JP6295783B2 - Method for producing sintered ore - Google Patents

Method for producing sintered ore Download PDF

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JP6295783B2
JP6295783B2 JP2014072585A JP2014072585A JP6295783B2 JP 6295783 B2 JP6295783 B2 JP 6295783B2 JP 2014072585 A JP2014072585 A JP 2014072585A JP 2014072585 A JP2014072585 A JP 2014072585A JP 6295783 B2 JP6295783 B2 JP 6295783B2
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granulated
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granulation
sintered ore
granulated product
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健一 八ヶ代
健一 八ヶ代
大山 浩一
浩一 大山
茂 樫村
茂 樫村
翼 原田
翼 原田
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Nippon Steel Corp
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Description

本発明は、鉄鋼製造用の焼結鉱の製造方法に関し、特に、窒素酸化物の発生を凝結材の事前処理によって抑制する方法に関する。   The present invention relates to a method for producing sintered ore for producing steel, and more particularly to a method for suppressing the generation of nitrogen oxides by pretreatment of a coagulation material.

鉄鋼製造に用いる焼結鉱は、原料となる鉄鉱石に凝結材及び石灰等を混合して造粒した擬似造粒物を焼結機で焼成することにより製造される。この時、凝結材に含まれる窒素分の一部が窒素酸化物(以下、「NOx」と記載する。)となって排ガス中に混入する。
NOxは大気汚染物質であることから、大気へのNOxの排出についてその濃度及び量に規制が設けられており、操業条件の調整などの制約が発生する。NOxを除去する排ガス処理装置の設置なども行われているが、多大な設備投資が必要となる。そのため、操業制約や設備投資の軽減を目的として、凝結材の事前処理によってNOxの発生を抑制する方法が従来より検討されてきた。
A sintered ore used for steel production is manufactured by firing a pseudo-granulated material obtained by mixing a granulated material such as a coagulant and lime with iron ore as a raw material and firing it with a sintering machine. At this time, a part of nitrogen contained in the coagulation material becomes nitrogen oxide (hereinafter referred to as “NOx”) and is mixed in the exhaust gas.
Since NOx is an air pollutant, there are restrictions on the concentration and amount of NOx emission to the atmosphere, and restrictions such as adjustment of operating conditions occur. Installation of an exhaust gas treatment device for removing NOx is also performed, but a great investment in equipment is required. Therefore, for the purpose of reducing operational restrictions and capital investment, methods for suppressing the generation of NOx by pretreatment of the aggregate have been studied.

なお、凝結材は、主として炭素を含むもので、NOx源になるものを含み、酸化によって発熱する材料である。例えば、石炭やコークスなどを指す。   The aggregating material is a material mainly containing carbon, including a material that becomes a NOx source, and generates heat by oxidation. For example, it refers to coal and coke.

凝結材の事前処理によってNOxの発生を抑制する方法の一つとして、生成したNOxを還元する物質で凝結材の表面を被覆する方法がある。例えば、特許文献1には、カルシウムフェライトを含有する微粉末触媒と凝結材を並存させ、生成したNOxを還元して抑制する技術が開示されている。
特許文献1記載の発明では、NOxの発生を抑制しつつコストを低減する目的で、カルシウムフェライト等の配合割合を規定しており、凝結材中の窒素分がNOxに転換した割合を示すNOx転換率は30%以上となっている。なお、NOx転換率とは、凝結材に含まれる窒素分の総量に対するNOxに転換した窒素分の割合である。
One method of suppressing the generation of NOx by pretreatment of the aggregate is to coat the surface of the aggregate with a substance that reduces the generated NOx. For example, Patent Document 1 discloses a technique in which a fine powder catalyst containing calcium ferrite and a coagulant coexist, and the generated NOx is reduced and suppressed.
In the invention described in Patent Document 1, in order to reduce the cost while suppressing the generation of NOx, the blending ratio of calcium ferrite and the like is specified, and the NOx conversion indicating the ratio of the nitrogen content in the coagulated material converted to NOx The rate is over 30%. The NOx conversion rate is the ratio of nitrogen content converted to NOx with respect to the total amount of nitrogen content contained in the coagulation material.

しかし、実操業では、さらにNOx転換率を低減することが望まれており、特許文献2では、特許文献1のカルシウムフェライト等を生石灰に特定することで、NOx転換率を20%台まで低減できることが示されている。   However, in actual operation, it is desired to further reduce the NOx conversion rate. In Patent Document 2, by specifying calcium ferrite or the like of Patent Document 1 as quick lime, the NOx conversion rate can be reduced to the 20% level. It is shown.

特開平8−60257号公報JP-A-8-60257 特開2012−172067号公報JP 2012-172067 A

特許文献2の段落[0005]には、0.25mmアンダーの微粉凝結材が低温で酸化し、NOxが発生しやすいことが記載されている。また、特許文献2の段落[0038]には、微粉凝結材と微粉生石灰の造粒物(造粒体(P型))であっても、凝結材が微粉であることに起因してNOxが増大することが記載されている。このため、特許文献2記載の発明では、0.25mmオーバーの凝結材を主として用いてNOxの発生を抑制している。   In paragraph [0005] of Patent Document 2, it is described that a fine powder condensate under 0.25 mm is oxidized at a low temperature and NOx is likely to be generated. Further, in paragraph [0038] of Patent Document 2, even if it is a granulated product (granulated body (P type)) of a fine powdered agglomerated material and fine powdered quicklime, NOx is attributed to the fact that the agglomerated material is a fine powder. It is described to increase. For this reason, in the invention described in Patent Document 2, the generation of NOx is suppressed by mainly using a condensing material over 0.25 mm.

凝結材は、一般に、石炭やコークスを粉砕して製造されるため、例えば0.25mmアンダーの微粉凝結材は定常的に生産される。そのため、0.25mmオーバーの凝結材を主として用いると、微粉凝結材が余剰となるという問題がある。また、NOx転換率をさらに低減したいというニーズもある。   Since the aggregate is generally produced by pulverizing coal or coke, for example, a pulverized aggregate of 0.25 mm or less is constantly produced. Therefore, there is a problem that if a condensing material over 0.25 mm is mainly used, the fine powder condensing material becomes excessive. There is also a need to further reduce the NOx conversion rate.

本発明はかかる事情に鑑みてなされたもので、従来に比べてNOxの発生を抑制することができ、しかも0.25mmアンダーの微粉凝結材が存在しても同様の効果を得ることが可能な焼結鉱の製造方法を提供することを目的とする。   The present invention has been made in view of such circumstances, and it is possible to suppress the generation of NOx as compared with the conventional case, and it is possible to obtain the same effect even if a fine powder condensate of 0.25 mm is present. It aims at providing the manufacturing method of a sintered ore.

