JP5593073B2 - ゴム組成物、その作製プロセス、およびそれから作られる製品 - Google Patents
ゴム組成物、その作製プロセス、およびそれから作られる製品 Download PDFInfo
- Publication number
- JP5593073B2 JP5593073B2 JP2009549096A JP2009549096A JP5593073B2 JP 5593073 B2 JP5593073 B2 JP 5593073B2 JP 2009549096 A JP2009549096 A JP 2009549096A JP 2009549096 A JP2009549096 A JP 2009549096A JP 5593073 B2 JP5593073 B2 JP 5593073B2
- Authority
- JP
- Japan
- Prior art keywords
- group
- triethoxysilane
- silane
- tributoxysilane
- rubber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 169
- 239000005060 rubber Substances 0.000 title claims abstract description 165
- 239000000203 mixture Substances 0.000 title claims abstract description 121
- 238000000034 method Methods 0.000 title claims abstract description 40
- 230000008569 process Effects 0.000 title claims abstract description 30
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 125
- 229910000077 silane Inorganic materials 0.000 claims abstract description 97
- 239000000945 filler Substances 0.000 claims abstract description 86
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 42
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 36
- 239000011593 sulfur Chemical group 0.000 claims abstract description 36
- 239000001257 hydrogen Substances 0.000 claims abstract description 30
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 30
- 238000002156 mixing Methods 0.000 claims abstract description 29
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 25
- 125000003118 aryl group Chemical group 0.000 claims abstract description 25
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 20
- 125000003710 aryl alkyl group Chemical group 0.000 claims abstract description 18
- 125000005842 heteroatom Chemical group 0.000 claims abstract description 15
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 14
- 239000001301 oxygen Substances 0.000 claims abstract description 14
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 11
- 125000005843 halogen group Chemical group 0.000 claims abstract description 10
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims abstract description 6
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 6
- 239000010703 silicon Substances 0.000 claims abstract description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 112
- 239000000377 silicon dioxide Substances 0.000 claims description 54
- -1 transition metal salt Chemical class 0.000 claims description 45
- 239000006229 carbon black Substances 0.000 claims description 22
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 15
- 244000043261 Hevea brasiliensis Species 0.000 claims description 14
- 150000002431 hydrogen Chemical class 0.000 claims description 14
- 229920003052 natural elastomer Polymers 0.000 claims description 14
- 229920001194 natural rubber Polymers 0.000 claims description 14
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 13
- 229910052799 carbon Inorganic materials 0.000 claims description 13
- 229920002554 vinyl polymer Polymers 0.000 claims description 13
- 229920001577 copolymer Polymers 0.000 claims description 12
- 229920003244 diene elastomer Polymers 0.000 claims description 12
- 229920002857 polybutadiene Polymers 0.000 claims description 12
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 12
- KAKZBPTYRLMSJV-UHFFFAOYSA-N vinyl-ethylene Natural products C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 12
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Natural products CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 11
- 239000000463 material Substances 0.000 claims description 11
- 239000000047 product Substances 0.000 claims description 11
- 239000012190 activator Substances 0.000 claims description 10
- UCSBCWBHZLSFGC-UHFFFAOYSA-N tributoxysilane Chemical compound CCCCO[SiH](OCCCC)OCCCC UCSBCWBHZLSFGC-UHFFFAOYSA-N 0.000 claims description 10
- 239000005062 Polybutadiene Substances 0.000 claims description 9
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 9
- 229910000323 aluminium silicate Inorganic materials 0.000 claims description 9
