JP5675971B2 - カチオン性ポリマーを含む可溶の1回用量物品 - Google Patents
カチオン性ポリマーを含む可溶の1回用量物品 Download PDFInfo
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- JP5675971B2 JP5675971B2 JP2013516755A JP2013516755A JP5675971B2 JP 5675971 B2 JP5675971 B2 JP 5675971B2 JP 2013516755 A JP2013516755 A JP 2013516755A JP 2013516755 A JP2013516755 A JP 2013516755A JP 5675971 B2 JP5675971 B2 JP 5675971B2
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- 235000019865 palm kernel oil Nutrition 0.000 description 1
- 108010087558 pectate lyase Proteins 0.000 description 1
- 238000001935 peptisation Methods 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-O phosphonium Chemical compound [PH4+] XYFCBTPGUUZFHI-UHFFFAOYSA-O 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical group 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical class N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 239000001007 phthalocyanine dye Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000006187 pill Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920001983 poloxamer Polymers 0.000 description 1
- 229920000712 poly(acrylamide-co-diallyldimethylammonium chloride) Polymers 0.000 description 1
- 229920000233 poly(alkylene oxides) Polymers 0.000 description 1
- 229920001308 poly(aminoacid) Polymers 0.000 description 1
- 229920002401 polyacrylamide Polymers 0.000 description 1
- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229940113115 polyethylene glycol 200 Drugs 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920000193 polymethacrylate Polymers 0.000 description 1
- 229920000098 polyolefin Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920005996 polystyrene-poly(ethylene-butylene)-polystyrene Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- MYGBBCKCTXSGOB-UHFFFAOYSA-M potassium;2-propan-2-ylbenzenesulfonate Chemical compound [K+].CC(C)C1=CC=CC=C1S([O-])(=O)=O MYGBBCKCTXSGOB-UHFFFAOYSA-M 0.000 description 1
- GHKGUEZUGFJUEJ-UHFFFAOYSA-M potassium;4-methylbenzenesulfonate Chemical compound [K+].CC1=CC=C(S([O-])(=O)=O)C=C1 GHKGUEZUGFJUEJ-UHFFFAOYSA-M 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- KEJZDYLNJACYGU-UHFFFAOYSA-N prop-2-enamide;trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].NC(=O)C=C.CC(=C)C(=O)NCCC[N+](C)(C)C KEJZDYLNJACYGU-UHFFFAOYSA-N 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- HFHDHCJBZVLPGP-UHFFFAOYSA-N schardinger α-dextrin Chemical compound O1C(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC(C(O)C2O)C(CO)OC2OC(C(C2O)O)C(CO)OC2OC2C(O)C(O)C1OC2CO HFHDHCJBZVLPGP-UHFFFAOYSA-N 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 229940079842 sodium cumenesulfonate Drugs 0.000 description 1
- 229940048842 sodium xylenesulfonate Drugs 0.000 description 1
- KVCGISUBCHHTDD-UHFFFAOYSA-M sodium;4-methylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1 KVCGISUBCHHTDD-UHFFFAOYSA-M 0.000 description 1
- QEKATQBVVAZOAY-UHFFFAOYSA-M sodium;4-propan-2-ylbenzenesulfonate Chemical compound [Na+].CC(C)C1=CC=C(S([O-])(=O)=O)C=C1 QEKATQBVVAZOAY-UHFFFAOYSA-M 0.000 description 1
- 239000012453 solvate Substances 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000008399 tap water Substances 0.000 description 1
- 235000020679 tap water Nutrition 0.000 description 1
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-O triethanolammonium Chemical compound OCC[NH+](CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-O 0.000 description 1
- 150000003673 urethanes Chemical class 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 229940071104 xylenesulfonate Drugs 0.000 description 1
- 108010083879 xyloglucan endo(1-4)-beta-D-glucanase Proteins 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/04—Detergent materials or soaps characterised by their shape or physical properties combined with or containing other objects
- C11D17/041—Compositions releasably affixed on a substrate or incorporated into a dispensing means
- C11D17/042—Water soluble or water disintegrable containers or substrates containing cleaning compositions or additives for cleaning compositions
- C11D17/043—Liquid or thixotropic (gel) compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
- C11D1/831—Mixtures of non-ionic with anionic compounds of sulfonates with ethers of polyoxyalkylenes without phosphates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D10/00—Compositions of detergents, not provided for by one single preceding group
- C11D10/04—Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/0004—Non aqueous liquid compositions comprising insoluble particles
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/22—Carbohydrates or derivatives thereof
- C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
- C11D3/227—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with nitrogen-containing groups
-
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3723—Polyamines or polyalkyleneimines
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- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3746—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/3769—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
- C11D3/3773—(Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines in liquid compositions
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- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/38—Products with no well-defined composition, e.g. natural products
- C11D3/386—Preparations containing enzymes, e.g. protease or amylase
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- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/225—Polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
-
- C—CHEMISTRY; METALLURGY
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
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- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
- C11D1/721—End blocked ethers
-
- C11D2111/12—
Description
カチオン性ポリマーと脂肪酸又は塩とを含む非水性液体組成物を、液体入り区画を少なくとも1つ含む1回用量物品に含有させる。液体充填区画とは、例えば衣類などの繊維を湿潤させることが可能な液体を含む1回用量物品の仕切を指す。このような1回用量物品は、カチオン性セルロースポリマー及びセルラーゼ酵素が非水性組成物に組み込まれ、水溶性又は水分散性フィルムに封入されているなどのような、単独で容易に使用することのできる剤型からなる。
本明細書で使用するとき、「非水性液体組成物」は、20重量%未満、好ましくは15重量%未満、より好ましくは12重量%未満、最も好ましくは8重量%未満の水を含む任意の液体組成物を指す。例えば、他の構成成分による持ち込みに由来する量を超える追加の水を含有しない。同様に、用語「液体」は、ゲル及びペーストなどの粘稠な形態も包含する。非水性液体には、好適に小分けすることのできる他の固体又は気体も包含され得るが、但し全く液体でない錠剤又は顆粒などの形態は除外される。
本発明の1回用量物品には、0.01重量%〜20重量%、好ましくは0.1重量%〜15重量%、より好ましくは0.6重量%〜10重量%のカチオン性ポリマーを含み得る。
a.mは20〜10,000の整数であり、
b.各R4はHであり、かつR1、R2、R3は各々独立して、H、C1〜C32アルキル、C1〜C32置換アルキル、C5〜C32若しくはC6〜C32アリール、C5〜C32若しくはC6〜C32置換アリール、又はC6〜C32アルキルアリール、又はC6〜C32置換アルキルアリール及び
(式中、
nは0〜10から選択される整数であり、
RxはR5、
式中、前記多糖類に含まれる少なくとも1つのRxは、
A−は好適なアニオンである)。好ましくは、A−は、Cl−、Br−、I−、メチルスルファート、エチルスルファート、トルエンスルホネート、カルボキシレート、及びホスフェートからなる群から選択され、
Zはカルボキシレートホスフェート、ホスホネート、及びサルフェートからなる群から選択され、
qは1〜4から選択される整数であり、
各R5は、H、C1〜C32アルキル、C1〜C32置換アルキル、C5〜C32若しくはC6〜C32アリール、C5〜C32若しくはC6〜C32置換アリール、C6〜C32アルキルアリール、C6〜C32置換アルキルアリール、及びOHからなる群から独立して選択される)。好ましくは、各R5は、H、C1〜C32アルキル、及びC1〜C32置換アルキルからなる群から選択される。より好ましくは、R5は、H、メチル、及びエチルからなる群から選択される。
上記多糖中の各vは1〜10の整数である。好ましくは、vは1〜5の整数である。上記多糖中の各Rxの添字vの総合計は1〜30の整数であり、より好ましくは1〜20、更により好ましくは1〜10である。鎖中の最後の
式中、各R2は、水素、ヒドロキシル、ハロゲン、C1〜C12アルキル、−ORa、置換又は非置換フェニル、置換又は非置換ベンジル、炭素環、複素環、及びこれらの組み合わせからなる群から独立して選択される。R2は、好ましくは、水素、C1〜C4アルキル、及びこれらの組み合わせからなる群から選択される。
各R4は、独立して、水素、C1〜C24アルキル、
カチオン性ポリマーに加えて、1回用量物品の非水性組成物は、0.2重量%〜40重量%、好ましくは0.5重量%〜30重量%、より好ましくは1重量%〜20重量%の脂肪酸又はその塩を含み得る。好適な脂肪酸及び塩としては、次式を有するものが挙げられる:
R1COOM
(式中、R1は4〜30個炭素原子を含有している一級又は二級アルキル基であり、かつMは水素カチオン又はその他の可溶性カチオンである)。酸(式中、Mは水素カチオンである)が好適であるものの、塩の方がカチオン性ポリマーに対しより親和性が大きいことから、塩も好ましい。したがって、脂肪酸又は塩は、好ましくは、脂肪酸又は塩のpKaが非水性液体組成物のpH未満になるように選択される。この理由から、非水性組成物のpHは、好ましくは6〜10.5、より好ましくは6.5〜9、最も好ましくは7〜8である。
本発明の1回用量物品は、アニオン性及び非イオン性界面活性剤、追加の界面活性剤、酵素、酵素安定剤、両親媒性アルコキシル化グリース洗浄ポリマー、粘土汚れ洗浄ポリマー、汚れ遊離ポリマー、汚れ懸濁ポリマー、漂白系、蛍光増白剤、色相染料、分散粒子、香料及び他の臭気制御剤、ヒドロトロープ、抑泡剤、布地ケア有益剤、pH調整剤、移染防止剤、保存料、非織物直接染料及びこれらの混合物からなる群から選択される従来の洗濯洗剤成分を含んでよい。使用することのできる一部の追加成分を、以下の通りに更に詳細に記載する:
アニオン性及び非イオン性界面活性剤:本発明の1回用量物品は、1重量%〜70重量%、好ましくは10重量%〜50重量%、及びより好ましくは15重量%〜45重量%のアニオン性及び/又は非イオン性界面活性剤を含んでもよい。
他の成分と組み合わせる前にカチオン性ポリマー及び脂肪酸又は塩を予混合することで、カチオン性ポリマーが水溶性又は水分散性フィルムと複合体を形成する可能性は更に低下する。したがって、本発明は、カチオン性ポリマーを脂肪酸又は塩と予混合して、カチオン性ポリマー/脂肪酸プレミックスを形成する工程と、カチオン性ポリマー及び脂肪酸又は塩のプレミックスを非水性液体フィードと組み合わせて非水性液体組成物を形成する工程と、非水性液体組成物を水溶性又は水分散性フィルムに封入する工程と、を含む、1回用量物品の好ましい製造方法も提供する。
1)pH測定:
ゲル充填プローブ(Toledoプローブ、部品番号52 000 100など)を取り付け、取扱説明書に記載の手順に従って較正したSantarius PT−10P pHメーターを用い未希釈組成物のpHを25℃にて測定する。
Occhio Flow Cell FC200−S(Angleur,Belgium)を使用して粒度分布を測定する。解析される粒子を含有しているサンプルをPEG200により2重量%に希釈して、確実に単独の粒子が検出されるようにする。装置について提供されている取扱説明書に従って、2mLの希釈サンプルを分析する。
5.0グラム±0.1グラムの水溶性又は水分散性フィルムを、予め重量を測った400mLのビーカーに入れ、245mL±1mLの蒸留水を添加する。これを、600rpmに設定した磁性撹拌器で、30分間激しく撹拌する。次いで、最大で20マイクロメートルの孔径を有する焼結ガラスフィルターを通して混合物を濾過する。回収した濾液からいずれかの従来法によって水を乾燥させ、残った材料の重量を測定する(これが溶解又は分散画分である)。次いで、溶解度又は分散度%を計算することができる。
フィルムを裁断し、スライド枠に合わせて折り畳んだ24mm×36mm透明陽画フィルム(diapositive film)をガラスは用いずにスライドに載せる(品番94.000.07、Else(The Netherlands)により市販、但し、他の供給元から市販されるプラスチック製折り畳み枠も使用することができる)。
2 Rhodia,Inc(Cranbury NJ)
3 BASF Corporation(North Mount Olive,NJ)
4 JR30M粒子形態のLK400,非水性分散剤(Pluriol E200)懸濁液として添加
5 粒子形態のLupasol SK,非水性分散剤(Pluriol E200)懸濁液として添加
Claims (15)
- 1回用量物品であって、
a)0.1重量%〜15重量%のカチオン性ポリマーであって、前記カチオン性ポリマーが、カチオン性ヒドロキシエチルセルロースであり、かつ粒子形態で存在するカチオン性ポリマーと、
b)0.2重量%〜40重量%の脂肪酸又は塩と、
c)0.01重量%〜10重量%の、非ポリマー結晶性ヒドロキシル官能性構造化剤、高分子構造化剤、およびこれらの混合物からなる群から選択される外部構造化系と、
d)10重量%〜70重量%のアニオン性及び/又は非イオン性界面活性剤と、
e)非水性溶媒と、
を含む非水性液体組成物を含み、
前記非水性液体組成物が、15%未満の水を含み、かつ水溶性又は水分散性フィルムに封入される、1回用量物品。 - 前記非水性液体組成物が、12%未満の水を含む、請求項1に記載の1回用量物品。
- 前記非水性液体組成物が、8%未満の水を含む、請求項1に記載の1回用量物品。
- 0.6重量%〜10重量%の前記カチオン性ポリマーを含む、請求項1〜3のいずれか一項に記載の1回用量物品。
- 0.5重量%〜30重量%の前記脂肪酸又はその塩を含む、請求項1〜4のいずれか一項に記載の1回用量物品。
- 1重量%〜20重量%の前記脂肪酸又はその塩を含む、請求項1〜4のいずれか一項に記載の1回用量物品。
- 前記非水性組成物のpHが、6〜10.5である、請求項1〜6のいずれか一項に記載の1回用量物品。
- 前記非水性組成物のpHが、6.5〜9である、請求項1〜6のいずれか一項に記載の1回用量物品。
- 前記非水性組成物のpHが、7〜8である、請求項1〜6のいずれか一項に記載の1回用量物品。
- 前記水溶性又は水分散性フィルムが、ポリビニルアルコール、ポリビニルアルコールコポリマー、ヒドロキシプロピルメチルセルロース(HPMC)、及びこれらの混合物を含む、請求項1〜9のいずれか一項に記載の1回用量物品。
- 前記非水性溶媒が、ポリアルキレングリコールである、請求項1〜10のいずれか一項に記載の1回用量物品。
- 前記ポリアルキレングリコールが、ポリエチレングリコールである、請求項11に記載の1回用量物品。
- 前記外部構造化系が、結晶化可能グリセリドである、請求項1〜12のいずれか一項に記載の1回用量物品。
- 前記一回用量物品が、複数区画の1回用量形態である、請求項1〜13のいずれか一項に記載の1回用量物品。
- 請求項1〜14のいずれか一項に記載の1回用量物品を調製するための方法であって、
a.前記カチオン性ポリマーを前記脂肪酸又は塩と予混合して、前記カチオン性ポリマー及び脂肪酸プレミックスのプレミックスを形成する工程と、
b.前記カチオン性ポリマー/脂肪酸又は塩プレミックスを非水性液体フィードと組み合わせて非水性液体組成物を形成する工程と、
c.前記非水性液体組成物を水溶性又は水分散性フィルムに封入する工程と、を含むことを特徴とする、方法。
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- 2010-06-24 EP EP10167234.3A patent/EP2399979B2/en active Active
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RU2012148752A (ru) | 2014-07-27 |
ZA201208667B (en) | 2014-04-30 |
MX353036B (es) | 2017-12-18 |
PL2399979T3 (pl) | 2015-03-31 |
EP2399979A1 (en) | 2011-12-28 |
EP2399979B2 (en) | 2021-12-29 |
EP2399979B1 (en) | 2014-10-15 |
US20150057210A1 (en) | 2015-02-26 |
ES2527679T5 (es) | 2022-04-19 |
US8889610B2 (en) | 2014-11-18 |
RU2543718C2 (ru) | 2015-03-10 |
CN105820885A (zh) | 2016-08-03 |
MX2012015197A (es) | 2013-01-24 |
ES2527679T3 (es) | 2015-01-28 |
CA2800008A1 (en) | 2011-12-29 |
BR112012032888A2 (pt) | 2016-11-29 |
US20110319311A1 (en) | 2011-12-29 |
PL2399979T5 (pl) | 2022-05-30 |
BR112012032888B1 (pt) | 2020-10-20 |
JP2013534554A (ja) | 2013-09-05 |
CA2800008C (en) | 2015-07-14 |
AR081983A1 (es) | 2012-10-31 |
WO2011163428A1 (en) | 2011-12-29 |
CN107603748A (zh) | 2018-01-19 |
CN102959070A (zh) | 2013-03-06 |
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