CA2746419C - Compacted pelletized additive blends for polymers - Google Patents
Compacted pelletized additive blends for polymers Download PDFInfo
- Publication number
- CA2746419C CA2746419C CA2746419A CA2746419A CA2746419C CA 2746419 C CA2746419 C CA 2746419C CA 2746419 A CA2746419 A CA 2746419A CA 2746419 A CA2746419 A CA 2746419A CA 2746419 C CA2746419 C CA 2746419C
- Authority
- CA
- Canada
- Prior art keywords
- additive
- additive blend
- blend
- silicates
- mixtures
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000654 additive Substances 0.000 title claims abstract description 284
- 239000000203 mixture Substances 0.000 title claims abstract description 242
- 230000000996 additive effect Effects 0.000 title claims abstract description 186
- 229920000642 polymer Polymers 0.000 title claims abstract description 69
- 238000005056 compaction Methods 0.000 claims abstract description 81
- 238000002844 melting Methods 0.000 claims abstract description 72
- 230000008018 melting Effects 0.000 claims abstract description 66
- 238000000034 method Methods 0.000 claims abstract description 48
- 150000004760 silicates Chemical class 0.000 claims abstract description 14
- 239000002952 polymeric resin Substances 0.000 claims abstract description 13
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims description 36
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 32
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 29
- 239000010445 mica Substances 0.000 claims description 21
- 229910052618 mica group Inorganic materials 0.000 claims description 21
- 229940075507 glyceryl monostearate Drugs 0.000 claims description 18
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 claims description 18
- 229910052628 phlogopite Inorganic materials 0.000 claims description 18
- 239000003963 antioxidant agent Substances 0.000 claims description 17
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 16
- 239000004408 titanium dioxide Substances 0.000 claims description 16
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 14
- QYFRTHZXAGSYGT-UHFFFAOYSA-L hexaaluminum dipotassium dioxosilane oxygen(2-) difluoride hydrate Chemical compound O.[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[O--].[F-].[F-].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O QYFRTHZXAGSYGT-UHFFFAOYSA-L 0.000 claims description 14
- -1 sorbitol acetals Chemical class 0.000 claims description 14
- UAUDZVJPLUQNMU-UHFFFAOYSA-N Erucasaeureamid Natural products CCCCCCCCC=CCCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-UHFFFAOYSA-N 0.000 claims description 13
- UAUDZVJPLUQNMU-KTKRTIGZSA-N erucamide Chemical compound CCCCCCCC\C=C/CCCCCCCCCCCC(N)=O UAUDZVJPLUQNMU-KTKRTIGZSA-N 0.000 claims description 13
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 12
- 229920005601 base polymer Polymers 0.000 claims description 12
- 239000000377 silicon dioxide Substances 0.000 claims description 12
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 11
- 239000002530 phenolic antioxidant Substances 0.000 claims description 11
- 238000012545 processing Methods 0.000 claims description 11
- 239000003381 stabilizer Substances 0.000 claims description 11
- 150000001412 amines Chemical class 0.000 claims description 10
- 230000003078 antioxidant effect Effects 0.000 claims description 9
- 239000006096 absorbing agent Substances 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 8
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical class [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims description 8
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 8
- 239000007788 liquid Substances 0.000 claims description 8
- SWHAQEYMVUEVNF-UHFFFAOYSA-N magnesium potassium Chemical compound [Mg].[K] SWHAQEYMVUEVNF-UHFFFAOYSA-N 0.000 claims description 8
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 8
- XRBCRPZXSCBRTK-UHFFFAOYSA-N phosphonous acid Chemical class OPO XRBCRPZXSCBRTK-UHFFFAOYSA-N 0.000 claims description 8
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 8
- 235000010234 sodium benzoate Nutrition 0.000 claims description 8
- 239000004299 sodium benzoate Substances 0.000 claims description 8
- 239000011787 zinc oxide Substances 0.000 claims description 8
- 239000002216 antistatic agent Substances 0.000 claims description 7
- 150000001565 benzotriazoles Chemical class 0.000 claims description 7
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 7
- 239000002667 nucleating agent Substances 0.000 claims description 7
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 7
- FATBGEAMYMYZAF-KTKRTIGZSA-N oleamide Chemical compound CCCCCCCC\C=C/CCCCCCCC(N)=O FATBGEAMYMYZAF-KTKRTIGZSA-N 0.000 claims description 7
- FATBGEAMYMYZAF-UHFFFAOYSA-N oleicacidamide-heptaglycolether Natural products CCCCCCCCC=CCCCCCCCC(N)=O FATBGEAMYMYZAF-UHFFFAOYSA-N 0.000 claims description 7
- 239000012748 slip agent Substances 0.000 claims description 7
- 150000003918 triazines Chemical class 0.000 claims description 7
- 239000012965 benzophenone Substances 0.000 claims description 6
- 150000008366 benzophenones Chemical class 0.000 claims description 6
- 239000004611 light stabiliser Substances 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 239000006078 metal deactivator Substances 0.000 claims description 5
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 claims description 5
- YGSDEFSMJLZEOE-UHFFFAOYSA-N salicylic acid Chemical class OC(=O)C1=CC=CC=C1O YGSDEFSMJLZEOE-UHFFFAOYSA-N 0.000 claims description 5
- IDZYHGDLWGVHQM-UHFFFAOYSA-N aluminum;calcium;sodium;silicate Chemical compound [Na+].[Al+3].[Ca+2].[O-][Si]([O-])([O-])[O-] IDZYHGDLWGVHQM-UHFFFAOYSA-N 0.000 claims description 4
- 239000000314 lubricant Substances 0.000 claims description 4
- 239000006082 mold release agent Substances 0.000 claims description 4
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 4
- ORAWFNKFUWGRJG-UHFFFAOYSA-N Docosanamide Chemical compound CCCCCCCCCCCCCCCCCCCCCC(N)=O ORAWFNKFUWGRJG-UHFFFAOYSA-N 0.000 claims description 3
- MLPUICDXVRINHD-UHFFFAOYSA-N [Li+].[Na+].[Mg+2].[O-][Si]([O-])([O-])F Chemical compound [Li+].[Na+].[Mg+2].[O-][Si]([O-])([O-])F MLPUICDXVRINHD-UHFFFAOYSA-N 0.000 claims description 3
- PGNYGWRFIFYBKV-UHFFFAOYSA-N [Mg].[Li].[Na] Chemical compound [Mg].[Li].[Na] PGNYGWRFIFYBKV-UHFFFAOYSA-N 0.000 claims description 3
- SNAAJJQQZSMGQD-UHFFFAOYSA-N aluminum magnesium Chemical compound [Mg].[Al] SNAAJJQQZSMGQD-UHFFFAOYSA-N 0.000 claims description 3
- 235000012241 calcium silicate Nutrition 0.000 claims description 3
- 229920001577 copolymer Polymers 0.000 claims description 3
- FLWCIIGMVIPYOY-UHFFFAOYSA-N fluoro(trihydroxy)silane Chemical compound O[Si](O)(O)F FLWCIIGMVIPYOY-UHFFFAOYSA-N 0.000 claims description 3
- 229940104869 fluorosilicate Drugs 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000012802 nanoclay Substances 0.000 claims description 3
- BITYAPCSNKJESK-UHFFFAOYSA-N potassiosodium Chemical compound [Na].[K] BITYAPCSNKJESK-UHFFFAOYSA-N 0.000 claims description 3
- 150000003242 quaternary ammonium salts Chemical class 0.000 claims description 3
- 229920000089 Cyclic olefin copolymer Polymers 0.000 claims description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 2
- 229910000503 Na-aluminosilicate Inorganic materials 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims description 2
