JP5676187B2 - 水中油型化粧料 - Google Patents
水中油型化粧料 Download PDFInfo
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- JP5676187B2 JP5676187B2 JP2010207308A JP2010207308A JP5676187B2 JP 5676187 B2 JP5676187 B2 JP 5676187B2 JP 2010207308 A JP2010207308 A JP 2010207308A JP 2010207308 A JP2010207308 A JP 2010207308A JP 5676187 B2 JP5676187 B2 JP 5676187B2
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Description
例えば、特許文献1には、肌の上で厚みのある化粧膜を形成させるため、ポリビニルアルコールや、ラテックス類、セルロース誘導体、シリコーン系樹脂などの皮膜形成剤と、低級アルコール、球状粉末及び清涼剤を含有する皮膚化粧料が開示されている。また、特許文献2には、所定のショ糖脂肪酸エステル及びポリグリセリン脂肪酸エステルに、ポリエチレンワックスやミツロウのような所定の固形油を組み合わせた水中油型化粧料が開示されている。
また、特許文献3には、固形油や皮膜形成剤の代わりに、高粘性油剤と、イソノナン酸イソトリデシルと、ポリエチレングリコールなどの高分子を併用することでハリ感を付与可能な水中油型乳化化粧料が開示されている。
[1] 100℃における動粘度が200mm2/s〜1000mm2/sである水添ポリイソブテンを含む油相と、ステアリン酸ソルビタンと、高級アルコール及び高級脂肪酸の少なくとも一方と、を含有し、前記水添ポリイソブテンの含有量が油相の質量の18質量%〜23質量%であり、油相及び水相から構成された水中油型化粧料。
[2] 油脂、炭化水素及びロウから選ばれる融点が60℃以上の固形油の合計含有量が0又は化粧料全質量の5質量%未満である[1]に記載の水中油型化粧料。
[3] 前記油相の含有量が、化粧料全質量の45質量%〜70質量%である[1]又は[2]に記載の水中油型化粧料。
[4] 前記水添ポリイソブテンの含有量が、化粧料全質量の5質量%〜20質量%である[1]又は[2]に記載の水中油型化粧料。
[5] 高級アルコール及び高級脂肪酸を共に含む[1]〜[4]のいずれかに記載の水中油型化粧料。
[6] 前記高級アルコールが、ベヘニルアルコール及びステアリルアルコールから選択された少なくとも1種である[1]〜[5]のいずれかに記載の水中油型化粧料。
[7] 前記高級アルコールが、ベヘニルアルコールである[1]〜[6]のいずれかに記載の水中油型化粧料。
[8] 前記高級脂肪酸が、パルミチン酸及びステアリン酸から選択された少なくとも1種である[1]〜[7]のいずれかに記載の水中油型化粧料。
[9] 前記高級脂肪酸が、ステアリン酸である[1]〜[8]のいずれかに記載の水中油型化粧料。
[10] スキンケア化粧料である[1]〜[9]のいずれかに記載の水中油型化粧料。
[11] 前記ステアリン酸ソルビタンの含有量が、化粧料全質量の0.3質量%〜2質量%である[1]〜[10]のいずれかに記載の水中油型化粧料。
[12] 前記高級アルコール及び高級脂肪酸の含有量が、各々、化粧料全質量の0.5質量%〜5質量%である[1]〜[11]のいずれかに記載の水中油型化粧料。
また、本発明の水中油型化粧料は、更に、高級アルコール及び高級脂肪酸の少なくとも一方を含有するものであって、水添ポリイソブテンの含有量が油相の質量の18質量%〜23質量%であることを要する。
本発明によれば、高粘性の所定の水添ポリイソブテンと、ステアリン酸ソルビタンとを組み合わせることによって、良好な使用感、特にハリ感が付与される。このため、ポリエチレングリコールなどの高分子化合物を使用しなくても、高い使用感を得ることができ、また、固形油や皮膜形成剤を使用する必要がないので、分離や析出などの発生が抑制される。
以下、本発明について説明する。
また、本明細書において「〜」を用いて示された数値範囲は、「〜」の前後に記載される数値をそれぞれ最小値及び最大値として含む範囲を示す。
また、本発明において、組成物中の各成分の量について言及する場合、組成物中に各成分に該当する物質が複数存在する場合には、特に断らない限り、組成物中に存在する当該複数の物質の合計量を意味する。
また、この水添ポリイソブテンは、良好な使用感、特にハリ感の付与の観点から、水中油型化粧料における油相の質量の10質量%〜40質量%であることが好ましく、16質量%〜30質量%であることがより好ましくは、18質量%〜23質量%であることが更に好ましいが、本発明では18質量%〜23質量%であることを要する。
油脂類としては、例えば、硬化ヤシ油、硬化ヒマシ油、パーム油、硬化油、モクロウ等が挙げられる。ロウとしては、例えば、融点68〜72℃のキャンデリラロウ、融点80〜86℃のカルナバロウ、融点60〜67℃のミツロウ、モンタンロウ、ヌカロウ、サトウキビロウ、パームロウ等が挙げられる。炭化水素類としては、例えば、ワセリン、セレシン、パラフィンワックス、マイクロクリスタリンワックス、ポリエチレンワックス、スクワラン、水添ポリデセン、流動パラフィン等が挙げられる。
ステアリン酸ソルビタンは、使用感(特にハリ感)の観点から、水中油型化粧料の全質量の0.3質量%〜2質量%であることが好ましく、0.5質量%〜1.0質量%であることがより好ましい。
また、ステアリン酸ソルビタンの質量に対する上述した所定の水添ポリイソブテンの質量は、使用感の観点から、5倍〜25倍であることが好ましく、9倍〜20倍であることがより好ましい。
ここで、水溶性高分子は、少なくとも0.001質量%程度以上、水(25℃)に溶解する高分子であれば何を用いてもよい。本発明において水溶性高分子を用いることで、水中油型化粧料の安定化を図ることができる。なお、本発明における水溶性高分子とは、従来化粧用組成物に用いられてきたものであり、特に限定されるものではない。
ここで、以下に示す実施例のうち、水添ポリイソブテンの油相中の含有量が18質量%〜23質量%の範囲外であるもの、また、高級アルコール及び高級脂肪酸の少なくとも一方を含まないものは、いずれも参考例とする。
下記の方法により、表1〜表7の示す実施例1〜25及び比較例1〜9の各水中油型化粧料としてクリームを作製した。なお、表1〜表7中の各成分の数値は、質量%を示す。
表1〜表7に記載の処方に従って、油相の各成分を、80℃に加熱して混合し、油相成分を調製した。次いで、表1〜表7に記載の処方に従って、水相の各成分を、80℃に加熱して混合し、調製済みの油相成分を添加して、ホモミキサーにより乳化した。得られた乳化物を30℃にまで冷却して、クリームを得た。
(1)使用感(ハリ感 ハリの持続感 保湿感 保湿の持続感)
専門パネル10名により、上記で得られた各クリームを、顔面に塗布し、塗布直後と、塗布後6時間のそれぞれにおいて、下記評価に基づいてハリ感、及び保湿感を評価した。
◎:専門パネル10名中8名以上10名未満が良好と回答した。
○:専門パネル10名中6名以上8名未満が良好と回答した。
△:専門パネル10名中4名以上6名未満が良好と回答した。
×:専門パネル10名中4名未満が良好と回答した。
上記で得られた各クリームを、100g秤量してガラス瓶に入れて密閉し、40℃/25℃/4℃の環境下でそれぞれ1ヵ月放置した。1ヵ月後に、外観、光学顕微鏡観察、粒度分布測定結果、硬度測定結果に基づいて、それぞれ経時安定性を評価した。評価は下記のとおりとした。
なお、粒度分布測定には、LA−920 HORIBA製を使用し、粒度分布d50(メジアン径)に基づいて評価した。
また硬度測定には、上記で得られたガラス瓶中の各クリームに対して、レオメーター FUDOHを使用し、20φアダプターを20mm進入させたときの硬度変化に基づいて評価した。
それぞれの評価結果を表1〜表7に示す。
○:全く分離がみられない
△:ごくわずかな分離が見られる
×:著しい分離が見られる
(b)光学顕微鏡観察(×1050)
○:凝集や合一による粗大粒子の発生・結晶等の析出がなく、調製直後と同等である
△:凝集や合一による粗大粒子の発生・結晶等の析出が、わずかに見られる
×:凝集や合一による粗大粒子の発生・結晶等の析出が、大量に発生する
○:粒度分布d50が0.5μm以上2.0μm未満である。
△:粒度分布d50が2.0μm以上3.0μm未満である
×:粒度分布d50が3.0μm以上4.0μm以下である
(d)硬度測定
◎:調製直後の状態と比較して、硬度変化が5%未満
○:調製直後の状態と比較して、硬度変化が5%以上15%未満
△:調製直後の状態と比較して、硬度変化が15%以上35%未満
×:調製直後の状態と比較して、硬度変化が35%以上
なお、ポリソルベート60の含有は、通常、ハリ感や保湿感の使用時の持続性に効果が期待される。しかし、実施例20に示されるように、ポリソルベート60を増量しても、高級脂肪酸及び/又は高級アルコールを含有する実施例と比して、ハリ感や保湿感の持続性の効果は得られておらず、本発明においては、高級脂肪酸及び/又は高級アルコールの含有がハリ感や保湿感の持続性の効果に対し、より有効であることが確認できる。
水添ポリイソブテンの代わりに他の油剤である流動パラフィンやワセリンを増量した場合(比較例5、6)や、ステアリン酸ソルビタンの代わりに他の界面活性剤を用いた場合(比較例8、9)でも、ハリ感は得られない。また、100℃における動粘度が200mm2/s〜1000mm2/s以外の水添ポリイソブテン(比較例4、7)では、使用感、安定性共に悪化した。
Claims (12)
- 100℃における動粘度が200mm2/s〜1000mm2/sである水添ポリイソブテンを含む油相と、ステアリン酸ソルビタンと、高級アルコール及び高級脂肪酸の少なくとも一方と、を含有し、前記水添ポリイソブテンの含有量が油相の質量の18質量%〜23質量%であり、油相及び水相から構成された水中油型化粧料。
- 油脂、炭化水素及びロウから選ばれる融点が60℃以上の固形油の合計含有量が0又は化粧料全質量の5質量%未満である請求項1記載の水中油型化粧料。
- 前記油相の含有量が、化粧料全質量の45質量%〜70質量%である請求項1又は請求項2記載の水中油型化粧料。
- 前記水添ポリイソブテンの含有量が、化粧料全質量の5質量%〜20質量%である請求項1又は請求項2記載の水中油型化粧料。
- 高級アルコール及び高級脂肪酸を共に含む請求項1〜請求項4のいずれか1項記載の水中油型化粧料。
- 前記高級アルコールが、ベヘニルアルコール及びステアリルアルコールから選択された少なくとも1種である請求項1〜請求項5のいずれか1項記載の水中油型化粧料。
- 前記高級アルコールが、ベヘニルアルコールである請求項1〜請求項6のいずれか1項記載の水中油型化粧料。
- 前記高級脂肪酸が、パルミチン酸及びステアリン酸から選択された少なくとも1種である請求項1〜請求項7のいずれか1項記載の水中油型化粧料。
- 前記高級脂肪酸が、ステアリン酸である請求項1〜請求項8のいずれか1項記載の水中油型化粧料。
- スキンケア化粧料である請求項1〜請求項9のいずれか1項記載の水中油型化粧料。
- 前記ステアリン酸ソルビタンの含有量が、化粧料全質量の0.3質量%〜2質量%である請求項1〜請求項10のいずれか1項記載の水中油型化粧料。
- 前記高級アルコール及び高級脂肪酸の含有量が、各々、化粧料全質量の0.5質量%〜5質量%である請求項1〜請求項11のいずれか1項記載の水中油型化粧料。
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JP2010207308A JP5676187B2 (ja) | 2010-09-15 | 2010-09-15 | 水中油型化粧料 |
PCT/JP2011/068315 WO2012035915A1 (ja) | 2010-09-15 | 2011-08-10 | 水中油型化粧料 |
EP11824923.4A EP2617410B1 (en) | 2010-09-15 | 2011-08-10 | Oil-in-water type cosmetic |
CN201180044226.6A CN103096871B (zh) | 2010-09-15 | 2011-08-10 | 水包油型化妆材料 |
KR1020137006381A KR101676696B1 (ko) | 2010-09-15 | 2011-08-10 | 수중유형 화장료 |
US13/801,258 US20130189210A1 (en) | 2010-09-15 | 2013-03-13 | Oil-in-water cosmetic |
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FR2858777B1 (fr) * | 2003-08-12 | 2007-02-09 | B Rossow Et Cie Ets | Procede de formulation d'emulsions huile-dans-eau complexes et stables, formulations ainsi obtenues et procede de formulation de produits contenant les dites emulsions |
JP2005089303A (ja) * | 2003-09-12 | 2005-04-07 | Nippon Menaade Keshohin Kk | 複合粉体 |
US8158136B2 (en) * | 2004-08-18 | 2012-04-17 | L'oréal | Emulsification system for use in cosmetics |
TWI365075B (en) * | 2004-09-22 | 2012-06-01 | Kao Corp | Microemulsion |
MX2007011784A (es) * | 2005-03-23 | 2008-03-14 | Mary Kay Inc | Composiciones para aclarar la piel. |
US20060222675A1 (en) * | 2005-03-29 | 2006-10-05 | Sabnis Ram W | Personal care compositions with color changing indicator |
JP4934304B2 (ja) * | 2005-09-15 | 2012-05-16 | 株式会社バスクリン | 鎮痒剤組成物 |
CN103961278A (zh) * | 2006-01-19 | 2014-08-06 | 玫琳凯有限公司 | 包括卡卡杜李提取物或巴西莓提取物的组合物 |
JP2009529032A (ja) * | 2006-03-06 | 2009-08-13 | ザ プロクター アンド ギャンブル カンパニー | 親油性パーソナルケア組成物 |
JP5138896B2 (ja) | 2006-03-28 | 2013-02-06 | 株式会社コーセー | 水中油型乳化化粧料 |
JP2008050271A (ja) * | 2006-08-22 | 2008-03-06 | Shiseido Co Ltd | メーキャップ化粧料 |
US20090036546A1 (en) * | 2007-07-31 | 2009-02-05 | Chevron U.S.A. Inc. | Medicinal Oil Compositions, Preparations, and Applications Thereof |
JP5277011B2 (ja) * | 2008-02-13 | 2013-08-28 | 株式会社 資生堂 | 水中油型乳化白濁皮膚化粧料 |
JP2009234971A (ja) | 2008-03-26 | 2009-10-15 | Kose Corp | 水中油型乳化化粧料 |
JP2009242269A (ja) * | 2008-03-31 | 2009-10-22 | Kose Corp | 水中油型乳化化粧料 |
JP2010207308A (ja) | 2009-03-09 | 2010-09-24 | Mrd Co Ltd | 遊技機の画像表示装置 |
JP5174789B2 (ja) * | 2009-11-25 | 2013-04-03 | 花王株式会社 | O/w型乳化化粧料 |
-
2010
- 2010-09-15 JP JP2010207308A patent/JP5676187B2/ja active Active
-
2011
- 2011-08-10 EP EP11824923.4A patent/EP2617410B1/en not_active Not-in-force
- 2011-08-10 KR KR1020137006381A patent/KR101676696B1/ko active IP Right Grant
- 2011-08-10 CN CN201180044226.6A patent/CN103096871B/zh active Active
- 2011-08-10 WO PCT/JP2011/068315 patent/WO2012035915A1/ja active Application Filing
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Also Published As
Publication number | Publication date |
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KR20130136979A (ko) | 2013-12-13 |
CN103096871A (zh) | 2013-05-08 |
EP2617410B1 (en) | 2017-12-27 |
WO2012035915A1 (ja) | 2012-03-22 |
EP2617410A1 (en) | 2013-07-24 |
JP2012062274A (ja) | 2012-03-29 |
CN103096871B (zh) | 2015-09-16 |
EP2617410A4 (en) | 2015-11-18 |
KR101676696B1 (ko) | 2016-11-16 |
US20130189210A1 (en) | 2013-07-25 |
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