JP5611593B2 - アモルファス金属の製品を製造する方法 - Google Patents
アモルファス金属の製品を製造する方法 Download PDFInfo
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- 239000005300 metallic glass Substances 0.000 title claims description 27
- 238000000034 method Methods 0.000 title claims description 24
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- 239000000843 powder Substances 0.000 claims description 43
- 238000001816 cooling Methods 0.000 claims description 24
- 229910052751 metal Inorganic materials 0.000 claims description 21
- 239000002184 metal Substances 0.000 claims description 20
- 239000000463 material Substances 0.000 claims description 15
- 229910045601 alloy Inorganic materials 0.000 claims description 14
- 239000000956 alloy Substances 0.000 claims description 14
- 229910052796 boron Inorganic materials 0.000 claims description 11
- 230000005855 radiation Effects 0.000 claims description 11
- 239000003507 refrigerant Substances 0.000 claims description 11
- 238000002844 melting Methods 0.000 claims description 9
- 230000008018 melting Effects 0.000 claims description 9
- 229910052758 niobium Inorganic materials 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- 229910006291 Si—Nb Inorganic materials 0.000 claims description 4
- 229910052804 chromium Inorganic materials 0.000 claims description 4
- 229910052733 gallium Inorganic materials 0.000 claims description 4
- 238000010309 melting process Methods 0.000 claims description 4
- 229910052750 molybdenum Inorganic materials 0.000 claims description 4
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 229910017944 Ag—Cu Inorganic materials 0.000 claims description 2
- 229910017755 Cu-Sn Inorganic materials 0.000 claims description 2
- 229910017870 Cu—Ni—Al Inorganic materials 0.000 claims description 2
- 229910017927 Cu—Sn Inorganic materials 0.000 claims description 2
- 229910008813 Sn—Si Inorganic materials 0.000 claims description 2
- 238000010276 construction Methods 0.000 claims description 2
- 229910052763 palladium Inorganic materials 0.000 claims description 2
- 229910052715 tantalum Inorganic materials 0.000 claims description 2
- 229910052723 transition metal Inorganic materials 0.000 claims description 2
- 150000003624 transition metals Chemical class 0.000 claims description 2
- 229910052718 tin Inorganic materials 0.000 claims 1
- 239000000155 melt Substances 0.000 description 8
- 239000002245 particle Substances 0.000 description 8
- 238000010894 electron beam technology Methods 0.000 description 7
- 238000005266 casting Methods 0.000 description 4
- 150000002739 metals Chemical class 0.000 description 4
- 239000007790 solid phase Substances 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- 229910052582 BN Inorganic materials 0.000 description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- 239000012298 atmosphere Substances 0.000 description 2
- 239000002826 coolant Substances 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000000113 differential scanning calorimetry Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910000808 amorphous metal alloy Inorganic materials 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000012300 argon atmosphere Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 229910001337 iron nitride Inorganic materials 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013526 supercooled liquid Substances 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C45/00—Amorphous alloys
