JP5710777B2 - 2成分モルタル組成物およびその使用 - Google Patents
2成分モルタル組成物およびその使用 Download PDFInfo
- Publication number
- JP5710777B2 JP5710777B2 JP2013539199A JP2013539199A JP5710777B2 JP 5710777 B2 JP5710777 B2 JP 5710777B2 JP 2013539199 A JP2013539199 A JP 2013539199A JP 2013539199 A JP2013539199 A JP 2013539199A JP 5710777 B2 JP5710777 B2 JP 5710777B2
- Authority
- JP
- Japan
- Prior art keywords
- component
- mortar composition
- meth
- acrylate
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004570 mortar (masonry) Substances 0.000 title claims description 60
- 239000000203 mixture Substances 0.000 title claims description 58
- 239000011347 resin Substances 0.000 claims description 62
- 229920005989 resin Polymers 0.000 claims description 62
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 36
- 239000003795 chemical substances by application Substances 0.000 claims description 32
- 150000002978 peroxides Chemical class 0.000 claims description 26
- 239000003381 stabilizer Substances 0.000 claims description 24
- 239000000126 substance Substances 0.000 claims description 13
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 10
- 239000000945 filler Substances 0.000 claims description 10
- 150000003254 radicals Chemical class 0.000 claims description 10
- -1 N-substituted aniline Chemical class 0.000 claims description 9
- 239000004848 polyfunctional curative Substances 0.000 claims description 9
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- 239000002562 thickening agent Substances 0.000 claims description 8
- 239000003085 diluting agent Substances 0.000 claims description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 6
- 239000004568 cement Substances 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 6
- 150000001451 organic peroxides Chemical class 0.000 claims description 5
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims description 4
- JUVSRZCUMWZBFK-UHFFFAOYSA-N 2-[n-(2-hydroxyethyl)-4-methylanilino]ethanol Chemical compound CC1=CC=C(N(CCO)CCO)C=C1 JUVSRZCUMWZBFK-UHFFFAOYSA-N 0.000 claims description 4
- LPYUENQFPVNPHY-UHFFFAOYSA-N 3-methoxycatechol Chemical compound COC1=CC=CC(O)=C1O LPYUENQFPVNPHY-UHFFFAOYSA-N 0.000 claims description 4
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical group C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 4
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical class CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 claims description 4
- 239000002202 Polyethylene glycol Substances 0.000 claims description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 4
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 4
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 claims description 4
- GGSUCNLOZRCGPQ-UHFFFAOYSA-N diethylaniline Chemical class CCN(CC)C1=CC=CC=C1 GGSUCNLOZRCGPQ-UHFFFAOYSA-N 0.000 claims description 4
- 229910021485 fumed silica Inorganic materials 0.000 claims description 4
- 235000011187 glycerol Nutrition 0.000 claims description 4
- 150000002334 glycols Chemical class 0.000 claims description 4
- 125000000623 heterocyclic group Chemical group 0.000 claims description 4
- 229920001223 polyethylene glycol Polymers 0.000 claims description 4
- CNHDIAIOKMXOLK-UHFFFAOYSA-N toluquinol Chemical compound CC1=CC(O)=CC=C1O CNHDIAIOKMXOLK-UHFFFAOYSA-N 0.000 claims description 4
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 3
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- 239000003960 organic solvent Substances 0.000 claims description 3
- 150000004992 toluidines Chemical class 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- UICXTANXZJJIBC-UHFFFAOYSA-N 1-(1-hydroperoxycyclohexyl)peroxycyclohexan-1-ol Chemical compound C1CCCCC1(O)OOC1(OO)CCCCC1 UICXTANXZJJIBC-UHFFFAOYSA-N 0.000 claims description 2
- LGJCFVYMIJLQJO-UHFFFAOYSA-N 1-dodecylperoxydodecane Chemical compound CCCCCCCCCCCCOOCCCCCCCCCCCC LGJCFVYMIJLQJO-UHFFFAOYSA-N 0.000 claims description 2
- WJFKNYWRSNBZNX-UHFFFAOYSA-N 10H-phenothiazine Chemical compound C1=CC=C2NC3=CC=CC=C3SC2=C1 WJFKNYWRSNBZNX-UHFFFAOYSA-N 0.000 claims description 2
- BPRYUXCVCCNUFE-UHFFFAOYSA-N 2,4,6-trimethylphenol Chemical compound CC1=CC(C)=C(O)C(C)=C1 BPRYUXCVCCNUFE-UHFFFAOYSA-N 0.000 claims description 2
- HXCWOOAEAHVMBJ-UHFFFAOYSA-N 2-(n,4-dimethylanilino)ethanol Chemical class OCCN(C)C1=CC=C(C)C=C1 HXCWOOAEAHVMBJ-UHFFFAOYSA-N 0.000 claims description 2
- HYVGFUIWHXLVNV-UHFFFAOYSA-N 2-(n-ethylanilino)ethanol Chemical class OCCN(CC)C1=CC=CC=C1 HYVGFUIWHXLVNV-UHFFFAOYSA-N 0.000 claims description 2
- MYFBFOCSISINPS-UHFFFAOYSA-N 2-tert-butylbenzenecarboperoxoic acid Chemical compound CC(C)(C)C1=CC=CC=C1C(=O)OO MYFBFOCSISINPS-UHFFFAOYSA-N 0.000 claims description 2
- FRIBMENBGGCKPD-UHFFFAOYSA-N 3-(2,3-dimethoxyphenyl)prop-2-enal Chemical compound COC1=CC=CC(C=CC=O)=C1OC FRIBMENBGGCKPD-UHFFFAOYSA-N 0.000 claims description 2
- UZFMOKQJFYMBGY-UHFFFAOYSA-N 4-hydroxy-TEMPO Chemical group CC1(C)CC(O)CC(C)(C)N1[O] UZFMOKQJFYMBGY-UHFFFAOYSA-N 0.000 claims description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
- 239000004593 Epoxy Substances 0.000 claims description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 2
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Chemical compound [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 2
- 239000004359 castor oil Substances 0.000 claims description 2
- 235000019438 castor oil Nutrition 0.000 claims description 2
- 239000000919 ceramic Substances 0.000 claims description 2
- 229910052593 corundum Inorganic materials 0.000 claims description 2
- 239000010431 corundum Substances 0.000 claims description 2
- 239000011521 glass Substances 0.000 claims description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 2
- VOZRXNHHFUQHIL-UHFFFAOYSA-N glycidyl methacrylate Chemical compound CC(=C)C(=O)OCC1CO1 VOZRXNHHFUQHIL-UHFFFAOYSA-N 0.000 claims description 2
- LHGVFZTZFXWLCP-UHFFFAOYSA-N guaiacol Chemical compound COC1=CC=CC=C1O LHGVFZTZFXWLCP-UHFFFAOYSA-N 0.000 claims description 2
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 2
- GYVGXEWAOAAJEU-UHFFFAOYSA-N n,n,4-trimethylaniline Chemical class CN(C)C1=CC=C(C)C=C1 GYVGXEWAOAAJEU-UHFFFAOYSA-N 0.000 claims description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 claims description 2
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 229950000688 phenothiazine Drugs 0.000 claims description 2
- 229920001451 polypropylene glycol Polymers 0.000 claims description 2
- 229920002635 polyurethane Polymers 0.000 claims description 2
- 239000004814 polyurethane Substances 0.000 claims description 2
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 2
- 239000010453 quartz Substances 0.000 claims description 2
- 239000004576 sand Substances 0.000 claims description 2
- 239000000377 silicon dioxide Substances 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- 229920006305 unsaturated polyester Polymers 0.000 claims description 2
- 229920001567 vinyl ester resin Polymers 0.000 claims description 2
- 239000000230 xanthan gum Substances 0.000 claims description 2
- 229920001285 xanthan gum Polymers 0.000 claims description 2
- 229940082509 xanthan gum Drugs 0.000 claims description 2
- 235000010493 xanthan gum Nutrition 0.000 claims description 2
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims 3
- PJZLSMMERMMQBJ-UHFFFAOYSA-N 3,5-ditert-butylbenzene-1,2-diol Chemical compound CC(C)(C)C1=CC(O)=C(O)C(C(C)(C)C)=C1 PJZLSMMERMMQBJ-UHFFFAOYSA-N 0.000 claims 1
- OVGORFFCBUIFIA-UHFFFAOYSA-N Fenipentol Chemical group CCCCC(O)C1=CC=CC=C1 OVGORFFCBUIFIA-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims 1
- 239000003112 inhibitor Substances 0.000 description 11
- 238000002156 mixing Methods 0.000 description 7
- 230000000052 comparative effect Effects 0.000 description 5
- 238000002347 injection Methods 0.000 description 4
- 239000007924 injection Substances 0.000 description 4
- 239000000758 substrate Substances 0.000 description 4
- 238000009472 formulation Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000003068 static effect Effects 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 2
- 239000004567 concrete Substances 0.000 description 2
- 238000005553 drilling Methods 0.000 description 2
- 238000001879 gelation Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 125000005641 methacryl group Chemical group 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 230000001235 sensitizing effect Effects 0.000 description 2
- VMNDRLYLEVCGAG-UHFFFAOYSA-N 2-[n-(2-hydroxyethyl)-3-methylanilino]ethanol Chemical compound CC1=CC=CC(N(CCO)CCO)=C1 VMNDRLYLEVCGAG-UHFFFAOYSA-N 0.000 description 1
- WFUGQJXVXHBTEM-UHFFFAOYSA-N 2-hydroperoxy-2-(2-hydroperoxybutan-2-ylperoxy)butane Chemical compound CCC(C)(OO)OOC(C)(CC)OO WFUGQJXVXHBTEM-UHFFFAOYSA-N 0.000 description 1
- AHWAAQOJHMFNIV-UHFFFAOYSA-N 2-tert-butylperoxy-2-ethylhexanoic acid Chemical compound CCCCC(CC)(C(O)=O)OOC(C)(C)C AHWAAQOJHMFNIV-UHFFFAOYSA-N 0.000 description 1
- ATVJXMYDOSMEPO-UHFFFAOYSA-N 3-prop-2-enoxyprop-1-ene Chemical compound C=CCOCC=C ATVJXMYDOSMEPO-UHFFFAOYSA-N 0.000 description 1
- XESZUVZBAMCAEJ-UHFFFAOYSA-N 4-tert-butylcatechol Chemical compound CC(C)(C)C1=CC=C(O)C(O)=C1 XESZUVZBAMCAEJ-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- 239000011398 Portland cement Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 150000004645 aluminates Chemical class 0.000 description 1
- 238000004873 anchoring Methods 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 239000011449 brick Substances 0.000 description 1
- 239000002775 capsule Substances 0.000 description 1
- 239000003975 dentin desensitizing agent Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000010440 gypsum Substances 0.000 description 1
- 229910052602 gypsum Inorganic materials 0.000 description 1
- 125000000687 hydroquinonyl group Chemical group C1(O)=C(C=C(O)C=C1)* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/06—Acrylates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/42—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells
- C09K8/46—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells containing inorganic binders, e.g. Portland cement
- C09K8/467—Compositions for cementing, e.g. for cementing casings into boreholes; Compositions for plugging, e.g. for killing wells containing inorganic binders, e.g. Portland cement containing additives for specific purposes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/16—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/04—Portland cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/06—Aluminous cements
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16B—DEVICES FOR FASTENING OR SECURING CONSTRUCTIONAL ELEMENTS OR MACHINE PARTS TOGETHER, e.g. NAILS, BOLTS, CIRCLIPS, CLAMPS, CLIPS OR WEDGES; JOINTS OR JOINTING
- F16B13/00—Dowels or other devices fastened in walls or the like by inserting them in holes made therein for that purpose
- F16B13/14—Non-metallic plugs or sleeves; Use of liquid, loose solid or kneadable material therefor
- F16B13/141—Fixing plugs in holes by the use of settable material
- F16B13/142—Fixing plugs in holes by the use of settable material characterised by the composition of the setting material or mixture
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00715—Uses not provided for elsewhere in C04B2111/00 for fixing bolts or the like
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- General Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Mechanical Engineering (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Civil Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Dispersion Chemistry (AREA)
- Analytical Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Description
比較例および実施例1〜3の硬化剤成分Aを、以下の表Iに規定される成分を混合することによって最初に生成する。比較例および実施例1〜3の硬化剤成分Bをそれに応じて生成する。このために、成分を、1リットルのプラスチックビーカー中で、手作業で最初に予め混合し、その後、溶解機(4500min-1;<100mbar)中で10分間混合する。
Claims (20)
- 少なくとも1種のラジカル重合性樹脂、充填剤、促進剤および安定剤の含量を有する硬化性樹脂成分と、硬化剤成分とを有する2成分モルタル組成物であって、前記硬化剤成分は、反応を阻害するために硬化性樹脂成分と別々に配置され、かつ穿孔への固定手段の化学的固定のための少なくとも1種の過酸化物の含量を有する2成分モルタル組成物において、
樹脂成分および硬化剤成分の総重量をそれぞれ基準にして、
前記樹脂成分は、8〜25重量%のラジカル重合性樹脂、8〜25重量%の反応性希釈剤、0.1〜0.5重量%の少なくとも1種の促進剤および0.003〜0.03重量%の少なくとも1種の安定剤を含有し、
前記硬化剤成分は、0.1〜0.35重量%の過酸化物を含有することを特徴とする2成分モルタル組成物。 - 樹脂成分および硬化剤成分の総重量をそれぞれ基準にして、
前記樹脂成分は、8〜25重量%のラジカル重合性樹脂、8〜25重量%の反応性希釈剤、0.1〜0.5重量%の促進剤および0.003〜0.03重量%の安定剤、40〜70重量%の充填剤および0.5〜5重量%の増粘剤を含有し、
前記硬化剤成分は、0.1〜0.35重量%の過酸化物、3〜15重量%の水、5〜25重量%の充填剤および0.1〜3重量%の増粘剤を含有することを特徴とする、請求項1に記載の2成分モルタル組成物。 - 前記樹脂成分は、ラジカル重合性樹脂として、不飽和ポリエステル、ビニルエステル、ウレタン(メタ)アクリレートおよび/またはエポキシ(メタ)アクリレートを含有することを特徴とする、請求項1または2のいずれか一項に記載の2成分モルタル組成物。
- 前記樹脂成分は、促進剤として、少なくとも第三級N,N−置換アニリン、第三級N,N−置換トルイジンおよび/またはそのアルコキシ化誘導体を含有することを特徴とする、請求項1〜3のいずれか一項に記載の2成分モルタル組成物。
- 前記樹脂成分は、N,N−置換アニリンまたはN,N−置換トルイジンのそれぞれとして、N,N−ジメチルアニリン、N,N−ジエチルアニリン、N−エチル−N−(ヒドロキシエチル)−アニリン、N,N−ジメチル−p−トルイジン、N−メチル−N−(ヒドロキシエチル)−p−トルイジン、N,N−ジイソプロピリデン−p−トルイジン、ジ(ヒドロキシエチル)−p−トルイジン、ジ(ヒドロキシエチル)−m−トルイジンおよび/またはエトキシ化ジ(ヒドロキシエチル)−p−トルイジンを含有することを特徴とする、請求項4に記載の2成分モルタル組成物。
- 前記樹脂成分は、フェノール系および/または非フェノール系安定剤を含有することを特徴とする、請求項1〜5のいずれか一項に記載の2成分モルタル組成物。
- 前記樹脂成分は、フェノール系安定剤として、ヒドロキノン、2−メチルヒドロキノン、メトキシフェノール、2,4,6−トリメチルフェノール、ピロカテコール、3−メトキシピロカテコール、3,5−ジ−tert−ブチルピロカテコール、ブチルヒドロキシトルエン基およびこれらの化合物の誘導体を代表する少なくとも1つを含有することを特徴とする、請求項6に記載の2成分モルタル組成物。
- 前記樹脂成分は、非フェノール系安定剤として、N−オキシル化合物および/または複素環系安定剤を含有することを特徴とする、請求項7に記載の2成分モルタル組成物。
- 前記樹脂成分は、N−オキシル化合物としてのピペリジニル−N−オキシルおよび/またはテトラヒドロピロール−N−オキシル誘導体および/または複素環系安定剤としてのフェノチアジンを含有することを特徴とする、請求項8に記載の2成分モルタル組成物。
- 前記樹脂成分は、ピペリジン−N−オキシル誘導体として、4−ヒドロキシ−2,2,6,6−テトラメチル−ピペリジン−N−オキシルを含有することを特徴とする、請求項9に記載の2成分モルタル組成物。
- 前記樹脂成分は、反応性希釈剤として、少なくとも1種のエチレン性不飽和化合物を含有することを特徴とする、請求項1〜10のいずれか一項に記載の2成分モルタル組成物。
- 前記樹脂成分は、反応性希釈剤として、スチレン、α−メチルスチレン、ジビニルベンゼン、(メタ)アクリルアミド、メチル(メタ)アクリレート、エチル(メタ)アクリレート、プロピル(メタ)アクリレート、ブチル(メタ)アクリレート、エチルヘキシル(メタ)アクリレート、ネオペンチルグリコール(メタ)アクリレート、エチレングリコールジ(メタ)アクリレート、ジエチレングリコールジ(メタ)アクリレート、ポリエチレングリコール(メタ)アクリレート、プロピレングリコールジ(メタ)アクリレート、ブタンジオールジ(メタ)アクリレート、グリセリン(メタ)アクリレート、ヒドロキシエチル(メタ)アクリレート、アセトアセタトエチル(メタ)アクリレート、アルコキシ化ビスフェノール−A−ジ(メタ)アクリレートおよび/またはグリシジルメタクリレートを含有することを特徴とする、請求項11に記載の2成分モルタル組成物。
- 前記硬化剤成分は、過酸化物として、有機過酸化物を含有することを特徴とする、請求項1〜12のいずれか一項に記載の2成分モルタル組成物。
- 前記硬化剤成分は、有機過酸化物として、過酸化ジベンゾイル、過酸化メチルエチルケトン、tert−ブチル過安息香酸、過酸化シクロヘキサノン、過酸化ラウリル、クメンヒドロペルオキシドおよび/またはtert−ブチルペルオキシ−2−エチルヘキサン酸を含有することを特徴とする、請求項13に記載の2成分モルタル組成物。
- 前記樹脂成分および/または前記硬化剤成分は、充填剤として、好適な粒度分布における、石英、砂、ヒュームドシリカ、コランダム、チョーク、タルク、セラミック、酸化アルミニウム、ガラス、セメント、軽質スパー(light spar)および/または重質スパー(heavy spar)を含有することを特徴とする、請求項1〜14のいずれか一項に記載の2成分モルタル組成物。
- 前記樹脂成分および/または前記硬化剤成分は、増粘剤として、ヒュームドシリカ、層状ケイ酸塩、アクリレートまたはポリウレタン増粘剤、ヒマシ油誘導体、ノイブルグ珪土および/またはキサンタンガムを含有することを特徴とする、請求項1〜15のいずれか一項に記載の2成分モルタル組成物。
- 前記硬化剤成分は、少なくとも1種の有機溶媒を0〜5重量%含有することを特徴とする、請求項1〜16のいずれか一項に記載の2成分モルタル組成物。
- 前記硬化剤成分は、有機溶媒として、前記ラジカル重合性樹脂と共重合可能な、グリコール、グリセリン、および/または水溶性ポリエチレングリコール誘導体および/またはポリプロピレングリコール誘導体を含有することを特徴とする、請求項17に記載の2成分モルタル組成物。
- 前記樹脂成分および前記硬化剤成分は、反応を阻害するために異なる容器中に別々に存在することを特徴とする、請求項1〜18のいずれか一項に記載の2成分モルタル組成物。
- 穿孔への固定手段の化学的固定のための、請求項1〜19のいずれか一項に記載の2成分モルタル組成物の使用。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE102010051818A DE102010051818B3 (de) | 2010-11-18 | 2010-11-18 | Zweikomponenten-Mörtelmasse und ihre Verwendung |
DE102010051818.2 | 2010-11-18 | ||
PCT/EP2011/069613 WO2012065878A1 (de) | 2010-11-18 | 2011-11-08 | Zweikomponenten-mörtelmasse und ihre verwendung |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2014503612A JP2014503612A (ja) | 2014-02-13 |
JP5710777B2 true JP5710777B2 (ja) | 2015-04-30 |
Family
ID=45047734
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013539199A Active JP5710777B2 (ja) | 2010-11-18 | 2011-11-08 | 2成分モルタル組成物およびその使用 |
Country Status (12)
Country | Link |
---|---|
US (1) | US9523029B2 (ja) |
EP (1) | EP2640675B1 (ja) |
JP (1) | JP5710777B2 (ja) |
CN (1) | CN103339082B (ja) |
AU (1) | AU2011331387B2 (ja) |
CA (1) | CA2817997C (ja) |
DE (1) | DE102010051818B3 (ja) |
DK (1) | DK2640675T3 (ja) |
ES (1) | ES2551903T3 (ja) |
PT (1) | PT2640675E (ja) |
RU (1) | RU2577552C2 (ja) |
WO (1) | WO2012065878A1 (ja) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016069270A (ja) * | 2014-09-23 | 2016-05-09 | フィッシャーヴェルケ ゲゼルシャフト ミット ベシュレンクテル ハフツング ウント コンパニー コマンディートゲゼルシャフトfischerwerke GmbH & Co. KG | 微細粒の充填剤を有する固定系 |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102011017619B4 (de) | 2011-04-27 | 2014-10-16 | Hilti Aktiengesellschaft | Beschleunigermischung für Peroxidhärter und diese enthaltendes Zweikomponenten-Mörtelsystem sowie Verwendung des Mörtelsystems |
CN102690081B (zh) * | 2012-06-11 | 2013-06-19 | 安徽省煤炭科学研究院 | 缓凝型树脂锚杆锚固剂的制备方法 |
JP2016522840A (ja) | 2013-04-05 | 2016-08-04 | フィッシャーヴェルケ ゲゼルシャフト ミット ベシュレンクテル ハフツング ウント コンパニー コマンディートゲゼルシャフトfischerwerke GmbH & Co. KG | 合成樹脂接着剤における生物由来の液状非反応性希釈剤 |
EP2796433A1 (de) * | 2013-04-22 | 2014-10-29 | HILTI Aktiengesellschaft | Reaktionsharz-Zusammensetzung sowie deren Verwendung |
EP2829524A1 (de) | 2013-07-24 | 2015-01-28 | HILTI Aktiengesellschaft | Harzmischung, Reaktionsharz-Mörtel, Mehrkomponenten-Mörtelsystem und deren Verwendung |
EP2829525A1 (de) * | 2013-07-24 | 2015-01-28 | HILTI Aktiengesellschaft | Reaktionsharzmörtel, Mehrkomponenten-Mörtelsystem und deren Verwendung |
EP3094422A4 (en) * | 2014-01-07 | 2017-11-22 | Reuven Hugi | Universal method, device and materials for fixating an insert to a substrate |
DE102014109355A1 (de) * | 2014-07-04 | 2016-01-07 | Fischerwerke Gmbh & Co. Kg | Reaktivverdünner für die chemische Befestigung |
RU2597601C2 (ru) * | 2014-07-17 | 2016-09-10 | Вячеслав Владимирович Попов | Ремонтный материал холодного отверждения "хрм-2" |
EP2980037A1 (de) * | 2014-07-31 | 2016-02-03 | HILTI Aktiengesellschaft | Zweikomponenten-Mörtelmasse und deren Verwendung |
CN107207681A (zh) * | 2015-02-19 | 2017-09-26 | 昭和电工株式会社 | 低温固化截面修复材料和使用该低温固化截面修复材料的截面修复方法 |
EP3365302B1 (en) * | 2015-10-20 | 2019-07-17 | Hilti Aktiengesellschaft | Fastening system and use thereof |
EP3299351A1 (de) * | 2016-09-26 | 2018-03-28 | HILTI Aktiengesellschaft | Zweikomponenten-mörtelmasse und deren verwendung |
EP3299350A1 (de) * | 2016-09-26 | 2018-03-28 | HILTI Aktiengesellschaft | Zweikomponenten-mörtelmasse und deren verwendung |
CN107417170A (zh) * | 2017-06-30 | 2017-12-01 | 常州瑞坦商贸有限公司 | 一种耐高温抗老化树脂锚固剂 |
CN108383428A (zh) * | 2018-01-29 | 2018-08-10 | 宁波坚朗科兴精密制造有限公司 | 一种潮湿环境下改性乙烯基砂浆及其制备方法 |
DE102019106854A1 (de) | 2019-03-18 | 2020-09-24 | Mkt Metall-Kunststoff-Technik Gmbh & Co. Kg | Befestigungssystem umfassend eine Härterkomponente mit mindestens einem Benzoat |
EP3805301A1 (de) * | 2019-10-10 | 2021-04-14 | Hilti Aktiengesellschaft | Lagerstabile härterzusammensetzung für ein reaktionsharz |
RU2721509C1 (ru) * | 2019-10-15 | 2020-05-19 | Мурат Сергеевич Качмазов | Состав водорастворимой пасты-вытеснителя для изготовления литых строительных изделий с рельефной лицевой поверхностью |
EP3835279A1 (de) * | 2019-12-09 | 2021-06-16 | Hilti Aktiengesellschaft | Füllstoffmischung für chemische befestigungssysteme und deren verwendung |
EP3851424A1 (de) * | 2020-01-14 | 2021-07-21 | Hilti Aktiengesellschaft | Verwendung von reaktionsharzmischungen mit vordefinierter polarität zur einstellung der gelzeit einer mörtelmasse sowie verfahren zur einstellung der gelzeit einer mörtelmasse |
CN113511855A (zh) * | 2021-04-16 | 2021-10-19 | 湖北三棵树新材料科技有限公司 | 一种双组份水性聚氨酯砂浆防水涂料及其制备方法 |
CN113929359B (zh) * | 2021-10-22 | 2022-07-01 | 林荣涛 | 一种粘土饽饽模型用凝固剂及制作方法 |
EP4261197A1 (de) * | 2022-04-12 | 2023-10-18 | Hilti Aktiengesellschaft | Zweikomponenten-mörtelmasse und deren verwendung |
EP4261196A1 (de) * | 2022-04-12 | 2023-10-18 | Hilti Aktiengesellschaft | Zweikomponenten-mörtelmasse und deren verwendung |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5436396A (en) * | 1992-06-22 | 1995-07-25 | Sandvik Rock Tools, Inc. | Stabilizing compositions and methods for stabilizing subterranean formations |
DE4231161A1 (de) | 1992-09-17 | 1994-03-24 | Hilti Ag | Mörtel und Vorrichtung zur Befestigung von Verankerungsmitteln in Bohrlöchern |
DE19531649A1 (de) | 1995-08-29 | 1997-03-06 | Basf Ag | Dübelmasse für die chemische Befestigungstechnik |
US6541545B1 (en) * | 1999-03-19 | 2003-04-01 | E. I. Du Pont De Nemours And Company | Grouting compositions |
EP1217017A1 (en) * | 2000-12-22 | 2002-06-26 | Dsm N.V. | Resin mortars for chemical fastening |
DE10115591A1 (de) * | 2001-03-29 | 2002-10-02 | Fischer Artur Werke Gmbh | Mehrkomponentenkits und Kombinationen, ihre Verwendung und erhältliche Kunstmörtel |
DE102004035567B4 (de) | 2004-07-22 | 2006-10-26 | Hilti Ag | Zweikomponenten-Mörtelmasse und ihre Verwendung |
DE102006030044A1 (de) | 2006-06-29 | 2008-01-03 | Fischerwerke Artur Fischer Gmbh & Co. Kg | Schnellhärtendes chemisches Befestigungssystem und dessen Verwendung |
JP5008177B2 (ja) * | 2006-06-30 | 2012-08-22 | 旭化成ケミカルズ株式会社 | アンカーボルト固着剤 |
-
2010
- 2010-11-18 DE DE102010051818A patent/DE102010051818B3/de active Active
-
2011
- 2011-11-08 ES ES11788396.7T patent/ES2551903T3/es active Active
- 2011-11-08 WO PCT/EP2011/069613 patent/WO2012065878A1/de active Application Filing
- 2011-11-08 JP JP2013539199A patent/JP5710777B2/ja active Active
- 2011-11-08 RU RU2013127395/03A patent/RU2577552C2/ru not_active IP Right Cessation
- 2011-11-08 US US13/988,220 patent/US9523029B2/en active Active
- 2011-11-08 DK DK11788396.7T patent/DK2640675T3/en active
- 2011-11-08 CN CN201180055687.3A patent/CN103339082B/zh active Active
- 2011-11-08 AU AU2011331387A patent/AU2011331387B2/en not_active Ceased
- 2011-11-08 EP EP11788396.7A patent/EP2640675B1/de active Active
- 2011-11-08 CA CA2817997A patent/CA2817997C/en active Active
- 2011-11-08 PT PT117883967T patent/PT2640675E/pt unknown
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016069270A (ja) * | 2014-09-23 | 2016-05-09 | フィッシャーヴェルケ ゲゼルシャフト ミット ベシュレンクテル ハフツング ウント コンパニー コマンディートゲゼルシャフトfischerwerke GmbH & Co. KG | 微細粒の充填剤を有する固定系 |
US10711116B2 (en) | 2014-09-23 | 2020-07-14 | Fischerwerke Gmbh & Co. Kg | Fixing systems having fine-particle fillers |
US11795301B2 (en) | 2014-09-23 | 2023-10-24 | Fischerwerke Gmbh & Co. Kg | Fixing systems having fine-particle fillers |
Also Published As
Publication number | Publication date |
---|---|
CA2817997C (en) | 2019-02-19 |
US20130237634A1 (en) | 2013-09-12 |
EP2640675B1 (de) | 2015-09-09 |
US9523029B2 (en) | 2016-12-20 |
WO2012065878A1 (de) | 2012-05-24 |
CN103339082A (zh) | 2013-10-02 |
AU2011331387B2 (en) | 2015-07-02 |
DK2640675T3 (en) | 2015-12-14 |
RU2577552C2 (ru) | 2016-03-20 |
JP2014503612A (ja) | 2014-02-13 |
CA2817997A1 (en) | 2012-05-24 |
PT2640675E (pt) | 2015-11-12 |
AU2011331387A1 (en) | 2013-06-27 |
ES2551903T3 (es) | 2015-11-24 |
RU2013127395A (ru) | 2014-12-27 |
DE102010051818B3 (de) | 2012-02-16 |
CN103339082B (zh) | 2015-08-26 |
EP2640675A1 (de) | 2013-09-25 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5710777B2 (ja) | 2成分モルタル組成物およびその使用 | |
US8440278B2 (en) | Inhibitor, resin mixture containing same and use of same | |
US10239787B2 (en) | Resin mixture, reaction resin—mortar, multi-component mortar system, and their application | |
JP2008156645A (ja) | 二成分熱硬化性樹脂およびその使用 | |
JP5886321B2 (ja) | 低温硬化性接着剤組成物 | |
US20090308533A1 (en) | Fast-curing chemical fixing system and use thereof | |
JP5219315B2 (ja) | 抑制剤の組み合わせの使用、樹脂組成物、反応性樹脂モルタル、2成分モルタル組成物、2成分モルタル組成物の化学固定用途への使用、並びに2成分モルタル組成物を収容するパトローネ、カートリッジ、及び薄膜袋 | |
US20160137552A1 (en) | Reaction resin mortar, multi-component mortar system and the use thereof | |
US10442964B2 (en) | Biogenic liquid non-reactive diluents in synthetic resin adhesive compositions | |
CN112638984A (zh) | 反应性胺促进剂、含有所述促进剂的反应性树脂及其使用 | |
CA3163493A1 (en) | Use of reaction resin mixtures with predefined polarity for setting the robustness of a mortar composition and method for setting the robustness of a mortar composition | |
JP2023506065A (ja) | 反応性樹脂成分、該成分を含有する反応性樹脂系、および該成分の使用 | |
KR20200024295A (ko) | 에폭시 메타크릴레이트 화합물 및 그것의 용도 | |
EP3838862A1 (de) | Verwendung einer reaktivharz-zusammensetzung für die chemische befestigung eines verankerungsmittels in einem bohrloch | |
WO2020187565A1 (de) | Beschleuniger-kombination | |
EP3838863A1 (de) | Verwendung einer reaktivharz-zusammensetzung für die chemische befestigung eines verankerungsmittels in einem bohrloch |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20140819 |
|
A871 | Explanation of circumstances concerning accelerated examination |
Free format text: JAPANESE INTERMEDIATE CODE: A871 Effective date: 20140819 |
|
A975 | Report on accelerated examination |
Free format text: JAPANESE INTERMEDIATE CODE: A971005 Effective date: 20141009 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20141112 |
|
RD13 | Notification of appointment of power of sub attorney |
Free format text: JAPANESE INTERMEDIATE CODE: A7433 Effective date: 20141203 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20141209 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A821 Effective date: 20141204 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20150119 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20150210 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20150304 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 5710777 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |