JP6263178B2 - 分配水素抽出システム - Google Patents
分配水素抽出システム Download PDFInfo
- Publication number
- JP6263178B2 JP6263178B2 JP2015524335A JP2015524335A JP6263178B2 JP 6263178 B2 JP6263178 B2 JP 6263178B2 JP 2015524335 A JP2015524335 A JP 2015524335A JP 2015524335 A JP2015524335 A JP 2015524335A JP 6263178 B2 JP6263178 B2 JP 6263178B2
- Authority
- JP
- Japan
- Prior art keywords
- hydrogen
- gas
- mixture
- sulfur
- gas mixture
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims description 133
- 229910052739 hydrogen Inorganic materials 0.000 title claims description 101
- 239000001257 hydrogen Substances 0.000 title claims description 101
- 238000000605 extraction Methods 0.000 title claims description 32
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 109
- 239000000203 mixture Substances 0.000 claims description 59
- 239000007789 gas Substances 0.000 claims description 57
- 239000003345 natural gas Substances 0.000 claims description 53
- 238000006477 desulfuration reaction Methods 0.000 claims description 30
- 230000023556 desulfurization Effects 0.000 claims description 30
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 26
- 229910052717 sulfur Inorganic materials 0.000 claims description 26
- 239000011593 sulfur Substances 0.000 claims description 26
- 239000012530 fluid Substances 0.000 claims description 22
- 239000012528 membrane Substances 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 20
- 230000005611 electricity Effects 0.000 claims description 10
- 239000000446 fuel Substances 0.000 claims description 10
- 150000002431 hydrogen Chemical class 0.000 claims description 10
- 238000003860 storage Methods 0.000 claims description 8
- 238000001179 sorption measurement Methods 0.000 claims description 4
- 238000009826 distribution Methods 0.000 description 12
- 238000010586 diagram Methods 0.000 description 11
- 238000012544 monitoring process Methods 0.000 description 10
- 239000000284 extract Substances 0.000 description 4
- 238000011065 in-situ storage Methods 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000012423 maintenance Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000012466 permeate Substances 0.000 description 2
- 230000008929 regeneration Effects 0.000 description 2
- 238000011069 regeneration method Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002803 fossil fuel Substances 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 239000012510 hollow fiber Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 229920005597 polymer membrane Polymers 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04082—Arrangements for control of reactant parameters, e.g. pressure or concentration
- H01M8/04201—Reactant storage and supply, e.g. means for feeding, pipes
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0462—Temperature swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/047—Pressure swing adsorption
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
- B01D53/229—Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption)
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/32—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00
- B01D53/326—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by electrical effects other than those provided for in group B01D61/00 in electrochemical cells
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/50—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification
- C01B3/56—Separation of hydrogen or hydrogen containing gases from gaseous mixtures, e.g. purification by contacting with solids; Regeneration of used solids
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
- C10L3/101—Removal of contaminants
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
- C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
- C10L3/10—Working-up natural gas or synthetic natural gas
- C10L3/101—Removal of contaminants
- C10L3/102—Removal of contaminants of acid contaminants
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06Q—INFORMATION AND COMMUNICATION TECHNOLOGY [ICT] SPECIALLY ADAPTED FOR ADMINISTRATIVE, COMMERCIAL, FINANCIAL, MANAGERIAL OR SUPERVISORY PURPOSES; SYSTEMS OR METHODS SPECIALLY ADAPTED FOR ADMINISTRATIVE, COMMERCIAL, FINANCIAL, MANAGERIAL OR SUPERVISORY PURPOSES, NOT OTHERWISE PROVIDED FOR
- G06Q30/00—Commerce
- G06Q30/02—Marketing; Price estimation or determination; Fundraising
- G06Q30/0283—Price estimation or determination
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06Q—INFORMATION AND COMMUNICATION TECHNOLOGY [ICT] SPECIALLY ADAPTED FOR ADMINISTRATIVE, COMMERCIAL, FINANCIAL, MANAGERIAL OR SUPERVISORY PURPOSES; SYSTEMS OR METHODS SPECIALLY ADAPTED FOR ADMINISTRATIVE, COMMERCIAL, FINANCIAL, MANAGERIAL OR SUPERVISORY PURPOSES, NOT OTHERWISE PROVIDED FOR
- G06Q50/00—Information and communication technology [ICT] specially adapted for implementation of business processes of specific business sectors, e.g. utilities or tourism
- G06Q50/06—Energy or water supply
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
- H01M8/0675—Removal of sulfur
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/06—Combination of fuel cells with means for production of reactants or for treatment of residues
- H01M8/0662—Treatment of gaseous reactants or gaseous residues, e.g. cleaning
- H01M8/0681—Reactant purification by the use of electrochemical cells
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2256/00—Main component in the product gas stream after treatment
- B01D2256/16—Hydrogen
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0405—Purification by membrane separation
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/042—Purification by adsorption on solids
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/042—Purification by adsorption on solids
- C01B2203/043—Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/048—Composition of the impurity the impurity being an organic compound
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/04—Integrated processes for the production of hydrogen or synthesis gas containing a purification step for the hydrogen or the synthesis gas
- C01B2203/0465—Composition of the impurity
- C01B2203/0485—Composition of the impurity the impurity being a sulfur compound
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
- C01B2203/06—Integration with other chemical processes
- C01B2203/066—Integration with other chemical processes with fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/32—Hydrogen storage
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Business, Economics & Management (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Analytical Chemistry (AREA)
- Electrochemistry (AREA)
- Development Economics (AREA)
- Strategic Management (AREA)
- Economics (AREA)
- Sustainable Energy (AREA)
- Sustainable Development (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Finance (AREA)
