JP5743327B2 - ポリマー用の圧縮ペレット化添加剤ブレンド - Google Patents
ポリマー用の圧縮ペレット化添加剤ブレンド Download PDFInfo
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- JP5743327B2 JP5743327B2 JP2011540863A JP2011540863A JP5743327B2 JP 5743327 B2 JP5743327 B2 JP 5743327B2 JP 2011540863 A JP2011540863 A JP 2011540863A JP 2011540863 A JP2011540863 A JP 2011540863A JP 5743327 B2 JP5743327 B2 JP 5743327B2
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- PGNYGWRFIFYBKV-UHFFFAOYSA-N [Mg].[Li].[Na] Chemical compound [Mg].[Li].[Na] PGNYGWRFIFYBKV-UHFFFAOYSA-N 0.000 claims 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/33—Heterocyclic compounds
- A61K31/395—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins
- A61K31/435—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins having six-membered rings with one nitrogen as the only ring hetero atom
- A61K31/44—Non condensed pyridines; Hydrogenated derivatives thereof
- A61K31/445—Non condensed piperidines, e.g. piperocaine
- A61K31/4523—Non condensed piperidines, e.g. piperocaine containing further heterocyclic ring systems
- A61K31/454—Non condensed piperidines, e.g. piperocaine containing further heterocyclic ring systems containing a five-membered ring with nitrogen as a ring hetero atom, e.g. pimozide, domperidone
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
- C07D417/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing three or more hetero rings
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
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- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/13—Phenols; Phenolates
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- C—CHEMISTRY; METALLURGY
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/20—Carboxylic acid amides
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- C—CHEMISTRY; METALLURGY
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Epidemiology (AREA)
- Pharmacology & Pharmacy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12224708P | 2008-12-12 | 2008-12-12 | |
| US61/122,247 | 2008-12-12 | ||
| PCT/US2009/067315 WO2010068666A1 (en) | 2008-12-12 | 2009-12-09 | Compacted pelletized additive blends for polymers |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2012512274A JP2012512274A (ja) | 2012-05-31 |
| JP2012512274A5 JP2012512274A5 (OSRAM) | 2013-01-31 |
| JP5743327B2 true JP5743327B2 (ja) | 2015-07-01 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2011540863A Expired - Fee Related JP5743327B2 (ja) | 2008-12-12 | 2009-12-09 | ポリマー用の圧縮ペレット化添加剤ブレンド |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US20100152341A1 (OSRAM) |
| EP (1) | EP2373730B1 (OSRAM) |
| JP (1) | JP5743327B2 (OSRAM) |
| KR (1) | KR20110110167A (OSRAM) |
| CN (1) | CN102272219B (OSRAM) |
| AR (1) | AR075667A1 (OSRAM) |
| BR (1) | BRPI0923369A2 (OSRAM) |
| CA (1) | CA2746419C (OSRAM) |
| ES (1) | ES2416486T3 (OSRAM) |
| MX (1) | MX2011006175A (OSRAM) |
| PL (1) | PL2373730T3 (OSRAM) |
| SG (1) | SG172111A1 (OSRAM) |
| WO (1) | WO2010068666A1 (OSRAM) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| ES2383549T3 (es) | 2006-09-14 | 2012-06-22 | Ingenia Polymers Inc. | Procedimiento de preparación de concentrados de aditivos en granza de alta concentración para polímero |
| US20100152341A1 (en) * | 2008-12-12 | 2010-06-17 | Ingenia Polymers Inc. | Compacted pelletized additive blends for polymers |
| EP2840112B1 (en) * | 2013-08-21 | 2019-04-10 | Baerlocher GmbH | Stabilized polymer compositions and methods of making same |
| WO2015010957A1 (en) * | 2013-07-22 | 2015-01-29 | Ineos Europe Ag | Method of cleaning a heat exchanger |
| US9630349B2 (en) | 2013-08-26 | 2017-04-25 | Ingenia Polymers, Inc. | Compacted pelletized additive blends containing a polymer carrier |
| CN103819949B (zh) * | 2014-03-13 | 2015-04-29 | 福建师范大学 | 一种无机粉体的表面改性方法 |
| KR101595094B1 (ko) * | 2014-12-18 | 2016-02-18 | 한국화학연구원 | 비철금속 포장용 변색방지 필름 조성물 |
| CN105367924B (zh) * | 2015-12-07 | 2018-08-10 | 中国石油天然气股份有限公司 | 一种颗粒化塑料添加剂及其制备方法与应用 |
| CN105504434A (zh) * | 2015-12-15 | 2016-04-20 | 中冠电缆有限公司 | 一种高韧性耐火复合丁苯橡胶电缆料及其制备方法 |
| EP3249004A1 (en) * | 2016-05-24 | 2017-11-29 | Clariant International Ltd | Release components to increase anti-adhesion properties of thermoplastic packaging material |
| CN113121851A (zh) * | 2019-12-31 | 2021-07-16 | 中国石油天然气股份有限公司 | 无载体型母粒组合物及无载体型母粒的制备方法 |
| CN115819238A (zh) * | 2020-03-26 | 2023-03-21 | 优禘股份有限公司 | 一种低迁移受阻酚抗氧化合物、制备方法及组合物 |
Family Cites Families (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3461081A (en) * | 1964-07-17 | 1969-08-12 | Mizusawa Industrial Chem | Stabilizing agent for a halogen containing synthetic resin consisting of a basic inorganic acid salt of lead coated with a fatty acid soap of lead,cadmium or calcium |
| US4080134A (en) | 1975-09-23 | 1978-03-21 | Mobil Oil Corporation | Apparatus for pelletizing plastic material |
| CA1116183A (en) * | 1979-03-29 | 1982-01-12 | John Blachford | Manufacture of metallic soaps |
| US4617060A (en) * | 1984-04-23 | 1986-10-14 | Mallinckrodt, Inc. | Silica catalyst supports |
| JPS62201954A (ja) * | 1986-03-03 | 1987-09-05 | Mitsubishi Gas Chem Co Inc | 強化ポリオレフイン樹脂組成物． |
| GB8621094D0 (en) * | 1986-09-01 | 1986-10-08 | Ici Plc | Loading of polymer additives |
| US5176751A (en) * | 1991-03-01 | 1993-01-05 | Thermocolor Corporation | Pellets useful in production of plastic resin materials |
| JP3241746B2 (ja) * | 1991-04-04 | 2001-12-25 | 三井化学株式会社 | タルク入りポリプロピレン樹脂組成物の製造方法 |
| IT1247941B (it) * | 1991-05-17 | 1995-01-05 | Enichem Sintesi | Processo per l'ottenimento di forme granulari di additivi per polimeri organici |
| US5844042A (en) | 1993-04-06 | 1998-12-01 | Great Lakes Chemical Italia S.R.L. | Process for obtaining granular forms of additives for organic polymers |
| US5997768A (en) * | 1993-06-29 | 1999-12-07 | Ciba Specialty Chemicals Corporation | Pelletization of metal soap powders |
| US6033600A (en) * | 1994-10-07 | 2000-03-07 | General Electric Company | Reduced dust stabilizer blends compact and a method for making thereof |
| US5597857A (en) * | 1994-12-28 | 1997-01-28 | Ciba-Geigy Corporation | Low-dust granules of plastic additives |
| AR003526A1 (es) * | 1995-09-08 | 1998-08-05 | Mallinckrodt Chemical Inc | Sistema estabilizador para estabilizar materiales polimeros y metodo para producir un sistema estabilizado en forma de pellets. |
| JPH09324073A (ja) * | 1996-06-04 | 1997-12-16 | Asahi Chem Ind Co Ltd | 粒状難燃剤組成物、及び難燃性熱可塑性樹脂組成物 |
| US5686513A (en) * | 1996-09-09 | 1997-11-11 | Zimmer Aktiengesellschaft | Process for the production of stabilizer concentrate for polyamide |
| BR9808874B1 (pt) * | 1997-04-15 | 2010-07-13 | processo para a preparação de um estabilizador com formação de pó reduzida. | |
| DE19817257A1 (de) * | 1998-04-19 | 1999-12-09 | Grace Gmbh | Granulatzusammensetzung aus Antiblockingmitteln und Additiven für Polymerherstellung |
| US6821456B2 (en) * | 1998-09-22 | 2004-11-23 | Albemarle Corporation | Granular polymer additives and their preparation |
| US6800228B1 (en) | 1998-09-22 | 2004-10-05 | Albemarle Corporation | Sterically hindered phenol antioxidant granules having balanced hardness |
| US6596198B1 (en) * | 2000-04-28 | 2003-07-22 | Albemarle Corporation | Additive system for polymers in pellet form which provides proportioned stabilization and internal mold release characteristics |
| US6515052B2 (en) * | 2001-02-23 | 2003-02-04 | Albemarle Corporation | Granular polymer additives and their preparation |
| SG147408A1 (en) * | 2003-10-01 | 2008-11-28 | Ciba Holding Inc | Additive mixtures |
| JP2005104794A (ja) * | 2003-10-01 | 2005-04-21 | Mitsui Chemicals Inc | タルク |
| JP2008534759A (ja) * | 2005-04-05 | 2008-08-28 | チバ スペシャルティ ケミカルズ エス．ピー．エイ． | 農業用品のための添加剤混合物 |
| KR20070046728A (ko) * | 2005-10-31 | 2007-05-03 | 스미또모 가가꾸 가부시끼가이샤 | 과립 물질 |
| JP4867593B2 (ja) * | 2006-11-10 | 2012-02-01 | 住友化学株式会社 | 亜リン酸エステル組成物及びその製造方法 |
| US7789957B2 (en) * | 2007-06-06 | 2010-09-07 | Ciba Corporation | Low-dust additive and pigment blends with improved color |
| US20100152341A1 (en) * | 2008-12-12 | 2010-06-17 | Ingenia Polymers Inc. | Compacted pelletized additive blends for polymers |
-
2009
- 2009-12-09 US US12/633,959 patent/US20100152341A1/en not_active Abandoned
- 2009-12-09 CN CN200980154450.3A patent/CN102272219B/zh not_active Expired - Fee Related
- 2009-12-09 JP JP2011540863A patent/JP5743327B2/ja not_active Expired - Fee Related
- 2009-12-09 EP EP09768306.4A patent/EP2373730B1/en not_active Revoked
- 2009-12-09 ES ES09768306T patent/ES2416486T3/es active Active
- 2009-12-09 PL PL09768306T patent/PL2373730T3/pl unknown
- 2009-12-09 MX MX2011006175A patent/MX2011006175A/es unknown
- 2009-12-09 WO PCT/US2009/067315 patent/WO2010068666A1/en not_active Ceased
- 2009-12-09 SG SG2011042926A patent/SG172111A1/en unknown
- 2009-12-09 BR BRPI0923369-5A patent/BRPI0923369A2/pt not_active Application Discontinuation
- 2009-12-09 KR KR1020117016083A patent/KR20110110167A/ko not_active Ceased
- 2009-12-09 CA CA2746419A patent/CA2746419C/en not_active Expired - Fee Related
- 2009-12-11 AR ARP090104809A patent/AR075667A1/es not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| CA2746419A1 (en) | 2010-06-17 |
| CN102272219B (zh) | 2016-05-04 |
| US20100152341A1 (en) | 2010-06-17 |
| PL2373730T3 (pl) | 2013-09-30 |
| BRPI0923369A2 (pt) | 2020-08-11 |
| EP2373730A1 (en) | 2011-10-12 |
| KR20110110167A (ko) | 2011-10-06 |
| AR075667A1 (es) | 2011-04-20 |
| SG172111A1 (en) | 2011-07-28 |
| CN102272219A (zh) | 2011-12-07 |
| EP2373730B1 (en) | 2013-05-08 |
| ES2416486T3 (es) | 2013-08-01 |
| JP2012512274A (ja) | 2012-05-31 |
| WO2010068666A1 (en) | 2010-06-17 |
| MX2011006175A (es) | 2011-09-27 |
| CA2746419C (en) | 2017-03-14 |
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