JP5989640B2 - ポリ乳酸製手袋およびその製造方法 - Google Patents
ポリ乳酸製手袋およびその製造方法 Download PDFInfo
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- JP5989640B2 JP5989640B2 JP2013516738A JP2013516738A JP5989640B2 JP 5989640 B2 JP5989640 B2 JP 5989640B2 JP 2013516738 A JP2013516738 A JP 2013516738A JP 2013516738 A JP2013516738 A JP 2013516738A JP 5989640 B2 JP5989640 B2 JP 5989640B2
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- Prior art keywords
- polylactic acid
- glove
- pla
- biodegradable
- plasticizer
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| US8563103B2 (en) | 2010-02-19 | 2013-10-22 | Smarthealth, Inc. | Polylactide hydrosol and articles made therefrom |
| US8992957B2 (en) * | 2010-02-19 | 2015-03-31 | Smarthealth, Inc. | Polylactide hydrosol and articles made therefrom |
| FR2965814B1 (fr) * | 2010-10-08 | 2012-11-16 | Roquette Freres | Plastification de polyesters aliphatiques par des esters alkyliques de dianhydrohexitols |
| US20120232652A1 (en) | 2011-03-07 | 2012-09-13 | Rolando Mora | Implant with a visual indicator of a barrier layer |
| US9294996B2 (en) * | 2012-02-24 | 2016-03-22 | Intel Deutschland Gmbh | Enhanced power management in communication device |
| FR2990210B1 (fr) * | 2012-05-03 | 2014-05-02 | Roquette Freres | Compositions plastifiantes comprenant des accelerateurs de gelification a base d'ester de 1,4 : 3,6-dianhydrohexitol de faible poids molaire |
| JP2014043540A (ja) * | 2012-08-03 | 2014-03-13 | Unitika Ltd | ポリ乳酸系樹脂組成物及びそれからなる成形体 |
| US20140087108A1 (en) * | 2012-09-26 | 2014-03-27 | Earth Renewable Technologies | Extrudable composition derived from renewable resources and method of making molded articles utilizing the same |
| US9370209B2 (en) | 2014-09-19 | 2016-06-21 | Summit Glove Inc. | Method of fabricating a glove with a widened cuff area |
| US20160143379A1 (en) * | 2013-07-22 | 2016-05-26 | Summit Glove Inc. | Glove having a widened cuff and with finger regions that include a flexible hinge region |
| KR101762996B1 (ko) | 2013-08-29 | 2017-07-28 | (주)엘지하우시스 | 발포 시트용 발포성 수지 조성물, 발포 시트, 입자상의 폴리락트산 수지의 제조 방법 및 발포 시트의 제조 방법 |
| CN104814545B (zh) * | 2015-04-22 | 2017-01-11 | 佛山市顺德区华创精工快速成型科技有限公司 | 一种基于3d打印的玉米手套及其制备方法 |
| US12446639B2 (en) | 2015-04-24 | 2025-10-21 | Summit Glove Inc. | Drug resistant glove |
| JP2017149927A (ja) * | 2016-02-25 | 2017-08-31 | 日本ゼオン株式会社 | ラテックス組成物の製造方法 |
| ES2906324T3 (es) | 2016-02-29 | 2022-04-18 | Michelman Inc | Dispersión hidrolíticamente estable de base acuosa de un polímero biodegradable |
| USD894526S1 (en) | 2016-05-25 | 2020-09-01 | Summit Glove Inc. | Patterned glove with a straight cuff |
| USD893129S1 (en) | 2016-05-25 | 2020-08-18 | Summit Glove Inc. | Patterned glove with a flared cuff |
| CN106674932A (zh) * | 2016-11-30 | 2017-05-17 | 中广核三角洲(苏州)新材料研发有限公司 | 电线电缆用耐热性可降解绝缘材料 |
| CN106977888A (zh) * | 2017-03-29 | 2017-07-25 | 合肥天沃能源科技有限公司 | 一种一次性薄膜手套及制备方法 |
| CN111629621B (zh) * | 2017-07-25 | 2023-08-01 | 皮肤防护有限公司 | 弹性体手套及其生产方法 |
| MY169982A (en) * | 2017-07-25 | 2019-06-19 | Skinprotect Corp Sdn Bhd | Elastomeric gloves and methods for their production |
| US20190069618A1 (en) * | 2017-09-06 | 2019-03-07 | Handgards, Inc. | Embossed gloves with gripping features |
| CN113227250B (zh) * | 2018-10-04 | 2024-01-30 | 亚历山德拉·乌尼诺夫 | 无聚氯乙烯的芳香的基于亲脂的聚合物的塑料溶胶 |
| CN109912946B (zh) * | 2019-01-07 | 2021-04-02 | 雄县旺达塑料包装制品有限公司 | 全生物降解手套及其制备方法 |
| NL1043452B1 (en) | 2019-11-07 | 2021-07-20 | Michiel Alphons Jacobus Kuijpers Mr | Enhanced biodegradable nitrile rubber glove |
| CN116003877A (zh) * | 2019-11-25 | 2023-04-25 | 星欧光学股份有限公司 | 塑化剂及塑胶产品 |
| NL1043526B1 (en) | 2019-12-30 | 2021-09-06 | Daniel Nick Lamens Mr | Double dipped enhanced biodegradable nitrile rubber glove |
| CN111290051A (zh) * | 2020-04-08 | 2020-06-16 | 中国科学院西北生态环境资源研究院 | 一种沙漠气象监测装置及其监测方法 |
| WO2021226365A1 (en) * | 2020-05-06 | 2021-11-11 | Green Logic, LLC | Dual chamber disinfection system |
| US20220087339A1 (en) * | 2020-09-23 | 2022-03-24 | Agnes Boyer | Reuasble Protective Glove Assembly |
| JP2024507160A (ja) * | 2021-02-12 | 2024-02-16 | モンド・ソシエタ・ペル・アチオニ | 芝インフィル材料および芝 |
| CN113512181B (zh) * | 2021-08-09 | 2022-08-12 | 重庆大学 | 一种可低温加工的聚乳酸及其制备方法 |
| CN114213636A (zh) * | 2021-09-14 | 2022-03-22 | 刘东明 | 一种可再生生物降解材料手套的制作方法 |
| CN114133599A (zh) * | 2021-12-09 | 2022-03-04 | 南通强生新材料科技股份有限公司 | 一种环保的功能性手套及其制备方法 |
| CN114349940B (zh) * | 2021-12-31 | 2023-05-23 | 德州恒昌医疗科技有限公司 | Pla基自增塑全生物降解手套及其制备方法 |
| CA3248778A1 (en) * | 2022-04-20 | 2023-10-26 | Dizolv Inc | BIODEGRADABLE THERMOPLASTIC MATERIALS |
| CN120457161A (zh) * | 2022-12-29 | 2025-08-08 | 埃万特公司 | 液体塑料溶胶组合物和由其制备的水溶性塑化制品 |
| CN116574282A (zh) * | 2023-06-12 | 2023-08-11 | 南通强生新材料科技股份有限公司 | 一种石墨烯降解手套及其制备方法 |
| WO2025071251A1 (ko) * | 2023-09-26 | 2025-04-03 | 주식회사 엘지화학 | 수지 조성물 및 이를 포함하는 생분해성 수지 성형품 |
| WO2025097215A1 (en) * | 2023-11-10 | 2025-05-15 | Ansell Limited | Bioderived glove |
| US12098285B1 (en) | 2024-04-26 | 2024-09-24 | Imam Mohammad Ibn Saud Islamic University | Bio-based wearable films and method of preparation thereof |
Family Cites Families (46)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59230716A (ja) * | 1983-06-13 | 1984-12-25 | Taki Gomme Kagaku Kk | 塩化ビニ−ル樹脂製手袋の製造法 |
| US5444113A (en) * | 1988-08-08 | 1995-08-22 | Ecopol, Llc | End use applications of biodegradable polymers |
| JPH0339449Y2 (enExample) * | 1990-06-14 | 1991-08-20 | ||
| US5365608A (en) * | 1992-07-21 | 1994-11-22 | Conrad Flick | Disposable, elastomeric glove |
| US5438708A (en) * | 1993-12-20 | 1995-08-08 | Jacovitz; Jay S. | Manual waste collection, containment, and disposal device |
| US5906823A (en) * | 1994-05-09 | 1999-05-25 | Mixon; Grover C. | Antimicrobial gloves and a method of manufacture thereof |
| US5763513A (en) * | 1994-05-19 | 1998-06-09 | Mitsui Toatsu Chemicals, Inc. | L-lactic acid polymer composition, molded product and film |
| US5849401A (en) * | 1995-09-28 | 1998-12-15 | Cargill, Incorporated | Compostable multilayer structures, methods for manufacture, and articles prepared therefrom |
| US5658969A (en) * | 1996-01-29 | 1997-08-19 | Pierce & Stevens Corporation | Light weight plastisols and method of making same |
| FI99268C (fi) * | 1996-04-04 | 1998-02-25 | Upm Kymmene Oy | Kerrosmateriaali |
| GB9625765D0 (en) * | 1996-12-11 | 1997-01-29 | Lrc Products | Process and apparatus for forming a thin-walled article |
| BR9809700A (pt) * | 1997-05-28 | 2000-07-11 | Reichhold Chemicals Inc | Material elastomérico para artigos de borracha |
| US6114495A (en) * | 1998-04-01 | 2000-09-05 | Cargill Incorporated | Lactic acid residue containing polymer composition and product having improved stability, and method for preparation and use thereof |
| US20020094444A1 (en) * | 1998-05-30 | 2002-07-18 | Koji Nakata | Biodegradable polyester resin composition, biodisintegrable resin composition, and molded objects of these |
| US6432547B1 (en) * | 1999-02-22 | 2002-08-13 | H.B. Fuller Licensing & Financing Inc. | Breathable film layer compositions |
| US6756331B2 (en) * | 2000-07-17 | 2004-06-29 | Mitsui Chemicals, Inc. | Lactic-acid base resin composition and molded articles made therefor |
| DE10193043D2 (de) * | 2000-07-27 | 2002-10-24 | Marinow Slaweyko | Chlorfreies Plastisol bzw. Organosol auf Polyolefin-Basis und Verfahren zur Herstellung |
| US6393614B1 (en) * | 2000-08-29 | 2002-05-28 | Lauren M. Eichelbaum | Disposable glove with pockets |
| JP4660035B2 (ja) * | 2000-09-28 | 2011-03-30 | 三井化学東セロ株式会社 | 脂肪族ポリエステル組成物、それからなるフィルム及びその積層体 |
| CN1476459A (zh) * | 2000-11-30 | 2004-02-18 | ����贻�ѧ��ҵ��ʽ���� | 脂肪族聚酯共聚物及其制造方法、脂肪族聚酯系生物降解性树脂成形物、和含内酯的树脂 |
| CN1439661A (zh) * | 2002-02-21 | 2003-09-03 | 上海生大医保股份有限公司 | “多组份/多相”绿色乳胶手套的制备 |
| US6699963B2 (en) * | 2002-03-18 | 2004-03-02 | The Procter & Gamble Company | Grinding process for plastic material and compositions therefrom |
| US20030204893A1 (en) * | 2002-05-02 | 2003-11-06 | Chou Belle L. | Elastomeric flexible article and manufacturing method |
| US6869985B2 (en) * | 2002-05-10 | 2005-03-22 | Awi Licensing Company | Environmentally friendly polylactide-based composite formulations |
| JP4476804B2 (ja) * | 2002-05-29 | 2010-06-09 | 株式会社クレハ | 生分解性耐熱性硬質樹脂成形容器 |
| JP2004107413A (ja) * | 2002-09-17 | 2004-04-08 | Mitsui Chemicals Inc | 可塑剤含有ポリ乳酸系樹脂水分散体 |
| US7455863B2 (en) * | 2002-11-07 | 2008-11-25 | Smarthealth, Inc. | Flexible elastomer articles and methods of manufacturing |
| US7585526B2 (en) * | 2002-11-07 | 2009-09-08 | Smarthealth, Inc. | Flexible elastomer articles and methods of manufacturing |
| JP4313076B2 (ja) * | 2003-04-16 | 2009-08-12 | ユニチカ株式会社 | 生分解性ポリエステル系フィルムおよびその製造方法 |
| JP2005036088A (ja) * | 2003-07-18 | 2005-02-10 | Riken Vitamin Co Ltd | 食品包装用樹脂組成物及び食品用包装体 |
| US7776368B2 (en) * | 2003-08-13 | 2010-08-17 | Smarthealth, Inc. | Gloves containing dry powdered aloe and method of manufacturing |
| FR2859729B1 (fr) * | 2003-09-12 | 2006-02-24 | Roquette Freres | Dispersions aqueuses d'au moins un polymere biodegradable |
| US20050112180A1 (en) * | 2003-11-22 | 2005-05-26 | Chou Belle L. | Antimicrobial elastomeric flexible article and manufacturing method |
| US7279545B2 (en) * | 2003-12-04 | 2007-10-09 | Kabushiki Kaisha J-Corporation | Production method of biodegradable plastic and apparatus for use in production thereof |
| JP4249075B2 (ja) * | 2004-04-16 | 2009-04-02 | 新第一塩ビ株式会社 | 塩化ビニル系プラスチゾル組成物及び発泡成形体 |
| JP2006027113A (ja) * | 2004-07-16 | 2006-02-02 | Mitsubishi Plastics Ind Ltd | 乳酸系シュリンク包装フィルム |
| JP4541085B2 (ja) * | 2004-09-27 | 2010-09-08 | ユニチカ株式会社 | ポリ乳酸樹脂水性分散体の製造方法 |
| US20060141186A1 (en) * | 2004-12-28 | 2006-06-29 | Janssen Robert A | Gloves with hydrogel coating for damp hand donning and method of making same |
| WO2007022080A2 (en) * | 2005-08-12 | 2007-02-22 | Michigan State University | Biodegradable polymeric nanocomposite compositions particularly for packaging |
| US20070207282A1 (en) * | 2006-03-01 | 2007-09-06 | Hamann Curtis P | Polylactic Acid Gloves and Methods of Manufacturing Same |
| DE102006026624A1 (de) * | 2006-06-08 | 2007-12-13 | Oxeno Olefinchemie Gmbh | Tripentylcitrate und deren Verwendung |
| AU2007339204A1 (en) * | 2006-12-27 | 2008-07-03 | Toray Industries, Inc. | Resin composition and molded article |
| CN101245164B (zh) * | 2007-02-15 | 2011-05-11 | 北京高盟新材料股份有限公司 | 无粉pvc手套用的功能性pvc塑溶胶及其应用 |
| DE102007028702A1 (de) * | 2007-06-21 | 2008-12-24 | Evonik Oxeno Gmbh | Verfahren zur Herstellung von Dianhydrohexitol-Diestern |
| JP5061868B2 (ja) * | 2007-12-06 | 2012-10-31 | 東レ株式会社 | ポリ乳酸系フィルム |
| US8563103B2 (en) * | 2010-02-19 | 2013-10-22 | Smarthealth, Inc. | Polylactide hydrosol and articles made therefrom |
-
2010
- 2010-06-22 US US12/820,580 patent/US20100257657A1/en not_active Abandoned
-
2011
- 2011-06-22 EP EP11798853.5A patent/EP2584925A4/en not_active Withdrawn
- 2011-06-22 JP JP2013516738A patent/JP5989640B2/ja active Active
- 2011-06-22 CN CN201180037913.5A patent/CN103096742B/zh active Active
- 2011-06-22 CN CN201711344542.0A patent/CN108102321B/zh active Active
- 2011-06-22 WO PCT/US2011/041467 patent/WO2011163377A2/en not_active Ceased
-
2015
- 2015-04-06 US US14/679,611 patent/US20150208743A1/en not_active Abandoned
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR102193034B1 (ko) | 2019-09-16 | 2020-12-18 | 이중혁 | 생분해성 친환경 빨대 및 그 제조방법 |
Also Published As
| Publication number | Publication date |
|---|---|
| US20150208743A1 (en) | 2015-07-30 |
| WO2011163377A3 (en) | 2012-04-19 |
| CN103096742A (zh) | 2013-05-08 |
| CN108102321A (zh) | 2018-06-01 |
| JP2013531746A (ja) | 2013-08-08 |
| US20100257657A1 (en) | 2010-10-14 |
| EP2584925A2 (en) | 2013-05-01 |
| WO2011163377A2 (en) | 2011-12-29 |
| CN108102321B (zh) | 2021-01-22 |
| EP2584925A4 (en) | 2014-12-17 |
| CN103096742B (zh) | 2018-02-02 |
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