JP5716036B2 - 高活性の小結晶ｚｓｍ−１２ - Google Patents

高活性の小結晶ｚｓｍ−１２ Download PDF

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Publication number
JP5716036B2
JP5716036B2 JP2012539050A JP2012539050A JP5716036B2 JP 5716036 B2 JP5716036 B2 JP 5716036B2 JP 2012539050 A JP2012539050 A JP 2012539050A JP 2012539050 A JP2012539050 A JP 2012539050A JP 5716036 B2 JP5716036 B2 JP 5716036B2
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JP
Japan
Prior art keywords
zsm
crystalline material
mixture
porous crystalline
molar ratio
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Expired - Fee Related
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JP2012539050A
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English (en)
Japanese (ja)
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JP2013510793A (ja
Inventor
レイ，フランク，ウェニー
ソーンダース，リチャード，ビー．
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ExxonMobil Technology and Engineering Co
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Exxon Research and Engineering Co
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    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
    • C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
    • C01B39/42—Type ZSM-12
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7034—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
    • C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
    • C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S423/00—Chemistry of inorganic compounds
    • Y10S423/33—MTW, e.g. ZSM-12, NU-13, CZH-5, TPZ-3

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Geology (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Diaphragms For Electromechanical Transducers (AREA)
  • Finger-Pressure Massage (AREA)
  • Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
JP2012539050A 2009-11-17 2010-11-15 高活性の小結晶ｚｓｍ−１２ Expired - Fee Related JP5716036B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/590,952 US8202506B2 (en) 2009-11-17 2009-11-17 High activity small crystal ZSM-12
US12/590,952 2009-11-17
PCT/US2010/056656 WO2011062855A1 (en) 2009-11-17 2010-11-15 High activity small crystal zsm-12

Publications (2)

Publication Number Publication Date
JP2013510793A JP2013510793A (ja) 2013-03-28
JP5716036B2 true JP5716036B2 (ja) 2015-05-13

Family

ID=43466952

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2012539050A Expired - Fee Related JP5716036B2 (ja) 2009-11-17 2010-11-15 高活性の小結晶ｚｓｍ−１２

Country Status (9)

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US (1) US8202506B2 (US20100009293A1-20100114-C00010.png)
EP (1) EP2501654B1 (US20100009293A1-20100114-C00010.png)
JP (1) JP5716036B2 (US20100009293A1-20100114-C00010.png)
KR (1) KR20120106954A (US20100009293A1-20100114-C00010.png)
CN (1) CN102666386B (US20100009293A1-20100114-C00010.png)
CA (1) CA2779371C (US20100009293A1-20100114-C00010.png)
IN (1) IN2012DN04748A (US20100009293A1-20100114-C00010.png)
WO (1) WO2011062855A1 (US20100009293A1-20100114-C00010.png)
ZA (1) ZA201203584B (US20100009293A1-20100114-C00010.png)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8202506B2 (en) * 2009-11-17 2012-06-19 Exxonmobil Research And Engineering Company High activity small crystal ZSM-12
WO2013090534A1 (en) 2011-12-16 2013-06-20 Shell Oil Company A titania-bound zsm-12 zeolite composition and method of making and using such composition
CN103435065B (zh) * 2013-08-23 2014-12-03 黑龙江大学 一种纳米zsm-12分子筛的制备方法
CN104445262A (zh) * 2013-09-24 2015-03-25 中国石油化工股份有限公司 具有特定晶体取向的zsm-12分子筛及其制备方法
US10053403B2 (en) 2015-02-04 2018-08-21 Exxonmobil Chemical Patents Inc. Catalyst compositions and their use in transalkylation of heavy aromatics to xylenes
US10118165B2 (en) 2015-02-04 2018-11-06 Exxonmobil Chemical Patents Inc. Catalyst compositions and use in heavy aromatics conversion processes
WO2017205091A1 (en) * 2016-05-25 2017-11-30 Uop Llc High charge density metallophosphate molecular sieves
WO2018080640A1 (en) 2016-10-24 2018-05-03 Chevron U.S.A. Inc. Synthesis of mtw framework type molecular sieves
JP6912564B2 (ja) 2016-11-17 2021-08-04 シェブロン ユー．エス．エー． インコーポレイテッド ゼオライト転換によるｍｔｗフレームワーク型ゼオライトの合成
HUE060395T2 (hu) 2016-12-16 2023-02-28 Shell Int Research Viaszmentesítõ katalizátoros rendszer
CN109665541B (zh) * 2017-10-17 2022-04-01 中国石油化工股份有限公司 低硅铝比zsm-12型沸石分子筛的合成方法
JP7138697B2 (ja) * 2017-10-27 2022-09-16 シェブロン ユー．エス．エー． インコーポレイテッド モレキュラーシーブｓｓｚ－１１２、その合成及び使用
CA3086339A1 (en) * 2017-12-21 2019-06-27 Exxonmobil Research And Engineering Company Emm-31 materials and processes and uses thereof
KR102433148B1 (ko) 2018-03-30 2022-08-17 엑손모빌 케미칼 패턴츠 인코포레이티드 혼합 크실렌 및 고옥탄가 c9+ 방향족의 공생산 방법
EP3781308A1 (en) 2018-04-17 2021-02-24 Shell Internationale Research Maatschappij B.V. Catalyst system for dewaxing
CN115959678A (zh) * 2021-10-11 2023-04-14 中国石油天然气股份有限公司 一种zsm-12分子筛及其制备方法

Family Cites Families (20)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3354078A (en) 1965-02-04 1967-11-21 Mobil Oil Corp Catalytic conversion with a crystalline aluminosilicate activated with a metallic halide
US3832449A (en) 1971-03-18 1974-08-27 Mobil Oil Corp Crystalline zeolite zsm{14 12
US4452769A (en) 1979-03-21 1984-06-05 Mobil Oil Corporation Method of preparing crystalline zeolite
US4537758A (en) 1979-03-21 1985-08-27 Mobil Oil Corporation Process for preparing highly siliceous porous ZSM-12 type crystalline material
US4391785A (en) 1981-12-21 1983-07-05 Mobil Oil Corporation Preparation of ZSM-12 type zeolites
US4482531A (en) * 1983-04-29 1984-11-13 Mobil Oil Corporation Synthesis of ZSM-12 zeolite
US4552739A (en) 1983-12-09 1985-11-12 Mobil Oil Corporation Method of preparing crystalline zeolite ZSM-12 and product
US4585639A (en) * 1984-04-16 1986-04-29 Mobil Oil Corporation Preparation of crystalline silicate ZSM-12
US4539193A (en) 1984-05-23 1985-09-03 Mobil Oil Corporation Synthesis of crystalline silicate ZSM-12
US4552738A (en) 1984-05-25 1985-11-12 Mobil Oil Corporation Synthesis of crystalline silicate ZSM-12
CA1239385A (en) 1984-06-26 1988-07-19 Mae K. Rubin Preparation of zeolite zsm-12
US4585637A (en) 1984-06-26 1986-04-29 Mobil Oil Corporation Synthesis of crystalline silicate ZSM-12
US4585746A (en) 1984-06-27 1986-04-29 Mobil Oil Corporation Synthesis of crystalline silicate ZSM-12
US5021141A (en) 1990-09-14 1991-06-04 Mobil Oil Corp. Synthesis of crystalline ZSM-12 type structure
US5192521A (en) 1991-11-19 1993-03-09 Mobil Oil Corp. Synthesis of crystalline silicate ZSM-12
CN1207197C (zh) * 2002-06-03 2005-06-22 刘希尧 一类十二员环结构两相共生分子筛及其合成方法
US6893624B2 (en) * 2002-11-15 2005-05-17 Exxonmobil Chemical Patents Inc. High activity small crystal ZSM-12
DE10314753A1 (de) * 2003-04-01 2004-10-14 Süd-Chemie AG Synthetischer Zeolith, insbesondere für die katalytische Hydroisomerisierung von höheren Paraffinen
JP4954854B2 (ja) * 2007-11-22 2012-06-20 ユーオーピー エルエルシー 層状化モレキュラーシーブ組成物の調製方法
US8202506B2 (en) * 2009-11-17 2012-06-19 Exxonmobil Research And Engineering Company High activity small crystal ZSM-12

Also Published As

Publication number Publication date
JP2013510793A (ja) 2013-03-28
IN2012DN04748A (US20100009293A1-20100114-C00010.png) 2015-08-07
CA2779371C (en) 2016-10-04
EP2501654A1 (en) 2012-09-26
CN102666386A (zh) 2012-09-12
ZA201203584B (en) 2013-01-30
EP2501654B1 (en) 2017-12-27
KR20120106954A (ko) 2012-09-27
US20110118520A1 (en) 2011-05-19
CN102666386B (zh) 2014-12-03
US8202506B2 (en) 2012-06-19
CA2779371A1 (en) 2011-05-26
WO2011062855A1 (en) 2011-05-26

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