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 claims description 9
- 229920000620 organic polymer Polymers 0.000 claims description 9
- 150000001993 dienes Chemical class 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 125000004122 cyclic group Chemical group 0.000 claims description 7
- JSFVRHAXCYPWRJ-UHFFFAOYSA-N 2-[4-(chloromethyl)phenyl]ethyl-triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=C(CCl)C=C1 JSFVRHAXCYPWRJ-UHFFFAOYSA-N 0.000 claims description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 6
- 229920001897 terpolymer Polymers 0.000 claims description 6
- IOLWRXMELRWXQY-UHFFFAOYSA-N 2-[4-(chloromethyl)phenyl]ethyl-trimethoxysilane Chemical compound CO[Si](OC)(OC)CCC1=CC=C(CCl)C=C1 IOLWRXMELRWXQY-UHFFFAOYSA-N 0.000 claims description 5
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 5
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical group [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 5
- 229910044991 metal oxide Inorganic materials 0.000 claims description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims description 5
- 239000011574 phosphorus Chemical group 0.000 claims description 5
- 229920003051 synthetic elastomer Polymers 0.000 claims description 5
- 229910052723 transition metal Inorganic materials 0.000 claims description 5
- CJTQAHPKGZJFOW-UHFFFAOYSA-N 2-[3-(chloromethyl)phenyl]ethyl-triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=CC(CCl)=C1 CJTQAHPKGZJFOW-UHFFFAOYSA-N 0.000 claims description 4
- JCWHKFPEYMEQST-UHFFFAOYSA-N 2-[4-(1-chloropropyl)phenyl]ethyl-trimethoxysilane Chemical compound CCC(Cl)C1=CC=C(CC[Si](OC)(OC)OC)C=C1 JCWHKFPEYMEQST-UHFFFAOYSA-N 0.000 claims description 4
- 239000000178 monomer Substances 0.000 claims description 4
- 239000004408 titanium dioxide Substances 0.000 claims description 4
- GVNVAWHJIKLAGL-UHFFFAOYSA-N 2-(cyclohexen-1-yl)cyclohexan-1-one Chemical compound O=C1CCCCC1C1=CCCCC1 GVNVAWHJIKLAGL-UHFFFAOYSA-N 0.000 claims description 3
- FCTNNRVMOMWRLR-UHFFFAOYSA-N 2-[3-(1-bromoethyl)phenyl]ethyl-triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=CC(C(C)Br)=C1 FCTNNRVMOMWRLR-UHFFFAOYSA-N 0.000 claims description 3
- QUFZCQMLDYDAHX-UHFFFAOYSA-N 2-[3-(1-bromoethyl)phenyl]ethyl-trimethoxysilane Chemical compound CO[Si](OC)(OC)CCC1=CC=CC(C(C)Br)=C1 QUFZCQMLDYDAHX-UHFFFAOYSA-N 0.000 claims description 3
- MIVUPHDBZKHSOG-UHFFFAOYSA-N 2-[3-(1-bromopropyl)phenyl]ethyl-tributoxysilane Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCC1=CC=CC(C(Br)CC)=C1 MIVUPHDBZKHSOG-UHFFFAOYSA-N 0.000 claims description 3
- DRGFJXRHBGKHQY-UHFFFAOYSA-N 2-[3-(1-bromopropyl)phenyl]ethyl-triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=CC(C(Br)CC)=C1 DRGFJXRHBGKHQY-UHFFFAOYSA-N 0.000 claims description 3
- UWWPRKUDLAHRPB-UHFFFAOYSA-N 2-[3-(1-bromopropyl)phenyl]ethyl-trimethoxysilane Chemical compound CCC(Br)C1=CC=CC(CC[Si](OC)(OC)OC)=C1 UWWPRKUDLAHRPB-UHFFFAOYSA-N 0.000 claims description 3
- OFHBFNGVGFANSU-UHFFFAOYSA-N 2-[3-(1-chloroethyl)phenyl]ethyl-triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=CC(C(C)Cl)=C1 OFHBFNGVGFANSU-UHFFFAOYSA-N 0.000 claims description 3
- DUQLGQUHTQGVEC-UHFFFAOYSA-N 2-[3-(1-chloropropyl)phenyl]ethyl-triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=CC(C(Cl)CC)=C1 DUQLGQUHTQGVEC-UHFFFAOYSA-N 0.000 claims description 3
- OTNOWSUZDGGYMQ-UHFFFAOYSA-N 2-[3-(1-chloropropyl)phenyl]ethyl-trimethoxysilane Chemical compound CCC(Cl)C1=CC=CC(CC[Si](OC)(OC)OC)=C1 OTNOWSUZDGGYMQ-UHFFFAOYSA-N 0.000 claims description 3
- WOCWOKUJCWHRSB-UHFFFAOYSA-N 2-[3-(1-iodoethyl)phenyl]ethyl-trimethoxysilane Chemical compound CO[Si](OC)(OC)CCC1=CC=CC(C(C)I)=C1 WOCWOKUJCWHRSB-UHFFFAOYSA-N 0.000 claims description 3
- YAOWBGBYSXPIGK-UHFFFAOYSA-N 2-[3-(bromomethyl)phenyl]ethyl-tributoxysilane Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCC1=CC=CC(CBr)=C1 YAOWBGBYSXPIGK-UHFFFAOYSA-N 0.000 claims description 3
- FGIPSLHLFLBNBX-UHFFFAOYSA-N 2-[3-(bromomethyl)phenyl]ethyl-triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=CC(CBr)=C1 FGIPSLHLFLBNBX-UHFFFAOYSA-N 0.000 claims description 3
