JP5882062B2 - 難燃化衝撃変性ポリカーボネート組成物 - Google Patents
難燃化衝撃変性ポリカーボネート組成物 Download PDFInfo
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- JP5882062B2 JP5882062B2 JP2011542700A JP2011542700A JP5882062B2 JP 5882062 B2 JP5882062 B2 JP 5882062B2 JP 2011542700 A JP2011542700 A JP 2011542700A JP 2011542700 A JP2011542700 A JP 2011542700A JP 5882062 B2 JP5882062 B2 JP 5882062B2
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- rubber
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- silicone
- acrylate
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- 239000000203 mixture Substances 0.000 title claims description 69
- 229920000515 polycarbonate Polymers 0.000 title claims description 26
- 239000004417 polycarbonate Substances 0.000 title claims description 26
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title description 3
- 239000003063 flame retardant Substances 0.000 title description 3
- 229920001971 elastomer Polymers 0.000 claims description 59
- 239000005060 rubber Substances 0.000 claims description 59
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 45
- -1 phosphonate amines Chemical class 0.000 claims description 38
- 239000000454 talc Substances 0.000 claims description 36
- 229910052623 talc Inorganic materials 0.000 claims description 36
- 125000003118 aryl group Chemical group 0.000 claims description 32
- 229920001296 polysiloxane Polymers 0.000 claims description 32
- 229920002379 silicone rubber Polymers 0.000 claims description 29
- 239000004945 silicone rubber Substances 0.000 claims description 29
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 25
- 229920000578 graft copolymer Polymers 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 21
- 239000002131 composite material Substances 0.000 claims description 18
- 239000000178 monomer Substances 0.000 claims description 18
- 229920000728 polyester Polymers 0.000 claims description 14
- 229920002554 vinyl polymer Polymers 0.000 claims description 12
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 10
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 9
- 229910019142 PO4 Inorganic materials 0.000 claims description 6
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 6
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- 229920002842 oligophosphate Polymers 0.000 claims description 5
- 239000010452 phosphate Substances 0.000 claims description 5
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 3
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 150000002367 halogens Chemical class 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 125000003710 aryl alkyl group Chemical group 0.000 claims description 2
- 229910052799 carbon Inorganic materials 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 2
- UNXRWKVEANCORM-UHFFFAOYSA-N triphosphoric acid Polymers OP(O)(=O)OP(O)(=O)OP(O)(O)=O UNXRWKVEANCORM-UHFFFAOYSA-N 0.000 claims description 2
- 125000001033 ether group Chemical group 0.000 claims 1
- 239000002245 particle Substances 0.000 description 20
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 16
- 238000002360 preparation method Methods 0.000 description 16
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 15
- 239000003431 cross linking reagent Substances 0.000 description 14
