JP5756087B2 - 高効率触媒による特定のアルキレンオキサイド製造パラメーターを達成かつ維持する改良方法 - Google Patents
高効率触媒による特定のアルキレンオキサイド製造パラメーターを達成かつ維持する改良方法 Download PDFInfo
- Publication number
- JP5756087B2 JP5756087B2 JP2012507297A JP2012507297A JP5756087B2 JP 5756087 B2 JP5756087 B2 JP 5756087B2 JP 2012507297 A JP2012507297 A JP 2012507297A JP 2012507297 A JP2012507297 A JP 2012507297A JP 5756087 B2 JP5756087 B2 JP 5756087B2
- Authority
- JP
- Japan
- Prior art keywords
- alkylene oxide
- concentration
- efficiency
- catalyst
- reaction temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
- C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
- C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/33—Heterocyclic compounds
- A61K31/395—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins
- A61K31/495—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins having six-membered rings with two or more nitrogen atoms as the only ring heteroatoms, e.g. piperazine or tetrazines
- A61K31/498—Pyrazines or piperazines ortho- and peri-condensed with carbocyclic ring systems, e.g. quinoxaline, phenazine
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
- B01J37/02—Impregnation, coating or precipitation
- B01J37/0201—Impregnation
- B01J37/0205—Impregnation in several steps
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D301/00—Preparation of oxiranes
- C07D301/02—Synthesis of the oxirane ring
- C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
- C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Pharmacology & Pharmacy (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Epidemiology (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Epoxy Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US17128409P | 2009-04-21 | 2009-04-21 | |
| US61/171,284 | 2009-04-21 | ||
| PCT/US2010/031673 WO2010123844A1 (en) | 2009-04-21 | 2010-04-20 | Improved method of achieving and maintaining a specified alkylene oxide production parameter with a high efficiency catalyst |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012524786A JP2012524786A (ja) | 2012-10-18 |
| JP2012524786A5 JP2012524786A5 (https=) | 2013-05-30 |
| JP5756087B2 true JP5756087B2 (ja) | 2015-07-29 |
Family
ID=42629694
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2012507297A Active JP5756087B2 (ja) | 2009-04-21 | 2010-04-20 | 高効率触媒による特定のアルキレンオキサイド製造パラメーターを達成かつ維持する改良方法 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US8362284B2 (https=) |
| EP (1) | EP2421841B1 (https=) |
| JP (1) | JP5756087B2 (https=) |
| KR (1) | KR101730667B1 (https=) |
| CN (1) | CN102414188B (https=) |
| CA (1) | CA2759397C (https=) |
| SG (1) | SG175771A1 (https=) |
| TW (1) | TWI481599B (https=) |
| WO (1) | WO2010123844A1 (https=) |
Families Citing this family (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9452209B2 (en) * | 2007-04-20 | 2016-09-27 | Glaxosmithkline Biologicals Sa | Influenza vaccine |
| TWI462912B (zh) * | 2009-04-21 | 2014-12-01 | Dow Technology Investments Llc | 環氧化反應及其操作條件 |
| US8884037B2 (en) | 2010-12-10 | 2014-11-11 | Dow Technology Investments Llc | Method of reducing the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst |
| SG190901A1 (en) | 2010-12-15 | 2013-07-31 | Dow Technology Investments Llc | Method of starting-up a process of producing an alkylene oxide using a high-efficiency catalyst |