- 239000004698 Polyethylene Substances 0.000 claims description 2
- 239000004793 Polystyrene Substances 0.000 claims description 2
- VEUACKUBDLVUAC-UHFFFAOYSA-N [Na].[Ca] Chemical compound [Na].[Ca] VEUACKUBDLVUAC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052782 aluminium Inorganic materials 0.000 claims description 2
- 235000012215 calcium aluminium silicate Nutrition 0.000 claims description 2
- 239000003063 flame retardant Substances 0.000 claims description 2
- 239000000391 magnesium silicate Substances 0.000 claims description 2
- 235000012243 magnesium silicates Nutrition 0.000 claims description 2
- 235000021317 phosphate Nutrition 0.000 claims description 2
- 229920001200 poly(ethylene-vinyl acetate) Polymers 0.000 claims description 2
- 229920001748 polybutylene Polymers 0.000 claims description 2
- 229920000573 polyethylene Polymers 0.000 claims description 2
- 229920002223 polystyrene Polymers 0.000 claims description 2
- DXGIRFAFSFKYCF-UHFFFAOYSA-N propanehydrazide Chemical class CCC(=O)NN DXGIRFAFSFKYCF-UHFFFAOYSA-N 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- KYKFCSHPTAVNJD-UHFFFAOYSA-L sodium adipate Chemical compound [Na+].[Na+].[O-]C(=O)CCCCC([O-])=O KYKFCSHPTAVNJD-UHFFFAOYSA-L 0.000 claims description 2
- 239000001601 sodium adipate Substances 0.000 claims description 2
- 235000011049 sodium adipate Nutrition 0.000 claims description 2
- 235000012217 sodium aluminium silicate Nutrition 0.000 claims description 2
- 239000000600 sorbitol Substances 0.000 claims description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 2
- 239000004711 α-olefin Substances 0.000 claims description 2
- 239000013036 UV Light Stabilizer Substances 0.000 claims 3
- 229920000219 Ethylene vinyl alcohol Polymers 0.000 claims 1
- 239000008188 pellet Substances 0.000 abstract description 93
- 230000008569 process Effects 0.000 abstract description 29
- 230000001617 migratory effect Effects 0.000 abstract description 6
- 238000006116 polymerization reaction Methods 0.000 abstract description 6
- 230000006641 stabilisation Effects 0.000 abstract description 3
- 238000011105 stabilization Methods 0.000 abstract description 3
- 230000002939 deleterious effect Effects 0.000 abstract description 2
- 239000000843 powder Substances 0.000 description 36
- 239000002245 particle Substances 0.000 description 27
- 230000000052 comparative effect Effects 0.000 description 25
- 238000009472 formulation Methods 0.000 description 21
- 238000002156 mixing Methods 0.000 description 18
- 239000007787 solid Substances 0.000 description 18
- 238000012360 testing method Methods 0.000 description 11
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 10
- 239000011230 binding agent Substances 0.000 description 10
- 238000001125 extrusion Methods 0.000 description 9
- 239000000454 talc Substances 0.000 description 9
- 229910052623 talc Inorganic materials 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 8
- 239000002904 solvent Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 8
- 230000008859 change Effects 0.000 description 7
- 239000008187 granular material Substances 0.000 description 7
- 239000000428 dust Substances 0.000 description 6
- 230000006872 improvement Effects 0.000 description 6
- 229910052500 inorganic mineral Inorganic materials 0.000 description 6
- 239000011707 mineral Substances 0.000 description 6
- 238000005453 pelletization Methods 0.000 description 6
- 235000013539 calcium stearate Nutrition 0.000 description 5
- 239000008116 calcium stearate Substances 0.000 description 5
- 238000000113 differential scanning calorimetry Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000000155 melt Substances 0.000 description 5
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 description 4
- 229910001701 hydrotalcite Inorganic materials 0.000 description 4
- 229960001545 hydrotalcite Drugs 0.000 description 4
- 125000001841 imino group Chemical group [H]N=* 0.000 description 4
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 4
- 239000010456 wollastonite Substances 0.000 description 4
- 229910052882 wollastonite Inorganic materials 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000004927 clay Substances 0.000 description 3
- 238000007906 compression Methods 0.000 description 3
- 230000006835 compression Effects 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000945 filler Substances 0.000 description 3
- 230000009477 glass transition Effects 0.000 description 3
- 230000001965 increasing effect Effects 0.000 description 3
- 229910052914 metal silicate Inorganic materials 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- SSDSCDGVMJFTEQ-UHFFFAOYSA-N octadecyl 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 SSDSCDGVMJFTEQ-UHFFFAOYSA-N 0.000 description 3
- 150000002989 phenols Chemical class 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920000098 polyolefin Polymers 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004594 Masterbatch (MB) Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011248 coating agent Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- YGANSGVIUGARFR-UHFFFAOYSA-N dipotassium dioxosilane oxo(oxoalumanyloxy)alumane oxygen(2-) Chemical compound [O--].[K+].[K+].O=[Si]=O.O=[Al]O[Al]=O YGANSGVIUGARFR-UHFFFAOYSA-N 0.000 description 2
- 238000010410 dusting Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexane-1,6-diamine Chemical compound NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 2
- 239000010423 industrial mineral Substances 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229940094522 laponite Drugs 0.000 description 2
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- HQKMJHAJHXVSDF-UHFFFAOYSA-L magnesium stearate Chemical compound [Mg+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O HQKMJHAJHXVSDF-UHFFFAOYSA-L 0.000 description 2
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 2
- 238000003801 milling Methods 0.000 description 2
- 229910052627 muscovite Inorganic materials 0.000 description 2
- 229920000620 organic polymer Polymers 0.000 description 2
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 description 2
- 230000009467 reduction Effects 0.000 description 2
- 239000000523 sample Substances 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 229910002029 synthetic silica gel Inorganic materials 0.000 description 2
- 238000005303 weighing Methods 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 2
- YWEWWNPYDDHZDI-JJKKTNRVSA-N (1r)-1-[(4r,4ar,8as)-2,6-bis(3,4-dimethylphenyl)-4,4a,8,8a-tetrahydro-[1,3]dioxino[5,4-d][1,3]dioxin-4-yl]ethane-1,2-diol Chemical compound C1=C(C)C(C)=CC=C1C1O[C@H]2[C@@H]([C@H](O)CO)OC(C=3C=C(C)C(C)=CC=3)O[C@H]2CO1 YWEWWNPYDDHZDI-JJKKTNRVSA-N 0.000 description 1
- KJYSXRBJOSZLEL-UHFFFAOYSA-N (2,4-ditert-butylphenyl) 3,5-ditert-butyl-4-hydroxybenzoate Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OC(=O)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 KJYSXRBJOSZLEL-UHFFFAOYSA-N 0.000 description 1
- DKBCURTUXYMRFB-LXTVHRRPSA-N (2r,3r,4s,5r)-7-(3,4-dimethylphenyl)hept-6-ene-1,2,3,4,5,6-hexol Chemical compound CC1=CC=C(C=C(O)[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO)C=C1C DKBCURTUXYMRFB-LXTVHRRPSA-N 0.000 description 1
- ABFCPWCUXLLRSC-UHFFFAOYSA-N 1,1-bis(2,4-ditert-butylphenyl)-2,2-bis(hydroxymethyl)propane-1,3-diol Chemical compound C(C)(C)(C)C1=C(C=CC(=C1)C(C)(C)C)C(O)(C(CO)(CO)CO)C1=C(C=C(C=C1)C(C)(C)C)C(C)(C)C ABFCPWCUXLLRSC-UHFFFAOYSA-N 0.000 description 1
- GXURZKWLMYOCDX-UHFFFAOYSA-N 2,2-bis(hydroxymethyl)propane-1,3-diol;dihydroxyphosphanyl dihydrogen phosphite Chemical compound OP(O)OP(O)O.OCC(CO)(CO)CO GXURZKWLMYOCDX-UHFFFAOYSA-N 0.000 description 1
- PFEFOYRSMXVNEL-UHFFFAOYSA-N 2,4,6-tritert-butylphenol Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 PFEFOYRSMXVNEL-UHFFFAOYSA-N 0.000 description 1
- ICKWICRCANNIBI-UHFFFAOYSA-N 2,4-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=C(O)C(C(C)(C)C)=C1 ICKWICRCANNIBI-UHFFFAOYSA-N 0.000 description 1
- RDDIIAYGQFICIL-UHFFFAOYSA-N 2-[4-(5,7-ditert-butyl-2-oxo-3h-1-benzofuran-3-yl)phenoxy]ethyl acetate Chemical compound C1=CC(OCCOC(=O)C)=CC=C1C1C(C=C(C=C2C(C)(C)C)C(C)(C)C)=C2OC1=O RDDIIAYGQFICIL-UHFFFAOYSA-N 0.000 description 1
- ZJYVOSGUICQZHC-UHFFFAOYSA-N 2-butyl-2-ethyl-1-(2,4,6-tritert-butylphenyl)propane-1,3-diol;phosphorous acid Chemical compound OP(O)O.CCCCC(CC)(CO)C(O)C1=C(C(C)(C)C)C=C(C(C)(C)C)C=C1C(C)(C)C ZJYVOSGUICQZHC-UHFFFAOYSA-N 0.000 description 1
- ACZGCWSMSTYWDQ-UHFFFAOYSA-N 3h-1-benzofuran-2-one Chemical class C1=CC=C2OC(=O)CC2=C1 ACZGCWSMSTYWDQ-UHFFFAOYSA-N 0.000 description 1
- MDWVSAYEQPLWMX-UHFFFAOYSA-N 4,4'-Methylenebis(2,6-di-tert-butylphenol) Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 MDWVSAYEQPLWMX-UHFFFAOYSA-N 0.000 description 1
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- JKIJEFPNVSHHEI-UHFFFAOYSA-N Phenol, 2,4-bis(1,1-dimethylethyl)-, phosphite (3:1) Chemical compound CC(C)(C)C1=CC(C(C)(C)C)=CC=C1OP(OC=1C(=CC(=CC=1)C(C)(C)C)C(C)(C)C)OC1=CC=C(C(C)(C)C)C=C1C(C)(C)C JKIJEFPNVSHHEI-UHFFFAOYSA-N 0.000 description 1
- 241001647090 Ponca Species 0.000 description 1
- XBDQKXXYIPTUBI-UHFFFAOYSA-M Propionate Chemical compound CCC([O-])=O XBDQKXXYIPTUBI-UHFFFAOYSA-M 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
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- 241000364021 Tulsa Species 0.000 description 1
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- DNEHKUCSURWDGO-UHFFFAOYSA-N aluminum sodium Chemical compound [Na].[Al] DNEHKUCSURWDGO-UHFFFAOYSA-N 0.000 description 1
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- OYACROKNLOSFPA-UHFFFAOYSA-N calcium;dioxido(oxo)silane Chemical compound [Ca+2].[O-][Si]([O-])=O OYACROKNLOSFPA-UHFFFAOYSA-N 0.000 description 1
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- MGNCLNQXLYJVJD-UHFFFAOYSA-N cyanuric chloride Chemical compound ClC1=NC(Cl)=NC(Cl)=N1 MGNCLNQXLYJVJD-UHFFFAOYSA-N 0.000 description 1
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- UREBDLICKHMUKA-CXSFZGCWSA-N dexamethasone Chemical compound C1CC2=CC(=O)C=C[C@]2(C)[C@]2(F)[C@@H]1[C@@H]1C[C@@H](C)[C@@](C(=O)CO)(O)[C@@]1(C)C[C@@H]2O UREBDLICKHMUKA-CXSFZGCWSA-N 0.000 description 1
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 150000002193 fatty amides Chemical class 0.000 description 1
- 239000013020 final formulation Substances 0.000 description 1
- 238000013038 hand mixing Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
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- 235000019359 magnesium stearate Nutrition 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- FRVPQJVZFCJNCO-UHFFFAOYSA-N morpholine;2,4,6-trichloro-1,3,5-triazine Chemical compound C1COCCN1.ClC1=NC(Cl)=NC(Cl)=N1 FRVPQJVZFCJNCO-UHFFFAOYSA-N 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 238000011017 operating method Methods 0.000 description 1
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- 235000010603 pastilles Nutrition 0.000 description 1
- 229940059574 pentaerithrityl Drugs 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 239000004597 plastic additive Substances 0.000 description 1
- 229920006254 polymer film Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 125000001501 propionyl group Chemical group O=C([*])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 239000010499 rapseed oil Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 229920006126 semicrystalline polymer Polymers 0.000 description 1
- 238000007873 sieving Methods 0.000 description 1
- ZHROMWXOTYBIMF-UHFFFAOYSA-M sodium;1,3,7,9-tetratert-butyl-11-oxido-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [Na+].C1C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP([O-])(=O)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C ZHROMWXOTYBIMF-UHFFFAOYSA-M 0.000 description 1
- BPILDHPJSYVNAF-UHFFFAOYSA-M sodium;diiodomethanesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C(I)I BPILDHPJSYVNAF-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000012453 solvate Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 125000000547 substituted alkyl group Chemical group 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K31/00—Medicinal preparations containing organic active ingredients
- A61K31/33—Heterocyclic compounds
- A61K31/395—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins
- A61K31/435—Heterocyclic compounds having nitrogen as a ring hetero atom, e.g. guanethidine or rifamycins having six-membered rings with one nitrogen as the only ring hetero atom
- A61K31/44—Non condensed pyridines; Hydrogenated derivatives thereof
- A61K31/445—Non condensed piperidines, e.g. piperocaine
- A61K31/4523—Non condensed piperidines, e.g. piperocaine containing further heterocyclic ring systems
- A61K31/454—Non condensed piperidines, e.g. piperocaine containing further heterocyclic ring systems containing a five-membered ring with nitrogen as a ring hetero atom, e.g. pimozide, domperidone
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D417/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00
- C07D417/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing three or more hetero rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/346—Clay
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/005—Stabilisers against oxidation, heat, light, ozone
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
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- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
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- C08K5/10—Esters; Ether-esters
- C08K5/101—Esters; Ether-esters of monocarboxylic acids
- C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- C08K5/13—Phenols; Phenolates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/20—Carboxylic acid amides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K9/00—Use of pretreated ingredients
- C08K9/04—Ingredients treated with organic substances
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L101/00—Compositions of unspecified macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Polymers & Plastics (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Pharmacology & Pharmacy (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Polymerisation Methods In General (AREA)
- Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
Applications Claiming Priority (3)
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| US12224708P | 2008-12-12 | 2008-12-12 | |
| US61/122,247 | 2008-12-12 | ||
| PCT/US2009/067315 WO2010068666A1 (en) | 2008-12-12 | 2009-12-09 | Compacted pelletized additive blends for polymers |
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| CA2746419A1 CA2746419A1 (en) | 2010-06-17 |
| CA2746419C true CA2746419C (en) | 2017-03-14 |
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| CA2746419A Expired - Fee Related CA2746419C (en) | 2008-12-12 | 2009-12-09 | Compacted pelletized additive blends for polymers |
Country Status (13)
| Country | Link |
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| US (1) | US20100152341A1 (OSRAM) |
| EP (1) | EP2373730B1 (OSRAM) |
| JP (1) | JP5743327B2 (OSRAM) |
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| CA (1) | CA2746419C (OSRAM) |
| ES (1) | ES2416486T3 (OSRAM) |
| MX (1) | MX2011006175A (OSRAM) |
| PL (1) | PL2373730T3 (OSRAM) |
| SG (1) | SG172111A1 (OSRAM) |
| WO (1) | WO2010068666A1 (OSRAM) |
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| EP2061831B1 (en) | 2006-09-14 | 2012-03-28 | Ingenia Polymers Inc. | A method for preparing high concentration pelletized additive concentrates for polymer |
| CN102272219B (zh) * | 2008-12-12 | 2016-05-04 | 英吉尼亚聚合物有限公司 | 用于聚合物的压实丸化添加剂共混物 |
| EP2840112B1 (en) * | 2013-08-21 | 2019-04-10 | Baerlocher GmbH | Stabilized polymer compositions and methods of making same |
| EP3025114B1 (en) * | 2013-07-22 | 2018-05-16 | Ineos Europe AG | Method of cleaning a heat exchanger |
| US9630349B2 (en) | 2013-08-26 | 2017-04-25 | Ingenia Polymers, Inc. | Compacted pelletized additive blends containing a polymer carrier |
| CN103819949B (zh) * | 2014-03-13 | 2015-04-29 | 福建师范大学 | 一种无机粉体的表面改性方法 |
| KR101595094B1 (ko) * | 2014-12-18 | 2016-02-18 | 한국화학연구원 | 비철금속 포장용 변색방지 필름 조성물 |
| CN105367924B (zh) * | 2015-12-07 | 2018-08-10 | 中国石油天然气股份有限公司 | 一种颗粒化塑料添加剂及其制备方法与应用 |
| CN105504434A (zh) * | 2015-12-15 | 2016-04-20 | 中冠电缆有限公司 | 一种高韧性耐火复合丁苯橡胶电缆料及其制备方法 |
| EP3249004A1 (en) * | 2016-05-24 | 2017-11-29 | Clariant International Ltd | Release components to increase anti-adhesion properties of thermoplastic packaging material |
| CN113121851A (zh) * | 2019-12-31 | 2021-07-16 | 中国石油天然气股份有限公司 | 无载体型母粒组合物及无载体型母粒的制备方法 |
| CN115819238A (zh) * | 2020-03-26 | 2023-03-21 | 优禘股份有限公司 | 一种低迁移受阻酚抗氧化合物、制备方法及组合物 |
| JP2024510891A (ja) * | 2021-02-25 | 2024-03-12 | ビーエーエスエフ ソシエタス・ヨーロピア | ポリマー安定剤混合物のペレット化 |
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| US3461081A (en) * | 1964-07-17 | 1969-08-12 | Mizusawa Industrial Chem | Stabilizing agent for a halogen containing synthetic resin consisting of a basic inorganic acid salt of lead coated with a fatty acid soap of lead,cadmium or calcium |
| US4080134A (en) * | 1975-09-23 | 1978-03-21 | Mobil Oil Corporation | Apparatus for pelletizing plastic material |
| CA1116183A (en) * | 1979-03-29 | 1982-01-12 | John Blachford | Manufacture of metallic soaps |
| US4617060A (en) * | 1984-04-23 | 1986-10-14 | Mallinckrodt, Inc. | Silica catalyst supports |
| JPS62201954A (ja) * | 1986-03-03 | 1987-09-05 | Mitsubishi Gas Chem Co Inc | 強化ポリオレフイン樹脂組成物． |
| GB8621094D0 (en) * | 1986-09-01 | 1986-10-08 | Ici Plc | Loading of polymer additives |
| US5176751A (en) * | 1991-03-01 | 1993-01-05 | Thermocolor Corporation | Pellets useful in production of plastic resin materials |
| JP3241746B2 (ja) * | 1991-04-04 | 2001-12-25 | 三井化学株式会社 | タルク入りポリプロピレン樹脂組成物の製造方法 |
| IT1247941B (it) * | 1991-05-17 | 1995-01-05 | Enichem Sintesi | Processo per l'ottenimento di forme granulari di additivi per polimeri organici |
| US5844042A (en) * | 1993-04-06 | 1998-12-01 | Great Lakes Chemical Italia S.R.L. | Process for obtaining granular forms of additives for organic polymers |
| US5997768A (en) * | 1993-06-29 | 1999-12-07 | Ciba Specialty Chemicals Corporation | Pelletization of metal soap powders |
| US6033600A (en) | 1994-10-07 | 2000-03-07 | General Electric Company | Reduced dust stabilizer blends compact and a method for making thereof |
| US5597857A (en) * | 1994-12-28 | 1997-01-28 | Ciba-Geigy Corporation | Low-dust granules of plastic additives |
| AR003526A1 (es) * | 1995-09-08 | 1998-08-05 | Mallinckrodt Chemical Inc | Sistema estabilizador para estabilizar materiales polimeros y metodo para producir un sistema estabilizado en forma de pellets. |
| JPH09324073A (ja) * | 1996-06-04 | 1997-12-16 | Asahi Chem Ind Co Ltd | 粒状難燃剤組成物、及び難燃性熱可塑性樹脂組成物 |
| US5686513A (en) * | 1996-09-09 | 1997-11-11 | Zimmer Aktiengesellschaft | Process for the production of stabilizer concentrate for polyamide |
| EP0975421B1 (en) * | 1997-04-15 | 2014-06-18 | Basf Se | Preparation of low-dust stabilisers |
| DE19817257A1 (de) * | 1998-04-19 | 1999-12-09 | Grace Gmbh | Granulatzusammensetzung aus Antiblockingmitteln und Additiven für Polymerherstellung |
| US6800228B1 (en) * | 1998-09-22 | 2004-10-05 | Albemarle Corporation | Sterically hindered phenol antioxidant granules having balanced hardness |
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| US6596198B1 (en) * | 2000-04-28 | 2003-07-22 | Albemarle Corporation | Additive system for polymers in pellet form which provides proportioned stabilization and internal mold release characteristics |
| US6515052B2 (en) * | 2001-02-23 | 2003-02-04 | Albemarle Corporation | Granular polymer additives and their preparation |
| JP2005104794A (ja) * | 2003-10-01 | 2005-04-21 | Mitsui Chemicals Inc | タルク |
| WO2005030855A2 (en) * | 2003-10-01 | 2005-04-07 | Ciba Specialty Chemicals Holding Inc. | Additive mixtures |
| EP1866367A2 (en) * | 2005-04-05 | 2007-12-19 | CIBA SPECIALTY CHEMICALS HOLDING INC. Patent Departement | Additive mixtures for agricultural articles |
| TW200732400A (en) * | 2005-10-31 | 2007-09-01 | Sumitomo Chemical Co | Granule mass |
| JP4867593B2 (ja) * | 2006-11-10 | 2012-02-01 | 住友化学株式会社 | 亜リン酸エステル組成物及びその製造方法 |
| US7789957B2 (en) * | 2007-06-06 | 2010-09-07 | Ciba Corporation | Low-dust additive and pigment blends with improved color |
| CN102272219B (zh) * | 2008-12-12 | 2016-05-04 | 英吉尼亚聚合物有限公司 | 用于聚合物的压实丸化添加剂共混物 |
-
2009
- 2009-12-09 CN CN200980154450.3A patent/CN102272219B/zh not_active Expired - Fee Related
- 2009-12-09 WO PCT/US2009/067315 patent/WO2010068666A1/en not_active Ceased
- 2009-12-09 KR KR1020117016083A patent/KR20110110167A/ko not_active Ceased
- 2009-12-09 US US12/633,959 patent/US20100152341A1/en not_active Abandoned
- 2009-12-09 EP EP09768306.4A patent/EP2373730B1/en not_active Revoked
- 2009-12-09 PL PL09768306T patent/PL2373730T3/pl unknown
- 2009-12-09 JP JP2011540863A patent/JP5743327B2/ja not_active Expired - Fee Related
- 2009-12-09 CA CA2746419A patent/CA2746419C/en not_active Expired - Fee Related
- 2009-12-09 ES ES09768306T patent/ES2416486T3/es active Active
- 2009-12-09 BR BRPI0923369-5A patent/BRPI0923369A2/pt not_active Application Discontinuation
- 2009-12-09 SG SG2011042926A patent/SG172111A1/en unknown
- 2009-12-09 MX MX2011006175A patent/MX2011006175A/es unknown
- 2009-12-11 AR ARP090104809A patent/AR075667A1/es not_active Application Discontinuation
Also Published As
| Publication number | Publication date |
|---|---|
| ES2416486T3 (es) | 2013-08-01 |
| PL2373730T3 (pl) | 2013-09-30 |
| MX2011006175A (es) | 2011-09-27 |
| BRPI0923369A2 (pt) | 2020-08-11 |
| AR075667A1 (es) | 2011-04-20 |
| EP2373730B1 (en) | 2013-05-08 |
| KR20110110167A (ko) | 2011-10-06 |
| EP2373730A1 (en) | 2011-10-12 |
| SG172111A1 (en) | 2011-07-28 |
| JP2012512274A (ja) | 2012-05-31 |
| JP5743327B2 (ja) | 2015-07-01 |
| WO2010068666A1 (en) | 2010-06-17 |
| CN102272219B (zh) | 2016-05-04 |
| CA2746419A1 (en) | 2010-06-17 |
| CN102272219A (zh) | 2011-12-07 |
| US20100152341A1 (en) | 2010-06-17 |
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