- 229920001283 Polyalkylene terephthalate Polymers 0.000 description 13
- 238000000034 method Methods 0.000 description 13
- 229920000642 polymer Polymers 0.000 description 12
- 238000000465 moulding Methods 0.000 description 11
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 10
- 238000012360 testing method Methods 0.000 description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- 239000002253 acid Substances 0.000 description 9
- 229940106691 bisphenol a Drugs 0.000 description 9
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 8
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 8
- 238000006116 polymerization reaction Methods 0.000 description 8
- 229920001169 thermoplastic Polymers 0.000 description 8
- 239000004416 thermosoftening plastic Substances 0.000 description 8
- XKZQKPRCPNGNFR-UHFFFAOYSA-N 2-(3-hydroxyphenyl)phenol Chemical compound OC1=CC=CC(C=2C(=CC=CC=2)O)=C1 XKZQKPRCPNGNFR-UHFFFAOYSA-N 0.000 description 7
- 239000006085 branching agent Substances 0.000 description 7
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 7
- 150000001735 carboxylic acids Chemical class 0.000 description 7
- 238000007720 emulsion polymerization reaction Methods 0.000 description 7
- 229910052500 inorganic mineral Inorganic materials 0.000 description 7
- 239000011707 mineral Substances 0.000 description 7
- 235000010755 mineral Nutrition 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 230000008961 swelling Effects 0.000 description 6
- 239000000460 chlorine Substances 0.000 description 5
- 238000005227 gel permeation chromatography Methods 0.000 description 5
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 5
- 229920000126 latex Polymers 0.000 description 5
- 239000004816 latex Substances 0.000 description 5
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 235000021317 phosphate Nutrition 0.000 description 5
- 150000003018 phosphorus compounds Chemical class 0.000 description 5
- 229920006163 vinyl copolymer Polymers 0.000 description 5
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 4
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 4
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 4
- 229910052794 bromium Inorganic materials 0.000 description 4
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 150000003949 imides Chemical class 0.000 description 4
- 239000011574 phosphorus Substances 0.000 description 4
- 229910052698 phosphorus Inorganic materials 0.000 description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 description 4
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 4
- KTZVZZJJVJQZHV-UHFFFAOYSA-N 1-chloro-4-ethenylbenzene Chemical compound ClC1=CC=C(C=C)C=C1 KTZVZZJJVJQZHV-UHFFFAOYSA-N 0.000 description 3
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 3
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- GYCMBHHDWRMZGG-UHFFFAOYSA-N Methylacrylonitrile Chemical compound CC(=C)C#N GYCMBHHDWRMZGG-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 150000008065 acid anhydrides Chemical class 0.000 description 3
- 150000008360 acrylonitriles Chemical class 0.000 description 3
- 238000012662 bulk polymerization Methods 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 150000002009 diols Chemical class 0.000 description 3