上記目的を達成するため、本発明は、鉄鋼製造用焼結鉱の製造に用いる凝結材を生石灰及び/又は消石灰と共に混練装置に装入して水分の存在下で造粒し、造粒された造粒物を圧縮成形装置に供給して圧縮成形した後、鉄鉱石を含む焼結原料を造粒するドラムミキサーに添加することを特徴としている。   In order to achieve the above-mentioned object, the present invention was prepared by charging a coagulation material used in the production of sintered ore for steel production together with quick lime and / or slaked lime into a kneading apparatus and granulating it in the presence of moisture. The granulated product is supplied to a compression molding apparatus and compressed and then added to a drum mixer for granulating a sintered raw material containing iron ore.

本発明では、凝結材を生石灰及び/又は消石灰と共に混練装置に装入して水分の存在下で造粒した造粒物を圧縮成形装置に供給する。これにより、凝結材と生石灰等からなる造粒物がロールによって圧縮成形され、緻密な造粒物が形成される。その結果、造粒物を構成する粒子同士の間の空気の透過性が抑制され、低温段階での凝結材の酸化が進行せず、NOxの発生が抑制される。   In the present invention, the agglomerated material is charged into a kneading apparatus together with quick lime and / or slaked lime and granulated in the presence of moisture and supplied to the compression molding apparatus. Thereby, the granulated material which consists of a condensing material, quicklime, etc. is compression-molded with a roll, and a dense granulated material is formed. As a result, the air permeability between the particles constituting the granulated product is suppressed, the oxidation of the coagulant does not proceed at the low temperature stage, and the generation of NOx is suppressed.

なお、本発明における造粒物は、特にことわりのない限り、凝結材粒子の周囲に生石灰等の被覆層が形成されたS型造粒物、並びに微粉凝結材と生石灰等が混合したP型造粒物の双方を指す。   The granulated product in the present invention is an S-type granulated product in which a coating layer such as quicklime is formed around the aggregated particles, and a P-type granulated product in which a fine powdered aggregate and quicklime are mixed, unless otherwise specified. It refers to both grains.

また、本発明に係る焼結鉱の製造方法では、前記凝結材は、粒度0.25mmアンダーの微粉を20質量%以上含んでいてもよい。   Moreover, in the manufacturing method of the sintered ore which concerns on this invention, the said condensing material may contain 20 mass% or more of fine powder with a particle size under 0.25 mm.

本発明により緻密な造粒物が形成されるので、凝結材が粒度0.25mmアンダーの微粉を含んでいても、従来に比べてNOxの発生を抑制することができる。その際、後述するように、0.25mmアンダーの微粉凝結材を20質量%以上含んでいると、NOx低減効果はより顕著となる。   Since a dense granulated product is formed according to the present invention, generation of NOx can be suppressed as compared with the conventional case even if the coagulant contains fine powder having a particle size of 0.25 mm or less. At that time, as will be described later, the NOx reduction effect becomes more conspicuous when 20% by mass or more of the fine powder condensate of 0.25 mm is included.

また、本発明に係る焼結鉱の製造方法では、前記混練装置による造粒を60秒間以上行うことを好適とする。
当該構成では、混練装置による造粒を60秒間以上行うことによって、造粒物や被覆層の緻密度が向上することでNOx低減効果が拡大する。
Moreover, in the manufacturing method of the sintered ore concerning this invention, it is suitable to perform granulation by the said kneading apparatus for 60 seconds or more.
In the said structure, by performing granulation with a kneading apparatus for 60 seconds or more, the density of a granulated material and a coating layer improves, and a NOx reduction effect expands.

また、本発明に係る焼結鉱の製造方法では、前記混練装置による造粒時の水分が10質量%以上となるように水分調整を行うことを好適とする。
当該構成では、上記水分調整を行うことにより、緻密な造粒物や被覆層が形成されNOx低減効果が拡大する。
Moreover, in the manufacturing method of the sintered ore which concerns on this invention, it is suitable to adjust a water | moisture content so that the water | moisture content at the time of granulation by the said kneading apparatus may be 10 mass% or more.
In the said structure, by performing the said water | moisture content adjustment, a precise granule and a coating layer are formed and a NOx reduction effect is expanded.

また、本発明に係る焼結鉱の製造方法では、圧縮成形された前記造粒物を造粒装置を用いてさらに造粒処理してもよい。
当該構成では、圧縮成形を行った造粒物を造粒装置を用いてさらに造粒処理することにより、造粒物や被覆層の緻密度がさらに向上してNOx低減効果が拡大する。
Moreover, in the manufacturing method of the sintered ore which concerns on this invention, you may further granulate the said granulated material compression-molded using a granulator.
In the said structure, by further granulating the granulated material which carried out the compression molding using the granulator, the density of a granulated material and a coating layer further improves, and a NOx reduction effect expands.

また、本発明に係る焼結鉱の製造方法では、圧縮成形された前記造粒物あるいは前記造粒装置でさらに造粒処理された造粒物を前記ドラムミキサーの後段に添加することを好適とする。
当該構成では、圧縮成形された前記造粒物あるいは前記造粒装置でさらに造粒処理された造粒物をドラムミキサーの後段に添加することによって、ドラムミキサー内における被覆層の剥離や造粒物の崩壊が抑制され、高いNOx低減効果を維持することができる。
Further, in the method for producing a sintered ore according to the present invention, it is preferable that the compressed granulated product or the granulated product further granulated by the granulating device is added to the subsequent stage of the drum mixer. To do.
In this configuration, the compressed granulated product or the granulated product further granulated by the granulator is added to the subsequent stage of the drum mixer, whereby the coating layer is peeled off or the granulated product in the drum mixer. Is suppressed, and a high NOx reduction effect can be maintained.

本発明に係る焼結鉱の製造方法によれば、凝結材を生石灰及び/又は消石灰と共に混練装置に装入して水分の存在下で造粒した造粒物を圧縮成形することにより緻密な造粒物が形成されるので、従来に比べてNOxの発生を抑制することができ、しかも0.25mmアンダーの微粉凝結材が存在しても同様の効果を得ることができる。   According to the method for producing a sintered ore according to the present invention, a compacted product is formed by compressing and molding a granulated product charged in a kneading apparatus together with quick lime and / or slaked lime, and granulated in the presence of moisture. Since particles are formed, the generation of NOx can be suppressed as compared with the conventional case, and the same effect can be obtained even when a fine powder condensate of 0.25 mm is present.

