JP6296981B2 - テトラフルオロプロペンをベースにした超臨界熱伝達流体 - Google Patents
テトラフルオロプロペンをベースにした超臨界熱伝達流体 Download PDFInfo
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- JP6296981B2 JP6296981B2 JP2014527716A JP2014527716A JP6296981B2 JP 6296981 B2 JP6296981 B2 JP 6296981B2 JP 2014527716 A JP2014527716 A JP 2014527716A JP 2014527716 A JP2014527716 A JP 2014527716A JP 6296981 B2 JP6296981 B2 JP 6296981B2
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- heat transfer
- transfer fluid
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- heat
- tetrafluoropropene
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B13/00—Compression machines, plants or systems, with reversible cycle
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K5/00—Heat-transfer, heat-exchange or heat-storage materials, e.g. refrigerants; Materials for the production of heat or cold by chemical reactions other than by combustion
- C09K5/02—Materials undergoing a change of physical state when used
- C09K5/04—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa
- C09K5/041—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems
- C09K5/044—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds
- C09K5/045—Materials undergoing a change of physical state when used the change of state being from liquid to vapour or vice versa for compression-type refrigeration systems comprising halogenated compounds containing only fluorine as halogen
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B30/00—Heat pumps
- F25B30/02—Heat pumps of the compression type
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/10—Components
- C09K2205/12—Hydrocarbons
- C09K2205/126—Unsaturated fluorinated hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2205/00—Aspects relating to compounds used in compression type refrigeration systems
- C09K2205/24—Only one single fluoro component present
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2400/00—General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
- F25B2400/12—Inflammable refrigerants
- F25B2400/121—Inflammable refrigerants using R1234
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/54—Improvements relating to the production of bulk chemicals using solvents, e.g. supercritical solvents or ionic liquids
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Mechanical Engineering (AREA)
- General Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Combustion & Propulsion (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Description
− 50から65%までのHFO−1234yfおよび35から50%までのHFC−134a、好ましくは53から58%までのHFO−1234yfおよび42から47%までのHFC−134a(例えば、およそ56%のHFO−1234yfおよび44%のHFC−134a);
− 15から90%までのHFO−1234yfおよび10から85%までのHFC−32;
− 90から99%までのHFO−1234yfおよび1から10%までのHFC−152a、好ましくは93から97%までのHFO−1234yfおよび3から7%までのHFC−152a(例えば、およそ95%のHFO−1234yfおよびおよそ5%のHFC−152a);
− 90から99%までのHFO−1234yfおよび1から10%までのHFC−125、好ましくは93から97%までのHFO−1234yfおよび3から7%までのHFC−125(例えば、およそ95%のHFO−1234yfおよびおよそ5%のHFC−125);
− 65から85%までのHFO−1234zeおよび15から35%までのHFC−134a、好ましくは70から80%までのHFO−1234zeおよび20から30%までのHFC−134a(例えば、およそ75%のHFO−1234zeおよび25%のHFC−134a);
− 80から98%までのHFO−1234zeおよび2から20%までのHFC−32、好ましくは85から95%までのHFO−1234zeおよび5から15%までのHFC−32(例えば、およそ90%のHFO−1234zeおよび10%のHFC−32);
− 90から99%までのHFO−1234zeおよび1から10%までのHFC−152a、好ましくは93から97%までのHFO−1234zeおよび3から7%までのHFC−152a(例えば、およそ95%のHFO−1234zeおよびおよそ5%のHFC−152a);
− 90から99%までのHFO−1234zeおよび1から10%までのHFC−125、好ましくは93から97%までのHFO−1234zeおよび3から7%までのHFC−125(例えば、およそ95%のHFO−1234zeおよびおよそ5%のHFC−125)。
− 好ましくは130から150℃の温度における、食品、例えば牛乳の加熱および滅菌;
− 好ましくは105から135℃の温度における加熱を伴う、特に化学工業、製紙工業、都市加熱における、加圧下での水蒸気の生成;
− 低温放出熱回収、例えば、50から90℃の温度での放出熱の回収により、100から150℃の温度で加熱することによる、工業プロセスの文脈における熱の生成。
(A)40℃における低温熱放出で、熱流体を70℃の初期温度から120℃の最終温度に加熱するための、亜臨界状況(図1による)においてCFC−114、HFC−245faまたはHCFC−123で動作するヒートポンプのもの;
(B)同じ熱流体を加熱するための、超臨界状況(図2による)においてHFO−1234yfまたはHFO−1234zeで動作するヒートポンプのもの。
Claims (11)
- 1,3,3,3−テトラフルオロプロペンを含む熱伝達流体を収容した蒸気圧縮回路によって、流体または物体を加熱する方法であって、熱伝達流体の蒸発と、熱伝達流体の圧縮と、熱伝達流体の冷却と、熱伝達流体の膨張とを順次かつ周期的に行うことを含み、熱伝達流体が、圧縮の終了時に超臨界状態にあり、前記流体または物体が100℃以上の温度で加熱される、方法。
- 冷却中に、熱伝達流体が、加熱される流体もしくは物体または熱交換流体と熱を交換し、好ましくは、熱交換中の加熱される流体もしくは物体または熱交換流体の温度の上昇は、10℃以上である、請求項1に記載の方法。
- 熱伝達流体が、1,3,3,3−テトラフルオロプロペンからなる、請求項1または2に記載の方法。
- 熱伝達流体が、少なくとも50%の1,3,3,3−テトラフルオロプロペンを含む、請求項1または2に記載の方法。
- 熱伝達流体が、1,1,1,2−テトラフルオロエタン、ジフルオロメタン、1,1−ジフルオロエタンおよび1,1,1,2,2−ペンタフルオロエタンから選択される、一または複数のハイドロフルオロカーボンも含む、請求項1、2または4のいずれか一項に記載の方法。
- 熱伝達流体が、潤滑剤、安定剤、界面活性剤、トレーサ、蛍光剤、付臭剤、可溶化剤、およびそれらの混合物から選択される一または複数の添加剤と組み合わせられる、請求項1から5のいずれか一項に記載の方法。
- 蒸発器と、圧縮機と、膨張弁と、冷却装置とを備える蒸気圧縮回路を具備し、蒸気圧縮回路内に1,3,3,3−テトラフルオロプロペンを含む熱伝達流体も収容し、熱伝達流体が、前記回路の少なくとも一部において超臨界状態にある、ヒートポンプ装置。
- 熱伝達流体が、1,3,3,3−テトラフルオロプロペンからなる、請求項7に記載のヒートポンプ装置。
- 熱伝達流体が、少なくとも50%のテトラフルオロプロペンを含む、請求項7に記載のヒートポンプ装置。
- 熱伝達流体が、1,1,1,2−テトラフルオロエタン、ジフルオロメタン、1,1−ジフルオロエタンおよび1,1,1,2,2−ペンタフルオロエタンから選択される一または複数のハイドロフルオロカーボンも含む、請求項7または9に記載のヒートポンプ装置。
- 流体または物体を、100℃以上の温度で加熱するのに好適な、請求項7から10のいずれか一項に記載のヒートポンプ装置。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR1157622 | 2011-08-30 | ||
FR1157622A FR2979419B1 (fr) | 2011-08-30 | 2011-08-30 | Fluides de transfert de chaleur supercritiques a base de tetrafluoropropene |
PCT/FR2012/051650 WO2013030476A1 (fr) | 2011-08-30 | 2012-07-12 | Fluides de transfert de chaleur supercritiques a base de tetrafluoropropene |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016131348A Division JP6640043B2 (ja) | 2011-08-30 | 2016-07-01 | テトラフルオロプロペンをベースにした超臨界熱伝達流体 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2014529661A JP2014529661A (ja) | 2014-11-13 |
JP6296981B2 true JP6296981B2 (ja) | 2018-03-20 |
Family
ID=46639613
Family Applications (3)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014527716A Active JP6296981B2 (ja) | 2011-08-30 | 2012-07-12 | テトラフルオロプロペンをベースにした超臨界熱伝達流体 |
JP2016131348A Active JP6640043B2 (ja) | 2011-08-30 | 2016-07-01 | テトラフルオロプロペンをベースにした超臨界熱伝達流体 |
JP2018135952A Pending JP2018199815A (ja) | 2011-08-30 | 2018-07-19 | テトラフルオロプロペンをベースにした超臨界熱伝達流体 |
Family Applications After (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2016131348A Active JP6640043B2 (ja) | 2011-08-30 | 2016-07-01 | テトラフルオロプロペンをベースにした超臨界熱伝達流体 |
JP2018135952A Pending JP2018199815A (ja) | 2011-08-30 | 2018-07-19 | テトラフルオロプロペンをベースにした超臨界熱伝達流体 |
Country Status (9)
Country | Link |
---|---|
US (2) | US9920961B2 (ja) |
EP (1) | EP2751501B1 (ja) |
JP (3) | JP6296981B2 (ja) |
CN (1) | CN103765129B (ja) |
CA (1) | CA2844478C (ja) |
ES (1) | ES2805733T3 (ja) |
FR (1) | FR2979419B1 (ja) |
PL (1) | PL2751501T3 (ja) |
WO (1) | WO2013030476A1 (ja) |
Families Citing this family (4)
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JPWO2015022958A1 (ja) * | 2013-08-14 | 2017-03-02 | セントラル硝子株式会社 | 熱伝達方法及び高温ヒートポンプ装置 |
EP3034579B1 (en) * | 2013-08-14 | 2019-11-13 | Central Glass Company, Limited | Heat transmission method |
FR3064275B1 (fr) * | 2017-03-21 | 2019-06-07 | Arkema France | Procede de chauffage et/ou climatisation d'un vehicule |
FR3102010B1 (fr) * | 2019-10-15 | 2022-06-03 | Arkema France | Procédé de régulation de la température d’une batterie comprenant un sel de lithium |
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DE10056606A1 (de) | 2000-11-15 | 2002-05-23 | Solvay Fluor & Derivate | Verwendung von Gemischen,die 1,1,1,3,3-Pentafluorbutan enthalten, als Kältemittel oder Wärmerträger |
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-
2011
- 2011-08-30 FR FR1157622A patent/FR2979419B1/fr not_active Expired - Fee Related
-
2012
- 2012-07-12 WO PCT/FR2012/051650 patent/WO2013030476A1/fr active Application Filing
- 2012-07-12 CN CN201280042425.8A patent/CN103765129B/zh active Active
- 2012-07-12 JP JP2014527716A patent/JP6296981B2/ja active Active
- 2012-07-12 US US14/241,301 patent/US9920961B2/en active Active
- 2012-07-12 CA CA2844478A patent/CA2844478C/fr active Active
- 2012-07-12 EP EP12744087.3A patent/EP2751501B1/fr active Active
- 2012-07-12 ES ES12744087T patent/ES2805733T3/es active Active
- 2012-07-12 PL PL12744087T patent/PL2751501T3/pl unknown
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2016
- 2016-07-01 JP JP2016131348A patent/JP6640043B2/ja active Active
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2018
- 2018-01-24 US US15/878,552 patent/US20180149392A1/en not_active Abandoned
- 2018-07-19 JP JP2018135952A patent/JP2018199815A/ja active Pending
Also Published As
Publication number | Publication date |
---|---|
FR2979419B1 (fr) | 2018-03-30 |
WO2013030476A1 (fr) | 2013-03-07 |
CN103765129A (zh) | 2014-04-30 |
US20180149392A1 (en) | 2018-05-31 |
CA2844478C (fr) | 2019-01-08 |
US9920961B2 (en) | 2018-03-20 |
PL2751501T3 (pl) | 2020-11-02 |
JP6640043B2 (ja) | 2020-02-05 |
CA2844478A1 (fr) | 2013-03-07 |
JP2014529661A (ja) | 2014-11-13 |
FR2979419A1 (fr) | 2013-03-01 |
JP2016217697A (ja) | 2016-12-22 |
EP2751501A1 (fr) | 2014-07-09 |
ES2805733T3 (es) | 2021-02-15 |
CN103765129B (zh) | 2016-01-20 |
JP2018199815A (ja) | 2018-12-20 |
US20140223935A1 (en) | 2014-08-14 |
EP2751501B1 (fr) | 2020-06-03 |
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