- KPUWHANPEXNPJT-UHFFFAOYSA-N disiloxane Chemical class [SiH3]O[SiH3] KPUWHANPEXNPJT-UHFFFAOYSA-N 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 125000005843 halogen group Chemical group 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 229910052739 hydrogen Inorganic materials 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 3
- 229910052751 metal Chemical class 0.000 description 3
- 239000002184 metal Chemical class 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 3
- 150000002825 nitriles Chemical class 0.000 description 3
- 125000005375 organosiloxane group Chemical group 0.000 description 3
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- FBCQUCJYYPMKRO-UHFFFAOYSA-N prop-2-enyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCC=C FBCQUCJYYPMKRO-UHFFFAOYSA-N 0.000 description 3
- YPFDHNVEDLHUCE-UHFFFAOYSA-N propane-1,3-diol Chemical compound OCCCO YPFDHNVEDLHUCE-UHFFFAOYSA-N 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 241000894007 species Species 0.000 description 3
- ISXSCDLOGDJUNJ-UHFFFAOYSA-N tert-butyl prop-2-enoate Chemical compound CC(C)(C)OC(=O)C=C ISXSCDLOGDJUNJ-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 2
- KPZGRMZPZLOPBS-UHFFFAOYSA-N 1,3-dichloro-2,2-bis(chloromethyl)propane Chemical compound ClCC(CCl)(CCl)CCl KPZGRMZPZLOPBS-UHFFFAOYSA-N 0.000 description 2
- BSWWXRFVMJHFBN-UHFFFAOYSA-N 2,4,6-tribromophenol Chemical compound OC1=C(Br)C=C(Br)C=C1Br BSWWXRFVMJHFBN-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 239000004971 Cross linker Substances 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
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- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 description 2
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- 229910004298 SiO 2 Inorganic materials 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 description 2
- 150000008064 anhydrides Chemical class 0.000 description 2
- 239000002216 antistatic agent Substances 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- QMKYBPDZANOJGF-UHFFFAOYSA-N benzene-1,3,5-tricarboxylic acid Chemical compound OC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QMKYBPDZANOJGF-UHFFFAOYSA-N 0.000 description 2
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- 125000005587 carbonate group Chemical group 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
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- 125000000853 cresyl group Chemical group C1(=CC=C(C=C1)C)* 0.000 description 2
- 229920003244 diene elastomer Polymers 0.000 description 2
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
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- 239000000945 filler Substances 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
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- 238000004128 high performance liquid chromatography Methods 0.000 description 2
- 230000003301 hydrolyzing effect Effects 0.000 description 2
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 2
