JP6416181B2 - タイヤトレッド及びその製造方法 - Google Patents
タイヤトレッド及びその製造方法 Download PDFInfo
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- JP6416181B2 JP6416181B2 JP2016245711A JP2016245711A JP6416181B2 JP 6416181 B2 JP6416181 B2 JP 6416181B2 JP 2016245711 A JP2016245711 A JP 2016245711A JP 2016245711 A JP2016245711 A JP 2016245711A JP 6416181 B2 JP6416181 B2 JP 6416181B2
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- Prior art keywords
- silica
- tread
- bar
- rubber
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000004519 manufacturing process Methods 0.000 title description 17
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 251
- 239000000377 silicon dioxide Substances 0.000 claims description 121
- 229920001971 elastomer Polymers 0.000 claims description 56
- 239000005060 rubber Substances 0.000 claims description 56
- 238000004073 vulcanization Methods 0.000 claims description 30
- 239000000203 mixture Substances 0.000 claims description 26
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- 239000002245 particle Substances 0.000 claims description 17
- 238000010521 absorption reaction Methods 0.000 claims description 12
- 239000006229 carbon black Substances 0.000 claims description 10
- 238000000034 method Methods 0.000 claims description 10
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- 230000003712 anti-aging effect Effects 0.000 claims description 7
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 claims description 6
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- 239000004594 Masterbatch (MB) Substances 0.000 claims description 4
- 238000001125 extrusion Methods 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 238000007670 refining Methods 0.000 claims description 4
- 229920000181 Ethylene propylene rubber Polymers 0.000 claims description 3
- 229920000459 Nitrile rubber Polymers 0.000 claims description 3
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- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims description 2
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- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
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- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 3
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- 239000011787 zinc oxide Substances 0.000 description 3
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- SZAQZZKNQILGPU-UHFFFAOYSA-N 2-[1-(2-hydroxy-3,5-dimethylphenyl)-2-methylpropyl]-4,6-dimethylphenol Chemical compound C=1C(C)=CC(C)=C(O)C=1C(C(C)C)C1=CC(C)=CC(C)=C1O SZAQZZKNQILGPU-UHFFFAOYSA-N 0.000 description 2
- AKQWHIMDQYDQSR-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylthiirane-2-carboxylate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C1(C)CS1 AKQWHIMDQYDQSR-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 206010028980 Neoplasm Diseases 0.000 description 2
- 235000019482 Palm oil Nutrition 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 2
- FZWLAAWBMGSTSO-UHFFFAOYSA-N Thiazole Chemical compound C1=CSC=N1 FZWLAAWBMGSTSO-UHFFFAOYSA-N 0.000 description 2
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- 201000011510 cancer Diseases 0.000 description 2
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- 239000012990 dithiocarbamate Substances 0.000 description 2
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- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 2
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- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- JLKZUNOWPPEBPX-UHFFFAOYSA-N zinc;3h-1,3-benzothiazole-2-thione Chemical compound [Zn+2].C1=CC=C2SC(=S)NC2=C1 JLKZUNOWPPEBPX-UHFFFAOYSA-N 0.000 description 1
- NEYNBSGIXOOZGZ-UHFFFAOYSA-L zinc;butoxymethanedithioate Chemical compound [Zn+2].CCCCOC([S-])=S.CCCCOC([S-])=S NEYNBSGIXOOZGZ-UHFFFAOYSA-L 0.000 description 1
- AUMBZPPBWALQRO-UHFFFAOYSA-L zinc;n,n-dibenzylcarbamodithioate Chemical compound [Zn+2].C=1C=CC=CC=1CN(C(=S)[S-])CC1=CC=CC=C1.C=1C=CC=CC=1CN(C(=S)[S-])CC1=CC=CC=C1 AUMBZPPBWALQRO-UHFFFAOYSA-L 0.000 description 1
- JGSUMMPGKPITGK-UHFFFAOYSA-L zinc;n,n-dipentylcarbamodithioate Chemical compound [Zn+2].CCCCCN(C([S-])=S)CCCCC.CCCCCN(C([S-])=S)CCCCC JGSUMMPGKPITGK-UHFFFAOYSA-L 0.000 description 1
- QUPAJUAGQJQKQE-UHFFFAOYSA-L zinc;n,n-dipropylcarbamodithioate Chemical compound [Zn+2].CCCN(C([S-])=S)CCC.CCCN(C([S-])=S)CCC QUPAJUAGQJQKQE-UHFFFAOYSA-L 0.000 description 1
- LAGTXXPOZSLGSF-UHFFFAOYSA-L zinc;n-butyl-n-phenylcarbamodithioate Chemical compound [Zn+2].CCCCN(C([S-])=S)C1=CC=CC=C1.CCCCN(C([S-])=S)C1=CC=CC=C1 LAGTXXPOZSLGSF-UHFFFAOYSA-L 0.000 description 1
- KMNUDJAXRXUZQS-UHFFFAOYSA-L zinc;n-ethyl-n-phenylcarbamodithioate Chemical compound [Zn+2].CCN(C([S-])=S)C1=CC=CC=C1.CCN(C([S-])=S)C1=CC=CC=C1 KMNUDJAXRXUZQS-UHFFFAOYSA-L 0.000 description 1
- XGTKIWKDACDPMK-UHFFFAOYSA-L zinc;n-hexadecyl-n-propan-2-ylcarbamodithioate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCN(C(C)C)C([S-])=S.CCCCCCCCCCCCCCCCN(C(C)C)C([S-])=S XGTKIWKDACDPMK-UHFFFAOYSA-L 0.000 description 1
- XIRMSEKPPCLFNS-UHFFFAOYSA-L zinc;n-octadecyl-n-propan-2-ylcarbamodithioate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCCN(C(C)C)C([S-])=S.CCCCCCCCCCCCCCCCCCN(C(C)C)C([S-])=S XIRMSEKPPCLFNS-UHFFFAOYSA-L 0.000 description 1
- YBKBEKGVHFHCRI-UHFFFAOYSA-L zinc;piperidine-1-carbodithioate Chemical compound [Zn+2].[S-]C(=S)N1CCCCC1.[S-]C(=S)N1CCCCC1 YBKBEKGVHFHCRI-UHFFFAOYSA-L 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
- B60C11/14—Anti-skid inserts, e.g. vulcanised into the tread band
- B60C11/18—Anti-skid inserts, e.g. vulcanised into the tread band of strip form, e.g. metallic combs, rubber strips of different wear resistance
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
- B60C11/0041—Tyre tread bands; Tread patterns; Anti-skid inserts comprising different tread rubber layers
- B60C11/005—Tyre tread bands; Tread patterns; Anti-skid inserts comprising different tread rubber layers with cap and base layers
- B60C11/0058—Tyre tread bands; Tread patterns; Anti-skid inserts comprising different tread rubber layers with cap and base layers with different cap rubber layers in the axial direction
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/16—Articles comprising two or more components, e.g. co-extruded layers
- B29C48/18—Articles comprising two or more components, e.g. co-extruded layers the components being layers
- B29C48/19—Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their edges
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D30/00—Producing pneumatic or solid tyres or parts thereof
- B29D30/06—Pneumatic tyres or parts thereof (e.g. produced by casting, moulding, compression moulding, injection moulding, centrifugal casting)
- B29D30/52—Unvulcanised treads, e.g. on used tyres; Retreading
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C11/00—Tyre tread bands; Tread patterns; Anti-skid inserts
- B60C11/0041—Tyre tread bands; Tread patterns; Anti-skid inserts comprising different tread rubber layers
- B60C11/005—Tyre tread bands; Tread patterns; Anti-skid inserts comprising different tread rubber layers with cap and base layers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/29—Compounds containing one or more carbon-to-nitrogen double bonds
- C08K5/31—Guanidine; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/39—Thiocarbamic acids; Derivatives thereof, e.g. dithiocarbamates
- C08K5/40—Thiurams, i.e. compounds containing groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
- C08K9/06—Ingredients treated with organic substances with silicon-containing compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29D—PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE
- B29D30/00—Producing pneumatic or solid tyres or parts thereof
- B29D30/06—Pneumatic tyres or parts thereof (e.g. produced by casting, moulding, compression moulding, injection moulding, centrifugal casting)
- B29D30/52—Unvulcanised treads, e.g. on used tyres; Retreading
- B29D30/66—Moulding treads on to tyre casings, e.g. non-skid treads with spikes
- B29D2030/667—Treads with antiskid properties, e.g. having special patterns or special rubber compositions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2021/00—Use of unspecified rubbers as moulding material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29K—INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D, RELATING TO MOULDING MATERIALS OR TO MATERIALS FOR MOULDS, REINFORCEMENTS, FILLERS OR PREFORMED PARTS, e.g. INSERTS
- B29K2709/00—Use of inorganic materials not provided for in groups B29K2703/00 - B29K2707/00, for preformed parts, e.g. for inserts
- B29K2709/08—Glass
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2030/00—Pneumatic or solid tyres or parts thereof
- B29L2030/002—Treads
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C19/00—Tyre parts or constructions not otherwise provided for
- B60C19/08—Electric-charge-dissipating arrangements
- B60C19/082—Electric-charge-dissipating arrangements comprising a conductive tread insert
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Tires In General (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Description
2)促進剤1:TT(チウラム系加硫促進剤)
3)促進剤2:DPG
4)シリカバー:表1の実施例及び比較例で製造したシリカバーを適用した。前記シリカバーの含量は、シリカバーの個数を通じて調節した。
*混/配合性能の点数表:1(非常に悪い)〜10(非常に良い)
2)吸水/排出性能は、配合後、ニーダーでの吸水/排出時間及び作業性を評価した。
*吸水/排出性能の点数表:1(非常に悪い)〜10(非常に良い)
3)グリップ性能は、前記ゴム組成物を使用してトレッド部を構成したサイズ280/640R18 Z207のタイヤを使用して、空気圧200kPaにし、テストドライバーがウェット路面の条件でサーキットコース(2km)を10回連続走行した後、走行毎のラップタイムを測定して、初期グリップ性能及びグリップ性能の持続性を評価した。
*グリップ性能の点数表:1(非常に悪い)〜10(非常に良い)
4)300%モジュラス、伸び率は、ISO 37の規格によって測定した。
5)摩耗度は、JIS K6264によって測定した。
110 トレッド部
111 キャップトレッド部
112 アンダートレッド部
120 シリカバー
121 シリカバーの上部
122 シリカバーの下部
Claims (12)
- タイヤ周方向に延びるシリカバーを含み、前記シリカバーの上部は路面に接地されるようにトレッドに露出され、
前記シリカバーは、トレッドの厚さ方向に上部と下部に互いに異なる粒子サイズのシリカが配列され、
前記シリカバーの上部には、粒径が1.5〜3.0μmであるシリカを含み、
前記シリカバーの下部には、粒径が3.5〜5.0μmであるシリカを含む、
タイヤトレッド。 - 前記シリカバーは、幅0.2〜30mm、高さ0.2〜30mmである、請求項1に記載のタイヤトレッド。
- 前記シリカバーとアンダートレッド部の間の角度が5〜90°である、請求項1に記載のタイヤトレッド。
- 前記シリカバーの上部はキャップトレッド部に位置し、
前記シリカバーの下部はアンダートレッド部に位置する、請求項1に記載のタイヤトレッド。 - 前記シリカバーの上部及び下部はキャップトレッド部に位置する、請求項1に記載のタイヤトレッド。
- 前記シリカバーは、原料ゴム100重量部、シリカ30〜180重量部、及び超微粒子カーボンブラック5〜50重量部からなるマスターバッチを用いて製造され、
前記超微粒子カーボンブラックは、ヨウ素吸着値が200〜1000mg/gであり、DBP吸油量が150〜800ml/100gである、請求項1に記載のタイヤトレッド。 - 前記シリカバーを含むトレッドは、キャップトレッド部とアンダートレッド部からなっており、
前記シリカバーを除いたキャップトレッド部は、
原料ゴム100重量部及びシリカ50〜80重量部を含む、請求項1に記載のタイヤトレッド。 - 前記シリカバーを含むトレッドは、キャップトレッド部とアンダートレッド部からなっており、
前記シリカバーを除いたアンダートレッド部は、
原料ゴム100重量部及びシリカ10〜20重量部を含む、請求項1に記載のタイヤトレッド。 - 前記原料ゴムは、ポリイソプレンゴム、ポリブタジエンゴム、共役ジエン芳香族ビニル共重合体、ニトリル共役ジエン共重合体、水素化ニトリルブタジエンゴム、オレフィンゴム、マレイン酸で変形されたエチレン−プロピレンゴム、ブチルゴム、イソブチレンと芳香族ビニルの共重合体、イソブチレンとジエンモノマーの共重合体、アクリルゴム、ハロゲン化ゴム、クロロプレンゴム及びこれらの混合物からなる群から選択されるいずれか1つである、請求項6乃至8のいずれかに記載のタイヤトレッド。
- 前記タイヤトレッドは、原料ゴム100重量部に対して、加硫剤0.5〜4.0重量部、加硫促進剤0.5〜2.0重量部、及び老化防止剤0.5〜2.0重量部をさらに含む、請求項6乃至8のいずれかに記載のタイヤトレッド。
- 請求項1に記載のタイヤトレッドはスリックタイヤのトレッドである、タイヤトレッド。
- シリカバーを製造するステップと、
タイヤトレッド組成物をバー状に精錬するステップと、
成形フレームにバー状に精錬されたタイヤトレッド組成物と、シリカバーとを交互に位置させるステップと、
押出工程を通じてトレッドを製造するステップとを含む、タイヤトレッドの製造方法であって、
前記シリカバーは、トレッドの厚さ方向に上部と下部に互いに異なる粒子サイズのシリカが配列され、
前記シリカバーの上部には、粒径が1.5〜3.0μmであるシリカを含み、
前記シリカバーの下部には、粒径が3.5〜5.0μmであるシリカを含む、
方法。
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JP7094450B2 (ja) | 2019-07-08 | 2022-07-01 | 三菱電機株式会社 | 回転電機の固定子、回転電機、回転電機の固定子の製造方法および回転電機の製造方法 |
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JP3361256B2 (ja) * | 1997-09-30 | 2003-01-07 | 住友ゴム工業株式会社 | 雪路用空気入りタイヤ |
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JP5626533B2 (ja) * | 2011-09-02 | 2014-11-19 | コニカミノルタ株式会社 | 画像形成装置 |
US20130296479A1 (en) * | 2012-05-03 | 2013-11-07 | Ppg Industries Ohio, Inc. | Rubber formulations including graphenic carbon particles |
KR101392733B1 (ko) * | 2012-11-29 | 2014-05-12 | 한국타이어 주식회사 | 타이어 사이드월용 고무 조성물 및 이를 이용하여 제조한 타이어 |
CN106164161B (zh) * | 2014-08-05 | 2018-05-11 | 住友橡胶工业株式会社 | 橡胶组合物与轮胎 |
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2016
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- 2016-12-19 JP JP2016245711A patent/JP6416181B2/ja not_active Expired - Fee Related
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2017
- 2017-01-03 US US15/397,047 patent/US20170240001A1/en not_active Abandoned
- 2017-01-31 EP EP17153960.4A patent/EP3208106B1/en active Active
- 2017-02-20 CN CN201710090293.0A patent/CN107099071B/zh active Active
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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JP7094450B2 (ja) | 2019-07-08 | 2022-07-01 | 三菱電機株式会社 | 回転電機の固定子、回転電機、回転電機の固定子の製造方法および回転電機の製造方法 |
Also Published As
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KR20170098444A (ko) | 2017-08-30 |
CN107099071A (zh) | 2017-08-29 |
EP3208106A1 (en) | 2017-08-23 |
CN107099071B (zh) | 2019-01-08 |
JP2017149407A (ja) | 2017-08-31 |
US20170240001A1 (en) | 2017-08-24 |
KR101787574B1 (ko) | 2017-10-19 |
EP3208106B1 (en) | 2018-12-05 |
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