凝結材の造粒方法ごとにNOx転換率の改善割合を示したグラフである。It is the graph which showed the improvement ratio of the NOx conversion rate for every granulation method of a coagulation material. 本発明の一実施の形態に係る焼結鉱の製造方法が適用される焼結プラントの模式図である。It is a schematic diagram of the sintering plant to which the manufacturing method of the sintered ore which concerns on one embodiment of this invention is applied. ブリケット製造機の断面図である。It is sectional drawing of a briquette manufacturing machine. 凝結材中の0.25mmアンダーの割合とNOx転換率の改善割合との関係を示すグラフである。It is a graph which shows the relationship between the ratio of 0.25mm under in a condensate, and the improvement ratio of NOx conversion rate. 混練装置による造粒時間とNOx転換率の改善割合との関係を示すグラフである。It is a graph which shows the relationship between the granulation time by a kneading apparatus, and the improvement rate of NOx conversion rate. 造粒物の水分割合とNOx転換率の改善割合との関係を示すグラフである。It is a graph which shows the relationship between the moisture ratio of a granulated material, and the improvement ratio of NOx conversion rate. 圧縮成形装置による圧縮成形後に造粒処理を行う場合と行わない場合、並びにドラムミキサーに造粒物を前添加する場合と後段添加する場合それぞれにおけるNOx転換率の改善割合を示したグラフである。It is the graph which showed the improvement ratio of the NOx conversion rate in the case where granulation is performed after compression molding by the compression molding apparatus and when it is not performed, and when the granulated product is added to the drum mixer and when it is added later.

続いて、添付した図面を参照しつつ、本発明を具体化した実施の形態について説明し、本発明の理解に供する。なお、以下の説明では、凝結材を生石灰等と共に造粒したものを「造粒物」、前記造粒物を鉄鉱石や無煙炭等に添加して造粒処理したものを「擬似造粒物」と呼ぶ。   Next, embodiments of the present invention will be described with reference to the accompanying drawings to provide an understanding of the present invention. In the following description, a granulated product obtained by granulating a coagulation material together with quick lime or the like is “granulated product”, and a granulated product obtained by adding the granulated product to iron ore or anthracite or the like “pseudo granulated product” Call it.

[NOxの発生を抑制するメカニズム]
本発明者等は、特許文献2に記載されている0.25mmアンダーの微粉凝結材を含む造粒物とNOx発生の関係について調べた。具体的には、凝結材の造粒方法、特に造粒物に作用させる加速度及び圧縮力(圧密度)の影響を調べるため、比較的加速度及び/又は圧縮力の小さなドラムミキサー及びパンペレタイザーに対し、圧縮力の大きな圧縮成形装置や加速度の大きなマルメライザーを比較検討した。
[Mechanism to suppress NOx generation]
The inventors of the present invention investigated the relationship between the granulated material described in Patent Document 2 containing a fine powder condensing material of 0.25 mm and NOx generation. Specifically, in order to investigate the effect of the agglomerated material granulation method, particularly the acceleration and compression force (pressure density) acting on the granulated product, the drum mixer and pan pelletizer with relatively low acceleration and / or compression force are used. A compression molding device with a large compressive force and a malmerizer with a large acceleration were compared.

比較実験では、凝結材であるコークスに対し、生石灰を10質量%添加(内掛け)し、最終水分が15質量%となるように水添加量を調整した後、各装置で凝結材の造粒を行った。次いで、各装置によって造粒処理された造粒物を、鉄鉱石を含む焼結原料を造粒するドラムミキサーの後段にそれぞれ添加して擬似造粒物を造粒した。そして、擬似造粒物を焼成した際に発生する排ガスの流量及び排ガスに含まれるNOx濃度を測定してNOx発生量を算出した。
比較実験に使用した焼結原料の配合(鉄鉱石を含む焼結原料を造粒するドラムミキサー出側の配合)を表1に示す。なお、コークスには0.25mmアンダーの微粉を25質量%含むものを使用した。
In the comparative experiment, 10% by mass of quicklime is added to the coke, which is a coagulant, and the amount of water added is adjusted so that the final moisture becomes 15% by mass. Went. Next, the granulated product granulated by each apparatus was added to the subsequent stage of the drum mixer for granulating the sintered raw material containing iron ore to granulate the pseudo granulated product. And the NOx generation amount was computed by measuring the flow rate of the exhaust gas generated when the pseudo granulated product was fired and the NOx concentration contained in the exhaust gas.
Table 1 shows the composition of the sintering material used in the comparative experiment (composition on the drum mixer outlet side for granulating the sintering material containing iron ore). Coke containing 25% by mass of 0.25 mm under fine powder was used.

Figure 0006295783
Figure 0006295783

凝結材の造粒に当たり、ドラムミキサーには直径1mの試験機を使用し、回転数20rpmで5分間造粒処理を行った。
パンペレタイザーには直径1m、傾斜角度45°のパンを使用し、回転数15rpmで5分間造粒処理を行った。
圧縮成形装置には、200φ双ロール式ブリケット製造機を使用し、凝結材及び生石灰を一旦、混練装置で造粒処理した後、上記ブリケット製造機の線圧を0.3ton/cmとして圧縮成形した。混練装置には、容量40Lの高速撹拌ミキサー(アイリッヒミキサー)を使用し、パンの回転速度13rpm、アジテータの回転速度300rpmとして300秒間造粒処理した。
マルメライザーによる造粒処理は、直径1mの竪型円筒容器底部の円盤の回転数を200rpmとして2分間行った。
In the granulation of the coagulant, a test machine having a diameter of 1 m was used for the drum mixer, and granulation was performed for 5 minutes at a rotation speed of 20 rpm.
A pan with a diameter of 1 m and an inclination angle of 45 ° was used as a pan pelletizer, and granulation was performed at a rotation speed of 15 rpm for 5 minutes.
For the compression molding apparatus, a 200φ twin roll briquette making machine was used, and after the agglomerated material and quicklime were granulated by the kneading apparatus, the briquette making machine was compression molded at a linear pressure of 0.3 ton / cm. . As the kneading apparatus, a high-speed stirring mixer (Eirich mixer) having a capacity of 40 L was used, and granulation was performed for 300 seconds at a bread rotation speed of 13 rpm and an agitator rotation speed of 300 rpm.
The granulation treatment by the Malmerizer was performed for 2 minutes with the number of rotations of the disk at the bottom of the vertical cylindrical container having a diameter of 1 m being 200 rpm.

図1に、造粒処理をしていない凝結材を用いた場合のNOx転換率に対する、各装置によって造粒処理された凝結材を用いた場合のNOx転換率の改善割合を示す。
なお、NOx転換率は、NOx発生量からNOxに転換した窒素量を算出し、予め分析しておいた凝結材中の窒素量を100としたときの割合に換算して求めた。また、NOx転換率の改善割合は次式で算出した。
NOx転換率の改善割合=(1−造粒処理した凝結材を用いた場合のNOx転換率/造粒処理しない凝結材を用いた場合のNOx転換率)×100%
FIG. 1 shows the improvement rate of the NOx conversion rate when the coagulated material granulated by each apparatus is used with respect to the NOx conversion rate when the coagulated material not subjected to granulation treatment is used.
The NOx conversion rate was determined by calculating the amount of nitrogen converted from NOx generation amount to NOx and converting it to a ratio when the amount of nitrogen in the coagulated material analyzed in advance was 100. Moreover, the improvement rate of the NOx conversion rate was calculated by the following equation.
Improvement rate of NOx conversion rate = (1−NOx conversion rate when using a granulated coagulated material / NOx conversion rate when using a coagulated material that is not granulated) × 100%

同図より、ドラムミキサーやパンペレタイザーで造粒した造粒物は、NOx転換率の改善割合が10%未満と低く、NOx発生量の抑制に寄与が少ないことがわかる。また、加速度の大きなマルメライザーもNOx転換率の改善割合が10%程度と、NOx抑制効果が小さいことがわかる。
ドラムミキサーやパンペレタイザーで造粒した造粒物は、造粒時の造粒物にかかる加速度が実質的に1G未満であるのに対し、マルメライザーでは20Gに達するが、NOx抑制効果が同等に低位であることから、必ずしも加速度を大きくすることではNOxの発生を十分に抑制することができないことが判明した。
From the figure, it can be seen that the granulated product granulated with a drum mixer or pan pelletizer has a low improvement rate of NOx conversion rate of less than 10%, and contributes little to the suppression of NOx generation. In addition, it can be seen that a Malmerizer with a large acceleration has a small NOx suppression effect when the improvement rate of the NOx conversion rate is about 10%.
The granulated product granulated with a drum mixer or pan pelletizer has a substantially less than 1G acceleration on the granulated product at the time of granulation, while the Malmerizer reaches 20G, but the NOx suppression effect is equivalent. From the low level, it has been found that the generation of NOx cannot be sufficiently suppressed by necessarily increasing the acceleration.

これに対し、本発明者等は、高速撹拌ミキサーで造粒した造粒物を例えば線圧0.3ton/cmのブリケット製造機で圧縮成形した成形物(以降、圧縮成形後の造粒物を「成形物」と呼ぶことがある。)を用いて焼成時のNOx発生量を調査した。その結果、ドラムミキサー、パンペレタイザー、マルメライザーで造粒した造粒物に比べて、ブリケット製造機で圧縮成形した成形物を使用した焼成では、NOx転換率の改善割合が30%台に上昇しNOx発生量が大幅に低減することを発見した。   On the other hand, the present inventors have compression molded a granulated product granulated with a high-speed agitating mixer, for example, with a briquette manufacturing machine with a linear pressure of 0.3 ton / cm (hereinafter referred to as a granulated product after compression molding). The amount of NOx generated at the time of firing was investigated using the “molded product”. As a result, compared with the granulated product granulated with a drum mixer, pan pelletizer, and mulmerizer, the improvement rate of NOx conversion increased to 30% in the firing using the molded product compressed by briquette making machine. It has been found that the amount of NOx generated is greatly reduced.

上述したNOx発生量の相違は、圧密度が小さな造粒物は、構成する粒子同士の間を空気が透過するため、比較的低温段階から造粒物内の微粉凝結材が酸化するのに対し、ブリケット製造機で圧縮成形した成形物は、構成する粒子が圧密されて粒子同士の間の空気の透過性が抑制され、低温段階での微粉凝結材の酸化が進まなかったためと考えられる。さらに焼結機内で温度が1000℃以上となった段階で、造粒物を構成する生石灰や消石灰が溶融流出し、露出した微粉凝結材が1000℃以上の高温で酸化することで、NOx発生が抑制されたと考えられる。   The difference in the amount of NOx generated as described above is that, in the granulated product having a low pressure density, air permeates between the constituent particles, so that the fine powder condensate in the granulated product is oxidized from a relatively low temperature stage. The molded product compression-molded by the briquette manufacturing machine is considered to be because the constituent particles are consolidated and the air permeability between the particles is suppressed, and oxidation of the fine powder condensate does not proceed at a low temperature stage. Furthermore, when the temperature reaches 1000 ° C. or higher in the sintering machine, quick lime and slaked lime constituting the granulated material melt and flow out, and the exposed fine aggregate is oxidized at a high temperature of 1000 ° C. or higher, thereby generating NOx. It is thought that it was suppressed.

また、ドラムミキサーで造粒した造粒物を数日間大気養生して乾燥させたものを1mの高さからコンクリート床に落下させたときの0.5mm以下粉の発生割合は10%以下となる。一方、ブリケット製造機で圧縮成形した成形物を1mの高さからコンクリート床に落下させたときの0.5mm以下粉の発生割合は25%である。従って、ドラムミキサーで造粒した造粒物は、大気養生することにより高強度の造粒物となる。
しかし、大気養生した造粒物とブリケット製造機で圧縮成形した成形物のNOx転換率の改善割合を比較すると、大気養生した造粒物のNOx抑制効果は、ブリケット製造機で圧縮成形した成形物に比べて十分ではなかった。
In addition, when the granulated product granulated with a drum mixer is air-cured for several days and dried and dropped onto a concrete floor from a height of 1 m, the generation ratio of powder of 0.5 mm or less is 10% or less. . On the other hand, when the molded product compression-molded by the briquetting machine is dropped onto a concrete floor from a height of 1 m, the generation ratio of 0.5 mm or less powder is 25%. Therefore, the granulated product granulated by the drum mixer becomes a high-strength granulated product by curing in the air.
However, comparing the improvement rate of the NOx conversion rate between the granulated product cured with air and the molded product compressed with briquette machine, the NOx suppression effect of the granulated product cured with air is the molded product compressed with briquette machine. Was not enough.

以上の結果より、造粒物に強い圧縮力を作用させ、緻密な造粒物を形成することがNOxの抑制に有効であることが判明した。特に養生によって造粒物強度を確保したにもかかわらず、十分なNOx抑制が図られなかった一方で、ロールによる強制的な圧縮力を造粒物に作用させた場合、NOx抑制効果が顕著であったことから、圧縮することによって造粒物が緻密化してNOx転換率が抑えられたと推定される。   From the above results, it has been found that it is effective in suppressing NOx to apply a strong compressive force to the granulated product to form a dense granulated product. In particular, even though the strength of the granulated product was ensured by curing, sufficient NOx suppression was not achieved, but when a forced compressive force by the roll was applied to the granulated product, the NOx suppressing effect was remarkable. Therefore, it is presumed that the granulated material was densified by compression and the NOx conversion rate was suppressed.

[本発明の構成について]
上記知見に基づき、本発明は、鉄鋼製造用焼結鉱の製造に用いる凝結材を生石灰及び/又は消石灰と共に混練装置に装入して水分の存在下で造粒し、造粒された造粒物を圧縮成形装置に供給して圧縮成形した後、鉄鉱石を含む焼結原料を造粒するドラムミキサーに添加することを特徴としている。
[Configuration of the present invention]
On the basis of the above knowledge, the present invention is a granulated product in which the agglomerated material used for the production of sintered ore for steel production is charged into a kneading apparatus together with quick lime and / or slaked lime, granulated in the presence of moisture, and granulated. After the product is supplied to a compression molding apparatus and compression molded, the sintered raw material containing iron ore is added to a drum mixer for granulating.

凝結材と生石灰等を造粒し、生石灰等で凝結材を被覆することにより、焼結機パレット内で1000℃程度まで凝結材の酸化が進行しにくくなる。1000℃を超えると、生石灰等と造粒物周囲の鉄鉱石が低融点化合物を形成し、造粒物から生石灰等が溶融流出する。これを受けて、凝結材が高温雰囲気に露出し、凝結材の酸化が顕著に進行する。このように、例えば1000℃以上の高温雰囲気において凝結材の酸化を進行させることが可能となるため、凝結材と生石灰等を造粒するのがよい。
加えて、生石灰は消化して微細な水酸化カルシウム微粒子となって分散が促進され、消石灰も一部溶解して水酸化カルシウム微粒子として凝結材粒子間に再析出するため分散が良好となる。その結果、強固で緻密な造粒物となる。
By granulating the condensate and quicklime, etc., and covering the condensate with quicklime, etc., oxidation of the condensate hardly proceeds to about 1000 ° C. in the sintering machine pallet. When it exceeds 1000 ° C., quick lime and the iron ore around the granulated material form a low melting point compound, and quick lime and the like melt out from the granulated material. In response to this, the aggregate is exposed to a high temperature atmosphere, and the oxidation of the aggregate progresses remarkably. Thus, since it becomes possible to oxidize a coagulation material in a high temperature atmosphere of 1000 degreeC or more, for example, it is good to granulate a coagulation material, quicklime, etc.
In addition, quick lime is digested to become fine calcium hydroxide fine particles, and dispersion is promoted, and slaked lime is partly dissolved and re-precipitated between the aggregated particles as calcium hydroxide fine particles. As a result, a strong and dense granulated product is obtained.

また、造粒された造粒物を圧縮成形装置に供給することにより、造粒物がロールによって圧縮成形されて緻密な造粒物となり、顕著なNOx低減効果が得られる。
圧縮成形装置としては、ブリケット製造機やローラーコンパクタ、ローラミルなど、原料に圧縮力を作用させるロールを有する装置であればよい。
なお、ブリケット製造機等の圧縮成形装置は、凝結材と生石灰等を混練する機能が低いため、混練装置を用いて凝結材と生石灰等を事前に混練(造粒)しておく必要がある。
Further, by supplying the granulated product to the compression molding apparatus, the granulated product is compression molded by a roll to become a dense granulated product, and a remarkable NOx reduction effect is obtained.
The compression molding apparatus may be an apparatus having a roll that applies a compressive force to the raw material, such as a briquette manufacturing machine, a roller compactor, and a roller mill.
Note that a compression molding apparatus such as a briquette manufacturing machine has a low function of kneading a coagulant and quicklime, and therefore it is necessary to knead (granulate) the coagulant and quicklime using a kneader in advance.

圧縮成形された成形物(造粒物)はフレーク状となる。生石灰等で凝結材を確実に覆うため、フレーク厚みは凝結材の平均粒径の1.5倍以上が好ましい。また、成形物中の凝結材の高温での酸化をより容易にし、鉄鉱石を含む焼結原料中で成形物をより均一に分散させるため、フレーク厚みは凝結材の平均粒径の4倍以下であることが好ましい。従って、フレーク厚みが上記範囲となるように、圧縮成形装置の線圧を調整することが望ましい。   The compression-molded product (granulated product) is flaked. The flake thickness is preferably 1.5 times or more the average particle size of the coagulated material in order to reliably cover the coagulated material with quick lime or the like. In addition, the flake thickness is less than 4 times the average particle size of the coagulated material in order to make it easier to oxidize the coagulated material in the molded product at a high temperature and more uniformly disperse the molded product in the sintered raw material containing iron ore. It is preferable that Therefore, it is desirable to adjust the linear pressure of the compression molding apparatus so that the flake thickness falls within the above range.

[焼結鉱の製造方法]
本発明の一実施の形態に係る焼結鉱の製造方法について、図2に示す焼結プラントにより説明する。
凝結材が蓄えられている貯留槽13と生石灰や消石灰が蓄えられている貯留槽14からそれぞれ所定量の凝結材及び生石灰等を切り出し、混練装置10に装入して水分の存在下で造粒する。
生石灰等の量は、凝結材と合わせた全量に対して、即ち内掛けで5質量%以上60質量%以下が好ましい。60質量%を超えると、凝結材燃焼性を抑制する影響が顕著となる。また、混練装置10による造粒時の水分が内掛けで10質量%以上となるように水分調整し、混練装置10による造粒時間は60秒間以上とする。
[Method for producing sintered ore]
A method for manufacturing a sintered ore according to an embodiment of the present invention will be described with reference to a sintering plant shown in FIG.
A predetermined amount of agglomerate and quicklime are cut out from the storage tank 13 in which the condensed material is stored and the storage tank 14 in which quicklime and slaked lime are stored, respectively, and charged in the kneading apparatus 10 and granulated in the presence of moisture. To do.
The amount of quicklime and the like is preferably 5% by mass or more and 60% by mass or less with respect to the total amount combined with the coagulant, that is, the inner amount. When it exceeds 60 mass%, the influence which suppresses a coagulation | solidification material combustibility will become remarkable. In addition, the moisture is adjusted so that the moisture at the time of granulation by the kneading apparatus 10 is 10% by mass or more on the inside, and the granulation time by the kneading apparatus 10 is 60 seconds or more.