- QGWVMDRNRLACFT-UHFFFAOYSA-N 2-[3-(iodomethyl)phenyl]ethyl-trimethoxysilane Chemical compound CO[Si](OC)(OC)CCC1=CC=CC(CI)=C1 QGWVMDRNRLACFT-UHFFFAOYSA-N 0.000 claims description 3
- IKUAMWKIGOPNTH-UHFFFAOYSA-N 2-[4-(1-bromoethyl)phenyl]ethyl-triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=C(C(C)Br)C=C1 IKUAMWKIGOPNTH-UHFFFAOYSA-N 0.000 claims description 3
- KBFOYKNHFSSEOP-UHFFFAOYSA-N 2-[4-(1-bromoethyl)phenyl]ethyl-trimethoxysilane Chemical compound CO[Si](OC)(OC)CCC1=CC=C(C(C)Br)C=C1 KBFOYKNHFSSEOP-UHFFFAOYSA-N 0.000 claims description 3
- LVBSEFFAVAVWGI-UHFFFAOYSA-N 2-[4-(1-bromopropyl)phenyl]ethyl-tributoxysilane Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCC1=CC=C(C(Br)CC)C=C1 LVBSEFFAVAVWGI-UHFFFAOYSA-N 0.000 claims description 3
- ABHPUKOXXXQGQI-UHFFFAOYSA-N 2-[4-(1-bromopropyl)phenyl]ethyl-triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=C(C(Br)CC)C=C1 ABHPUKOXXXQGQI-UHFFFAOYSA-N 0.000 claims description 3
- QSISEYAHIBRTMI-UHFFFAOYSA-N 2-[4-(1-bromopropyl)phenyl]ethyl-trimethoxysilane Chemical compound CCC(Br)C1=CC=C(CC[Si](OC)(OC)OC)C=C1 QSISEYAHIBRTMI-UHFFFAOYSA-N 0.000 claims description 3
- CLVGHASSJXFTRU-UHFFFAOYSA-N 2-[4-(1-chloroethyl)phenyl]ethyl-triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=C(C(C)Cl)C=C1 CLVGHASSJXFTRU-UHFFFAOYSA-N 0.000 claims description 3
- OMTHBTPGLGZLMD-UHFFFAOYSA-N 2-[4-(1-chloropropyl)phenyl]ethyl-triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=C(C(Cl)CC)C=C1 OMTHBTPGLGZLMD-UHFFFAOYSA-N 0.000 claims description 3
- QEOLCOONMZKKAU-UHFFFAOYSA-N 2-[4-(1-iodoethyl)phenyl]ethyl-trimethoxysilane Chemical compound CO[Si](OC)(OC)CCC1=CC=C(C(C)I)C=C1 QEOLCOONMZKKAU-UHFFFAOYSA-N 0.000 claims description 3
- DAXVAOZPRQGFEQ-UHFFFAOYSA-N 2-[4-(bromomethyl)phenyl]ethyl-triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=C(CBr)C=C1 DAXVAOZPRQGFEQ-UHFFFAOYSA-N 0.000 claims description 3
- VCUMWKVYHWUGJB-UHFFFAOYSA-N 2-[4-(bromomethyl)phenyl]ethyl-trimethoxysilane Chemical compound CO[Si](OC)(OC)CCC1=CC=C(CBr)C=C1 VCUMWKVYHWUGJB-UHFFFAOYSA-N 0.000 claims description 3
- CWTUPLGSOGOWGN-UHFFFAOYSA-N 2-[4-(chloromethyl)phenyl]ethyl-diethoxy-methylsilane Chemical compound CCO[Si](C)(OCC)CCC1=CC=C(CCl)C=C1 CWTUPLGSOGOWGN-UHFFFAOYSA-N 0.000 claims description 3
- NYUCLSVFNKDMET-UHFFFAOYSA-N 2-[4-(chloromethyl)phenyl]ethyl-ethoxy-dimethylsilane Chemical compound CCO[Si](C)(C)CCC1=CC=C(CCl)C=C1 NYUCLSVFNKDMET-UHFFFAOYSA-N 0.000 claims description 3
- YTRBSYISFMMVSM-UHFFFAOYSA-N 2-[4-(dichloromethyl)phenyl]ethyl-triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=C(C(Cl)Cl)C=C1 YTRBSYISFMMVSM-UHFFFAOYSA-N 0.000 claims description 3
- UWCBRAJYURMKSQ-UHFFFAOYSA-N 2-[4-(iodomethyl)phenyl]ethyl-trimethoxysilane Chemical compound CO[Si](OC)(OC)CCC1=CC=C(CI)C=C1 UWCBRAJYURMKSQ-UHFFFAOYSA-N 0.000 claims description 3
- 101150065749 Churc1 gene Proteins 0.000 claims description 3
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 3
- 102100038239 Protein Churchill Human genes 0.000 claims description 3
- KLNGEMFETVLZNY-UHFFFAOYSA-N [1-[4-(chloromethyl)phenyl]-3-triethoxysilylpropan-2-yl]-triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CC([Si](OCC)(OCC)OCC)CC1=CC=C(CCl)C=C1 KLNGEMFETVLZNY-UHFFFAOYSA-N 0.000 claims description 3
- 239000007795 chemical reaction product Substances 0.000 claims description 3
- 239000000839 emulsion Substances 0.000 claims description 3
- HQQADJVZYDDRJT-UHFFFAOYSA-N ethene;prop-1-ene Chemical group C=C.CC=C HQQADJVZYDDRJT-UHFFFAOYSA-N 0.000 claims description 3
- OZLVHIOWFGMAHR-UHFFFAOYSA-N tributoxy-[2-[3-(1-iodoethyl)phenyl]ethyl]silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCC1=CC=CC(C(C)I)=C1 OZLVHIOWFGMAHR-UHFFFAOYSA-N 0.000 claims description 3
- QJTXKTJNFZRJAY-UHFFFAOYSA-N tributoxy-[2-[3-(1-iodopropyl)phenyl]ethyl]silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCC1=CC=CC(C(I)CC)=C1 QJTXKTJNFZRJAY-UHFFFAOYSA-N 0.000 claims description 3
