JP5709304B2 - 水中油型乳化化粧料 - Google Patents
水中油型乳化化粧料 Download PDFInfo
- Publication number
- JP5709304B2 JP5709304B2 JP2011000932A JP2011000932A JP5709304B2 JP 5709304 B2 JP5709304 B2 JP 5709304B2 JP 2011000932 A JP2011000932 A JP 2011000932A JP 2011000932 A JP2011000932 A JP 2011000932A JP 5709304 B2 JP5709304 B2 JP 5709304B2
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- Prior art keywords
- oil
- component
- mass
- emulsified cosmetic
- water
- Prior art date
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- 239000011259 mixed solution Substances 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- MNAZHGAWPCLLGX-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]docosanamide Chemical compound CCCCCCCCCCCCCCCCCCCCCC(=O)NCCCN(C)C MNAZHGAWPCLLGX-UHFFFAOYSA-N 0.000 description 1
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 1
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Description
下記の表1および表2に示す乳化化粧料を調製した。表中の成分(a)アルキルグリセリルエーテル及び成分(b)炭素数12〜22の高級脂肪酸およびその塩を80℃で加温溶解した後、ホモミキサーで混合し、さらに高圧ホモジナイザーで処理した。その後、常温まで冷却し、目的の乳化化粧料を得た。
(2)アルキルグリセリルエーテル配合ローションの安定性評価
乳化化粧料を調製直後に、コールターN4 PLUSを用いて粒子径を測定し、B型粘度計を用いて粘度を測定した。調製直後に明らかなクリーミングや分離及び結晶析出が観察された場合は観察不可とした。また、5℃と45℃の恒温槽に1か月間静置し、粘度の測定及び、外観を目視にて観察した。5℃に静置した乳化化粧料は顕微鏡を用いて、アルキルグリセリルエーテルの結晶析出の有無を観察した。45℃に静置した乳化化粧料はクリーミングや分離の有無を目視観察により判断した。
○:結晶および外観の変化が認められず
×:結晶又は、分離・クリーミングが認められた
(A)キミルアルコール 2.0%
バチルアルコール 0.5%
パルミチン酸 0.1%
ステアリン酸 0.3%
ベヘン酸 0.2%
流動パラフィン 3.0%
(B)ステアロイルグルタミン酸ナトリウム 0.3%
アルギニン 0.2%
グリセリン 3.0%
ヒドロキシプロピルメチルセルロースステアロキシエーテル 0.1%
防腐剤 適量
イオン交換水 残量
調製方法:AおよびBをそれぞれ80℃まで加温し、均一溶解後ホモミキサーで予備乳化する。その後、温度を保ったまま高圧ホモジナイザーで処理し攪拌しながら常温まで冷却し、調製終了とする。
粒子径 :119.0nm
粘度 :560mPa・s
安定性 :室温、5℃、45℃の恒温槽に1ヶ月静置したところ、結晶析出やクリーミングはなく、外観変化は確認されなかった。
(A)キミルアルコール 3.0%
ステアリン酸 0.7%
ベヘン酸 0.7%
トリ2−エチルヘキサン酸グリセリル 4.0%
(B)ステアロイルグルタミン酸ナトリウム 0.5%
アルギニン 0.4%
グリセリン 5.0%
ヒドロキシプロピルメチルセルロースドコシロキシエーテル 1.0%
キサンタンガム 0.02%
防腐剤 適量
イオン交換水 残量
調製方法:AおよびBをそれぞれ80℃まで加温し、均一溶解後ホモミキサーで予備乳化する。その後、温度を保ったまま高圧ホモジナイザーで処理し攪拌しながら常温まで冷却し、調製終了とする。
粒子径 :92.4nm
粘度 :1690mPa・s
安定性 :室温、5℃、45℃の恒温槽に1ヶ月静置したところ、結晶析出やクリーミングはなく、外観変化は確認されなかった。
(A)セラキルアルコール 0.3%
バチルアルコール 1.0%
パルミチン酸 0.2%
ベヘン酸 0.4%
オレフィンオリゴマー 3.0%
(B)ラウロイルグルタミン酸ナトリウム 0.3%
ステアロイルグルタミン酸ナトリウム 0.5%
アルギニン 0.3%
ベヘナミドプロピルジメチルアミン 0.1%
1,3−ブチレングリコール 4.0%
ヒドロキシプロピルメチルセルロースラウロキシエーテル 1.0%
キサンタンガム 0.01%
防腐剤 適量
イオン交換水 残量
調製方法:AおよびBをそれぞれ80℃まで加温し、均一溶解後ホモミキサーで予備乳化する。その後、温度を保ったまま高圧ホモジナイザーで処理し攪拌しながら常温まで冷却し、調製終了とする。
粒子径 :104.2nm
粘度 :880mPa・s
安定性 :室温、5℃、45℃の恒温槽に1ヶ月静置したところ、結晶析出やクリーミングはなく、外観変化は確認されなかった。
Claims (5)
- 次の成分(a)〜(e)を必須成分として含有することを特徴とする水中油型乳化化粧料。
(a)キミルアルコール、バチルアルコール、セラキルアルコールより選ばれる1種又は2種以上からなるアルキルグリセリルエーテル
(b)炭素数12〜22の高級脂肪酸塩
(c)常温で液状の油性成分
(d)疎水化処理した水溶性セルロース誘導体
(e)アシルグルタミン酸塩 - 成分(a)を0.01〜7.0質量%、成分(b)を0.01〜3.0質量%、成分(c)を0.01〜14.0質量%、成分(d)を0.01〜2.0質量%、成分(e)を0.01〜3.0質量%含有することを特徴とする請求項1に記載の水中油型乳化化粧料。
- 25℃における粘度が2000mPa・s以下の低粘度製剤であることを特徴とする請求項1又は2に記載の水中油型乳化化粧料。
- 乳化滴の平均粒子径が200nm以下であることを特徴とする請求項1〜3のいずれか1項に記載の水中油型乳化化粧料。
- 成分(d)の疎水化した水溶性セルロース誘導体が、不飽和結合を含んでいてもよい炭素数6〜22の直鎖、および/または分岐のアルキル基を持つアルキル化多糖類であることを特徴とする請求項1〜4のいずれか1項に記載の水中油型乳化化粧料。
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US10806688B2 (en) | 2014-10-03 | 2020-10-20 | The Procter And Gamble Company | Method of achieving improved volume and combability using an anti-dandruff personal care composition comprising a pre-emulsified formulation |
US10912723B2 (en) | 2016-01-20 | 2021-02-09 | The Procter And Gamble Company | Hair conditioning composition comprising monoalkyl glyceryl ether |
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WO2017182264A1 (en) * | 2016-04-21 | 2017-10-26 | Unilever Plc | Novel nanoemulsions comprising fatty acid and n-acyl derivatives of amino acid salt |
US11026869B2 (en) * | 2016-04-21 | 2021-06-08 | Conopco, Inc. | Process for producing small droplet emulsions at low pressure |
CN109568153A (zh) * | 2017-09-29 | 2019-04-05 | 株式会社资生堂 | 水包油型乳化组合物及其制备方法和制品 |
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US10806688B2 (en) | 2014-10-03 | 2020-10-20 | The Procter And Gamble Company | Method of achieving improved volume and combability using an anti-dandruff personal care composition comprising a pre-emulsified formulation |
US10912723B2 (en) | 2016-01-20 | 2021-02-09 | The Procter And Gamble Company | Hair conditioning composition comprising monoalkyl glyceryl ether |
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