混練装置10で造粒された造粒物は圧縮成形装置11に供給され、フレーク厚みが凝結材の平均粒径の1.5倍〜4倍程度となるように圧縮成形される。
図3に圧縮成形装置11の一例であるブリケット製造機を示す。この圧縮成形装置11は、造粒物が投入されるホッパ21と、造粒物を圧縮成形する一対のロール22と、ホッパ21内に設置され、一対のロール22間に造粒物を供給するスクリューフィーダ23とから概略構成されている。
The granulated product granulated by the kneading apparatus 10 is supplied to the compression molding apparatus 11 and compression molded so that the flake thickness is about 1.5 to 4 times the average particle diameter of the aggregate.
FIG. 3 shows a briquette manufacturing machine which is an example of the compression molding apparatus 11. The compression molding apparatus 11 is installed in a hopper 21 into which a granulated product is charged, a pair of rolls 22 for compressing and molding the granulated product, and supplies the granulated product between the pair of rolls 22. The screw feeder 23 is generally configured.

ホッパ21に造粒物が投入されると、ホッパ21内の造粒物はスクリューフィーダ23によって一対のロール22間に送られる。僅かなクリアランスを有して並設された一対のロール22は互いに逆方向に回転しており、一対のロール22間に挿入した造粒物は、一対のロール22を通過することによって圧縮成形され、フレーク状の成形物となる。   When the granulated material is put into the hopper 21, the granulated material in the hopper 21 is sent between the pair of rolls 22 by the screw feeder 23. The pair of rolls 22 arranged side by side with a slight clearance are rotating in opposite directions, and the granulated material inserted between the pair of rolls 22 is compressed by passing through the pair of rolls 22. It becomes a flaky shaped product.

圧縮成形装置11によって圧縮成形された成形物(造粒物)は、パンペレタイザー12(造粒装置の一例)に装入され、造粒処理された後、貯留槽17もしくは一時貯留槽18に貯留される。鉄鉱石を含む焼結原料を造粒するドラムミキサー19に造粒物を前添加する場合は貯留槽17に、ドラムミキサー19に造粒物を後段添加する場合は一時貯留槽18にそれぞれ貯留する。
なお、造粒物の一部を貯留槽17に、残りを一時貯留槽18に貯留してもよい。また、パンペレタイザー12による追加造粒を行わずに、貯留槽17もしくは一時貯留槽18に貯留してもよい。
A molded product (granulated product) compression-molded by the compression molding device 11 is charged into a pan pelletizer 12 (an example of a granulating device), granulated, and then stored in a storage tank 17 or a temporary storage tank 18. Is done. When the granulated product is pre-added to the drum mixer 19 for granulating the sintered raw material containing iron ore, it is stored in the storage tank 17, and when the granulated product is added later to the drum mixer 19, it is stored in the temporary storage tank 18. .
A part of the granulated material may be stored in the storage tank 17 and the rest in the temporary storage tank 18. Moreover, you may store in the storage tank 17 or the temporary storage tank 18, without performing the additional granulation by the pan pelletizer 12. FIG.

一方、ドラムミキサー19には、鉄鉱石が蓄えられている貯留槽15や無煙炭が蓄えられている貯留槽16などからそれぞれ切り出された鉄鉱石や無煙炭等が装入される。また、貯留槽17から切り出された造粒物がドラムミキサー19に前添加され、あるいは一時貯留槽18から切り出された造粒物がドラムミキサー19に後段添加される。ドラムミキサー19では、ドラムミキサー19に前添加もしくは後段添加された造粒物が、鉄鉱石や無煙炭等と共に造粒処理され、擬似造粒物が製造される。   On the other hand, the drum mixer 19 is charged with iron ore or anthracite cut out from the storage tank 15 in which iron ore is stored, the storage tank 16 in which anthracite is stored, or the like. In addition, the granulated product cut out from the storage tank 17 is added to the drum mixer 19 in advance, or the granulated product cut out from the temporary storage tank 18 is added to the drum mixer 19 in the subsequent stage. In the drum mixer 19, the granulated product that has been added to the drum mixer 19 before or after the subsequent stage is granulated together with iron ore, anthracite, or the like to produce a pseudo-granulated product.

ドラムミキサー19で製造された擬似造粒物は焼結機20に装入されて焼成され、焼結鉱となる。焼結時に発生する排ガスは、ブロワ(図示省略)により焼結機20から吸引され、電気集塵機(図示省略)により粉塵等が除去された後、煙突(図示省略)から大気中に排出される。   The pseudo-granulated product produced by the drum mixer 19 is charged into the sintering machine 20 and fired to become a sintered ore. Exhaust gas generated during sintering is sucked from the sintering machine 20 by a blower (not shown), and dust and the like are removed by an electric dust collector (not shown), and then discharged from the chimney (not shown) to the atmosphere.

以上、本発明の一実施の形態について説明してきたが、本発明は何ら上記した実施の形態に記載の構成に限定されるものではなく、特許請求の範囲に記載されている事項の範囲内で考えられるその他の実施の形態や変形例も含むものである。例えば、上記実施の形態では、圧縮成形装置による圧縮成形を行った後、パンペレタイザーを用いて造粒処理を行ったが、パンペレタイザーではなくドラムミキサーやレディゲミキサーなど他の造粒装置を用いてもよい。   Although one embodiment of the present invention has been described above, the present invention is not limited to the configuration described in the above-described embodiment, and is within the scope of matters described in the claims. Other possible embodiments and modifications are also included. For example, in the above embodiment, after performing compression molding with a compression molding apparatus, granulation processing was performed using a pan pelletizer, but instead of a pan pelletizer, other granulation apparatuses such as a drum mixer and a Redige mixer were used. May be.

本発明によれば、凝結材の酸化を、従来の技術より高温で開始することができるため、NOx抑制効果が著しい。従って、従来ではNOx発生量が多いといわれていた粒径分布でも好適にNOxを低減でき、0.25mmアンダーの微粉凝結材を用いた場合でも高いNOx抑制効果が得られる。   According to the present invention, since the oxidation of the aggregate can be started at a higher temperature than in the conventional technique, the NOx suppression effect is remarkable. Therefore, NOx can be suitably reduced even in a particle size distribution that is conventionally said to have a large amount of NOx generation, and a high NOx suppression effect can be obtained even when a fine powder condensate of 0.25 mm or less is used.

図4は、凝結材に含まれる微粉を変化させた場合のNOx転換率の改善割合を示したグラフである。凝結材の造粒には高速撹拌ミキサーを用い、生石灰10質量%、水分15質量%を添加し、パンの回転速度13rpm、アジテータの回転速度300rpmとして300秒間行った。その後、ロール径200mmのブリケット製造機を用いて線圧0.3ton/cmで造粒物を圧縮成形した。   FIG. 4 is a graph showing the improvement rate of the NOx conversion rate when the fine powder contained in the coagulation material is changed. For the granulation of the agglomerated material, 10% by mass of quick lime and 15% by mass of water were added using a high-speed stirring mixer, and the pan rotation speed was 13 rpm and the agitator rotation speed was 300 rpm, which was performed for 300 seconds. Thereafter, the granulated product was compression molded at a linear pressure of 0.3 ton / cm using a briquette manufacturing machine having a roll diameter of 200 mm.

同図より、微粉凝結材が15質量%までの少ない段階ではNOx転換率の改善割合が10%程度に止まるのに対し、20質量%以上ではNOx転換率の改善割合が大きくなることがわかる。微粉凝結材に対しても緻密な造粒物が形成されることから、改善効果が拡大すると考えられる。
このことから、本発明では、凝結材に含まれる0.25mmアンダーの微粉割合を20質量%以上と規定した。一方、凝結材に含まれる0.25mmアンダーの微粉割合の上限については規定しないが、0.25mmアンダーの微粉割合が多くなると、凝結材の破砕処理時間が長くなるため、通常は50質量%以下とする。
From the figure, it can be seen that the improvement rate of the NOx conversion rate is limited to about 10% at a stage where the amount of fine powder condensate is as low as 15% by mass, whereas the improvement rate of the NOx conversion rate is increased at 20% by mass or more. It is considered that the improvement effect is expanded because a dense granulated material is also formed on the fine powder agglomerated material.
For this reason, in the present invention, the proportion of fine powder of 0.25 mm under contained in the coagulant is defined as 20% by mass or more. On the other hand, the upper limit of the fine powder ratio under 0.25 mm contained in the coagulant is not specified, but when the fine powder ratio under 0.25 mm increases, the crushing time of the coagulant increases, and usually 50% by mass or less. And

図5は、混練装置による造粒時間とNOx転換率の改善割合との関係を示したグラフである。凝結材の造粒処理には高速撹拌ミキサーを用い、0.25mm以下の微粉を20質量%含む凝結材に生石灰を10質量%添加して水分を15質量%に調整し、パンの回転速度を13rpm、アジテータの回転速度を300rpmとして造粒した。高速撹拌ミキサーにより造粒した造粒物は、ロール径200mmのブリケット製造機を用いて線圧0.3ton/cmで圧縮成形した。
同図より、造粒時間が60秒未満ではNOx転換率の改善割合が小さいのに対し、60秒以上において大きく改善することがわかる。緻密度が向上してNOx低減効果が拡大すると考えられる。
このことから、本発明では、混練装置による凝結材の造粒時間を60秒以上と規定した。一方、混練装置による凝結材の造粒時間が600秒を超えると造粒物が破砕することから、混練装置による凝結材の造粒時間の上限は600秒とする。
FIG. 5 is a graph showing the relationship between the granulation time by the kneading apparatus and the improvement rate of the NOx conversion rate. The granulation treatment of the coagulant is performed using a high-speed agitating mixer, and 10% by mass of quicklime is added to the coagulant containing 20% by mass of fine powder of 0.25 mm or less to adjust the water content to 15% by mass. Granulation was carried out at 13 rpm and an agitator rotation speed of 300 rpm. The granulated product granulated by the high-speed stirring mixer was compression-molded at a linear pressure of 0.3 ton / cm using a briquette manufacturing machine having a roll diameter of 200 mm.
From the figure, it can be seen that when the granulation time is less than 60 seconds, the improvement rate of the NOx conversion rate is small, but when the granulation time is less than 60 seconds, the improvement greatly occurs. It is considered that the density is improved and the NOx reduction effect is expanded.
Therefore, in the present invention, the granulation time of the coagulating material by the kneading apparatus is defined as 60 seconds or more. On the other hand, if the granulation time of the coagulation material by the kneading device exceeds 600 seconds, the granulated material is crushed. Therefore, the upper limit of the granulation time of the coagulation material by the kneading device is 600 seconds.

図6は、造粒物の水分割合とNOx転換率の改善割合との関係を示したグラフである。凝結材の造粒処理には高速撹拌ミキサーを用い、0.25mm以下の微粉を20質量%含む凝結材に生石灰を10質量%添加し、パンの回転速度を13rpm、アジテータの回転速度を300rpmとして300秒間造粒した。高速撹拌ミキサーにより造粒した造粒物は、ロール径200mmのブリケット製造機を用いて線圧0.3ton/cmで圧縮成形した。
同図より、水分が10質量%未満ではNOx転換率の改善割合が小さいのに対し、10質量%以上において大きく改善することが判明した。高水分化によって緻密な造粒物や被覆層が形成されNOx抑制効果が拡大すると考えられる。
このことから、本発明では、混練装置による凝結材の造粒時の水分を10質量%以上と規定した。また、凝結材の造粒時の水分が20質量%までは同様の傾向を示すことから、凝結材の造粒時の水分の上限は20質量%とする。
FIG. 6 is a graph showing the relationship between the moisture content of the granulated product and the improvement rate of the NOx conversion rate. For the granulation of the agglomerated material, a high-speed stirring mixer is used, 10% by mass of quicklime is added to the agglomerated material containing 20% by mass of fine powder of 0.25 mm or less, the rotation speed of the pan is 13 rpm, and the rotation speed of the agitator is 300 rpm. Granulated for 300 seconds. The granulated product granulated by the high-speed stirring mixer was compression-molded at a linear pressure of 0.3 ton / cm using a briquette manufacturing machine having a roll diameter of 200 mm.
From the figure, it was found that when the moisture content is less than 10% by mass, the improvement rate of the NOx conversion rate is small, but when the moisture content is 10% by mass or more, the improvement rate is greatly improved. It is thought that dense granulations and coating layers are formed by increasing the moisture content, and the NOx suppression effect is expanded.
For this reason, in the present invention, the water content at the time of granulation of the coagulated material by the kneader is defined as 10% by mass or more. Further, since the same tendency is shown until the moisture content at the time of granulation of the coagulation material is 20% by mass, the upper limit of the moisture content at the time of granulation of the coagulation material is set to 20% by mass.

図7は、圧縮成形装置による圧縮成形後に造粒処理を行う場合と行わない場合、並びにドラムミキサーに造粒物を前添加する場合と後段添加する場合それぞれにおけるNOx転換率の改善割合を示したグラフである。なお、図中のDMはドラムミキサー、PPはパンペレタイザーである。
凝結材の造粒処理には高速撹拌ミキサーを用い、0.25mm以下の微粉を25質量%含む凝結材に生石灰を10%添加して水分を15質量%に調整し、パンの回転速度を13rpm、アジテータの回転速度を300rpmとして300秒間造粒した。高速撹拌ミキサーにより造粒した造粒物は、ロール径200mmのブリケット製造機を用いて線圧0.3ton/cmで圧縮成形した(PP無し)。また、この成形物を直径1mのパンペレタイザーを用いて、パンの傾斜角度45°、回転数15rpmで5分間造粒した(PP有り)。
FIG. 7 shows the improvement rate of the NOx conversion rate when the granulation treatment is performed after compression molding by the compression molding apparatus and when the granulation product is added to the drum mixer and when the granulation product is added later. It is a graph. In the figure, DM is a drum mixer and PP is a pan pelletizer.
For the granulation of the coagulated material, a high-speed stirring mixer is used, 10% of quicklime is added to the coagulated material containing 25% by mass of fine powder of 0.25 mm or less to adjust the moisture to 15% by mass, and the rotation speed of the pan is 13 rpm. The agitator was granulated for 300 seconds at a rotational speed of 300 rpm. The granulated product granulated by the high-speed stirring mixer was compression-molded at a linear pressure of 0.3 ton / cm using a briquette manufacturing machine having a roll diameter of 200 mm (without PP). Further, this molded product was granulated with a pan pelletizer having a diameter of 1 m for 5 minutes at a pan inclination angle of 45 ° and a rotation speed of 15 rpm (with PP).

同図より、いずれの条件においてもパンペレタイザー造粒を追加することで、NOx転換率の改善割合が増大することがわかる。追加の造粒によって被覆厚みが増加するためと考えられる。
また、鉄鉱石を含む焼結原料を造粒するドラムミキサーの後段に造粒物を添加することによりNOx転換率の改善割合が顕著に増大することが同図よりわかる。ドラムミキサー内における生石灰及び/又は消石灰の被覆層の剥離や造粒物の崩壊が抑えられ、緻密な被覆層や造粒物が確保されるためと考えられる。
From the figure, it can be seen that the improvement rate of the NOx conversion rate increases by adding the pan pelletizer granulation under any condition. This is probably because the coating thickness increases due to the additional granulation.
In addition, it can be seen from the figure that the improvement rate of the NOx conversion rate is remarkably increased by adding the granulated material after the drum mixer for granulating the sintered raw material containing iron ore. It is considered that peeling of the coating layer of quick lime and / or slaked lime in the drum mixer and collapse of the granulated product are suppressed, and a dense coating layer and granulated product are secured.

10:混練装置、11:圧縮成形装置、12:パンペレタイザー、13〜17:貯留槽、18:一時貯留槽、19:ドラムミキサー、20:焼結機、21:ホッパ、22:ロール、23:スクリューフィーダ 10: kneading apparatus, 11: compression molding apparatus, 12: pan pelletizer, 13-17: storage tank, 18: temporary storage tank, 19: drum mixer, 20: sintering machine, 21: hopper, 22: roll, 23: Screw feeder

Claims (7)

鉄鋼製造用焼結鉱の製造に用いる凝結材を生石灰及び/又は消石灰と共に混練装置に装入して水分の存在下で造粒し、造粒された造粒物を圧縮成形装置に供給して圧縮成形した後、鉄鉱石を含む焼結原料を造粒するドラムミキサーに添加することを特徴とする焼結鉱の製造方法。   The coagulation material used for the production of sintered ore for steel production is charged into a kneading device together with quicklime and / or slaked lime, granulated in the presence of moisture, and the granulated product is supplied to a compression molding device. A method for producing sintered ore, comprising adding a sintered raw material containing iron ore to a drum mixer for granulating after compression molding. 請求項1記載の焼結鉱の製造方法において、前記凝結材は、粒度0.25mmアンダーの微粉を20質量%以上含むことを特徴とする焼結鉱の製造方法。   2. The method for producing a sintered ore according to claim 1, wherein the coagulant contains 20% by mass or more of fine powder having a particle size of 0.25 mm or less. 請求項1又は2記載の焼結鉱の製造方法において、前記混練装置による造粒を60秒間以上行うことを特徴とする焼結鉱の製造方法。   3. The method for producing a sintered ore according to claim 1, wherein granulation by the kneading apparatus is performed for 60 seconds or more. 請求項1〜3のいずれか1項に記載の焼結鉱の製造方法において、前記混練装置による造粒時の水分が10質量%以上となるように水分調整を行うことを特徴とする焼結鉱の製造方法。   The method for producing a sintered ore according to any one of claims 1 to 3, wherein moisture adjustment is performed so that moisture at the time of granulation by the kneading apparatus is 10% by mass or more. Manufacturing method of ore. 請求項1〜4のいずれか1項に記載の焼結鉱の製造方法において、圧縮成形された前記造粒物を造粒装置を用いてさらに造粒処理することを特徴とする焼結鉱の製造方法。   In the manufacturing method of the sintered ore of any one of Claims 1-4, the granulation process is further granulated using the granulation apparatus of the said granulated material by compression molding, The sintered ore characterized by the above-mentioned. Production method. 請求項1〜4のいずれか1項に記載の焼結鉱の製造方法において、圧縮成形された前記造粒物を前記ドラムミキサーの後段に添加することを特徴とする焼結鉱の製造方法。   5. The method for producing a sintered ore according to claim 1, wherein the granulated product that has been compression-molded is added to a subsequent stage of the drum mixer. 請求項5記載の焼結鉱の製造方法において、前記造粒装置で造粒処理された造粒物を前記ドラムミキサーの後段に添加することを特徴とする焼結鉱の製造方法。   6. The method for producing a sintered ore according to claim 5, wherein the granulated product granulated by the granulator is added to the subsequent stage of the drum mixer.
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