- ADMIQROVGXKBEW-UHFFFAOYSA-N tributoxy-[2-[3-(chloromethyl)phenyl]ethyl]silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCC1=CC=CC(CCl)=C1 ADMIQROVGXKBEW-UHFFFAOYSA-N 0.000 claims description 3
- RMHBTZDMZWBKJY-UHFFFAOYSA-N tributoxy-[2-[4-(1-iodoethyl)phenyl]ethyl]silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCC1=CC=C(C(C)I)C=C1 RMHBTZDMZWBKJY-UHFFFAOYSA-N 0.000 claims description 3
- UFSJZFNQZLSLNS-UHFFFAOYSA-N tributoxy-[2-[4-(1-iodopropyl)phenyl]ethyl]silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCC1=CC=C(C(I)CC)C=C1 UFSJZFNQZLSLNS-UHFFFAOYSA-N 0.000 claims description 3
- IMXRNLICYXRKAE-UHFFFAOYSA-N tributoxy-[2-[4-(chloromethyl)phenyl]ethyl]silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCC1=CC=C(CCl)C=C1 IMXRNLICYXRKAE-UHFFFAOYSA-N 0.000 claims description 3
- IRGSFBKRUDXZBB-UHFFFAOYSA-N tributoxy-[2-[4-(iodomethyl)phenyl]ethyl]silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCC1=CC=C(CI)C=C1 IRGSFBKRUDXZBB-UHFFFAOYSA-N 0.000 claims description 3
- DGUKQIPFAXYYAN-UHFFFAOYSA-N triethoxy-[2-[3-(1-iodoethyl)phenyl]ethyl]silane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=CC(C(C)I)=C1 DGUKQIPFAXYYAN-UHFFFAOYSA-N 0.000 claims description 3
- ZQZIUGZFPKFKTR-UHFFFAOYSA-N triethoxy-[2-[3-(iodomethyl)phenyl]ethyl]silane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=CC(CI)=C1 ZQZIUGZFPKFKTR-UHFFFAOYSA-N 0.000 claims description 3
- SYHKVPOSTZEBLU-UHFFFAOYSA-N triethoxy-[2-[4-(iodomethyl)phenyl]ethyl]silane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=C(CI)C=C1 SYHKVPOSTZEBLU-UHFFFAOYSA-N 0.000 claims description 3
- IFEYCVPGRHECME-UHFFFAOYSA-N triethoxy-[2-[4-(trichloromethyl)phenyl]ethyl]silane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=C(C(Cl)(Cl)Cl)C=C1 IFEYCVPGRHECME-UHFFFAOYSA-N 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 3
- YDDDAZSAKXOWGG-UHFFFAOYSA-N 2-[3-(1-bromoethyl)phenyl]ethyl-tributoxysilane Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCC1=CC=CC(C(C)Br)=C1 YDDDAZSAKXOWGG-UHFFFAOYSA-N 0.000 claims 2
- FRANMEYRGGHNHN-UHFFFAOYSA-N 2-[3-(1-chloroethyl)phenyl]ethyl-trimethoxysilane Chemical compound CO[Si](OC)(OC)CCC1=CC=CC(C(C)Cl)=C1 FRANMEYRGGHNHN-UHFFFAOYSA-N 0.000 claims 2
- HOJOKODKNBIXJU-UHFFFAOYSA-N 2-[3-(1-iodopropyl)phenyl]ethyl-trimethoxysilane Chemical compound CCC(I)C1=CC=CC(CC[Si](OC)(OC)OC)=C1 HOJOKODKNBIXJU-UHFFFAOYSA-N 0.000 claims 2
- RPSCMKMPBNFRON-UHFFFAOYSA-N 2-[3-(bromomethyl)phenyl]ethyl-trimethoxysilane Chemical compound CO[Si](OC)(OC)CCC1=CC=CC(CBr)=C1 RPSCMKMPBNFRON-UHFFFAOYSA-N 0.000 claims 2
- LQGLXJAMDDNOLJ-UHFFFAOYSA-N 2-[4-(1-bromoethyl)phenyl]ethyl-tributoxysilane Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCC1=CC=C(C(C)Br)C=C1 LQGLXJAMDDNOLJ-UHFFFAOYSA-N 0.000 claims 2
- PWHLBOPARVWKRX-UHFFFAOYSA-N 2-[4-(1-chloroethyl)phenyl]ethyl-trimethoxysilane Chemical compound CO[Si](OC)(OC)CCC1=CC=C(C(C)Cl)C=C1 PWHLBOPARVWKRX-UHFFFAOYSA-N 0.000 claims 2
- AOKIIYWHRGIHAT-UHFFFAOYSA-N 2-[4-(1-iodopropyl)phenyl]ethyl-trimethoxysilane Chemical compound CCC(I)C1=CC=C(CC[Si](OC)(OC)OC)C=C1 AOKIIYWHRGIHAT-UHFFFAOYSA-N 0.000 claims 2
- 238000000889 atomisation Methods 0.000 claims 2
- SOFOFLWVEFGAER-UHFFFAOYSA-N tributoxy-[2-[3-(1-chloropropyl)phenyl]ethyl]silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCC1=CC=CC(C(Cl)CC)=C1 SOFOFLWVEFGAER-UHFFFAOYSA-N 0.000 claims 2
- IEIKNCXFVMGUKI-UHFFFAOYSA-N tributoxy-[2-[3-(iodomethyl)phenyl]ethyl]silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCC1=CC=CC(CI)=C1 IEIKNCXFVMGUKI-UHFFFAOYSA-N 0.000 claims 2
- REKGACMCGUJYHD-UHFFFAOYSA-N tributoxy-[2-[4-(1-chloropropyl)phenyl]ethyl]silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCC1=CC=C(C(Cl)CC)C=C1 REKGACMCGUJYHD-UHFFFAOYSA-N 0.000 claims 2
- DFNHKTJNVVWTNC-UHFFFAOYSA-N triethoxy-[2-[3-(1-iodopropyl)phenyl]ethyl]silane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=CC(C(I)CC)=C1 DFNHKTJNVVWTNC-UHFFFAOYSA-N 0.000 claims 2
- VRVCRTKOTQVNLT-UHFFFAOYSA-N triethoxy-[2-[4-(1-iodoethyl)phenyl]ethyl]silane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=C(C(C)I)C=C1 VRVCRTKOTQVNLT-UHFFFAOYSA-N 0.000 claims 2
- OBHZZDKHNGVWJW-UHFFFAOYSA-N triethoxy-[2-[4-(1-iodopropyl)phenyl]ethyl]silane Chemical compound CCO[Si](OCC)(OCC)CCC1=CC=C(C(I)CC)C=C1 OBHZZDKHNGVWJW-UHFFFAOYSA-N 0.000 claims 2
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 5
- 229930195733 hydrocarbon Natural products 0.000 abstract description 3
- 230000003213 activating effect Effects 0.000 abstract 1
- 125000001183 hydrocarbyl group Chemical group 0.000 abstract 1
- 235000019241 carbon black Nutrition 0.000 description 20
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 18
- 230000000052 comparative effect Effects 0.000 description 15
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 8
- 239000004594 Masterbatch (MB) Substances 0.000 description 7
- 239000000806 elastomer Substances 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 7
- 239000011148 porous material Substances 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 description 7
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 7
- 239000004615 ingredient Substances 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 239000012763 reinforcing filler Substances 0.000 description 6
- 239000011230 binding agent Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000009472 formulation Methods 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 5
- 229910052753 mercury Inorganic materials 0.000 description 5
- 229910052751 metal Inorganic materials 0.000 description 5
- 239000002184 metal Substances 0.000 description 5
- 230000003014 reinforcing effect Effects 0.000 description 5
- 150000004756 silanes Chemical class 0.000 description 5
- 238000006467 substitution reaction Methods 0.000 description 5
- 238000004073 vulcanization Methods 0.000 description 5
- OXGPXSALMHTDHQ-UHFFFAOYSA-N 3-chloroprop-1-enyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=CCCl OXGPXSALMHTDHQ-UHFFFAOYSA-N 0.000 description 4
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 4
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- 125000000396 limonene group Chemical group 0.000 description 1
- 150000005309 metal halides Chemical class 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- ARYZCSRUUPFYMY-UHFFFAOYSA-N methoxysilane Chemical compound CO[SiH3] ARYZCSRUUPFYMY-UHFFFAOYSA-N 0.000 description 1
- OFHMODDLBXETIK-UHFFFAOYSA-N methyl 2,3-dichloropropanoate Chemical compound COC(=O)C(Cl)CCl OFHMODDLBXETIK-UHFFFAOYSA-N 0.000 description 1
- 239000004200 microcrystalline wax Substances 0.000 description 1
- 235000019808 microcrystalline wax Nutrition 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 150000002780 morpholines Chemical class 0.000 description 1
- IUJLOAKJZQBENM-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)-2-methylpropan-2-amine Chemical compound C1=CC=C2SC(SNC(C)(C)C)=NC2=C1 IUJLOAKJZQBENM-UHFFFAOYSA-N 0.000 description 1
- ILSQBBRAYMWZLQ-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)-n-propan-2-ylpropan-2-amine Chemical compound C1=CC=C2SC(SN(C(C)C)C(C)C)=NC2=C1 ILSQBBRAYMWZLQ-UHFFFAOYSA-N 0.000 description 1
- DEQZTKGFXNUBJL-UHFFFAOYSA-N n-(1,3-benzothiazol-2-ylsulfanyl)cyclohexanamine Chemical compound C1CCCCC1NSC1=NC2=CC=CC=C2S1 DEQZTKGFXNUBJL-UHFFFAOYSA-N 0.000 description 1
- ZHDORMMHAKXTPT-UHFFFAOYSA-N n-benzoylbenzamide Chemical compound C=1C=CC=CC=1C(=O)NC(=O)C1=CC=CC=C1 ZHDORMMHAKXTPT-UHFFFAOYSA-N 0.000 description 1
- UMRZSTCPUPJPOJ-KNVOCYPGSA-N norbornane Chemical compound C1C[C@H]2CC[C@@H]1C2 UMRZSTCPUPJPOJ-KNVOCYPGSA-N 0.000 description 1
- 125000002868 norbornyl group Chemical group C12(CCC(CC1)C2)* 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000013500 performance material Substances 0.000 description 1
- PMJHHCWVYXUKFD-UHFFFAOYSA-N piperylene Natural products CC=CC=C PMJHHCWVYXUKFD-UHFFFAOYSA-N 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- PIZSEPSUZMIOQF-UHFFFAOYSA-N platinum;2,4,6,8-tetrakis(ethenyl)-2,4,6,8-tetramethyl-1,3,5,7,2,4,6,8-tetraoxatetrasilocane Chemical compound [Pt].C=C[Si]1(C)O[Si](C)(C=C)O[Si](C)(C=C)O[Si](C)(C=C)O1 PIZSEPSUZMIOQF-UHFFFAOYSA-N 0.000 description 1
- 239000004848 polyfunctional curative Substances 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 238000002459 porosimetry Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002028 premature Effects 0.000 description 1
- 239000010734 process oil Substances 0.000 description 1
- LJZPPWWHKPGCHS-UHFFFAOYSA-N propargyl chloride Chemical compound ClCC#C LJZPPWWHKPGCHS-UHFFFAOYSA-N 0.000 description 1
- 239000012264 purified product Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000012779 reinforcing material Substances 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- JPPLPDOXWBVPCW-UHFFFAOYSA-N s-(3-triethoxysilylpropyl) octanethioate Chemical compound CCCCCCCC(=O)SCCC[Si](OCC)(OCC)OCC JPPLPDOXWBVPCW-UHFFFAOYSA-N 0.000 description 1
- WHALSQRTWNBBCV-UHFFFAOYSA-N s-aminosulfanylthiohydroxylamine Chemical class NSSN WHALSQRTWNBBCV-UHFFFAOYSA-N 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical group [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 description 1
- 238000010059 sulfur vulcanization Methods 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- PUGUQINMNYINPK-UHFFFAOYSA-N tert-butyl 4-(2-chloroacetyl)piperazine-1-carboxylate Chemical compound CC(C)(C)OC(=O)N1CCN(C(=O)CCl)CC1 PUGUQINMNYINPK-UHFFFAOYSA-N 0.000 description 1
- LPSXSORODABQKT-UHFFFAOYSA-N tetrahydrodicyclopentadiene Chemical compound C1C2CCC1C1C2CCC1 LPSXSORODABQKT-UHFFFAOYSA-N 0.000 description 1
- 150000003557 thiazoles Chemical class 0.000 description 1
- 150000003558 thiocarbamic acid derivatives Chemical class 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- UBZYKBZMAMTNKW-UHFFFAOYSA-J titanium tetrabromide Chemical compound Br[Ti](Br)(Br)Br UBZYKBZMAMTNKW-UHFFFAOYSA-J 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- XVPGJZHJCKOMGG-UHFFFAOYSA-N tributoxy(3-chloroprop-1-enyl)silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)C=CCCl XVPGJZHJCKOMGG-UHFFFAOYSA-N 0.000 description 1
- XOQCXMHSNFVVOK-UHFFFAOYSA-N tributoxy(3-iodoprop-1-enyl)silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)C=CCI XOQCXMHSNFVVOK-UHFFFAOYSA-N 0.000 description 1
- XANCLGFGMPNOEC-UHFFFAOYSA-N tributoxy-[2-[3-(1-chloroethyl)phenyl]ethyl]silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCC1=CC=CC(C(C)Cl)=C1 XANCLGFGMPNOEC-UHFFFAOYSA-N 0.000 description 1
- UGIYQKPRJBAVCN-UHFFFAOYSA-N tributoxy-[2-[4-(1-chloroethyl)phenyl]ethyl]silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCC1=CC=C(C(C)Cl)C=C1 UGIYQKPRJBAVCN-UHFFFAOYSA-N 0.000 description 1
- KDXJADYYCKBIBL-UHFFFAOYSA-N trichloro-[2-(4-methylphenyl)ethyl]silane Chemical compound CC1=CC=C(CC[Si](Cl)(Cl)Cl)C=C1 KDXJADYYCKBIBL-UHFFFAOYSA-N 0.000 description 1
- ZDHXKXAHOVTTAH-UHFFFAOYSA-N trichlorosilane Chemical compound Cl[SiH](Cl)Cl ZDHXKXAHOVTTAH-UHFFFAOYSA-N 0.000 description 1
- 239000005052 trichlorosilane Substances 0.000 description 1
- DDHNQHHKUCIXAT-UHFFFAOYSA-N triethoxy(3-iodoprop-1-enyl)silane Chemical compound CCO[Si](OCC)(OCC)C=CCI DDHNQHHKUCIXAT-UHFFFAOYSA-N 0.000 description 1
- 229930195735 unsaturated hydrocarbon Natural products 0.000 description 1
- 239000003039 volatile agent Substances 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000004246 zinc acetate Substances 0.000 description 1
- 229940102001 zinc bromide Drugs 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
- NEYNBSGIXOOZGZ-UHFFFAOYSA-L zinc;butoxymethanedithioate Chemical compound [Zn+2].CCCCOC([S-])=S.CCCCOC([S-])=S NEYNBSGIXOOZGZ-UHFFFAOYSA-L 0.000 description 1
- MBBWTVUFIXOUBE-UHFFFAOYSA-L zinc;dicarbamodithioate Chemical compound [Zn+2].NC([S-])=S.NC([S-])=S MBBWTVUFIXOUBE-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0016—Compositions of the tread
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
- C08K3/013—Fillers, pigments or reinforcing additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/5406—Silicon-containing compounds containing elements other than oxygen or nitrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/54—Silicon-containing compounds
- C08K5/548—Silicon-containing compounds containing sulfur
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US11/703,969 US7625965B2 (en) | 2007-02-08 | 2007-02-08 | Rubber composition, process of preparing same and articles made therefrom |
| US11/703,969 | 2007-02-08 | ||
| PCT/US2008/001587 WO2008097587A1 (en) | 2007-02-08 | 2008-02-06 | Rubber composition, process of preparing same and articles made therefrom |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2010518229A JP2010518229A (ja) | 2010-05-27 |
| JP2010518229A5 JP2010518229A5 (enExample) | 2010-07-29 |
| JP5593073B2 true JP5593073B2 (ja) | 2014-09-17 |
Family
ID=39563341
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009549096A Expired - Fee Related JP5593073B2 (ja) | 2007-02-08 | 2008-02-06 | ゴム組成物、その作製プロセス、およびそれから作られる製品 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US7625965B2 (enExample) |
| EP (1) | EP2121349B1 (enExample) |
| JP (1) | JP5593073B2 (enExample) |
| CN (2) | CN101641226B (enExample) |
| AT (1) | ATE488381T1 (enExample) |
| DE (1) | DE602008003526D1 (enExample) |
| PL (1) | PL2121349T3 (enExample) |
| TW (1) | TWI441858B (enExample) |
| WO (1) | WO2008097587A1 (enExample) |
Families Citing this family (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7816435B2 (en) * | 2007-10-31 | 2010-10-19 | Momentive Performance Materials Inc. | Halo-functional silane, process for its preparation, rubber composition containing same and articles manufactured therefrom |
| US8143336B2 (en) * | 2008-08-07 | 2012-03-27 | Momentive Performance Materials Inc. | Activated halo-containing aralkylsilane composition, process of preparing same and rubber compositions made therefrom |
| EP2284217B1 (de) * | 2009-08-07 | 2011-12-07 | Rhein Chemie Rheinau GmbH | Vulkanisationsbeschleunigende Mischung |
| US8846806B2 (en) * | 2011-09-23 | 2014-09-30 | Ppg Industries Ohio, Inc. | Treated fillers, compositions containing same, and articles prepared therefrom |
| ITTO20111208A1 (it) * | 2011-12-23 | 2013-06-24 | Bridgestone Corp | Mescola di gomma per pneumatici |
| RU2487893C1 (ru) * | 2011-12-26 | 2013-07-20 | Виктор Александрович Стариков | Резиновая смесь для изготовления пористых изделий |
| CN102675697B (zh) * | 2012-06-21 | 2014-03-12 | 三角轮胎股份有限公司 | 抗硫化返原的胎肩垫胶橡胶组合物 |
| US11312824B2 (en) * | 2015-07-15 | 2022-04-26 | Cabot Corporation | Elastomer compounds reinforced with silica and products containing same |
| JP6669851B2 (ja) | 2015-07-15 | 2020-03-18 | キャボット コーポレイションＣａｂｏｔ Ｃｏｒｐｏｒａｔｉｏｎ | シリカで補強されたエラストマー複合材の製造方法およびそれを含む製品 |
| CN105131380A (zh) * | 2015-08-18 | 2015-12-09 | 合肥市再德高分子材料有限公司 | 一种高性能改性羧基丁腈橡胶复合材料 |
| DE102015223246A1 (de) * | 2015-11-24 | 2017-05-24 | Wacker Chemie Ag | Organocopolymer-Dispersionen |
| WO2018128141A1 (ja) * | 2017-01-06 | 2018-07-12 | 住友ゴム工業株式会社 | 加硫後ゴム組成物及び空気入りタイヤ |
| DE102017221232A1 (de) * | 2017-11-28 | 2019-05-29 | Continental Reifen Deutschland Gmbh | Schwefelvernetzbare Kautschukmischung, Vulkanisat der Kautschukmischung und Fahrzeugreifen |
| EP3650246B1 (de) | 2018-11-12 | 2025-01-08 | Continental Reifen Deutschland GmbH | Schwefelvernetzbare kautschukmischung, vulkanisat und fahrzeugreifen |
| ES2963676T3 (es) | 2018-11-12 | 2024-04-01 | Continental Reifen Deutschland Gmbh | Mezcla de cauchos reticulable con azufre, vulcanizado y neumático para vehículo |
| KR102791600B1 (ko) | 2019-06-05 | 2025-04-09 | 비욘드 로투스 엘엘씨 | 엘라스토머 및 충전제를 갖는 복합재를 제조하는 방법 |
| JP7331566B2 (ja) * | 2019-09-06 | 2023-08-23 | 住友ゴム工業株式会社 | タイヤ部材の物性予測方法 |
Family Cites Families (23)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3692812A (en) * | 1971-04-21 | 1972-09-19 | Gen Electric | Method of producing alkoxy-substituted mercaptoalkyl silanes |
| GB1435894A (en) * | 1972-07-21 | 1976-05-19 | Ici Ltd | Production of isocyanates |
| DE2819638C3 (de) * | 1978-05-05 | 1986-11-13 | Degussa Ag, 6000 Frankfurt | Vulkanisierbare Halogenkautschuk-Mischungen |
| DE2933346C2 (de) * | 1979-08-17 | 1982-07-01 | Degussa Ag, 6000 Frankfurt | Silan/Füllstoff-Präparationen, Verfahren zu deren Herstellung und Anwendung derselben |
| JP2630596B2 (ja) | 1987-07-27 | 1997-07-16 | 株式会社ブリヂストン | シランカップリング剤 |
| DE4004781A1 (de) * | 1990-02-16 | 1991-08-22 | Degussa | Verfahren zur herstellung von mit organosiliciumverbindungen modifizierten fuellstoffen, die so hergestellten fuellstoffe und deren verwendung |
| US5268439A (en) * | 1991-01-02 | 1993-12-07 | Bridgestone/Firestone, Inc. | Tin containing elastomers and products having reduced hysteresis properties |
| CA2105719A1 (en) | 1993-06-28 | 1994-12-29 | Rene Jean Zimmer | Silica based aggregates, elastomers reinforced therewith and tire with tread thereof |
| JP3382322B2 (ja) * | 1993-11-09 | 2003-03-04 | 住友ゴム工業株式会社 | 車両用タイヤ |
| IT1274257B (it) * | 1995-02-24 | 1997-07-15 | Pirelli | Procedimento per la produzione di una mescola di gomma vulcanizzabile con carica rinforzante a base di silice |
| US6005027A (en) * | 1995-08-16 | 1999-12-21 | Witco Corporation | Stable silane compositions on silica carrier |
| DE69622235T2 (de) * | 1995-10-04 | 2003-01-23 | Compagnie Generale Des Etablissements Michelin-Michelin & Cie., Clermont-Ferrand | Kautschukmischung basierend auf einem Dienpolymer mit von Organosilanen abgeleiteten Gruppen zur Verwendung in Reifenlaufflächen |
| CN1278842A (zh) * | 1997-12-15 | 2001-01-03 | 埃克森化学专利公司 | 透明和可着色的弹性体组合物 |
| ATE252614T1 (de) | 1999-12-30 | 2003-11-15 | Michelin Soc Tech | Kautschukzusammensetzung für reifen mit einem kupplungsmittel (wesiser füllstoff/dienelastomer),das durch einen thermisch initierbaren radikalstarter aktiviert wird |
| RU2002134760A (ru) * | 2000-06-13 | 2004-07-27 | Эксонмобил Кемикэл Пейтентс Инк. (Us) | Способ приготовления наполненных диоксидом кремния эластомерных композиций |
| JP5244280B2 (ja) | 2000-09-15 | 2013-07-24 | コンパニー ゼネラール デ エタブリッスマン ミシュラン | シトラコンイミド−アルコキシシランをカップリング剤として含むタイヤ用ゴム組成物 |
| US20040014869A1 (en) * | 2001-05-09 | 2004-01-22 | Wong Wai Keung | Method for preparing silica filled elastomeric compositions |
| EP1539878A1 (fr) | 2002-09-10 | 2005-06-15 | Société de Technologie Michelin | Composition de caoutchouc pour bande de roulement de pneumatique |
| US6706398B1 (en) * | 2002-09-13 | 2004-03-16 | Dow Corning Corporation | Organosilicon compounds and blends for treating silica |
| US6811823B2 (en) * | 2002-09-13 | 2004-11-02 | Dow Corning Corporation | Hydrophobing silica with organosilicon compounds and blends thereof |
| KR100629684B1 (ko) | 2003-01-23 | 2006-09-29 | 전남대학교산학협력단 | 둥지 실리카를 포함하는 고무조성물 |
| JP2005232445A (ja) | 2004-01-23 | 2005-09-02 | Daiso Co Ltd | ゴム用添加剤およびそれを用いたゴム組成物 |
| US20060025506A1 (en) * | 2004-07-30 | 2006-02-02 | Weller Keith J | Silane compositions, processes for their preparation and rubber compositions containing same |
-
2007
- 2007-02-08 US US11/703,969 patent/US7625965B2/en active Active
-
2008
- 2008-02-04 TW TW097104334A patent/TWI441858B/zh not_active IP Right Cessation
- 2008-02-06 CN CN200880009764XA patent/CN101641226B/zh not_active Expired - Fee Related
- 2008-02-06 WO PCT/US2008/001587 patent/WO2008097587A1/en not_active Ceased
- 2008-02-06 DE DE602008003526T patent/DE602008003526D1/de active Active
- 2008-02-06 JP JP2009549096A patent/JP5593073B2/ja not_active Expired - Fee Related
- 2008-02-06 CN CN201110259015.6A patent/CN102432924B/zh not_active Expired - Fee Related
- 2008-02-06 PL PL08725244T patent/PL2121349T3/pl unknown
- 2008-02-06 AT AT08725244T patent/ATE488381T1/de not_active IP Right Cessation
- 2008-02-06 EP EP08725244A patent/EP2121349B1/en not_active Not-in-force
Also Published As
| Publication number | Publication date |
|---|---|
| CN101641226A (zh) | 2010-02-03 |
| TWI441858B (zh) | 2014-06-21 |
| EP2121349B1 (en) | 2010-11-17 |
| ATE488381T1 (de) | 2010-12-15 |
| HK1140729A1 (en) | 2010-10-22 |
| CN101641226B (zh) | 2013-02-13 |
| PL2121349T3 (pl) | 2011-06-30 |
| US20080194746A1 (en) | 2008-08-14 |
| EP2121349A1 (en) | 2009-11-25 |
| TW200904875A (en) | 2009-02-01 |
| DE602008003526D1 (de) | 2010-12-30 |
| CN102432924A (zh) | 2012-05-02 |
| CN102432924B (zh) | 2014-04-09 |
| US7625965B2 (en) | 2009-12-01 |
| WO2008097587A1 (en) | 2008-08-14 |
| JP2010518229A (ja) | 2010-05-27 |
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