| BR112013027585B1 (pt) | 2011-04-29 | 2020-09-29 | Shell Internationale Research Maatschappij B.V | Método para melhorar a seletividade de um catalisador de alta seletividade suportado usado na epoxidação de etileno e método para preparar um 1,2-diol, um 1,2-diol éter, um 1,2-carbonato ou uma alcanolamina |
| IN2014DN03028A (https=) | 2011-10-18 | 2015-05-08 | AHMADI Hassan Eisa AL | |
| CA2858551C (en) * | 2011-12-09 | 2021-10-26 | Dow Technology Investments Llc | Method of maintaining the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst |
| KR102155068B1 (ko) * | 2012-12-31 | 2020-09-11 | 사이언티픽 디자인 컴파니 인코포레이티드 | 고 선택성 산화에틸렌 촉매를 위한 스타트-업 공정 |
| CA2904972C (en) | 2013-03-15 | 2017-10-17 | Dow Technology Investments Llc | Method for the production of ethylene oxide |
| SG11201705409WA (en) * | 2014-12-30 | 2017-07-28 | Dow Technology Investments Llc | Process for manufacturing ethylene oxide using scaled selectivity values |
| WO2019055773A1 (en) * | 2017-09-15 | 2019-03-21 | MultiPhase Solutions, Inc. | GAS PHASE CHROMATOGRAPHY OF SELECTIVE HALOGEN DETECTION FOR ONLINE ANALYSIS AND CONTROL OF SELECTIVE OXIDATION CHEMICAL PRODUCTION PROCESSES |
| CN110673557B (zh) * | 2019-09-27 | 2021-09-24 | 南京大学 | 基于工艺条件选择的智能化工系统 |
| CA3204704A1 (en) | 2020-12-29 | 2022-07-07 | Shell Internationale Research Maatschappij B.V. | Process for the production of ethylene oxide |
| EP4320621A1 (en) * | 2021-04-08 | 2024-02-14 | Shell Internationale Research Maatschappij B.V. | Moderator and catalyst performance optimization for epoxidation of ethylene |
| CA3232520A1 (en) * | 2021-09-23 | 2023-03-30 | Wen -Sheng LEE | Process for reducing the aging-related deactivation of high selectivity ethylene oxide catalysts |
Family Cites Families (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE752859R (fr) | 1969-07-10 | 1971-01-04 | Halcon International Inc | Oxydation controlee de l'oxyde |
| US5387751A (en) * | 1978-02-10 | 1995-02-07 | Imperial Chemical Industries Plc | Production of olefine oxides |
| JPS6110570A (ja) * | 1984-06-25 | 1986-01-18 | Mitsui Toatsu Chem Inc | エチレンオキシドの製造方法 |
| CA1286687C (en) | 1985-08-13 | 1991-07-23 | Michael Paul Habenschuss | Process for manufacture of alkene oxide |
| US4820675A (en) * | 1986-10-31 | 1989-04-11 | Shell Oil Company | Ethylene oxide catalyst & process for preparing the catalyst |
| US4761394A (en) * | 1986-10-31 | 1988-08-02 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
| US4808738A (en) * | 1986-10-31 | 1989-02-28 | Shell Oil Company | Ethylene oxide process |
| US4766105A (en) * | 1986-10-31 | 1988-08-23 | Shell Oil Company | Ethylene oxide catalyst and process for preparing the catalyst |
| IL84232A (en) | 1986-10-31 | 1992-06-21 | Shell Int Research | Catalyst and process for the catalytic production of ethylene oxide |
| GB8626687D0 (en) * | 1986-11-07 | 1986-12-10 | Shell Int Research | Preparing silver catalyst |
| US4908343A (en) * | 1987-02-20 | 1990-03-13 | Union Carbide Chemicals And Plastics Company Inc. | Catalyst composition for oxidation of ethylene to ethylene oxide |
| US4769047A (en) * | 1987-06-29 | 1988-09-06 | Shell Oil Company | Process for the production of ethylene oxide |
| GB8716653D0 (en) * | 1987-07-15 | 1987-08-19 | Shell Int Research | Silver-containing catalyst |
| US4759313A (en) * | 1987-10-30 | 1988-07-26 | Shell Oil Company | Ethylene oxide process improvement |
| CA1339317C (en) | 1988-07-25 | 1997-08-19 | Ann Marie Lauritzen | Process for producing ethylene oxide |
| US4874879A (en) * | 1988-07-25 | 1989-10-17 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
| EP0357292A1 (en) | 1988-08-30 | 1990-03-07 | Imperial Chemical Industries Plc | Production of ethylene oxide and catalysts therefor |
| CA1337722C (en) * | 1989-04-18 | 1995-12-12 | Madan Mohan Bhasin | Alkylene oxide catalysts having enhanced activity and/or stability |
| GB9005964D0 (en) * | 1990-03-16 | 1990-05-09 | Shell Int Research | Catalyst preparation process |
| US5102848A (en) * | 1990-09-28 | 1992-04-07 | Union Carbide Chemicals & Plastics Technology Corporation | Catalyst composition for oxidation of ethylene to ethylene oxide |
| JPH04298241A (ja) | 1990-10-12 | 1992-10-22 | Union Carbide Chem & Plast Co Inc | 向上した安定性を有する超高性能アルキレンオキシド触媒 |
| AU656537B2 (en) | 1990-10-12 | 1995-02-09 | Union Carbide Chemicals & Plastics Technology Corporation | Alkylene oxide catalysts having enhanced activity and/or stability |
| US5145824A (en) * | 1991-01-22 | 1992-09-08 | Shell Oil Company | Ethylene oxide catalyst |
| US5228484A (en) * | 1991-06-20 | 1993-07-20 | Catalyst Technology, Inc. | Air lance reel for catalyst unloading of tubular reactors |
| US5155242A (en) * | 1991-12-05 | 1992-10-13 | Shell Oil Company | Process for starting-up an ethylene oxide reactor |
| US5262551A (en) * | 1992-04-20 | 1993-11-16 | Texaco Chemical Company | Process for ethylene expoxidation |
| US5447897A (en) * | 1993-05-17 | 1995-09-05 | Shell Oil Company | Ethylene oxide catalyst and process |
| US5380697A (en) * | 1993-09-08 | 1995-01-10 | Shell Oil Company | Ethylene oxide catalyst and process |
| US5364826A (en) * | 1993-09-13 | 1994-11-15 | Shell Oil Company | Process for preparing ethylene oxide catalysts |
| TW314512B (https=) * | 1993-09-20 | 1997-09-01 | Shell Int Research | |
| US5418202A (en) * | 1993-12-30 | 1995-05-23 | Shell Oil Company | Ethylene oxide catalyst and process |
| US5545603A (en) * | 1994-11-01 | 1996-08-13 | Shell Oil Company | Ethylene oxide catalyst and process |
| MY120409A (en) * | 1995-04-18 | 2005-10-31 | Shell Int Research | Process for the catalytic vapour phase oxidation of ethylene |
| US5739075A (en) * | 1995-10-06 | 1998-04-14 | Shell Oil Company | Process for preparing ethylene oxide catalysts |
| KR100447357B1 (ko) * | 1995-11-23 | 2004-12-03 | 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 | 알킬렌글리콜의제조방법 |
| US5801259A (en) * | 1996-04-30 | 1998-09-01 | Shell Oil Company | Ethylene oxide catalyst and process |
| US5840932A (en) * | 1996-05-21 | 1998-11-24 | Shell Oil Company | Process for ethylene oxide production |
| WO1997046317A1 (en) * | 1996-06-05 | 1997-12-11 | Shell Internationale Research Maatschappij B.V. | Epoxidation catalyst and process |
| US5770746A (en) * | 1997-06-23 | 1998-06-23 | Arco Chemical Technology, L.P. | Epoxidation process using supported silver catalysts pretreated with organic chloride |
| US7193094B2 (en) | 2001-11-20 | 2007-03-20 | Shell Oil Company | Process and systems for the epoxidation of an olefin |
| CN100358880C (zh) | 2001-11-20 | 2008-01-02 | 国际壳牌研究有限公司 | 烯烃的环氧化方法和系统 |
| WO2004002971A1 (en) | 2002-06-28 | 2004-01-08 | Shell Internationale Research Maatschappij B.V. | A method for the start-up of an epoxidation process, a catalyst and a process for the epoxidation of an olefin |
| DE60333292D1 (de) | 2002-06-28 | 2010-08-19 | Shell Int Research | Verfahren für den start eines epoxierungsprozesses und epoxidierungsverfahren für olefine |
| IN2005DN04374A (https=) * | 2003-04-01 | 2010-01-15 | Shell Int Research | |
| CA2540563C (en) * | 2003-09-29 | 2013-01-08 | Union Carbide Chemicals & Plastics Technology Corporation | A process for the production of alkylene oxide using a gas-phase promoter system |
| US7479565B2 (en) | 2004-06-18 | 2009-01-20 | Shell Oil Company | Process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine |
| US7803957B2 (en) * | 2007-09-11 | 2010-09-28 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Ethylene oxide production using fixed moderator concentration |
| US7553980B2 (en) | 2007-09-26 | 2009-06-30 | Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg | Process for initiating a highly selective ethylene oxide catalyst |
| JP2012524785A (ja) * | 2009-04-21 | 2012-10-18 | ダウ テクノロジー インベストメンツ リミティド ライアビリティー カンパニー | 高効率触媒を用いたアルキレンオキシド簡易製造方法 |
-
2010
- 2010-04-20 CA CA2759397A patent/CA2759397C/en active Active
- 2010-04-20 JP JP2012507297A patent/JP5756087B2/ja active Active
- 2010-04-20 US US12/763,285 patent/US8362284B2/en active Active
- 2010-04-20 SG SG2011077583A patent/SG175771A1/en unknown
- 2010-04-20 WO PCT/US2010/031673 patent/WO2010123844A1/en not_active Ceased
- 2010-04-20 EP EP10732499.8A patent/EP2421841B1/en not_active Revoked
- 2010-04-20 TW TW099112279A patent/TWI481599B/zh active
- 2010-04-20 KR KR1020117027501A patent/KR101730667B1/ko active Active
- 2010-04-20 CN CN201080017748.2A patent/CN102414188B/zh active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CA2759397C (en) | 2019-01-29 |
| TW201105641A (en) | 2011-02-16 |
| US20100267972A1 (en) | 2010-10-21 |
| US8362284B2 (en) | 2013-01-29 |
| KR101730667B1 (ko) | 2017-04-26 |
| EP2421841B1 (en) | 2018-12-26 |
| KR20120014160A (ko) | 2012-02-16 |
| CA2759397A1 (en) | 2010-10-28 |
| TWI481599B (zh) | 2015-04-21 |
| CN102414188A (zh) | 2012-04-11 |
| WO2010123844A1 (en) | 2010-10-28 |
| JP2012524786A (ja) | 2012-10-18 |
| EP2421841A1 (en) | 2012-02-29 |
| CN102414188B (zh) | 2015-05-27 |
| SG175771A1 (en) | 2011-12-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5756087B2 (ja) | 高効率触媒による特定のアルキレンオキサイド製造パラメーターを達成かつ維持する改良方法 | |
| JP6034436B2 (ja) | エポキシ化反応及びその運転条件 | |
| CN102414187B (zh) | 采用催化剂随其老化而制备环氧烷的方法 | |
| TWI510476B (zh) | 以高效能催化劑起始一製造環氧烷烴製程的方法 | |
| US8884037B2 (en) | Method of reducing the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130409 |
|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20130409 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20140805 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20141031 |
|
| A02 | Decision of refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A02 Effective date: 20141209 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150407 |
|
| A911 | Transfer to examiner for re-examination before appeal (zenchi) |
Free format text: JAPANESE INTERMEDIATE CODE: A911 Effective date: 20150414 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20150512 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20150528 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5756087 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |