JP6212219B2 - 新規なキレート化剤の組合せによる相乗的汚れ除去 - Google Patents
新規なキレート化剤の組合せによる相乗的汚れ除去 Download PDFInfo
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- JP6212219B2 JP6212219B2 JP2016539424A JP2016539424A JP6212219B2 JP 6212219 B2 JP6212219 B2 JP 6212219B2 JP 2016539424 A JP2016539424 A JP 2016539424A JP 2016539424 A JP2016539424 A JP 2016539424A JP 6212219 B2 JP6212219 B2 JP 6212219B2
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- cleaning composition
- concentrated cleaning
- alkali metal
- acid
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- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
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- PDEFQWNXOUGDJR-UHFFFAOYSA-M sodium;2,2-dichloropropanoate Chemical compound [Na+].CC(Cl)(Cl)C([O-])=O PDEFQWNXOUGDJR-UHFFFAOYSA-M 0.000 description 1
- YDLQSTFHBCVEJV-UHFFFAOYSA-M sodium;2-(3,5,5-trimethylhexanoyloxy)benzenesulfonate Chemical compound [Na+].CC(C)(C)CC(C)CC(=O)OC1=CC=CC=C1S([O-])(=O)=O YDLQSTFHBCVEJV-UHFFFAOYSA-M 0.000 description 1
- OVONNAXAHAIEDF-UHFFFAOYSA-M sodium;4-benzoyloxybenzenesulfonate Chemical compound [Na+].C1=CC(S(=O)(=O)[O-])=CC=C1OC(=O)C1=CC=CC=C1 OVONNAXAHAIEDF-UHFFFAOYSA-M 0.000 description 1
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- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 1
- UZVUJVFQFNHRSY-OUTKXMMCSA-J tetrasodium;(2s)-2-[bis(carboxylatomethyl)amino]pentanedioate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CC[C@@H](C([O-])=O)N(CC([O-])=O)CC([O-])=O UZVUJVFQFNHRSY-OUTKXMMCSA-J 0.000 description 1
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- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- OHOTVSOGTVKXEL-UHFFFAOYSA-K trisodium;2-[bis(carboxylatomethyl)amino]propanoate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)C(C)N(CC([O-])=O)CC([O-])=O OHOTVSOGTVKXEL-UHFFFAOYSA-K 0.000 description 1
- 239000012588 trypsin Substances 0.000 description 1
- AQLJVWUFPCUVLO-UHFFFAOYSA-N urea hydrogen peroxide Chemical compound OO.NC(N)=O AQLJVWUFPCUVLO-UHFFFAOYSA-N 0.000 description 1
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- 235000012141 vanillin Nutrition 0.000 description 1
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/10—Carbonates ; Bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/06—Phosphates, including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/12—Carbonates bicarbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/02—Inorganic compounds
