JP5855476B2 - 固体触媒のオフサイト再生方法 - Google Patents

固体触媒のオフサイト再生方法 Download PDF

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JP5855476B2
JP5855476B2 JP2012014626A JP2012014626A JP5855476B2 JP 5855476 B2 JP5855476 B2 JP 5855476B2 JP 2012014626 A JP2012014626 A JP 2012014626A JP 2012014626 A JP2012014626 A JP 2012014626A JP 5855476 B2 JP5855476 B2 JP 5855476B2
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catalyst
stage
fluid
supercritical state
temperature
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JP2012143754A (ja
JP2012143754A5 (enExample
Inventor
ケルロー フィリップ
ケルロー フィリップ
デュフレーヌ ピエール
デュフレーヌ ピエール
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ユーレキャット ソシエテ アノニム
ユーレキャット ソシエテ アノニム
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74Iron group metals
    • B01J23/75Cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04Alumina
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/88Molybdenum
    • B01J23/882Molybdenum and cobalt
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85Chromium, molybdenum or tungsten
    • B01J23/88Molybdenum
    • B01J23/883Molybdenum and nickel
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90Regeneration or reactivation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90Regeneration or reactivation
    • B01J23/94Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the iron group metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90Regeneration or reactivation
    • B01J23/96Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides of the noble metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/064Crystalline aluminosilicate zeolites; Isomorphous compounds thereof containing iron group metals, noble metals or copper
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/90Regeneration or reactivation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/60Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61Surface area
    • B01J35/615100-500 m2/g
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/02Heat treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/04Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/10Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst using elemental hydrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/04Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12Treating with free oxygen-containing gas
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/50Liquid treating or treating in liquid phase, e.g. dissolved or suspended using organic liquids
    • B01J38/56Hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/48Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/68Liquid treating or treating in liquid phase, e.g. dissolved or suspended including substantial dissolution or chemical precipitation of a catalyst component in the ultimate reconstitution of the catalyst
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J2038/005Regeneration or reactivation of catalysts, in general involving supercritical treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90Regeneration or reactivation
    • B01J23/92Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
JP2012014626A 2011-01-11 2012-01-10 固体触媒のオフサイト再生方法 Expired - Fee Related JP5855476B2 (ja)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR1150198A FR2970187B1 (fr) 2011-01-11 2011-01-11 Procede de regeneration hors site de catalyseurs solides.
FR1150198 2011-01-11
US201161440218P 2011-02-07 2011-02-07
US61/440,218 2011-02-07

Publications (3)

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JP2012143754A JP2012143754A (ja) 2012-08-02
JP2012143754A5 JP2012143754A5 (enExample) 2015-03-05
JP5855476B2 true JP5855476B2 (ja) 2016-02-09

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JP2012014626A Expired - Fee Related JP5855476B2 (ja) 2011-01-11 2012-01-10 固体触媒のオフサイト再生方法

Country Status (8)

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US (1) US8772191B2 (enExample)
EP (1) EP2474359B1 (enExample)
JP (1) JP5855476B2 (enExample)
CN (1) CN102600914A (enExample)
BR (1) BRPI1105404B1 (enExample)
CA (1) CA2763514C (enExample)
FR (1) FR2970187B1 (enExample)
SA (1) SA112330154B1 (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2951226B2 (ja) 1995-02-03 1999-09-20 三洋電機株式会社 盗難防止システム及び盗難防止用信号送信装置

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2970187B1 (fr) * 2011-01-11 2013-02-08 Eurecat Sa Procede de regeneration hors site de catalyseurs solides.
ES2839076T3 (es) 2013-01-22 2021-07-05 Anellotech Inc Reactor con inyector de gas y método para la pirolisis rápida catalítica
MX2015012138A (es) 2013-03-12 2016-06-02 Anellotech Inc Regeneracion de catalizador de pirolisis rapida catalitica.
US9796648B2 (en) 2014-05-02 2017-10-24 University Of Tennessee Research Foundation Glycerol dehydration methods and products thereof
CN105214740A (zh) * 2015-09-30 2016-01-06 广西大学 内部汽化膨胀法再生改性fcc废触媒及其应用
KR20180087437A (ko) * 2015-12-15 2018-08-01 사우디 아라비안 오일 컴퍼니 석유의 업그레이드를 위한 초임계 반응기 시스템 및 방법
CN108325567A (zh) * 2018-03-12 2018-07-27 河南工业大学 一种负载钌催化剂的再生方法

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DE2853065A1 (de) * 1978-12-08 1980-06-19 Varta Batterie Verfahren zur extraktion der reaktionsprodukte aus altkatalysatoren
DE3902515A1 (de) * 1989-01-28 1990-08-02 Hoechst Ag Verfahren zur reinigung und rueckgewinnung der bei der carbonylierung von methanol und/oder methylacetat und/oder dimethylether anfallenden verunreinigten katalysatorloesung
ES2127113B1 (es) * 1996-07-11 1999-11-16 Univ De Salmanca Procedimiento para la regeneracion de catalizadores y materiales adsorbentes.
DE19723949A1 (de) * 1997-06-06 1998-12-10 Basf Ag Verfahren zur Regenerierung eines Zeolith-Katalysators
US6294194B1 (en) * 1997-10-14 2001-09-25 Boehringer Ingelheim Pharmaceuticals, Inc. Method for extraction and reaction using supercritical fluids
JP2000093805A (ja) * 1998-09-22 2000-04-04 Kobe Steel Ltd ゼオライト系触媒の再生法および触媒再生装置
US6753354B2 (en) * 2002-01-29 2004-06-22 Exxonmobil Research And Engineering Company Fischer-tropsch catalyst enhancement
US6800579B2 (en) * 2002-01-29 2004-10-05 Exxonmobil Research And Engineering Company Catalyst regeneration
US6753286B2 (en) * 2002-01-29 2004-06-22 Exxonmobil Research And Engineering Company Supported catalyst regeneration
US6838487B1 (en) * 2003-12-04 2005-01-04 Rentech, Inc. Method and apparatus for regenerating an iron-based Fischer-Tropsch catalyst
CN100337753C (zh) * 2004-10-22 2007-09-19 中国石油化工股份有限公司 一种超临界流体再生催化剂的方法
GB0604285D0 (en) * 2006-03-03 2006-04-12 Johnson Matthey Plc Catalyst reprocessing
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CA2755952C (en) * 2008-12-15 2016-10-11 Sasol Technology (Proprietary) Limited Process for regenerating spent particulate wax-containing cobalt-based fischer-tropsch synthesis catalyst
FR2970187B1 (fr) * 2011-01-11 2013-02-08 Eurecat Sa Procede de regeneration hors site de catalyseurs solides.

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2951226B2 (ja) 1995-02-03 1999-09-20 三洋電機株式会社 盗難防止システム及び盗難防止用信号送信装置

Also Published As

Publication number Publication date
BRPI1105404A2 (pt) 2014-03-11
SA112330154B1 (ar) 2015-01-20
FR2970187B1 (fr) 2013-02-08
EP2474359B1 (fr) 2019-03-20
JP2012143754A (ja) 2012-08-02
BRPI1105404B1 (pt) 2019-09-10
CN102600914A (zh) 2012-07-25
EP2474359A1 (fr) 2012-07-11
US20120231947A1 (en) 2012-09-13
FR2970187A1 (fr) 2012-07-13
US8772191B2 (en) 2014-07-08
CA2763514A1 (fr) 2012-07-11
CA2763514C (fr) 2019-04-09

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