストリームとして利用した。また、50ppmのポリグリコール PE−K 270を90ppmのAtmer 163及び20ppmのCithrol GMS 40−PW−(GD)の代わりに帯電防止剤として第2反応器に供給した。5kg/hの流量の液体プロパンを第2反応器内にポリグリコール PE−K 270を導入するための供給ストリームとして利用した。また、比較例Bと同一の流動床反応器でのエチレン濃度を有するために第1反応器への触媒供給を6.7g/hに減少させた。
実施例1の重合を繰り返したが、帯電防止剤ポリグリコール PE―K 270をライン9aを介して第1反応器のポリマー床に供給した。5kg/hの流量の液体プロパンを第1反応器内にポリグリコール PE K―270を導入するための供給ストリームとして利用した。
Claims (5)
- 前記帯電防止剤は、固体ポリマー粒子の密度が少なくとも30kg/m3である反応器の部分に帯電防止剤を供給することによって気相重合反応器内に導入される、請求項1に記載の方法。
- 前記帯電防止剤は、液体炭化水素の供給ストリームによって重合反応器内に導入され、反応器内に導入された混合ストリームで帯電防止剤対液体炭化水素の重量比は、1:5000〜1:10の範囲である、請求項1または2に記載の方法。
- 前記重合は、流動床反応器及びマルチゾーン循環反応器を含む重合反応器カスケードで行われ、マルチゾーン循環反応器で成長するポリマーは、迅速な流動化または移送条件下で第1重合ゾーンを通って上方に流動し、前記第1重合ゾーンを出て第2重合ゾーンに入り、このゾーンを通って粒子は、重力の作用下で下方に流動し、前記ダウンカマー(downcomer)を出てライザーに再び入って、ポリマーの循環を確立し、前記流動床反応器は、マルチゾーン循環反応器の上流に配置される、請求項1〜3のいずれか一項に記載の方法。
- 前記ポリオレフィンは、エチレンを単独重合するとか、エチレン及び最大20重量%のC3−C8−1−アルケンを共重合して製造されたポリエチレンである、請求項1〜4のいずれか一項に記載の方法。
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
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EP15161098 | 2015-03-26 | ||
EP15161098.7 | 2015-03-26 | ||
EP15200102.0 | 2015-12-15 | ||
EP15200102 | 2015-12-15 | ||
PCT/EP2016/056340 WO2016150997A1 (en) | 2015-03-26 | 2016-03-23 | Polymerization process in the presence of antistatic agent |
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JP2018512482A JP2018512482A (ja) | 2018-05-17 |
JP6421248B2 true JP6421248B2 (ja) | 2018-11-07 |
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JP2017546978A Active JP6421248B2 (ja) | 2015-03-26 | 2016-03-23 | 帯電防止剤の存在下での重合方法 |
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US (1) | US9932465B1 (ja) |
EP (1) | EP3274376B1 (ja) |
JP (1) | JP6421248B2 (ja) |
KR (1) | KR101851919B1 (ja) |
CN (1) | CN107406537B (ja) |
BR (1) | BR112017018429B1 (ja) |
RU (1) | RU2653535C1 (ja) |
SG (1) | SG11201705983VA (ja) |
WO (1) | WO2016150997A1 (ja) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
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US10604645B2 (en) | 2015-12-21 | 2020-03-31 | Basell Poliolefine Italia S.R.L. | Olefin polymerization process in the presence of antistatic composition |
CN109923130B (zh) | 2016-11-10 | 2020-05-15 | 巴塞尔聚烯烃股份有限公司 | 包含上升管装置和降液管的气相反应器中的烯烃聚合方法 |
US10570278B2 (en) * | 2016-11-24 | 2020-02-25 | Basell Polyolefine Gmbh | Polyethylene composition for blow molding having high swell ratio and impact resistance |
PT3570969T (pt) | 2017-01-20 | 2021-06-07 | Basell Poliolefine Italia Srl | Método para alimentar um fluido a um reator de polimerização de fase gasosa |
CN109422947B (zh) * | 2017-08-29 | 2021-03-09 | 中国石油天然气股份有限公司 | 多峰聚乙烯及其制备方法 |
WO2019059607A1 (ko) | 2017-09-20 | 2019-03-28 | 타이코에이엠피 주식회사 | 인쇄회로기판 어셈블리 |
EP3524343A1 (en) * | 2018-02-07 | 2019-08-14 | Basell Polyolefine GmbH | Process for polymerizing olefins in the gas-phase |
KR20220162726A (ko) * | 2020-03-31 | 2022-12-08 | 다우 글로벌 테크놀로지스 엘엘씨 | 방오제 및 공정 |
KR20240008900A (ko) | 2021-05-18 | 2024-01-19 | 바젤 폴리올레핀 게엠베하 | 분석용 기체 샘플을 회수하는 단계를 포함하는 올레핀 중합체의 제조 공정 |
EP4335877A1 (en) | 2022-09-09 | 2024-03-13 | Basell Polyolefine GmbH | Continuous olefin polymerization process in the presence of an antistatic agent |
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US3242150A (en) | 1960-03-31 | 1966-03-22 | Phillips Petroleum Co | Method and apparatus for the recovery of solid olefin polymer from a continuous path reaction zone |
US3248179A (en) | 1962-02-26 | 1966-04-26 | Phillips Petroleum Co | Method and apparatus for the production of solid polymers of olefins |
JPS5964604A (ja) * | 1982-10-06 | 1984-04-12 | Sumitomo Chem Co Ltd | ポリオレフインの製造方法 |
DE3600610A1 (de) * | 1986-01-11 | 1987-07-16 | Basf Ag | Einsatz von antistatika zur vermeidung von belagbildung bei der herstellung von ethylenpolymerisaten in gasphasenreaktoren |
CA1318740C (en) | 1987-04-17 | 1993-06-01 | Simon Hsiao-Pao Yu | Copolymers of ethylene oxide as antistatic additives |
JPH06500817A (ja) | 1990-09-13 | 1994-01-27 | ザ ビー.エフ.グッドリッチ カンパニー | エチレンオキシドコポリマーを含む帯電防止性オレフィンポリマー組成物及びその製造方法 |
EP0555197A3 (en) | 1992-01-29 | 1993-11-18 | Monsanto Co | Antistatic agent for thermoplastic polymers |
IT1262933B (it) | 1992-01-31 | 1996-07-22 | Montecatini Tecnologie Srl | Processo per la polimerizzazione in fase gas di alfa-olefine |
IT1275573B (it) | 1995-07-20 | 1997-08-07 | Spherilene Spa | Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine |
TR200000617T1 (tr) | 1998-07-08 | 2000-10-23 | Montell Tecnology Company Bv | Gazı-fazı polimerizasyonu için işlem ve aygıt. |
KR101167538B1 (ko) | 2003-05-29 | 2012-07-20 | 바셀 폴리올레핀 이탈리아 에스.알.엘 | 촉매 성분의 제조 방법 및 그로부터 수득된 성분들 |
CN1918197B (zh) * | 2004-02-13 | 2010-05-26 | 托塔尔石油化学产品研究弗吕公司 | 在防垢剂存在下的烯烃聚合方法 |
JP2009292964A (ja) * | 2008-06-06 | 2009-12-17 | Prime Polymer Co Ltd | オレフィン重合体の製造方法 |
US20110065846A1 (en) * | 2009-09-11 | 2011-03-17 | Abel Grosjean | Olefin polymerisation process |
EP2475690B1 (en) | 2009-09-11 | 2014-01-08 | Basell Poliolefine Italia S.r.l. | Process for the gas-phase polymerization of olefins |
KR101465916B1 (ko) * | 2010-07-30 | 2014-11-26 | 토탈 리서치 앤드 테크놀로지 펠루이 | 폴리올레핀 제조 방법 |
EP2722347A1 (en) | 2012-10-22 | 2014-04-23 | Basell Polyolefine GmbH | Multistage process for the polymerization of olefins |
BR112015020142B1 (pt) | 2013-02-27 | 2020-07-07 | Basell Polyolefine Gmbh | processos para polietileno e composições deste material |
EP2813520A1 (en) * | 2013-06-11 | 2014-12-17 | Basell Polyolefine GmbH | Polymerization process in the presence of an antistatically acting composition |
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- 2016-03-23 BR BR112017018429-0A patent/BR112017018429B1/pt active IP Right Grant
- 2016-03-23 JP JP2017546978A patent/JP6421248B2/ja active Active
- 2016-03-23 SG SG11201705983VA patent/SG11201705983VA/en unknown
- 2016-03-23 KR KR1020177028717A patent/KR101851919B1/ko active IP Right Grant
- 2016-03-23 US US15/560,424 patent/US9932465B1/en active Active
- 2016-03-23 WO PCT/EP2016/056340 patent/WO2016150997A1/en active Application Filing
- 2016-03-23 EP EP16714319.7A patent/EP3274376B1/en active Active
- 2016-03-23 CN CN201680016297.8A patent/CN107406537B/zh active Active
- 2016-03-23 RU RU2017134074A patent/RU2653535C1/ru active
Also Published As
Publication number | Publication date |
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BR112017018429B1 (pt) | 2022-04-12 |
WO2016150997A1 (en) | 2016-09-29 |
KR101851919B1 (ko) | 2018-04-24 |
SG11201705983VA (en) | 2017-08-30 |
RU2653535C1 (ru) | 2018-05-11 |
CN107406537A (zh) | 2017-11-28 |
EP3274376B1 (en) | 2018-06-20 |
US20180072876A1 (en) | 2018-03-15 |
JP2018512482A (ja) | 2018-05-17 |
KR20170121296A (ko) | 2017-11-01 |
EP3274376A1 (en) | 2018-01-31 |
CN107406537B (zh) | 2019-08-20 |
US9932465B1 (en) | 2018-04-03 |
BR112017018429A2 (pt) | 2018-04-17 |
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