- Accounting & Taxation (AREA)
- Marketing (AREA)
- Physics & Mathematics (AREA)
- General Business, Economics & Management (AREA)
- General Physics & Mathematics (AREA)
- Theoretical Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Combustion & Propulsion (AREA)
- Game Theory and Decision Science (AREA)
- Entrepreneurship & Innovation (AREA)
- Tourism & Hospitality (AREA)
- Public Health (AREA)
- General Health & Medical Sciences (AREA)
- Water Supply & Treatment (AREA)
- Primary Health Care (AREA)
- Human Resources & Organizations (AREA)
- Hydrogen, Water And Hydrids (AREA)
- Filling Or Discharging Of Gas Storage Vessels (AREA)
- Separation By Low-Temperature Treatments (AREA)
- Fuel Cell (AREA)
- Compressor (AREA)
- Pipeline Systems (AREA)
Description
(式中、VH2は水素ガスに関する市場価値因子を表し、mH2は水素ガスの質量流量を表し、VNGはNGに関する市場価値因子を表し、cfmは計量器400から読み取られる全質量流量を表す)
[0049]図5Bは、消費者がパイプライン30によって供給される気体混合物から水素ガスのみを抽出し、全てのNGをパイプライン30に戻すシナリオを示す。上記で説明したように、消費者に請求される価格は、2以上の計算値の合計であってよい。第1の計算値は、消費されたエネルギーに水素の市場価値を乗じた値に比例させることができる。第2の計算値は、パイプライン30へのNGの戻りによって減じられるエネルギー価値に比例させることができる。以下の等式(式2)を用いてエネルギー価格を決定することができる。
(式中、Fdepletionは、消費者の水素ガスの抽出によってNGネットワークから減じられる価値を計上する因子を表し、他の変数は式1に関して上記に記載した通りである)
[0050]図5Cは、消費者がパイプライン30によって供給される気体混合物からNGのみを抽出し、全ての水素ガスをパイプライン30に戻すシナリオを示す。消費者へ請求される価格は、2つの計算値の間の差にすることができる。第1の計算値は、消費されたエネルギーにNGに関する市場価値を乗じた値に比例させることができる。第2の計算値は、パイプライン30への水素ガスの戻りによって加えられるエネルギー価値に比例させることができる。以下の等式(式3)を用いてエネルギー価格を決定することができる。
(式中、Fadditionは、消費者の水素ガスの戻しによってNGネットワークに加えられる価値を計上する因子を表し、他の変数は式1に関して上記に記載した通りである)
[0051]本発明の他の態様は、本明細書及び本明細書において開示する概念の実施を考察することによって当業者に明らかになるであろう。例えば、NG以外の他のタイプの気体又は流体を、上記の発明に関して用いることができる。更に、上記のシステムの1以上の機能又は構成要素を単一のユニットに組み合わせることができる。更に、上記に記載のものと異なるパラメーターを用いるが、同様の概念又は原理を用いる異なる等式又はアルゴリズムを用いることができる。明細書及び実施例は例示のみのものと考えられ、本発明の真の範囲及び精神は特許請求の範囲によって示されると意図される。
Claims (20)
- 水素を含む気体混合物を圧縮する圧縮器;
圧縮された気体混合物を受容する脱硫ユニット;
脱硫ユニットからイオウが減少した気体混合物を受容する水素抽出装置;及び
抽出された水素ガスを受容する水素貯蔵装置;
を含む水素抽出システム。 - 脱硫ユニットによって、圧縮された気体混合物中に含まれるイオウの少なくとも一部を除去してイオウが減少した気体混合物を生成させる、請求項1に記載のシステム。
- 水素抽出装置によって、イオウが減少した気体混合物中に含まれる水素の少なくとも一部を除去して抽出された水素ガスを生成させる、請求項1に記載のシステム。
- 水素抽出システムが、天然ガス及び水素ガスを含む気体混合物を供給するネットワークに流体接続されている、請求項1に記載のシステム。
- 脱硫ユニットが、イオウが減少した気体混合物から水素の少なくとも一部を除去した後の水素抽出装置からのイオウが減少した気体混合物の供給流を更に受容し、イオウが減少した気体混合物の供給流を圧縮された気体混合物から除去されるイオウと混合し、混合した気体混合物をネットワークに戻す、請求項4に記載のシステム。
- 水素抽出装置が圧力スイング吸着装置を含む、請求項1に記載のシステム。
- 圧縮器から排出される圧縮された気体混合物を受容する選択膜装置を更に含み、選択膜装置が、圧縮された気体混合物の水素濃度を増加させる水素選択膜を含む、請求項6に記載のシステム。
- 選択膜装置によって水素富化流体を脱硫ユニットに供給する、請求項7に記載のシステム。
- 水素抽出装置が電気化学スタックを含む、請求項1に記載のシステム。
- 電気化学スタックが、抽出された水素ガスを少なくとも部分的に精製及び圧縮するように構成されている、請求項9に記載のシステム。
- 抽出された水素ガスを受容し、電気を生成させる燃料電池を更に含む、請求項1に記載のシステム。
- 気体混合物を圧縮し;
圧縮された気体混合物中に含まれるイオウの少なくとも一部を除去して、イオウに富む流れ及びイオウが減少した混合物を形成し;
水素抽出装置において脱硫ユニットからのイオウが減少した混合物を受容し;
イオウが減少した混合物中に含まれる水素の少なくとも一部を除去して、水素貧化混合物及び水素ガスを形成し;そして
水素ガスを水素貯蔵装置に供給する;
ことを含む、天然ガス及び水素を含む気体混合物から水素を抽出する方法。 - ネットワークから気体混合物を受容し;
水素貧化混合物をイオウに富む流れと混合して再硫化混合物を形成し;そして
再硫化混合物をネットワークに供給する;
ことを更に含む、請求項12に記載の方法。 - ネットワークが既存の天然ガスネットワークを含む、請求項13に記載の方法。
- 膜を通して水素を選択的に通過させて水素ガス濃度を増加させることを更に含む、請求項12に記載の方法。
- 貯蔵された水素ガスを燃料電池に供給して電気を生成させることを更に含む、請求項12に記載の方法。
- (a)水素ガスの質量流量を求め;
(b)天然ガスの質量流量を求め;
(c)水素ガスの質量流量に、水素ガスに関する因子を乗じ;
(d)天然ガスの質量流量に、天然ガスに関する因子を乗じ;そして
(e)工程(c)及び工程(d)の値を合計する;
ことを含む、気体混合物のためのエネルギー価格を決定することを更に含む、請求項12に記載の方法。 - 水素ガス及び天然ガスを含む気体混合物の流量から水素ガスの質量流量を減じることによって天然ガスの質量流量を求める、請求項17に記載の方法。
- 水素ガスに関する因子が水素ガスに関する市場価値因子を含み、天然ガスに関する因子が天然ガスに関する市場価値因子を含む、請求項17に記載の方法。
- 水素ガスに関する因子が、ネットワークへの水素ガスの戻りによってネットワークに加えられる値を計上する因子を含み、天然ガスに関する因子が、ネットワークからの水素ガスの抽出によってネットワークから減じられる値を計上する因子を含む、請求項17に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US201261675041P | 2012-07-24 | 2012-07-24 | |
US61/675,041 | 2012-07-24 | ||
PCT/US2013/051286 WO2014018389A1 (en) | 2012-07-24 | 2013-07-19 | Distributed hydrogen extraction system |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2015524786A JP2015524786A (ja) | 2015-08-27 |
JP6263178B2 true JP6263178B2 (ja) | 2018-01-17 |
Family
ID=48917702
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2015524335A Active JP6263178B2 (ja) | 2012-07-24 | 2013-07-19 | 分配水素抽出システム |
Country Status (8)
Country | Link |
---|---|
US (3) | US9531024B2 (ja) |
EP (1) | EP2877426A1 (ja) |
JP (1) | JP6263178B2 (ja) |
KR (2) | KR101955897B1 (ja) |
CN (2) | CN110127612A (ja) |
BR (1) | BR112015001470A2 (ja) |
CA (1) | CA2879508C (ja) |
WO (1) | WO2014018389A1 (ja) |
Families Citing this family (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2912650A1 (en) | 2013-05-31 | 2014-12-04 | Nuvera Fuel Cells, Inc. | Distributed hydrogen refueling cascade method and system |
WO2015031116A1 (en) * | 2013-08-29 | 2015-03-05 | V-GRID Energy Systems | Hydrogen separation from synthesis gas near stp |
EP2979743B1 (de) * | 2014-07-28 | 2019-10-09 | RAG Austria AG | Vorrichtung und Verfahren zur Speicherung und Verteilung von erneuerbarer Energie |
JP6247623B2 (ja) * | 2014-10-10 | 2017-12-13 | 東京瓦斯株式会社 | 燃料電池システム |
EP3446349B1 (en) | 2016-04-21 | 2021-03-17 | Fuelcell Energy, Inc. | Molten carbonate fuel cell anode exhaust post-processing for carbon dioxide capture |
JP6799078B2 (ja) | 2016-04-29 | 2020-12-09 | フュエルセル エナジー, インコーポレイテッドFuelcell Energy, Inc. | 二酸化炭素捕捉を高めるためのアノード排ガスのメタン化 |
CN108977242B (zh) * | 2017-06-05 | 2022-08-23 | 通用电气公司 | 焦炉气体处理系统及其方法 |
KR102610181B1 (ko) | 2018-11-30 | 2023-12-04 | 퓨얼셀 에너지, 인크 | 향상된 co2 이용률로 작동되는 연료 전지를 위한 촉매 패턴의 개질 |
WO2020122709A1 (en) * | 2018-12-10 | 2020-06-18 | Technische Universiteit Eindhoven | Method for low hydrogen content separation from a natural gas mixture |
CN109784551A (zh) * | 2018-12-29 | 2019-05-21 | 重庆大学 | 一种考虑电解水与甲烷化运行特性的电转气系统优化调度方法 |
EP4118029A1 (en) | 2020-03-11 | 2023-01-18 | Fuelcell Energy, Inc. | Steam methane reforming unit for carbon capture |
JP2023521627A (ja) * | 2020-03-30 | 2023-05-25 | ビーエーエスエフ ソシエタス・ヨーロピア | パイプラインから水素を電気化学的に分離する方法 |
KR102437060B1 (ko) * | 2020-07-30 | 2022-08-25 | 중앙대학교 산학협력단 | 적층형 스택 구조를 가진 수소 압축기 |
DE102020211162A1 (de) | 2020-09-04 | 2022-03-10 | Volkswagen Aktiengesellschaft | Ladesäule zum Laden eines Stromspeichers eines Elektrofahrzeugs |
EP4001734B1 (de) | 2020-11-11 | 2023-08-23 | L'Air Liquide, Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude | Verfahren zum transportieren von wasserstoff |
CN113088990A (zh) * | 2021-03-29 | 2021-07-09 | 中国华能集团清洁能源技术研究院有限公司 | 一种天然气管道掺氢输运与氢气提取供应系统及运行方法 |
JPWO2022230120A1 (ja) * | 2021-04-28 | 2022-11-03 | ||
EP4332437A1 (en) * | 2021-04-28 | 2024-03-06 | Hitachi, Ltd. | Hydrogen supply system |
US11746427B2 (en) | 2021-07-05 | 2023-09-05 | EvolOH, Inc. | Scalable electrolysis cell and stack and method of high-speed manufacturing the same |
CN114561235B (zh) * | 2022-01-11 | 2022-12-13 | 广东省氢一能源科技有限公司 | 一种基于压力能回收的氢气天然气混输与分离装置及方法 |
JP2024040712A (ja) * | 2022-09-13 | 2024-03-26 | 株式会社日立製作所 | ガス価格管理システム及びガス価格管理方法 |
Family Cites Families (22)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1090479A (en) | 1965-09-06 | 1967-11-08 | Int Nickel Ltd | Separation of hydrogen from other gases |
EP0411506A2 (en) * | 1989-08-02 | 1991-02-06 | Air Products And Chemicals, Inc. | Production of hydrogen, carbon monoxide and mixtures thereof |
DE19615562C1 (de) * | 1996-04-19 | 1997-10-09 | Zsw | Vorrichtung und Verfahren zur kombinierten Reinigung und Kompression von CO-haltigem Wasserstoff sowie Verwendung des mit dem Verfahren erhaltenen Wasserstoffs als Brenngas in Brennstoffzellen |
JP2002020102A (ja) * | 2000-06-30 | 2002-01-23 | Mitsubishi Kakoki Kaisha Ltd | 水素製造装置の起動方法およびその停止方法 |
JP2002212575A (ja) * | 2001-01-16 | 2002-07-31 | Nippon Steel Corp | 精製コークス炉ガスの高度処理装置および利用方法 |
WO2002103833A1 (en) | 2001-06-15 | 2002-12-27 | Ztek Corporation | Zero/low emission and co-production energy supply station |
JP2003095612A (ja) * | 2001-09-25 | 2003-04-03 | Mitsubishi Kakoki Kaisha Ltd | 水素製造設備 |
FR2836061B1 (fr) * | 2002-02-15 | 2004-11-19 | Air Liquide | Procede de traitement d'un melange gazeux comprenant de l'hydrogene et du sulfure d'hydrogene |
JP2004079262A (ja) | 2002-08-13 | 2004-03-11 | Mitsubishi Heavy Ind Ltd | 水素供給システム及び移動式水素製造装置 |
JP3914118B2 (ja) * | 2002-08-30 | 2007-05-16 | 本田技研工業株式会社 | 水素供給装置 |
US20040112427A1 (en) * | 2002-12-16 | 2004-06-17 | Ballard Generation Systems | Hydrogen distribution systems and methods |
FR2857884B1 (fr) * | 2003-07-24 | 2006-11-24 | Air Liquide | Procede de production d'hydrogene par adsorption et installation pour la mise en oeuvre de ce procede |
US7405243B2 (en) * | 2004-03-08 | 2008-07-29 | Chevron U.S.A. Inc. | Hydrogen recovery from hydrocarbon synthesis processes |
WO2006083296A2 (en) | 2004-06-11 | 2006-08-10 | Nuvera Fuel Cells, Inc. | Fuel fired hydrogen generator |
JP2006169357A (ja) * | 2004-12-15 | 2006-06-29 | Nihonkai Gas Co Ltd | 水素混合都市ガスとその製造方法並びに都市ガス供給方法 |
US7354464B2 (en) * | 2004-12-17 | 2008-04-08 | Texaco Inc. | Apparatus and method for producing hydrogen |
US7909898B2 (en) * | 2006-02-01 | 2011-03-22 | Air Products And Chemicals, Inc. | Method of treating a gaseous mixture comprising hydrogen and carbon dioxide |
FR2904821B1 (fr) * | 2006-08-09 | 2009-02-20 | Air Liquide | Procede de purification d'hydrogene |
JP5105937B2 (ja) * | 2007-03-30 | 2012-12-26 | 学校法人早稲田大学 | 一酸化炭素濃度を低減する方法 |
DE102008031509A1 (de) * | 2008-07-03 | 2010-01-07 | Linde Aktiengesellschaft | Verfahren zur Abtrennung von Schwefel aus einem Schwefel-enthaltenden Gas |
US8313556B2 (en) * | 2009-02-17 | 2012-11-20 | Mcalister Technologies, Llc | Delivery systems with in-line selective extraction devices and associated methods of operation |
US8500868B2 (en) * | 2009-05-01 | 2013-08-06 | Massachusetts Institute Of Technology | Systems and methods for the separation of carbon dioxide and water |
-
2013
- 2013-07-19 KR KR1020157003926A patent/KR101955897B1/ko active IP Right Grant
- 2013-07-19 WO PCT/US2013/051286 patent/WO2014018389A1/en active Application Filing
- 2013-07-19 KR KR1020197005467A patent/KR20190021497A/ko not_active Application Discontinuation
- 2013-07-19 CN CN201910357492.2A patent/CN110127612A/zh active Pending
- 2013-07-19 JP JP2015524335A patent/JP6263178B2/ja active Active
- 2013-07-19 CA CA2879508A patent/CA2879508C/en active Active
- 2013-07-19 CN CN201380049444.8A patent/CN104661954A/zh active Pending
- 2013-07-19 US US13/946,537 patent/US9531024B2/en active Active
- 2013-07-19 BR BR112015001470A patent/BR112015001470A2/pt not_active IP Right Cessation
- 2013-07-19 EP EP13745513.5A patent/EP2877426A1/en not_active Withdrawn
-
2016
- 2016-11-17 US US15/353,818 patent/US10103395B2/en active Active
-
2018
- 2018-09-17 US US16/132,834 patent/US20190013532A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
US20190013532A1 (en) | 2019-01-10 |
US20170069921A1 (en) | 2017-03-09 |
CN104661954A (zh) | 2015-05-27 |
CN110127612A (zh) | 2019-08-16 |
CA2879508A1 (en) | 2014-01-30 |
JP2015524786A (ja) | 2015-08-27 |
US20140030615A1 (en) | 2014-01-30 |
US10103395B2 (en) | 2018-10-16 |
KR101955897B1 (ko) | 2019-03-11 |
US9531024B2 (en) | 2016-12-27 |
EP2877426A1 (en) | 2015-06-03 |
CA2879508C (en) | 2019-12-17 |
KR20150038081A (ko) | 2015-04-08 |
BR112015001470A2 (pt) | 2017-07-04 |
WO2014018389A1 (en) | 2014-01-30 |
WO2014018389A8 (en) | 2015-03-12 |
KR20190021497A (ko) | 2019-03-05 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6263178B2 (ja) | 分配水素抽出システム | |
Yáñez et al. | PSA purification of waste hydrogen from ammonia plants to fuel cell grade | |
Hu et al. | A review of technical advances, barriers, and solutions in the power to hydrogen (P2H) roadmap | |
JP6356237B2 (ja) | ガス充填方法、及びステーション | |
EP3388135B1 (en) | Ammonia removal equipment, ammonia removal method, and hydrogen gas production method | |
Calbry-Muzyka et al. | Direct methanation of biogas—technical challenges and recent progress | |
Peppers et al. | Performance analysis of membrane separation for upgrading biogas to biomethane at small scale production sites | |
US20220226775A1 (en) | System for processing of biogas to produce electricity in fuel cells | |
JP4886229B2 (ja) | 水素ステーション | |
Burgers et al. | Techno-economic analysis of PSA separation for hydrogen/natural gas mixtures at hydrogen refuelling stations | |
CN103159192B (zh) | 氦气的纯化方法和纯化装置 | |
CN103523822A (zh) | 氦气的纯化方法及纯化装置 | |
WO2006132040A1 (ja) | 高純度水素製造方法 | |
JP6375255B2 (ja) | 水素充填設備、及び、水素充填設備での品質管理方法 | |
Ruan et al. | Multi-technique integration separation frameworks after steam reforming for coal-based hydrogen generation | |
Joo et al. | A novel on-site SMR process integrated with a hollow fiber membrane module for efficient blue hydrogen production: Modeling, validation, and techno-economic analysis | |
CN204387673U (zh) | Lng撬装加气站 | |
JP2005353497A (ja) | 燃料電池用燃料供給装置 | |
CN103224225B (zh) | 氩气的纯化方法及纯化装置 | |
Burgers | Novel technology for hydrogen separation from natural gas using pressure Swing adsorption | |
Pan et al. | Design and operation of the hydrogen supply chain for fuel-cell vehicles in Expo Shanghai 2010 | |
Racanella | Techno-economic assessment of manure to hydrogen plants: a real case study based on a cattle farm in an isolated location | |
WO2022230124A1 (ja) | 水素需給管理方法、および、水素需給管理装置 | |
Hu et al. | A review of technical advances, barriers, and solutions in the power to hydrogen roadmap | |
Yáñez Díaz | Hydrogen recovery from industrial waste gas streams for fuel cell application |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20160620 |
|
A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20170328 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20170330 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20170630 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20171116 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20171215 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6263178 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |