JP5708959B2 - 鉛蓄電池 - Google Patents
鉛蓄電池 Download PDFInfo
- Publication number
- JP5708959B2 JP5708959B2 JP2014182415A JP2014182415A JP5708959B2 JP 5708959 B2 JP5708959 B2 JP 5708959B2 JP 2014182415 A JP2014182415 A JP 2014182415A JP 2014182415 A JP2014182415 A JP 2014182415A JP 5708959 B2 JP5708959 B2 JP 5708959B2
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- JP
- Japan
- Prior art keywords
- active material
- electrode active
- negative electrode
- mol
- positive electrode
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 239000002253 acid Substances 0.000 title claims description 9
- -1 polyethylene Polymers 0.000 claims description 25
- 229910052782 aluminium Inorganic materials 0.000 claims description 23
- 239000007774 positive electrode material Substances 0.000 claims description 21
- 239000007773 negative electrode material Substances 0.000 claims description 19
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 claims description 18
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 18
- 229910001416 lithium ion Inorganic materials 0.000 claims description 18
- 239000003792 electrolyte Substances 0.000 claims description 9
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 239000007788 liquid Substances 0.000 claims description 2
- 239000011244 liquid electrolyte Substances 0.000 claims description 2
- 238000003860 storage Methods 0.000 description 20
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 description 9
- 239000008151 electrolyte solution Substances 0.000 description 8
- 239000011149 active material Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 238000009825 accumulation Methods 0.000 description 5
- WABPQHHGFIMREM-UHFFFAOYSA-N lead(0) Chemical compound [Pb] WABPQHHGFIMREM-UHFFFAOYSA-N 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 2
- 238000000498 ball milling Methods 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 210000005069 ears Anatomy 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000005484 gravity Effects 0.000 description 2
- INHCSSUBVCNVSK-UHFFFAOYSA-L lithium sulfate Inorganic materials [Li+].[Li+].[O-]S([O-])(=O)=O INHCSSUBVCNVSK-UHFFFAOYSA-L 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- RBTVSNLYYIMMKS-UHFFFAOYSA-N tert-butyl 3-aminoazetidine-1-carboxylate;hydrochloride Chemical compound Cl.CC(C)(C)OC(=O)N1CC(N)C1 RBTVSNLYYIMMKS-UHFFFAOYSA-N 0.000 description 2
- 229910014474 Ca-Sn Inorganic materials 0.000 description 1
- JLVVSXFLKOJNIY-UHFFFAOYSA-N Magnesium ion Chemical compound [Mg+2] JLVVSXFLKOJNIY-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229920005610 lignin Polymers 0.000 description 1
- 229910001425 magnesium ion Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910001414 potassium ion Inorganic materials 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 150000003839 salts Chemical group 0.000 description 1
- 229910001415 sodium ion Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Cell Separators (AREA)
- Secondary Cells (AREA)
Description
・ 鉛蓄電池の電解液にアルミニウムイオンを含有させると、負極への硫酸鉛の蓄積が抑制され、
・ 鉛蓄電池の電解液にリチウムイオンを含有させると、5時間率容量が増加するとしている。
しかしながら発明者らの実験では、電解液にリチウムイオンを含有させることにより蓄電池の5時間率容量が増加することはなかった。
Claims (2)
- 正極板と、負極板と、ポリエチレンの多孔質セパレータと、硫酸とアルミニウムイオンとを含む液状の電解液を備えた鉛蓄電池において、
負極板の負極活物質と正極板の正極活物質との質量比が0.7以上0.85以下で、かつ電解液中のアルミニウムイオン濃度が0.02mol/L以上0.2mol/L以下であり、
前記電解液はリチウムイオン濃度が0.01mol/L以下であることを特徴とする、液式の鉛蓄電池。 - 負極活物質と正極活物質との質量比が0.7以上0.8以下であることを特徴とする、請求項1の液式の鉛蓄電池。
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014182415A JP5708959B2 (ja) | 2014-09-08 | 2014-09-08 | 鉛蓄電池 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2014182415A JP5708959B2 (ja) | 2014-09-08 | 2014-09-08 | 鉛蓄電池 |
Related Parent Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2011210433A Division JP5637503B2 (ja) | 2011-09-27 | 2011-09-27 | 鉛蓄電池 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2015008151A JP2015008151A (ja) | 2015-01-15 |
JP5708959B2 true JP5708959B2 (ja) | 2015-04-30 |
Family
ID=52338268
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2014182415A Active JP5708959B2 (ja) | 2014-09-08 | 2014-09-08 | 鉛蓄電池 |
Country Status (1)
Country | Link |
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JP (1) | JP5708959B2 (ja) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP6115796B2 (ja) * | 2015-02-18 | 2017-04-19 | 株式会社Gsユアサ | 鉛蓄電池 |
Family Cites Families (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS52136332A (en) * | 1976-05-08 | 1977-11-15 | Kouhei Mogi | Lead battery and method of regenerating lead battery |
JPH04296464A (ja) * | 1991-03-26 | 1992-10-20 | Shin Kobe Electric Mach Co Ltd | 密閉形鉛蓄電池 |
JP2001028263A (ja) * | 1999-07-14 | 2001-01-30 | Japan Storage Battery Co Ltd | 鉛蓄電池の化成方法 |
JP2001155762A (ja) * | 1999-11-26 | 2001-06-08 | Shin Kobe Electric Mach Co Ltd | 自動車用密閉型鉛電池 |
JP4798972B2 (ja) * | 2004-08-03 | 2011-10-19 | 古河電池株式会社 | スタンバイ用制御弁式鉛蓄電池 |
US8771871B2 (en) * | 2005-09-27 | 2014-07-08 | The Furukawa Battery Co., Ltd. | Lead storage battery and manufacturing method of the same |
JP2008243487A (ja) * | 2007-03-26 | 2008-10-09 | Furukawa Battery Co Ltd:The | 鉛電池 |
JP2011181436A (ja) * | 2010-03-03 | 2011-09-15 | Shin Kobe Electric Mach Co Ltd | 鉛蓄電池 |
JP5531746B2 (ja) * | 2010-04-14 | 2014-06-25 | 株式会社Gsユアサ | 鉛蓄電池 |
JP5748091B2 (ja) * | 2010-09-29 | 2015-07-15 | 株式会社Gsユアサ | 鉛蓄電池 |
JP5618253B2 (ja) * | 2010-09-30 | 2014-11-05 | 株式会社Gsユアサ | 鉛蓄電池 |
JP5637503B2 (ja) * | 2011-09-27 | 2014-12-10 | 株式会社Gsユアサ | 鉛蓄電池 |
-
2014
- 2014-09-08 JP JP2014182415A patent/JP5708959B2/ja active Active
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Publication number | Publication date |
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JP2015008151A (ja) | 2015-01-15 |
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