- C11D7/04—Water-soluble compounds
- C11D7/10—Salts
- C11D7/16—Phosphates including polyphosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/22—Organic compounds
- C11D7/32—Organic compounds containing nitrogen
- C11D7/3245—Aminoacids
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- C11D2111/14—
Description
バチルスアミロリケファシエンス(Bacillus amyloliquefaciens)由来のプロテアーゼ、例えばPrimase(登録商標);並びにバチルスアルカロフィルス(Bacillus alcalophilus)由来のプロテアーゼ、例えばDeterzyme APYが挙げられる。商業的に入手可能な例示的なプロテアーゼ酵素としては、Novo Industries A/S社(デンマーク)から、商品名Alcalase(登録商標)、Savinase(登録商標)、Primase(登録商標)、Durazym(登録商標)、又はEsperase(登録商標)の下で販売されているもの;Gist−Brocades社(オランダ)によって、商品名Maxatase(登録商標)、Maxacal(登録商標)、又はMaxapem(登録商標)の下で販売されているもの;Genencor International社によって、商品名Purafect(登録商標)、Purafect OX、及びProperaseの下で販売されているもの;Solvay Enzymes社によって、商品名Opticlean(登録商標)、又はOptimase(登録商標)の下で販売されているもの;Deerland社等によって、商品名Deterzyme(登録商標)、Deterzyme APY、及びDeterzyme PAG 510/220の下で販売されているものなどが挙げられる。
[1]
アルカリ金属炭酸塩、メチルグリシン二酢酸、グルタミン酸N,N−二酢酸、及びアルカリ金属トリポリホスフェートを含む、濃縮洗浄組成物。
[2]
前記アルカリ金属トリポリホスフェートに対する、前記メチルグリシン二酢酸のモル比が0.14〜14.3である、項目1に記載の濃縮洗浄組成物。
[3]
前記メチルグリシン二酢酸、及び前記アルカリ金属トリポリホスフェートの合計に対する、前記グルタミン酸N,N−二酢酸のモル比が0.03〜29である、項目1又は2に記載の濃縮洗浄組物。
[4]
前記アルカリ金属炭酸塩に対する、前記グルタミン酸N,N−二酢酸、前記メチルグリシン二酢酸、及び前記アルカリ金属トリポリホスフェートの合計のモル比が0.01〜0.5である、項目1〜3のいずれか一項に記載の濃縮洗浄組成物。
[5]
組成物が、少なくとも5質量%の前記アルカリ金属炭酸塩を含む、項目1〜4のいずれか一項に記載の濃縮洗浄組成物。
[6]
前記アルカリ金属炭酸塩が、炭酸ナトリウム若しくは炭酸カリウム、重炭酸ナトリウム若しくは重炭酸カリウム、セスキ炭酸ナトリウム若しくはセスキ炭酸カリウム、又はこれらの混合物である、項目1〜5のいずれか一項に記載の濃縮洗浄組成物。
[7]
前記アルカリ金属トリポリホスフェートがトリポリリン酸ナトリウムである、項目1〜6のいずれか一項に記載の濃縮洗浄組成物。
[8]
1g/Lの濃度で蒸留水中に希釈し、温度20℃で測定したときに、組成物が少なくとも6のpHを提供する、項目1〜7のいずれか一項に記載の濃縮洗浄組成物。
[9]
組成物が、界面活性剤、漂白剤、活性化剤、キレート剤/封鎖剤、シリケート、洗浄剤フィラー、又は結合剤、消泡剤、抗再析剤、酵素、色素、臭気物質、触媒、スレッショルドポリマー、汚れ懸濁剤、抗菌剤、及びこれらの混合物からなる群から選択される化合物の少なくとも1つを更に含む、項目1〜8のいずれか一項に記載の濃縮洗浄組成物。
[10]
組成物が、固体、粉末、液体、ゲル、又はペーストの形態で提供される、項目1〜9のいずれか一項に記載の濃縮洗浄組成物。
[11]
項目1〜10のいずれか一項に記載の濃縮洗浄組成物を0.1〜10g/L含む、水溶液。
[12]
酸化ポリフェノール及びケイ酸カルシウムを含む汚れを除去する物品洗浄用洗浄剤としての、項目1〜10のいずれか一項に記載の濃縮洗浄組成物の使用。
[13]
前記濃縮洗浄組成物を希釈して、0.1〜10g/Lの濃度を有する使用溶液を提供する、項目12に記載の使用。
[14]
前記濃縮洗浄組成物を、少なくとも50mg/LのCaCO 3 の硬度を有する水で希釈する、項目13に記載の使用。
[15]
前記物品洗浄用洗浄剤は、お茶及びコーヒー汚れを除去するために用いられる、項目12〜14のいずれか一項に記載の使用。
Claims (14)
- 20〜60質量%のアルカリ金属炭酸塩、
2〜22質量%のメチルグリシン二酢酸、
1〜30質量%のグルタミン酸N,N−二酢酸、及び
8〜10質量%のアルカリ金属トリポリホスフェート
を含む、濃縮洗浄組成物。 - 前記アルカリ金属トリポリホスフェートに対する、前記メチルグリシン二酢酸のモル比が0.14〜14.3である、請求項1に記載の濃縮洗浄組成物。
- 前記メチルグリシン二酢酸、及び前記アルカリ金属トリポリホスフェートの合計に対する、前記グルタミン酸N,N−二酢酸のモル比が0.03〜29である、請求項1又は2に記載の濃縮洗浄組物。
- 前記アルカリ金属炭酸塩に対する、前記グルタミン酸N,N−二酢酸、前記メチルグリシン二酢酸、及び前記アルカリ金属トリポリホスフェートの合計のモル比が0.01〜0.5である、請求項1〜3のいずれか一項に記載の濃縮洗浄組成物。
- 前記アルカリ金属炭酸塩が、炭酸ナトリウム若しくは炭酸カリウム、重炭酸ナトリウム若しくは重炭酸カリウム、セスキ炭酸ナトリウム若しくはセスキ炭酸カリウム、又はこれらの混合物である、請求項1〜4のいずれか一項に記載の濃縮洗浄組成物。
- 前記アルカリ金属トリポリホスフェートがトリポリリン酸ナトリウムである、請求項1〜5のいずれか一項に記載の濃縮洗浄組成物。
- 1g/Lの濃度で蒸留水中に希釈し、温度20℃で測定したときに、組成物が少なくとも6のpHを提供する、請求項1〜6のいずれか一項に記載の濃縮洗浄組成物。
- 組成物が、界面活性剤、漂白剤、活性化剤、キレート剤/封鎖剤、シリケート、洗浄剤フィラー、又は結合剤、消泡剤、抗再析剤、酵素、色素、臭気物質、触媒、スレッショルドポリマー、汚れ懸濁剤、抗菌剤、及びこれらの混合物からなる群から選択される化合物の少なくとも1つを更に含む、請求項1〜7のいずれか一項に記載の濃縮洗浄組成物。
- 組成物が、固体、粉末、液体、ゲル、又はペーストの形態で提供される、請求項1〜8のいずれか一項に記載の濃縮洗浄組成物。
- 請求項1〜9のいずれか一項に記載の濃縮洗浄組成物を0.1〜10g/L含む、水溶液。
- 酸化ポリフェノール及びケイ酸カルシウムを含む汚れを除去する物品洗浄用洗浄剤としての、請求項1〜9のいずれか一項に記載の濃縮洗浄組成物の使用。
- 前記濃縮洗浄組成物を希釈して、0.1〜10g/Lの濃度を有する使用溶液を提供する、請求項11に記載の使用。
- 前記濃縮洗浄組成物を、少なくとも50mg/LのCaCO3の硬度を有する水で希釈する、請求項12に記載の使用。
- 前記物品洗浄用洗浄剤は、お茶及びコーヒー汚れを除去するために用いられる、請求項11〜13のいずれか一項に記載の使用。
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JP2018508643A (ja) * | 2015-03-04 | 2018-03-29 | エコラボ ユーエスエー インコーポレイティド | 新規のキレーターの組み合わせによる相乗的タンパク質汚れの除去 |
US10767139B2 (en) | 2015-03-04 | 2020-09-08 | Ecolab Usa Inc. | Synergistic protein soil removal through novel chelator combination |
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US10246667B2 (en) | 2019-04-02 |
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US10017718B2 (en) | 2018-07-10 |
ES2654192T3 (es) | 2018-02-12 |
EP4095222B1 (en) | 2024-04-24 |
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CN105518118B (zh) | 2019-09-17 |
CA2921800C (en) | 2018-10-02 |
ES2743376T3 (es) | 2020-02-18 |
EP3561034B1 (en) | 2022-07-13 |
EP3044300A1 (en) | 2016-07-20 |
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AU2013399895B2 (en) | 2016-10-13 |
US20190177659A1 (en) | 2019-06-13 |
CN105518118A (zh) | 2016-04-20 |
US20170088799A1 (en) | 2017-03-30 |
EP3044300B1 (en) | 2017-10-25 |
EP3561034A1 (en) | 2019-10-30 |
CA2921800A1 (en) | 2015-03-12 |
WO2015032447A1 (en) | 2015-03-12 |
US20180291310A1 (en) | 2018-10-11 |
AU2013399895A1 (en) | 2016-03-10 |
US10519404B2 (en) | 2019-12-31 |
US9546345B2 (en) | 2017-01-17 |
EP3279304B1 (en) | 2019-06-05 |
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AU2017200130A1 (en) | 2017-02-02 |
AU2017200130B2 (en) | 2018-03-22 |
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BR112016005255B1 (pt) | 2021-06-29 |
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