JP6292438B2 - 二糖類化合物、変性オルガノポリシロキサン化合物及び界面活性剤 - Google Patents
二糖類化合物、変性オルガノポリシロキサン化合物及び界面活性剤 Download PDFInfo
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- JP6292438B2 JP6292438B2 JP2013252090A JP2013252090A JP6292438B2 JP 6292438 B2 JP6292438 B2 JP 6292438B2 JP 2013252090 A JP2013252090 A JP 2013252090A JP 2013252090 A JP2013252090 A JP 2013252090A JP 6292438 B2 JP6292438 B2 JP 6292438B2
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- disaccharide
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- modified organopolysiloxane
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- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 239000008278 cosmetic cream Substances 0.000 description 1
- 239000008271 cosmetic emulsion Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 1
- SBZXBUIDTXKZTM-UHFFFAOYSA-N diglyme Chemical compound COCCOCCOC SBZXBUIDTXKZTM-UHFFFAOYSA-N 0.000 description 1
- ZBZBIUAFLQPECG-UHFFFAOYSA-N diisocyanatomethane hex-1-ene Chemical compound C(N=C=O)N=C=O.C=CCCCC ZBZBIUAFLQPECG-UHFFFAOYSA-N 0.000 description 1
- 239000003822 epoxy resin Substances 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- HDERJYVLTPVNRI-UHFFFAOYSA-N ethene;ethenyl acetate Chemical group C=C.CC(=O)OC=C HDERJYVLTPVNRI-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229920001038 ethylene copolymer Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000001815 facial effect Effects 0.000 description 1
- 239000003925 fat Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- DLRVVLDZNNYCBX-CQUJWQHSSA-N gentiobiose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)C(O)O1 DLRVVLDZNNYCBX-CQUJWQHSSA-N 0.000 description 1
- 150000002276 gentiobiuloses Chemical class 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002366 halogen compounds Chemical class 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- DLRVVLDZNNYCBX-RTPHMHGBSA-N isomaltose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1OC[C@@H]1[C@@H](O)[C@H](O)[C@@H](O)C(O)O1 DLRVVLDZNNYCBX-RTPHMHGBSA-N 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 125000000468 ketone group Chemical group 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 229960001375 lactose Drugs 0.000 description 1
- JCQLYHFGKNRPGE-FCVZTGTOSA-N lactulose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 JCQLYHFGKNRPGE-FCVZTGTOSA-N 0.000 description 1
- 229960000511 lactulose Drugs 0.000 description 1
- PFCRQPBOOFTZGQ-UHFFFAOYSA-N lactulose keto form Natural products OCC(=O)C(O)C(C(O)CO)OC1OC(CO)C(O)C(O)C1O PFCRQPBOOFTZGQ-UHFFFAOYSA-N 0.000 description 1
- QIGJYVCQYDKYDW-LCOYTZNXSA-N laminarabiose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@H]1[C@H](O)[C@@H](CO)OC(O)[C@@H]1O QIGJYVCQYDKYDW-LCOYTZNXSA-N 0.000 description 1
- 239000011968 lewis acid catalyst Substances 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 239000007934 lip balm Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 229960002160 maltose Drugs 0.000 description 1
- JCQLYHFGKNRPGE-HFZVAGMNSA-N maltulose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 JCQLYHFGKNRPGE-HFZVAGMNSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- QIGJYVCQYDKYDW-NSYYTRPSSA-N nigerose Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](CO)OC(O)[C@@H]1O QIGJYVCQYDKYDW-NSYYTRPSSA-N 0.000 description 1
- 125000000962 organic group Chemical group 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- XOPPYWGGTZVUFP-DLWPFLMGSA-N primeverose Chemical compound O=C[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO[C@@H]1OC[C@@H](O)[C@H](O)[C@H]1O XOPPYWGGTZVUFP-DLWPFLMGSA-N 0.000 description 1
- QYNRIDLOTGRNML-UHFFFAOYSA-N primeverose Natural products OC1C(O)C(O)COC1OCC1C(O)C(O)C(O)C(O)O1 QYNRIDLOTGRNML-UHFFFAOYSA-N 0.000 description 1
- LVTJOONKWUXEFR-FZRMHRINSA-N protoneodioscin Natural products O(C[C@@H](CC[C@]1(O)[C@H](C)[C@@H]2[C@]3(C)[C@H]([C@H]4[C@@H]([C@]5(C)C(=CC4)C[C@@H](O[C@@H]4[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@@H](O)[C@H](O[C@H]6[C@@H](O)[C@@H](O)[C@@H](O)[C@H](C)O6)[C@H](CO)O4)CC5)CC3)C[C@@H]2O1)C)[C@H]1[C@H](O)[C@H](O)[C@H](O)[C@@H](CO)O1 LVTJOONKWUXEFR-FZRMHRINSA-N 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- HIWPGCMGAMJNRG-RTPHMHGBSA-N sophorose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)OC(O)[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 HIWPGCMGAMJNRG-RTPHMHGBSA-N 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 229960004793 sucrose Drugs 0.000 description 1
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 description 1
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 229940074409 trehalose dihydrate Drugs 0.000 description 1
- RULSWEULPANCDV-PIXUTMIVSA-N turanose Chemical compound OC[C@@H](O)[C@@H](O)[C@@H](C(=O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O RULSWEULPANCDV-PIXUTMIVSA-N 0.000 description 1
- 238000010792 warming Methods 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H15/00—Compounds containing hydrocarbon or substituted hydrocarbon radicals directly attached to hetero atoms of saccharide radicals
- C07H15/02—Acyclic radicals, not substituted by cyclic structures
- C07H15/04—Acyclic radicals, not substituted by cyclic structures attached to an oxygen atom of the saccharide radical
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/10—Washing or bathing preparations
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/38—Polysiloxanes modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/10—Block- or graft-copolymers containing polysiloxane sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/12—Polysiloxanes containing silicon bound to hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/42—Block-or graft-polymers containing polysiloxane sequences
Landscapes
- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Animal Behavior & Ethology (AREA)
- Organic Chemistry (AREA)
- Veterinary Medicine (AREA)
- Dermatology (AREA)
- Epidemiology (AREA)
- Birds (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Biotechnology (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Genetics & Genomics (AREA)
- Molecular Biology (AREA)
- General Chemical & Material Sciences (AREA)
- Cosmetics (AREA)
- Silicon Polymers (AREA)
- Saccharide Compounds (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Paints Or Removers (AREA)
Description
まず、本発明の二糖類化合物について説明する。
本発明の二糖類化合物は、二糖類と、アリル基及びエポキシ基を有する化合物とを反応させることにより得られたことを特徴とする。
次に、本発明の変性オルガノポリシロキサン化合物について説明する。
本発明の変性オルガノポリシロキサン化合物は、本発明の二糖類化合物と、ハイドロジェンポリシロキサンとをヒドロシリル化反応させることにより得られたことを特徴とする。
本発明の界面活性剤は、本発明の変性ポリオルガノシロキサン化合物を含有することを特徴とする。
次に、本発明の化粧品について説明する。本発明の化粧品は、本発明の界面活性剤を含有することを特徴とし、そのため分散安定性に優れる。本発明の化粧品は、本発明の界面活性剤に加えて、任意に他の成分を含有していても良い。他の成分としては、特に限定されないが、例えば、精製水、アルコール類(低級アルコール、多価アルコールなど)、油脂類、ロウ類、炭化水素類等の基剤や、増粘剤、紫外線吸収剤、紫外線散乱剤、安定剤、防腐剤、着色剤、香料等の添加剤等が挙げられる。
次に、本発明の発泡材料について説明する。本発明の発泡材料は、本発明の界面活性剤を含有することを特徴とする。本発明の発泡材料において、本発明の界面活性剤は整泡剤として機能する。本発明の発泡材料は、本発明の界面活性剤に加えて、任意に他の成分を含有していても良い。他の成分としては、特に限定されないが、例えば、ポリオール成分、発泡剤、イソシアネート成分、触媒、酸化防止剤、紫外線吸収剤、光安定剤、難燃剤、着色剤、フィラー、有機界面活性剤、フロン類、炭化水素類等が挙げられる。
次に、本発明の塗料について説明する。本発明の塗料は、本発明の界面活性剤を含有することを特徴とし、そのため分散安定性に優れる。本発明の塗料は、本発明の界面活性剤に加えて、任意に他の成分を含有していても良い。他の成分としては、特に限定されないが、例えば、溶剤、顔料等が挙げられる。
1Lのセパラブルフラスコに、トレハロース二水和物(林原社製)200.0g、45%ホウフッ化亜鉛水溶液7.0g、イオン交換水25mLを仕込み、攪拌しながら100℃まで昇温した後、アリルグリシジルエーテル(東京化成工業社製)600.2gを滴下し、3時間反応を行った。反応終了後、撹拌しながら、反応物に48%水酸化ナトリウム水溶液を1.5g加え、pHを5〜8に調整した。反応物をアセトン1L中に滴下し、沈澱物をアセトンで洗浄した。これを80℃、10hPa(ゲージ圧)以下で減圧乾燥し、トレハロースAGE反応物125.0gを得た。液体クロマトグラフ質量分析計(Waters社製、micromass ZQ)を用いたLC−MS質量分析の結果、M−1が341、455、569、683である、4つのピークが検出され、それぞれトレハロース原料、1置換体、2置換体、3置換体に対応する分子量であることを確認した。
次に、50mLナスフラスコに、トレハロースAGE反応物5.0g、ハイドロジェンポリシロキサン(アヅマックス社製、HMS−301)5.4g、塩化白金酸・六水和物の0.5%イソプロパノール溶液0.13g、イソプロパノール5.4g、メタノール8.0gを仕込み、撹拌しながら、90℃まで昇温した後、2時間反応を行った。反応物を室温にて、10hPa(ゲージ圧)以下で減圧乾燥し、変性オルガノポリシロキサンA10.8gを得た。
1Lのセパラブルフラスコに、キシリトール(東京化成工業社製)400.0g、45%ホウフッ化亜鉛水溶液34.9gを仕込み、攪拌しながら100℃まで昇温した後、アリルグリシジルエーテル(東京化成工業社製)360.1gを滴下し、5時間反応を行った。反応終了後、撹拌しながら、反応物に48%水酸化ナトリウム水溶液を2g加え、pHを5〜8に調整した。これを80℃、10hPa(ゲージ圧)以下で減圧乾燥し、キシリトールAGE反応物692.1gを得た。液体クロマトグラフ質量分析計(Waters社製、micromass ZQ)を用いたLC−MS質量分析の結果、M−1が151、265、379、493、607、721である、6つのピークが検出され、それぞれキシリトール原料、1置換体、2置換体、3置換体、4置換体、5置換体に対応する分子量であることを確認した。
次に、50mLナスフラスコに、キシリトールAGE反応物2.0 g、ハイドロジェンポリシロキサン(アヅマックス社製、HMS−301)3.7g、塩化白金酸・六水和物の0.5%イソプロパノール溶液0.10g、イソプロパノール3.7g、メタノール3.0gを仕込み、撹拌しながら、90℃まで昇温した後、2時間反応を行った。反応物を室温にて、10hPa(ゲージ圧)以下で減圧乾燥し、変性オルガノポリシロキサンB5.2gを得た。
特許文献1の実施例1の方法にて、キシリトールとアリルクロライドとの反応物で変性された変性オルガノポリシロキサンCを合成した。13C−NMR分析の結果、δ(ppm):1.0、1.6、14.5、24.3、64.3、72.1、72.2、73.2、74.0、75.1であり、特許文献1に記載のデータと一致していることを確認した。
合成例1で得られた変性オルガノポリシロキサン化合物A1.0g、イオン交換水5mL、シリコーンオイル(信越化学工業社製、KF−968)5mLをスクリュー管に仕込み、室温下、ホモジナイザーで5分間撹拌することにより乳化物を得た。
合成例1で得られた変性オルガノポリシロキサン化合物Aに代えて、合成例2で得られた変性オルガノポリシロキサン化合物B、又は、合成例3で得られた変性オルガノポリシロキサン化合物Cを用いたこと以外、実施例1と同様にして乳化物を得た。
実施例1及び比較例1、2で得られた乳化物を室温下にて放置し、5分後、1日後、1週間後のそれぞれの分離状態を目視により確認した。分離が確認されなかったものを○、分離が確認されたものを×として評価した。結果を表1に示す。
シリコーン変性剤として、キシリトールとアリルクロライドとの反応物を用いた比較例2では、わずか5分後に分離が確認され、ほとんど乳化安定性を確保することができなかった。キシリトールとアリルグリシジルエーテルとの反応物を用いた比較例1では、5分後、1日後の乳化安定性は確保されたものの、1週間後には分離が確認され、乳化安定性が不充分となっている。これに対し、トレハロースとアリルグリシジルエーテルとの反応物を用いた実施例1では、5分後、1日後だけでなく、1週間後にも乳化安定性が確保されている。
Claims (7)
- 前記二糖類は、トレハロースである請求項1に記載の二糖類化合物。
- 請求項1又は2記載の二糖類化合物と、ハイドロジェンポリシロキサンとをヒドロシリル化反応させることにより得られたことを特徴とする変性オルガノポリシロキサン化合物。
- 請求項3記載の変性オルガノポリシロキサン化合物を含有することを特徴とする界面活性剤。
- 請求項4記載の界面活性剤を含有することを特徴とする化粧品。
- 請求項4記載の界面活性剤を含有することを特徴とする発泡材料。
- 請求項4記載の界面活性剤を含有することを特徴とする塗料。
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