JP6039747B2 - ニッケル非含有緑色顔料 - Google Patents
ニッケル非含有緑色顔料 Download PDFInfo
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- JP6039747B2 JP6039747B2 JP2015112753A JP2015112753A JP6039747B2 JP 6039747 B2 JP6039747 B2 JP 6039747B2 JP 2015112753 A JP2015112753 A JP 2015112753A JP 2015112753 A JP2015112753 A JP 2015112753A JP 6039747 B2 JP6039747 B2 JP 6039747B2
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- elements
- mixed metal
- nickel
- metal oxide
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/14—Methods for preparing oxides or hydroxides in general
- C01B13/18—Methods for preparing oxides or hydroxides in general by thermal decomposition of compounds, e.g. of salts or hydroxides
- C01B13/185—Preparing mixtures of oxides
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G1/00—Methods of preparing compounds of metals not covered by subclasses C01B, C01C, C01D, or C01F, in general
- C01G1/02—Oxides
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- C—CHEMISTRY; METALLURGY
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- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G19/00—Compounds of tin
- C01G19/006—Compounds containing, besides tin, two or more other elements, with the exception of oxygen or hydrogen
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G23/00—Compounds of titanium
- C01G23/003—Titanates
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G37/00—Compounds of chromium
- C01G37/006—Compounds containing, besides chromium, two or more other elements, with the exception of oxygen or hydrogen
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/006—Compounds containing, besides manganese, two or more other elements, with the exception of oxygen or hydrogen
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/12—Manganates manganites or permanganates
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
- C01G49/0018—Mixed oxides or hydroxides
- C01G49/0027—Mixed oxides or hydroxides containing one alkali metal
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G51/00—Compounds of cobalt
- C01G51/006—Compounds containing, besides cobalt, two or more other elements, with the exception of oxygen or hydrogen
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
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Description
名称BO3433は150.6°の色相角度(hue angle)を有し、他方、化合物Li1.5Co0.5(Ti2.5Li0.5Cr)O8は150.9°の色相角度を有する。したがって、Li1.5Co0.5(Ti2.5Li0.5Cr)O8はBO3433のほぼ完璧なニッケルを含まない代替物である。[124]スピネルCoLi(Ti3Li)O8と[134]Li2(Cr2Ti2)O8スピネルの固溶体はニッケルを含まずに、フエロ株式会社のBO3443の系列に従ったより強い緑色を呈する。
Na2(Cr2Ti2)O8, Na2(Cr2Mn2)O8, Na2(Cr2Ge2)O8, Na2(Cr2Sn2)O8, Na2(B2Ti2)O8, Na2(B2Mn2)O8, Na2(B2Ge2)O8, Na2(B2Sn2)O8, Na2(Fe2Ti2)O8, Na2(Fe2Mn2)O8, Na2(Fe2Ge2)O8, Na2(Sn2Mn2)O8, Na2(Mn2Ti2)O8, Na2(Mn2Ge2)O8, Na2(Al2Ti2)O8, Na2(Al2Mn2)O8, Na2(Al2Sn2)O8, 及び Na2(Al2Ge2)O8及びそれらの組み合わせからなる群から選択される第2の混合酸化金属を含んでも良い。
Li2(Cr2Ti2)O8+CoLi(Ti3Li)O8 →Li3Co(Ti5LiCr2)O16 = Li1.5Co0.5(Ti2.5Li0.5Cr)O8
試験の色値(CIELab D65 10°)はプラスチゾル中で測定された。
本実施例と全ての実施例のプラスチゾルは液体可塑剤中のPVC懸濁液であり、標準的処方であり、ロットリンベルク-ユリウスロッター合資会社(Rottolin-Werk-Julius Rotter& Co.KG) (バイロイト, ドイツ)から入手できる。製品名はプラスチゾル U91.7.0.429.59型(Plastisol Typ U91.7.0.429.59)である。
加えて、本化合物のTSR(黒色に対して(over black))は、同一処方されたときの22のTSRを示す従来のNi含有顔料に匹敵する31である。TSRはASTM E903により測定され、これは標準参照分光放射照度ASTM G173に基づき計算される。
Claims (24)
- 第1の混合酸化金属と第2の混合酸化金属の固溶体を含む、ニッケルを含まない緑色の顔料であって、
a. [124]スピネル構造をもつ前記第1の混合酸化金属が、
i.リチウムとナトリウムからなる群から選択された1以上の元素A、
ii.コバルト、亜鉛、カルシウム、マグネシウム、銅からなる群から選択される1以上の元素B、並びに
iii.チタン、マンガン、スズ及びゲルマニウムからなる群から選択される1以上の元素D
を含み、
b. [134]スピネル構造をもつ前記第2の混合酸化金属が、
i.リチウムとナトリウムからなる群から選択される1以上の元素A、
ii.クロム、ホウ素、鉄、マンガン及びアルミニウムからなる群から選択される1以上の元素C、並びに
iii.チタン、マンガン、スズ及びゲルマニウムからなる群から選択される1以上の元素D、
を含み、かつ
c.ニッケルを含まない
顔料。 - 請求項1のニッケルを含まない緑色の顔料であって、前記第1の混合酸化金属は式BA(D3A)O8を有するものである、顔料。
- 請求項1のニッケルを含まない緑色の顔料であって、前記第2の混合酸化金属は式A2(C2D2)O8を有するものである、顔料。
- 請求項1のニッケルを含まない緑色の顔料を含む塗料または被膜。
- 黒色に対して15%以上の総日射反射率を有する請求項4の塗料又は被膜。
- 請求項1のニッケルを含まない緑色の顔料を含むプラスチック組成物。
- 請求項1のニッケルを含まない緑色の顔料であって、800-1100nmの波長範囲にわたり50%以上の反射を有する、顔料。
- 請求項1のニッケルを含まない緑色の顔料であって、DIN EN71/3:2013によれば1ppm未満の浸出し得るNiを有する、顔料。
- 第1と第2の混合酸化金属の固溶体を含みニッケルを含まない緑色の顔料を調製する方法であって、
a. 目的とする金属を含む反応性化合物を混合し混合物を調製する工程と、
b. 前記混合物を800-1700℃の温度で、1-1000分加熱し、緑色顔料の粒子と凝集物(agglomerates)のうち1以上を形成する工程と、を含み、
i. 前記第1の混合酸化金属が[124]スピネル構造を有し、
1. リチウムとナトリウムからなる群から選択された1以上の元素A、
2. コバルト、亜鉛、カルシウム、マグネシウム、銅からなる群から選択される1以上の元素B、並びに
3. チタン、マンガン、スズ及びゲルマニウムからなる群から選択される1以上の元素Dを含み、かつ
4. ニッケルを含まず、
ii. 前記第2の混合酸化金属が[134]スピネル構造を有し、
1.リチウムとナトリウムからなる群から選択される1以上の元素A、
2.クロム、ホウ素、鉄、マンガン及びアルミニウムからなる群から選択される1以上の元素C、並びに
3. チタン、マンガン、スズ及びゲルマニウムからなる群から選択される1以上の元素Dを含み、かつ
4. ニッケルを含まない、
方法。 - 請求項9の方法であって、さらに毎分1-50℃の速度で室温にまで前記緑色顔料を冷却する工程を含む、方法。
- 請求項9の方法であって、さらに1-10ミクロンのD50サイズにまで顔料粒子又は凝集物のサイズを減少させる工程を含む、方法。
- 請求項9の方法であって、前記第1の混合酸化金属が式BA(D3A)O8を有するものである、方法。
- 請求項9の方法であって、前記第2の混合酸化金属が式A2(C2D2)O8を有するものである、方法。
- 緑色を基材に与える方法であって、第1と第2の混合酸化金属の固溶体を含有する、ニッケルを含まない緑色顔料を
a. 基材に塗布する工程と、
b. 焼成する工程と、
を含み、
i. 前記第1の混合酸化金属は[124]スピネル構造を有し、
1. リチウムとナトリウムからなる群から選択される1以上の元素A、
2. コバルト、亜鉛、カルシウム、マグネシウム、銅からなる群から選択される1以上の元素B、並びに
3. チタン、マンガン、スズ及びゲルマニウムからなる群から選択される1以上の元素D、を含み、
4. ニッケルを含まない
ii. 前記第2の混合酸化金属は[134]スピネル構造を有し、
1.リチウムとナトリウムからなる群から選択される1以上の元素A、
2. クロム、ホウ素、鉄、マンガン及びアルミニウムからなる群から選択される1以上の元素C、並びに
3. チタン、マンガン、スズ及びゲルマニウムからなる群から選択される1以上の元素D、を含み、
4. ニッケルを含まない
ものである、方法。 - 請求項14の方法であって、前記第1の混合酸化金属は式BA(D3A)O8を有するものである、方法。
- 請求項14の方法であって、前記第2の混合酸化金属は式A2(C2D2)O8を有するものである、方法。
- 請求項15の方法であって、前記第2混合酸化金属は、式A2(C2D2)O8を有するものである、方法。
- 請求項14の方法であって、前記基材は塗料、硬化性被膜、インク、プラスチック、ゴム、セラミック、エナメル、ガラスからなる群から選択されるものである、方法。
- プラスチック組成物に緑色を与える方法であって、以下のaとbを溶融混合することを含む方法であり、
a. はプラスチック組成物であり、
b. は第1と第2の混合酸化金属の固溶体を含有するニッケルを含まない緑色の顔料であり、
i. 前記第1の混合酸化金属が[124]スピネル構造をもち、
1. リチウムとナトリウムからなる群から選択される1以上の元素A、
2. コバルト、亜鉛、カルシウム、マグネシウム、銅からなる群から選択される1以上の元素B、並びに
3. チタン、マンガン、スズ及びゲルマニウムからなる群から選択される1以上の元素D、を含み、
4. ニッケルを含まない、
ものであり、
ii. 前記第2の混合酸化金属が[134]スピネル構造をもち、
1. リチウムとナトリウムからなる群から選択された1以上の元素A、
2. クロム、ホウ素、鉄、マンガン及びアルミニウムからなる群から選択される1以上の元素C、並びに
3. チタン、マンガン、スズ及びゲルマニウムからなる群から選択される1以上の元素D、を含み、
4. ニッケルを含まない、
ものである、方法。 - 請求項19の方法であって、前記第1の混合酸化金属は式BA(D3A)O8を有するものである、方法。
- 請求項19の方法であって、前記第2の混合酸化金属は式A2(C2D2)O8を有するものである、方法。
- 請求項20の方法であって、前記第2の混合酸化金属は式A2(C2D2)O8を有するものである、方法。
- 請求項1のニッケルを含まない緑色の顔料であって、前記顔料は、CoLi(Ti3Li)O8, CoLi(Ti3Na)O8, CoLi(Mn3Li)O8, CoLi(Ge3Li)O8, CoLi(Mn3Na)O8, CoLi(Ge3Na)O8, CoLi(Sn3Li)O8, CoLi(Sn3Na)O8, CoNa(Ti3Li)O8, CoNa(Ti3Na)O8, CoNa(Mn3Li)O8, CoNa(Ti3Li)O8, CoNa(Ge3Li)O8, CoNa(Mn3Na)O8, CoNa(Ge3Na)O8, CoNa(Sn3Li)O8,CoNa(Sn3Na)O8, ZnLi(Ti3Li)O8, ZnLi(Ti3Na)O8, ZnLi(Mn3Li)O8, ZnLi(Ge3Li)O8, ZnLi(Mn3Na)O8, ZnLi(Ge3Na)O8, ZnLi(Sn3Li)O8, ZnLi(Sn3Na)O8, ZnNa(Ti3Li)O8, ZnNa(Ti3Na)O8, ZnNa(Mn3Li)O8, ZnNa(Ti3Li)O8, ZnNa(Ge3Li)O8, ZnNa(Mn3Na)O8, ZnNa(Ge3Na)O8, ZnNa(Sn3Li)O8, ZnNa(Sn3Na)O8, CaLi(Ti3Li)O8, CaLi(Ti3Na)O8, CaLi(Mn3Li)O8, CaLi(Ti3Li)O8, CaLi(Ge3Li)O8, CaLi(Mn3Na)O8, CaLi(Ge3Na)O8, CaLi(Sn3Li)O8, CaLi(Sn3Na)O8, CaNa(Ti3Li)O8, CaNa(Ti3Na)O8, CaNa(Mn3Li)O8, CaNa(Ge3Li)O8, CaNa(Mn3Na)O8, CaNa(Ge3Na)O8, CaNa(Sn3Li)O8, CaNa(Sn3Na)O8, MgLi(Ti3Li)O8, MgLi(Ti3Na)O8, MgLi(Mn3Li)O8, MgLi(Ti3Li)O8, MgLi(Ge3Li)O8, MgLi(Mn3Na)O8, MgLi(Ge3Na)O8, MgLi(Sn3Li)O8, MgLi(Sn3Na)O8, MgNa(Ti3Li)O8, MgNa(Ti3Na)O8, MgNa(Mn3Li)O8, MgNa(Ti3Li)O8, MgNa(Ge3Li)O8, MgNa(Mn3Na)O8, MgNa(Ge3Na)O8, MgNa(Sn3Li)O8, MgNa(Sn3Na)O8, CuLi(Ti3Li)O8, CuLi(Ti3Na)O8, CuLi(Mn3Li)O8, CuLi(Ge3Li)O8, CuLi(Mn3Na)O8, CuLi(Ge3Na)O8, CuLi(Sn3Li)O8, CuLi(Sn3Na)O8, CuNa(Ti3Li)O8, CuNa(Ti3Na)O8, CuNa(Mn3Li)O8, CuNa(Ti3Li)O8, CuNa(Ge3Li)O8, CuNa(Mn3Na)O8, CuNa(Ge3Na)O8, CuNa(Sn3Li)O8, CuNa(Sn3Na)O8及びそれらの組み合わせからなる群から選択される前記第1の混合酸化金属を含むものである、顔料。
- 請求項1または23のニッケルを含まない緑色顔料であって、前記顔料は、Li2(Cr2Ti2)O8, Li2(Cr2Mn2)O8, Li2(Cr2Sn2)O8, Li2(Cr2Ge2)O8, Li2(B2Ti2)O8, Li2(B2Mn2)O8, Li2(B2Sn2)O8, Li2(B2Ge2)O8, Li2(Fe2Ti2)O8, Li2(Fe2Mn2)O8, Li2(Fe2Sn2)O8, Li2(Fe2Ge2)O8, Li2(Mn2Ti2)O8, Li2(Mn2Sn2)O8, Li2(Mn2Ge2)O8, Li2(Al2Ti2)O8, Li2(Al2Mn2)O8, Li2(Al2Sn2)O8, Li2(Al2Ge2)O8, Na2(Cr2Ti2)O8, Na2(Cr2Mn2)O8, Na2(Cr2Ge2)O8, Na2(Cr2Sn2)O8, Na2(B2Ti2)O8, Na2(B2Mn2)O8, Na2(B2Ge2)O8, Na2(B2Sn2)O8, Na2(Fe2Ti2)O8, Na2(Fe2Mn2)O8, Na2(Fe2Ge2)O8, Na2(Sn2Mn2)O8, Na2(Mn2Ti2)O8, Na2(Mn2Ge2)O8, Na2(Al2Ti2)O8, Na2(Al2Mn2)O8, Na2(Al2Sn2)O8, Na2(Al2Ge2)O8及びそれらの組み合わせからなる群から選択される前記第2の混合酸化金属を含むものである、顔料。
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US14/296,401 US9187617B1 (en) | 2014-06-04 | 2014-06-04 | Nickel-free green pigment |
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EP3486217B1 (de) | 2017-11-20 | 2020-01-15 | Helvetia Pigmente AG | Grünes pigment |
CN112759970A (zh) * | 2019-11-01 | 2021-05-07 | 常州市道曼新型建材科技有限公司 | 一种高红外反射率低钴含量的纳米绿色粉体及其制备方法 |
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JP5723894B2 (ja) | 2010-02-19 | 2015-05-27 | フエロ コーポレーション | 日射反射率改良のための顔料添加剤 |
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EP2952479A3 (en) | 2016-01-06 |
CN105273484A (zh) | 2016-01-27 |
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US20150353706A1 (en) | 2015-12-10 |
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