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- 238000005259 measurement Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- RXOHFPCZGPKIRD-UHFFFAOYSA-N naphthalene-2,6-dicarboxylic acid Chemical compound C1=C(C(O)=O)C=CC2=CC(C(=O)O)=CC=C21 RXOHFPCZGPKIRD-UHFFFAOYSA-N 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- CYIDZMCFTVVTJO-UHFFFAOYSA-N pyromellitic acid Chemical compound OC(=O)C1=CC(C(O)=O)=C(C(O)=O)C=C1C(O)=O CYIDZMCFTVVTJO-UHFFFAOYSA-N 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 150000003254 radicals Chemical class 0.000 description 2
- 239000012966 redox initiator Substances 0.000 description 2
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- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
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- DNIAPMSPPWPWGF-VKHMYHEASA-N (+)-propylene glycol Chemical compound C[C@H](O)CO DNIAPMSPPWPWGF-VKHMYHEASA-N 0.000 description 1
- XMNDMAQKWSQVOV-UHFFFAOYSA-N (2-methylphenyl) diphenyl phosphate Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 XMNDMAQKWSQVOV-UHFFFAOYSA-N 0.000 description 1
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- 125000006833 (C1-C5) alkylene group Chemical group 0.000 description 1
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- VDYWHVQKENANGY-UHFFFAOYSA-N 1,3-Butyleneglycol dimethacrylate Chemical compound CC(=C)C(=O)OC(C)CCOC(=O)C(C)=C VDYWHVQKENANGY-UHFFFAOYSA-N 0.000 description 1
- RMSGQZDGSZOJMU-UHFFFAOYSA-N 1-butyl-2-phenylbenzene Chemical group CCCCC1=CC=CC=C1C1=CC=CC=C1 RMSGQZDGSZOJMU-UHFFFAOYSA-N 0.000 description 1
- YIYBRXKMQFDHSM-UHFFFAOYSA-N 2,2'-Dihydroxybenzophenone Chemical compound OC1=CC=CC=C1C(=O)C1=CC=CC=C1O YIYBRXKMQFDHSM-UHFFFAOYSA-N 0.000 description 1
- VSIKJPJINIDELZ-UHFFFAOYSA-N 2,2,4,4,6,6,8,8-octakis-phenyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound O1[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si](C=2C=CC=CC=2)(C=2C=CC=CC=2)O[Si]1(C=1C=CC=CC=1)C1=CC=CC=C1 VSIKJPJINIDELZ-UHFFFAOYSA-N 0.000 description 1
- FQXGHZNSUOHCLO-UHFFFAOYSA-N 2,2,4,4-tetramethyl-1,3-cyclobutanediol Chemical compound CC1(C)C(O)C(C)(C)C1O FQXGHZNSUOHCLO-UHFFFAOYSA-N 0.000 description 1
- JCTXKRPTIMZBJT-UHFFFAOYSA-N 2,2,4-trimethylpentane-1,3-diol Chemical compound CC(C)C(O)C(C)(C)CO JCTXKRPTIMZBJT-UHFFFAOYSA-N 0.000 description 1
- XXKHDSGLCLCFSC-UHFFFAOYSA-N 2,3-diphenylphenol Chemical compound C=1C=CC=CC=1C=1C(O)=CC=CC=1C1=CC=CC=C1 XXKHDSGLCLCFSC-UHFFFAOYSA-N 0.000 description 1
- IRVZFACCNZRHSJ-UHFFFAOYSA-N 2,4,6,8-tetramethyl-2,4,6,8-tetraphenyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound O1[Si](C)(C=2C=CC=CC=2)O[Si](C)(C=2C=CC=CC=2)O[Si](C)(C=2C=CC=CC=2)O[Si]1(C)C1=CC=CC=C1 IRVZFACCNZRHSJ-UHFFFAOYSA-N 0.000 description 1
- BJELTSYBAHKXRW-UHFFFAOYSA-N 2,4,6-triallyloxy-1,3,5-triazine Chemical compound C=CCOC1=NC(OCC=C)=NC(OCC=C)=N1 BJELTSYBAHKXRW-UHFFFAOYSA-N 0.000 description 1
- VPVTXVHUJHGOCM-UHFFFAOYSA-N 2,4-bis[2-(4-hydroxyphenyl)propan-2-yl]phenol Chemical compound C=1C=C(O)C(C(C)(C)C=2C=CC(O)=CC=2)=CC=1C(C)(C)C1=CC=C(O)C=C1 VPVTXVHUJHGOCM-UHFFFAOYSA-N 0.000 description 1
- FLOYTFHQGVFPRS-UHFFFAOYSA-N 2,6-bis[1-(2-hydroxyphenyl)ethyl]-4-methylphenol Chemical compound C=1C(C)=CC(C(C)C=2C(=CC=CC=2)O)=C(O)C=1C(C)C1=CC=CC=C1O FLOYTFHQGVFPRS-UHFFFAOYSA-N 0.000 description 1
- VXHYVVAUHMGCEX-UHFFFAOYSA-N 2-(2-hydroxyphenoxy)phenol Chemical compound OC1=CC=CC=C1OC1=CC=CC=C1O VXHYVVAUHMGCEX-UHFFFAOYSA-N 0.000 description 1
- XSVZEASGNTZBRQ-UHFFFAOYSA-N 2-(2-hydroxyphenyl)sulfinylphenol Chemical compound OC1=CC=CC=C1S(=O)C1=CC=CC=C1O XSVZEASGNTZBRQ-UHFFFAOYSA-N 0.000 description 1
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- 239000001095 magnesium carbonate Substances 0.000 description 1
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 description 1
- 235000014380 magnesium carbonate Nutrition 0.000 description 1
- 229910000021 magnesium carbonate Inorganic materials 0.000 description 1
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 1
- 235000019341 magnesium sulphate Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- 239000010705 motor oil Substances 0.000 description 1
- AKIDPNOWIHDLBQ-UHFFFAOYSA-N naphthalene-1,4,5,8-tetracarbonyl chloride Chemical compound C1=CC(C(Cl)=O)=C2C(C(=O)Cl)=CC=C(C(Cl)=O)C2=C1C(Cl)=O AKIDPNOWIHDLBQ-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 239000002667 nucleating agent Substances 0.000 description 1
- HMMGMWAXVFQUOA-UHFFFAOYSA-N octamethylcyclotetrasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 HMMGMWAXVFQUOA-UHFFFAOYSA-N 0.000 description 1
- YAFOVCNAQTZDQB-UHFFFAOYSA-N octyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OCCCCCCCC)OC1=CC=CC=C1 YAFOVCNAQTZDQB-UHFFFAOYSA-N 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 229960001553 phloroglucinol Drugs 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid group Chemical group C(C=1C(C(=O)O)=CC=CC1)(=O)O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920002587 poly(1,3-butadiene) polymer Polymers 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 229920005862 polyol Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- XRVCFZPJAHWYTB-UHFFFAOYSA-N prenderol Chemical compound CCC(CC)(CO)CO XRVCFZPJAHWYTB-UHFFFAOYSA-N 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000001294 propane Substances 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- XWGJFPHUCFXLBL-UHFFFAOYSA-M rongalite Chemical compound [Na+].OCS([O-])=O XWGJFPHUCFXLBL-UHFFFAOYSA-M 0.000 description 1
- 238000007665 sagging Methods 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid group Chemical group C(CCCCCCCCC(=O)O)(=O)O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- WIJVUKXVPNVPAQ-UHFFFAOYSA-N silyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)O[SiH3] WIJVUKXVPNVPAQ-UHFFFAOYSA-N 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229920006132 styrene block copolymer Polymers 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid group Chemical group C(CCC(=O)O)(=O)O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- UQMOLLPKNHFRAC-UHFFFAOYSA-N tetrabutyl silicate Chemical compound CCCCO[Si](OCCCC)(OCCCC)OCCCC UQMOLLPKNHFRAC-UHFFFAOYSA-N 0.000 description 1
- LFQCEHFDDXELDD-UHFFFAOYSA-N tetramethyl orthosilicate Chemical compound CO[Si](OC)(OC)OC LFQCEHFDDXELDD-UHFFFAOYSA-N 0.000 description 1
- ZQZCOBSUOFHDEE-UHFFFAOYSA-N tetrapropyl silicate Chemical compound CCCO[Si](OCCC)(OCCC)OCCC ZQZCOBSUOFHDEE-UHFFFAOYSA-N 0.000 description 1
- 238000003856 thermoforming Methods 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 230000002463 transducing effect Effects 0.000 description 1
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 description 1
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 description 1
- TUQLLQQWSNWKCF-UHFFFAOYSA-N trimethoxymethylsilane Chemical compound COC([SiH3])(OC)OC TUQLLQQWSNWKCF-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- LIPMRGQQBZJCTM-UHFFFAOYSA-N tris(2-propan-2-ylphenyl) phosphate Chemical compound CC(C)C1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C(C)C)OC1=CC=CC=C1C(C)C LIPMRGQQBZJCTM-UHFFFAOYSA-N 0.000 description 1
- 238000005199 ultracentrifugation Methods 0.000 description 1
- 125000002256 xylenyl group Chemical group C1(C(C=CC=C1)C)(C)* 0.000 description 1
Classifications
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
-
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
-
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
-
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0066—Flame-proofing or flame-retarding additives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
-
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- C08L33/04—Homopolymers or copolymers of esters
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/04—Polysiloxanes
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
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- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/52—Phosphorus bound to oxygen only
- C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
- C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds
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- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
- C08L51/085—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds on to polysiloxanes
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- Chemical & Material Sciences (AREA)
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- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
B)グラフトベースがシリコーンゴムおよびポリアルキル(メタ)アクリレートゴムの相互侵入したシリコーン/アクリレートコンポジットゴムであるグラフトポリマー0.5〜20重量部、好ましくは1〜12重量部、特に好ましくは2〜8重量部(各々、成分の重量部の和A+B+C+Dに基づく)、
C)d98値(「トップカット」とも呼ぶ。)20μm未満、好ましくは15μm未満、特に好ましくは8μm未満を有するタルク0.1〜20重量部、好ましくは1〜15重量部、特に好ましくは4〜12重量部(各々、成分の重量部の和A+B+C+Dに基づく)、
D)モノ−およびオリゴマー状リン酸エステルおよびホスホン酸エステル、ホスホネートアミンおよびホスファゼンからなる群の少なくとも一つから選択された防炎加工剤0.4〜20重量部、好ましくは4〜17重量部、特に好ましくは8〜14重量部(各々、成分の重量部の和A+B+C+Dに基づく)
E)ゴム−フリービニル(コ)ポリマー、ポリアルキレンテレフタレートおよび成分Bと異なるグラフトポリマーからなる群から選択される1以上のポリマー0〜20重量部、好ましくは0〜6.5重量部(成分の重量部の和A+B+C+Dに基づく)、但し特に好ましくは組成物はゴム−フリービニル(コ)ポリマー、ポリアルキレンテレフタレートおよび/または成分Bと異なるグラフトポリマーを含まない、
F)添加剤0〜50重量部、好ましくは0.5〜25重量部(各々、成分の重量部の和A+B+C+Dに基づく)
(但し、本明細書中のすべての重量部は、組成物中の成分A+B+C+Dの重量部の和が100であるように標準化する)
を含有する組成物により達成することができる。
本発明に好適な成分Aによる芳香族ポリカーボネートおよび/または芳香族ポリエステルカーボネートは、文献に知られているか、文献に知られている方法により調製されうる(芳香族ポリカーボネートの調製には、Schnellの「Chemistry and Physics of Polycrbonates」、Interscience Publishers、1964年およびDE−AS 1 495 626、DE−A2 232 877、DE−A2 703 376、DE−A2 714 544、DE−A3 000 610およびDE−A3 832 396;芳香族ポリエステルカーボネートの調製には、DE−A3 077 934)。
Bは各々C1〜C12−アルキル、好ましくはメチル、またはハロゲン、好ましくは塩素および/または臭素であり、
xは各々互いに独立して0、1または2であり、
pは1または0であり、
R5およびR6は、X1に関して独立に選択され、かつ互いに独立して水素またはC1〜C5−アルキル、好ましくは水素、メチルまたはエチルを示し、
X1は炭素を示し、かつ
mは4〜7の整数、好ましくは4または5を示し、
但し、少なくとも1つの原子X1上で、、R5およびR6は同時にアルキルである。)
で表されるものが好ましい。
成分Bは、好ましくは、
B.1 1種以上のビニルモノマー5〜95重量%、好ましくは10〜90重量%、および
B.2 グラフトベースとして1以上のシリコーン/アクリレートコンポジットゴム95〜5重量%であって、該シリコーン/アクリレートゴムがB.2.1シリコーンゴム65〜95重量%およびB.2.2ポリアルキル(メタ)アクリレートゴム35〜5重量%を含有し、上記2種のゴム成分B2.1.1およびB.2.2が相互にコンポジットゴム中で相互に侵入して実質上互いに分離することができないものであるもの、
B.2上でB.1が重合したもの
である1種以上のグラフトポリマーを包含する。
で表させる構造を形成しうる化合物である。
タルクは天然のものまたは合成のものであって、上述の本発明によるトップカット(d98値)を有するものを意味するものと考えられる。d98が高すぎるタルクを含む組成物は加水分解が起こりやすく、同じ量用いたときに、比較して機械特性が悪くなる(低いEモジュラスおよび低いノッチ衝撃力)。d98値はその粒子径の下に粒子の98重量%が存在する粒子径である。d98値はSedigaraph5100(ミクロメリティックス(Micromeritics)GmbH、ドイツ国41238メンチェングラドバッハ、エルフトシュトラーセ43番)を用いる粒径分布を測定することにより決定される。
リン含有化合物は成分Dの防炎加工剤として使用される。これらはモノ−およびオリゴマー状リン酸およびホスホン酸エステル、ホスホネートアミンおよびホスファゼンから好ましくは選択され、これらのグループの1種または複数種の混合物を用いることもできる。ここに記載されていない他のハロゲンフリーのリン化合物も単独で、またはたのハロゲンフリーのリン化合物と組み合わせて使用しても良い。
nは互いに独立して0または1を示し、
qは0〜30を示し、
Xは炭素数6〜30を有するモノ−または多核芳香族基、または炭素数2〜30を有する直鎖または分岐鎖脂肪族基であり、これらはOHで置換されていてもよくまた8個までのエーテル結合を有していてもよい。)
を有するものである。
成分Eは一以上の熱可塑性ビニル(コ)ポリマーE.1、ポリアルキレンテレフタレートE.2および/またはグラフトポリマーE.3が含まれ、これらは成分Bとは異なる。
E.1.1 ビニル芳香族および/または核上で置換されたビニル芳香族、例えばスチレン、α−メチルスチレン、p−メチルスチレンおよびp−クロロスチレン、および/または(メタ)アクリル酸(C1−C8)−アルキルエステル、例えばメチルメタクリレートおよびエチルメタクリレート50〜99重量部、好ましくは60〜80重量部、および
E.1.2 ビニルシアニド(不飽和ニトリル)、例えばアクリロニトリルおよびメタクリロニトリル、および/または(メタ)アクリル酸(C1−C8)−アルキルエステル、例えばメチルメタクリレート、n−ブチルアクリレートおよびt−ブチルアクリレート、および/または不飽和カルボン酸、例えばマレイン酸、および/または不飽和カルボン酸の誘導体、例えば無水物およびイミド(例えば、マレイン酸無水物およびN−フェニルマレイミド)1〜50重量部、好ましくは20〜40重量部のものである。
E.3.1.1ビニル芳香族および/または核上で置換されたビニル芳香族(例えば、スチレン、α−メチルスチレン、p−メチルスチレンおよびp−クロロスチレン)および/または(メタ)アクリル酸(C1〜C8)−アルキルエステル(例えば、メチルメタクリレートおよびエチルメタクリレート)50〜99重量部(E.3.1.1およびE.3.1.2の合計100重量部に基づく)、および
E.3.1.2ビニルシアニド(不飽和ニトリル、例えばアクリロニトリルおよびメタクリロニトリル)および/または(メタ)アクリル酸C1〜C8アルキルエステル、例えばメチルメタクリレート、n−ブチルアクリレートおよびt−ブチルアクリレート、および/または不飽和カルボン酸の誘導体(例えば、酸無水物およびイミド)、例えばマレイン酸無水物およびN−フェニルマレイミド1〜50重量部(E.3.1.1およびE.3.1.2の合計100重量部に基づく)
の混合物である。
組成物は更に成分Fとして市販の添加剤、例えば防炎助剤、流れ防止剤(例えば、フッ素化ポリオレフィン、シリコーンおよびアラミドファイバーの群の化合物)、潤滑剤および離型剤(例えば、ペンタエリスリトールテトラステアレート)、核化剤、安定剤、帯電防止剤(例えば、導電性カーボンブラック、カーボン繊維、カーボンナノチューブおよび有機帯電防止剤、例えばポリアルキレンエーテル、アルキルスルフォネートまたはポリアミド−含有ポリマー)、酸、充填剤およびタルクとは異なる補強剤(例えば、ガラスファイバーまたはカーボン繊維、マイカ、カオリン、CaCO3およびガラスフレーク)および染料および顔料を含んでもよい。
本発明の熱可塑性成形性組成物は公知の方法で特定の成分を混合し、混合物を溶融コンパウンドし、240〜300℃の温度で常套のユニット、例えばインターナルニーダー、押出機および二軸押出機で溶融押出する。
成分A−1
溶媒としてCH2Cl2中で25℃濃度0.5g/100mlで測定された相対溶液粘度ηrel=1.28を有するビスフェノールAに基づく非分岐ポリカーボネート
溶媒としてCH2Cl2中で25℃濃度0.5g/100mlで測定された相対溶液粘度ηrel=1.20を有するビスフェノールAに基づく非分岐ポリカーボネート
B−1.1 メチルメタクリレート11重量%、および
B−1.2 グラフトベースとしてシリコーン/アクリレートコンポジットゴム89重量%、ただしシリコーン/アクリレートゴムはB−1.2.1シリコーンゴム92重量%およびB−1.2.2ポリアルキル(メタ)アクリレートゴム8重量%であり、上記二つのゴム成分B.2.1およびB.2.2は互いにコンポジットゴムに進入して実質的に互いに分離することができないもので、
B−1.2上にB−1.1がグラフトしたもの
の衝撃変性グラフトポリマー
B−2.1 メチルメタクリレート17重量%、および
B−2.2 グラフトベースとしてシリコーン/アクリレートコンポジットゴム83重量%、ただしシリコーン/アクリレートゴムはB−2.2.1シリコーンゴム11重量%およびB−2.2.2ポリアルキル(メタ)アクリレートゴム89重量%であり、上記二つのゴム成分B.2.1およびB.2.2は互いにコンポジットゴムに進入して実質的に互いに分離することができないもので、
B−1.2上にB−1.1がグラフトしたもの
の衝撃変性グラフトポリマー
C−1 d98値5μmおよび平均粒径(d50)1μmを有するタルク(オーストリア、グラッツ(Graz)、Luzenac NaintschまたはRio Tinto Minerals、JetfineR3CA)
C−2 d98値22μmおよび平均粒径(d50)4.5μmを有するタルク(オランダ、アムステルダム、Mondo Minerals、FinntalcRM15-AW)
C−3 d98値25μmおよび平均粒径(d50)6μmを有するタルク(オランダ、アムステルダム、Mondo Minerals、FinntalcRM20SL-AW)
C−4 d98値35μmおよび平均粒径(d50)9μmを有するタルク(オランダ、アムステルダム、Mondo Minerals、FinntalcRM30)
重量平均分子量Mw130Kg/mol(GPCで測定)を有するバルク方法で調製されたスチレン77重量%およびアクリロニトリル23重量%のコポリマー
スチレン含量26重量%を有するブタジエン/スチレンブロックコポリマーがABSポリマーに基づいて18重量%の量で存在時に、アクリロニトリル24重量%およびスチレン76重量%の混合物82重量%(ABSポリマーに基づく)のバルク重合に酔って調製されたABSポリマー。ABSポリマー中の遊離SANコポリマー含量の重量平均分子量MWは80,000g/mol(THF中GPCで測定)である。ABSポリマーのゲル含量は24重量%(アセトン中で測定)である。
成分F−1 CFP6000N、ポリテトラフルオロエチレン粉末(スイス、ジュネーブ、デュポン社)
成分F−2 ペンタエリスリトールテトラスレアレート
成分F−3 イルガノックスRB900(製造元:スイス、バーゼル、チバ・スペシャリルティ・ケミカルズ・インク)
成分F−4 ベーマイト構造を有するピューラル(Pural)R200、AlO(OH)(製造元:ドイツ、ハンブルグ、ザゾル)
表1〜5に記載の出発物質を2軸スクリュー押出機(ZSK−25)(ヴェルナーウントプフライダーラー(Verner und pfleiderer))で回転速度225rpmおよびスルーアウトプット20Kg/hで、機械温度260℃でコンパウンドし、造粒した。
(a)テスト媒体としてトルエン:イロプロパノールの体積比60:40(ISO4599)を用いて、可変末端ファイバー伸び、即ち末端ファイバー伸びで5分間露出を測定し、その場合のテスト試料の破断を記載する。
(b)テスト媒体としてトルエン:イロプロパノールの体積比60:40(ISO4599)を用いて、末端ファイバー伸び2.4%、即ち所定期間の露出を測定し、その場合のテスト試料の破断を記載する。
(c)テスト媒体として菜種油を用いる以外は、(b)と同様。
(d)テスト媒体としてエンジンオイルを用いる以外は、(b)と同様。
Claims (5)
- A)芳香族ポリカーボネートおよび/または芳香族ポリエステルカーボネート40〜99重量部(各々、成分の重量部の和A+B+C+Dに基づく)
B)グラフトベースがシリコーンゴムおよびポリアルキル(メタ)アクリレートゴムの相互侵入したシリコーン/アクリレートコンポジットゴムであり、シリコーンゴムの含有量が65〜95重量%(グラフトベースに基づく)であるグラフトポリマー0.5〜20重量部(各々、成分の重量部の和A+B+C+Dに基づく)、
C)d98値8μm未満およびd50値0.2〜2μmを有するタルク0.1〜20重量部(各々、成分の重量部の和A+B+C+Dに基づく)
D)モノ−およびオリゴマー状リン酸エステルおよびホスホン酸エステル、ホスホネートアミンおよびホスファゼンからなる群の少なくとも一つから選択された防炎加工剤0.4〜20重量部(各々、成分の重量部の和A+B+C+Dに基づく)
を含有し、
成分Bのグラフトポリマーが、
B.1 B.2上の1種以上のビニルモノマー5〜95重量%、および
B.2 グラフトベースとして1以上のシリコーン/アクリレートコンポジットゴム95〜5重量%であって、該シリコーン/アクリレートゴムがB.2.1シリコーンゴム65〜95重量%およびB.2.2ポリアルキル(メタ)アクリレートゴム35〜5重量%を含有し、上記2種のゴム成分B.2.1およびB.2.2が相互にコンポジットゴム中に相互に侵入して互いに分離することができないものであるもの、
B.2上でB.1がグラフトしたものであり、
組成物中の成分A+B+C+Dの重量部の和が100である
組成物。 - 成分Dとして、一般式(VIII):
を有するモノ−およびオリゴマー状リン酸エステルまたはホスホン酸エステルを含有する請求項1記載の組成物。 - 成形物品の製造への請求項1記載の組成物の使用。
- 請求項1〜3いずれかに記載の組成物を含む成形物品。
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-
2008
- 2008-12-23 DE DE102008062945A patent/DE102008062945A1/de not_active Withdrawn
-
2009
- 2009-12-15 EP EP09795706.2A patent/EP2382268B1/de active Active
- 2009-12-15 CA CA2748327A patent/CA2748327C/en not_active Expired - Fee Related
- 2009-12-15 ES ES09795706.2T patent/ES2553564T3/es active Active
- 2009-12-15 MX MX2011006277A patent/MX2011006277A/es not_active Application Discontinuation
- 2009-12-15 KR KR1020117014355A patent/KR101719827B1/ko active IP Right Grant
- 2009-12-15 JP JP2011542700A patent/JP5882062B2/ja active Active
- 2009-12-15 BR BRPI0923545A patent/BRPI0923545A2/pt not_active IP Right Cessation
- 2009-12-15 WO PCT/EP2009/008965 patent/WO2010072350A1/de active Application Filing
- 2009-12-15 CN CN200980152248.7A patent/CN102264835B/zh active Active
- 2009-12-18 US US12/641,649 patent/US8748521B2/en active Active
- 2009-12-22 TW TW98144060A patent/TWI466946B/zh not_active IP Right Cessation
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US11603467B2 (en) | 2016-09-09 | 2023-03-14 | Mitsubishi Engineering-Plastics Corporation | Polycarbonate resin composition |
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CA2748327A1 (en) | 2010-07-01 |
US8748521B2 (en) | 2014-06-10 |
CN102264835B (zh) | 2014-10-29 |
ES2553564T3 (es) | 2015-12-10 |
WO2010072350A1 (de) | 2010-07-01 |
CN102264835A (zh) | 2011-11-30 |
EP2382268A1 (de) | 2011-11-02 |
CA2748327C (en) | 2016-10-11 |
TW201035236A (en) | 2010-10-01 |
DE102008062945A1 (de) | 2010-06-24 |
JP2012513504A (ja) | 2012-06-14 |
JP2014240492A (ja) | 2014-12-25 |
KR101719827B1 (ko) | 2017-03-24 |
TWI466946B (zh) | 2015-01-01 |
BRPI0923545A2 (pt) | 2016-01-26 |
MX2011006277A (es) | 2011-06-24 |
US20100160508A1 (en) | 2010-06-24 |
KR20110100630A (ko) | 2011-09-14 |
EP2382268B1 (de) | 2015-10-07 |
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