JP5756087B2 - 高効率触媒による特定のアルキレンオキサイド製造パラメーターを達成かつ維持する改良方法 - Google Patents
高効率触媒による特定のアルキレンオキサイド製造パラメーターを達成かつ維持する改良方法 Download PDFInfo
- Publication number
- JP5756087B2 JP5756087B2 JP2012507297A JP2012507297A JP5756087B2 JP 5756087 B2 JP5756087 B2 JP 5756087B2 JP 2012507297 A JP2012507297 A JP 2012507297A JP 2012507297 A JP2012507297 A JP 2012507297A JP 5756087 B2 JP5756087 B2 JP 5756087B2
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- Japan
- Prior art keywords
- alkylene oxide
- concentration
- efficiency
- catalyst
- reaction temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/33—Heterocyclic compounds
- A61K31/395—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins
- A61K31/495—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins having six-membered rings with two or more nitrogen atoms as the only ring heteroatoms, e.g. piperazine or tetrazines
- A61K31/498—Pyrazines or piperazines ortho- and peri-condensed with carbocyclic ring systems, e.g. quinoxaline, phenazine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Pharmacology & Pharmacy (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US17128409P | 2009-04-21 | 2009-04-21 | |
| US61/171,284 | 2009-04-21 | ||
| PCT/US2010/031673 WO2010123844A1 (en) | 2009-04-21 | 2010-04-20 | Improved method of achieving and maintaining a specified alkylene oxide production parameter with a high efficiency catalyst |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012524786A JP2012524786A (ja) | 2012-10-18 |
| JP2012524786A5 JP2012524786A5 (https=) | 2013-05-30 |
| JP5756087B2 true JP5756087B2 (ja) | 2015-07-29 |
Family
ID=42629694
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012507297A Active JP5756087B2 (ja) | 2009-04-21 | 2010-04-20 | 高効率触媒による特定のアルキレンオキサイド製造パラメーターを達成かつ維持する改良方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8362284B2 (https=) |
| EP (1) | EP2421841B1 (https=) |
| JP (1) | JP5756087B2 (https=) |
| KR (1) | KR101730667B1 (https=) |
| CN (1) | CN102414188B (https=) |
| CA (1) | CA2759397C (https=) |
| SG (1) | SG175771A1 (https=) |
| TW (1) | TWI481599B (https=) |
| WO (1) | WO2010123844A1 (https=) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PE20090146A1 (es) * | 2007-04-20 | 2009-03-23 | Glaxosmithkline Biolog Sa | Composicion inmunogenica contra el virus influenza |
| CN102414189B (zh) * | 2009-04-21 | 2014-09-17 | 陶氏技术投资有限公司 | 环氧化反应及其操作条件 |
| KR101886462B1 (ko) * | 2010-12-10 | 2018-08-07 | 다우 테크놀로지 인베스트먼츠 엘엘씨. | 고효율 촉매를 사용하는 알킬렌 옥사이드 제조 방법에서 알킬렌 옥사이드 생산 변수의 값을 감소시키는 방법 |
| SG190901A1 (en) | 2010-12-15 | 2013-07-31 | Dow Technology Investments Llc | Method of starting-up a process of producing an alkylene oxide using a high-efficiency catalyst |
| CN103502229B (zh) | 2011-04-29 | 2016-02-03 | 国际壳牌研究有限公司 | 用于改善环氧乙烷催化剂选择性的方法 |
| WO2013059225A1 (en) * | 2011-10-18 | 2013-04-25 | Al-Ahmadi Hassan Eisa | Epoxidation process with added moderator |
| EP2788337B1 (en) | 2011-12-09 | 2016-03-02 | Dow Technology Investments LLC | Method of maintaining the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst |
| WO2014105770A1 (en) * | 2012-12-31 | 2014-07-03 | Scientific Design Company, Inc. | Start-up process for high selectivity ethylene oxide catalysts |
| CN105143161B (zh) | 2013-03-15 | 2018-08-10 | 陶氏技术投资有限责任公司 | 用于制造环氧乙烷的方法 |
| US10208005B2 (en) | 2014-12-30 | 2019-02-19 | Dow Technology Investments Llc | Process for manufacturing ethylene oxide using scaled selectivity values |
| WO2019055773A1 (en) * | 2017-09-15 | 2019-03-21 | MultiPhase Solutions, Inc. | GAS PHASE CHROMATOGRAPHY OF SELECTIVE HALOGEN DETECTION FOR ONLINE ANALYSIS AND CONTROL OF SELECTIVE OXIDATION CHEMICAL PRODUCTION PROCESSES |
| CN110673557B (zh) * | 2019-09-27 | 2021-09-24 | 南京大学 | 基于工艺条件选择的智能化工系统 |
| CA3204704A1 (en) * | 2020-12-29 | 2022-07-07 | Shell Internationale Research Maatschappij B.V. | Process for the production of ethylene oxide |
| CN117099163A (zh) * | 2021-04-08 | 2023-11-21 | 国际壳牌研究有限公司 | 乙烯环氧化的缓和剂和催化剂性能优化 |
| CN118019732A (zh) * | 2021-09-23 | 2024-05-10 | 陶氏环球技术有限责任公司 | 用于降低高选择性环氧乙烷催化剂的老化相关失活的方法 |
Family Cites Families (49)
| Publication number | Priority date | Publication date | Assignee | Title |
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| BE752859R (fr) | 1969-07-10 | 1971-01-04 | Halcon International Inc | Oxydation controlee de l'oxyde |
| US5387751A (en) * | 1978-02-10 | 1995-02-07 | Imperial Chemical Industries Plc | Production of olefine oxides |
| JPS6110570A (ja) * | 1984-06-25 | 1986-01-18 | Mitsui Toatsu Chem Inc | エチレンオキシドの製造方法 |
| CA1286687C (en) | 1985-08-13 | 1991-07-23 | Michael Paul Habenschuss | Process for manufacture of alkene oxide |
| US4808738A (en) * | 1986-10-31 | 1989-02-28 | Shell Oil Company | Ethylene oxide process |
| US4766105A (en) * | 1986-10-31 | 1988-08-23 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
| IL84232A (en) | 1986-10-31 | 1992-06-21 | Shell Int Research | Catalyst and process for the catalytic production of ethylene oxide |
| US4761394A (en) * | 1986-10-31 | 1988-08-02 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
| US4820675A (en) * | 1986-10-31 | 1989-04-11 | Shell Oil Company | Ethylene oxide catalyst & process for preparing the catalyst |
| GB8626687D0 (en) * | 1986-11-07 | 1986-12-10 | Shell Int Research | Preparing silver catalyst |
| US4908343A (en) * | 1987-02-20 | 1990-03-13 | Union Carbide Chemicals And Plastics Company Inc. | Catalyst composition for oxidation of ethylene to ethylene oxide |
| US4769047A (en) * | 1987-06-29 | 1988-09-06 | Shell Oil Company | Process for the production of ethylene oxide |
| GB8716653D0 (en) * | 1987-07-15 | 1987-08-19 | Shell Int Research | Silver-containing catalyst |
| US4759313A (en) * | 1987-10-30 | 1988-07-26 | Shell Oil Company | Ethylene oxide process improvement |
| US4874879A (en) * | 1988-07-25 | 1989-10-17 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
| CA1339317C (en) | 1988-07-25 | 1997-08-19 | Ann Marie Lauritzen | Process for producing ethylene oxide |
| EP0357293B1 (en) | 1988-08-30 | 1996-02-28 | Union Carbide Corporation | Catalysts for the production of ethylene oxide and their preparation processes |
| CA1337722C (en) * | 1989-04-18 | 1995-12-12 | Madan Mohan Bhasin | Alkylene oxide catalysts having enhanced activity and/or stability |
| GB9005964D0 (en) * | 1990-03-16 | 1990-05-09 | Shell Int Research | Catalyst preparation process |
| US5102848A (en) * | 1990-09-28 | 1992-04-07 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
| JP2720124B2 (ja) * | 1990-10-12 | 1998-02-25 | ユニオン・カーバイド、ケミカルズ、アンド、プラスチックス、テクノロジー、コーポレーション | 向上された活性度及び/又は安定度を有するアルキレンオキシド触媒 |
| CA2053404A1 (en) | 1990-10-12 | 1992-04-13 | Erlind M. Thorsteinson | Ultrahigh efficiency alkylene oxide catalysts having enhanced stability |
| US5145824A (en) * | 1991-01-22 | 1992-09-08 | Shell Oil Company | Ethylene oxide catalyst |
| US5228484A (en) * | 1991-06-20 | 1993-07-20 | Catalyst Technology, Inc. | Air lance reel for catalyst unloading of tubular reactors |
| US5155242A (en) * | 1991-12-05 | 1992-10-13 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
| US5262551A (en) * | 1992-04-20 | 1993-11-16 | Texaco Chemical Company | Process for ethylene expoxidation |
| US5447897A (en) * | 1993-05-17 | 1995-09-05 | Shell Oil Company | Ethylene oxide catalyst and process |
| US5380697A (en) * | 1993-09-08 | 1995-01-10 | Shell Oil Company | Ethylene oxide catalyst and process |
| US5364826A (en) * | 1993-09-13 | 1994-11-15 | Shell Oil Company | Process for preparing ethylene oxide catalysts |
| TW314512B (https=) * | 1993-09-20 | 1997-09-01 | Shell Int Research | |
| US5418202A (en) * | 1993-12-30 | 1995-05-23 | Shell Oil Company | Ethylene oxide catalyst and process |
| US5545603A (en) * | 1994-11-01 | 1996-08-13 | Shell Oil Company | Ethylene oxide catalyst and process |
| ZA963000B (en) * | 1995-04-18 | 1996-10-22 | Shell Int Research | Process for the catalytic vapour phase oxidation of ethylene |
| US5739075A (en) | 1995-10-06 | 1998-04-14 | Shell Oil Company | Process for preparing ethylene oxide catalysts |
| CZ161198A3 (cs) * | 1995-11-23 | 1998-09-16 | Shell Internationale Research Maatschappij B. V. | Postup přípravy alkylenglykolů |
| US5801259A (en) * | 1996-04-30 | 1998-09-01 | Shell Oil Company | Ethylene oxide catalyst and process |
| US5840932A (en) * | 1996-05-21 | 1998-11-24 | Shell Oil Company | Process for ethylene oxide production |
| WO1997046317A1 (en) * | 1996-06-05 | 1997-12-11 | Shell Internationale Research Maatschappij B.V. | Epoxidation catalyst and process |
| US5770746A (en) * | 1997-06-23 | 1998-06-23 | Arco Chemical Technology, L.P. | Epoxidation process using supported silver catalysts pretreated with organic chloride |
| US7193094B2 (en) * | 2001-11-20 | 2007-03-20 | Shell Oil Company | Process and systems for the epoxidation of an olefin |
| BR0214282A (pt) * | 2001-11-20 | 2004-09-21 | Shell Int Research | Processos e sistemas para epoxidação de uma olefina |
| DE60304197T2 (de) | 2002-06-28 | 2006-12-14 | Shell Internationale Research Maatschappij B.V. | Verfahren zum initiieren eines epoxidationsverfahrens, katalysator und verfahren zur epoxidation eines olefins |
| RU2005102097A (ru) | 2002-06-28 | 2005-08-27 | Шелл Интернэшнл Рисерч Маатсхаппий Б.В. (NL) | Способ введения в действие способа эпоксидирования и способ эпоксидирования олефина |
| ATE376879T1 (de) * | 2003-04-01 | 2007-11-15 | Shell Int Research | Olefinepoxidationsverfahren und katalysator zur verwendung bei dem verfahren |
| RU2360908C2 (ru) * | 2003-09-29 | 2009-07-10 | Дау Текнолоджи Инвестментс Ллс. | Способ получения алкиленоксида с использованием газофазной промоторной системы |
| EP1765800B1 (en) | 2004-06-18 | 2012-04-18 | Shell Internationale Research Maatschappij B.V. | A process for the production of an olefin oxide, a 1,2-diol, a 1.2-diol ether, or an alkanolamine |
| US7803957B2 (en) * | 2007-09-11 | 2010-09-28 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Ethylene oxide production using fixed moderator concentration |
| US7553980B2 (en) | 2007-09-26 | 2009-06-30 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Process for initiating a highly selective ethylene oxide catalyst |
| JP2012524785A (ja) * | 2009-04-21 | 2012-10-18 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | 高効率触媒を用いたアルキレンオキシド簡易製造方法 |
-
2010
- 2010-04-20 WO PCT/US2010/031673 patent/WO2010123844A1/en not_active Ceased
- 2010-04-20 EP EP10732499.8A patent/EP2421841B1/en not_active Revoked
- 2010-04-20 CA CA2759397A patent/CA2759397C/en active Active
- 2010-04-20 US US12/763,285 patent/US8362284B2/en active Active
- 2010-04-20 KR KR1020117027501A patent/KR101730667B1/ko active Active
- 2010-04-20 TW TW099112279A patent/TWI481599B/zh active
- 2010-04-20 CN CN201080017748.2A patent/CN102414188B/zh active Active
- 2010-04-20 JP JP2012507297A patent/JP5756087B2/ja active Active
- 2010-04-20 SG SG2011077583A patent/SG175771A1/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| US20100267972A1 (en) | 2010-10-21 |
| EP2421841A1 (en) | 2012-02-29 |
| TW201105641A (en) | 2011-02-16 |
| KR101730667B1 (ko) | 2017-04-26 |
| JP2012524786A (ja) | 2012-10-18 |
| US8362284B2 (en) | 2013-01-29 |
| WO2010123844A1 (en) | 2010-10-28 |
| EP2421841B1 (en) | 2018-12-26 |
| CN102414188B (zh) | 2015-05-27 |
| KR20120014160A (ko) | 2012-02-16 |
| CA2759397C (en) | 2019-01-29 |
| CA2759397A1 (en) | 2010-10-28 |
| TWI481599B (zh) | 2015-04-21 |
| SG175771A1 (en) | 2011-12-29 |
| CN102414188A (zh) | 2012-04-11 |
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