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/006—Amorphous articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F12/00—Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
- B22F12/20—Cooling means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y10/00—Processes of additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y30/00—Apparatus for additive manufacturing; Details thereof or accessories therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B33—ADDITIVE MANUFACTURING TECHNOLOGY
- B33Y—ADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
- B33Y70/00—Materials specially adapted for additive manufacturing
- B33Y70/10—Composites of different types of material, e.g. mixtures of ceramics and polymers or mixtures of metals and biomaterials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/20—Direct sintering or melting
- B22F10/28—Powder bed fusion, e.g. selective laser melting [SLM] or electron beam melting [EBM]
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F10/00—Additive manufacturing of workpieces or articles from metallic powder
- B22F10/30—Process control
- B22F10/32—Process control of the atmosphere, e.g. composition or pressure in a building chamber
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F12/00—Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
- B22F12/22—Driving means
- B22F12/222—Driving means for motion along a direction orthogonal to the plane of a layer
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F12/00—Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
- B22F12/22—Driving means
- B22F12/224—Driving means for motion along a direction within the plane of a layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F12/00—Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
- B22F12/50—Means for feeding of material, e.g. heads
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F12/00—Apparatus or devices specially adapted for additive manufacturing; Auxiliary means for additive manufacturing; Combinations of additive manufacturing apparatus or devices with other processing apparatus or devices
- B22F12/60—Planarisation devices; Compression devices
- B22F12/67—Blades
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/25—Process efficiency
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Structural Engineering (AREA)
- Composite Materials (AREA)
- Civil Engineering (AREA)
- Ceramic Engineering (AREA)
- Powder Metallurgy (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Description
本発明によれば、金属粉末の層が、熱伝導ベースに適用(塗布)され、前記層の限定されたエリアが放射銃(radiation gun)によって融解され、その融解したエリアがアモルファス金属の状態に凝固するように、そのエリアが冷却される。この融解プロセスはアモルファス金属の連続的な層が形成されるまで、粉末層の新しい限定されたエリア上に逐次的に繰り返される。その後新しい粉末層が適用され、三次元物体の逐次的な(段階的な)構築のために、前記方法が繰り返されて、新しい層が下層のアモルファス金属に融合される。
好ましくは、熱伝導ベースは冷媒(水など)によって冷却される。例えば、作業台は、ヒートシンク/作業台に吸収された熱を継続的に偏向できるように、冷媒が通過する冷却用ダクトを備えることができる。
Ni-Nb-Sn
Co-Fe-Ta-B
Ca-Mg-Ag-Cu
Co-Fe-B-Si-Nb
Fe-Ga-(Cr,Mo)-(P,C,B)
Ti-Ni-Cu-Sn
Fe-Co-Ln-B
Co-(Al,Ga)-(P,B,Si)
Fe-B-Si-Nb
Ni-(Nb,Ta)-Zr-Ti
Ni-Zr-Ti-Sn-Si
Fe-Ga-(P,B)
Co-Ta-B
Ni-(Nb,Cr,Mo)-(P,B)
Fe-(Al,Ga)-(P,C,B,Si,Ge)
Zr-Ti-Cu-Ni-Al
Zr-(Ti,Nb,Pd)-Al-TM
Zr-Ti-TM-Be
Ti-Zr-TM
Zr-Al-TM
Mg-Ln-M
TM=遷移金属 M=金属
好ましくは、前記金属粉末は、通常、イノウエ合金(Inoue alloy)とも称される第二世代のアモルファス合金である。
放射銃は、YAGレーザーなどの高出力レーザー、もしくは電子ビームであってもよい。
Claims (10)
- 全体もしくは選択された部分がアモルファス金属からなる三次元物体を製造する方法であって、
金属粉末層(4)が熱伝導ベース(1,13)に適用され、当該層の限定エリアが放射銃(5)によって融解され、当該融解されたエリアをアモルファス金属の状態に凝固させるために当該エリアが冷却されること、
上記融解プロセスが、アモルファス金属の連続的な層が形成されるまで、前記粉末層の新しい限定エリア上にて逐次的に繰り返されること、および、
新しい粉末層(4)が適用され、前記三次元物体の逐次的な構築のために、上述の方法が繰り返されて、前記新しい層が下層のアモルファス金属に融着されること
を特徴とする方法。 - 前記アモルファス金属の連続的な層が、前記三次元物体の断面に対応することを特徴とする、請求項1に記載の方法。
- 最初の粉末層(4)が熱伝導ベース(1,13)に融着されることを特徴とする、請求項1または2に記載の方法。
- 前記熱伝導ベースが、完成後の三次元物体の一部をなす、アモルファス金属もしくは結晶性金属の物体(13)であって、その一部にアモルファス金属が追加されることを特徴とする、請求項1〜3のいずれか1項に記載の方法。
- 前記熱伝導ベースが作業台(1)であることを特徴とする、請求項1〜3のいずれか1項に記載の方法。
- 前記熱伝導ベース(1,13)が高熱伝導度の材質からなり、前記粉末層の融解エリアを迅速に冷却するヒートシンクとしての機能を果たすことを特徴とする、請求項1〜5のいずれか1項に記載の方法。
- 前記金属粉末が、
Ni-Nb-Sn、Co-Fe-Ta-B、Ca-Mg-Ag-Cu、Co-Fe-B-Si-Nb、Fe-Ga-(Cr,Mo)-(P,C,B)、Ti-Ni-Cu-Sn、Fe-Co-Ln-B、Co-(Al,Ga)-(P,B,Si)、Fe-B-Si-Nb、Ni-(Nb,Ta)-Zr-Ti、Ni-Zr-Ti-Sn-Si、Fe-Ga-(P,B)、Co-Ta-B、Ni-(Nb,Cr,Mo)-(P,B)、Fe-(Al,Ga)-(P,C,B,Si,Ge)、Zr-Ti-Cu-Ni-Al、Zr-(Ti,Nb,Pd)-Al-TM、Zr-Ti-TM-Be、Ti-Zr-TM、Zr-Al-TM、Mg-Ln-M(TMは遷移金属を意味し、Mは金属を意味する)
からなる群から選択される合金からなることを特徴とする、請求項1〜6のいずれか1項に記載の方法。 - 前記熱伝導ベース(1,13)が冷媒によって冷却されることを特徴とする、請求項1〜7のいずれか1項に記載の方法。
- 前記冷媒が、熱伝導ベース内の冷却用ダクト(10)を通過することを特徴とする、請求項8に記載の方法。
- 前記冷媒が、前記熱伝導ベースを取り巻く冷却コイル(15)を通過することを特徴とする、請求項8に記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SE0602001A SE530323C2 (sv) | 2006-09-26 | 2006-09-26 | Sätt att framställa föremål av amorf metall |
SE0602001-0 | 2006-09-26 | ||
PCT/SE2007/000844 WO2008039134A1 (en) | 2006-09-26 | 2007-09-26 | Method of producing products of amorphous metal |
Publications (3)
Publication Number | Publication Date |
---|---|
JP2010505041A JP2010505041A (ja) | 2010-02-18 |
JP2010505041A5 JP2010505041A5 (ja) | 2010-10-14 |
JP5611593B2 true JP5611593B2 (ja) | 2014-10-22 |
Family
ID=39230452
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2009530307A Active JP5611593B2 (ja) | 2006-09-26 | 2007-09-26 | アモルファス金属の製品を製造する方法 |
Country Status (7)
Country | Link |
---|---|
US (1) | US8052923B2 (ja) |
EP (1) | EP2081714B1 (ja) |
JP (1) | JP5611593B2 (ja) |
ES (1) | ES2525686T3 (ja) |
PL (1) | PL2081714T3 (ja) |
SE (1) | SE530323C2 (ja) |
WO (1) | WO2008039134A1 (ja) |
Cited By (2)
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US11773475B2 (en) | 2017-06-02 | 2023-10-03 | California Institute Of Technology | High toughness metallic glass-based composites for additive manufacturing |
US11905578B2 (en) | 2017-05-24 | 2024-02-20 | California Institute Of Technology | Hypoeutectic amorphous metal-based materials for additive manufacturing |
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JP5760222B2 (ja) * | 2011-03-31 | 2015-08-05 | 地方独立行政法人大阪府立産業技術総合研究所 | 金属ガラス成形体の製造方法 |
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US11905578B2 (en) | 2017-05-24 | 2024-02-20 | California Institute Of Technology | Hypoeutectic amorphous metal-based materials for additive manufacturing |
US11773475B2 (en) | 2017-06-02 | 2023-10-03 | California Institute Of Technology | High toughness metallic glass-based composites for additive manufacturing |
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ES2525686T3 (es) | 2014-12-29 |
EP2081714A1 (en) | 2009-07-29 |
EP2081714B1 (en) | 2014-10-29 |
WO2008039134A1 (en) | 2008-04-03 |
SE530323C2 (sv) | 2008-05-06 |
JP2010505041A (ja) | 2010-02-18 |
US20090277540A1 (en) | 2009-11-12 |
US8052923B2 (en) | 2011-11-08 |
PL2081714T3 (pl) | 2015-04-30 |
SE0602001L (sv) | 2008-03-27 |
EP2081714A4 (en) | 2011-12-21 |
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