JP5568093B2 - 農薬粒子と両親媒性物質とを含む水性分散液 - Google Patents
農薬粒子と両親媒性物質とを含む水性分散液 Download PDFInfo
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- JP5568093B2 JP5568093B2 JP2011541347A JP2011541347A JP5568093B2 JP 5568093 B2 JP5568093 B2 JP 5568093B2 JP 2011541347 A JP2011541347 A JP 2011541347A JP 2011541347 A JP2011541347 A JP 2011541347A JP 5568093 B2 JP5568093 B2 JP 5568093B2
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- 235000021286 stilbenes Nutrition 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- NVBFHJWHLNUMCV-UHFFFAOYSA-N sulfamide Chemical compound NS(N)(=O)=O NVBFHJWHLNUMCV-UHFFFAOYSA-N 0.000 description 1
- 125000000446 sulfanediyl group Chemical group *S* 0.000 description 1
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 description 1
- YROXIXLRRCOBKF-UHFFFAOYSA-N sulfonylurea Chemical class OC(=N)N=S(=O)=O YROXIXLRRCOBKF-UHFFFAOYSA-N 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 230000000475 sunscreen effect Effects 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- DZLFLBLQUQXARW-UHFFFAOYSA-N tetrabutylammonium Chemical compound CCCC[N+](CCCC)(CCCC)CCCC DZLFLBLQUQXARW-UHFFFAOYSA-N 0.000 description 1
- MLGCXEBRWGEOQX-UHFFFAOYSA-N tetradifon Chemical compound C1=CC(Cl)=CC=C1S(=O)(=O)C1=CC(Cl)=C(Cl)C=C1Cl MLGCXEBRWGEOQX-UHFFFAOYSA-N 0.000 description 1
- CXWXQJXEFPUFDZ-UHFFFAOYSA-N tetralin Chemical compound C1=CC=C2CCCCC2=C1 CXWXQJXEFPUFDZ-UHFFFAOYSA-N 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- VLLMWSRANPNYQX-UHFFFAOYSA-N thiadiazole Chemical compound C1=CSN=N1.C1=CSN=N1 VLLMWSRANPNYQX-UHFFFAOYSA-N 0.000 description 1
- YFNCATAIYKQPOO-UHFFFAOYSA-N thiophanate Chemical compound CCOC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OCC YFNCATAIYKQPOO-UHFFFAOYSA-N 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- JOXIMZWYDAKGHI-UHFFFAOYSA-M toluene-4-sulfonate Chemical compound CC1=CC=C(S([O-])(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-M 0.000 description 1
- 150000003918 triazines Chemical class 0.000 description 1
- YWBFPKPWMSWWEA-UHFFFAOYSA-O triazolopyrimidine Chemical compound BrC1=CC=CC(C=2N=C3N=CN[N+]3=C(NCC=3C=CN=CC=3)C=2)=C1 YWBFPKPWMSWWEA-UHFFFAOYSA-O 0.000 description 1
- 229940066528 trichloroacetate Drugs 0.000 description 1
- YNJBWRMUSHSURL-UHFFFAOYSA-N trichloroacetic acid Chemical compound OC(=O)C(Cl)(Cl)Cl YNJBWRMUSHSURL-UHFFFAOYSA-N 0.000 description 1
- ITMCEJHCFYSIIV-UHFFFAOYSA-N triflic acid Chemical compound OS(=O)(=O)C(F)(F)F ITMCEJHCFYSIIV-UHFFFAOYSA-N 0.000 description 1
- WMRNPTXYRLMGPC-UHFFFAOYSA-L trimethyl(octyl)azanium;sulfate Chemical compound [O-]S([O-])(=O)=O.CCCCCCCC[N+](C)(C)C.CCCCCCCC[N+](C)(C)C WMRNPTXYRLMGPC-UHFFFAOYSA-L 0.000 description 1
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 1
- SBXWFLISHPUINY-UHFFFAOYSA-N triphenyltin Chemical class C1=CC=CC=C1[Sn](C=1C=CC=CC=1)C1=CC=CC=C1 SBXWFLISHPUINY-UHFFFAOYSA-N 0.000 description 1
- 229940035893 uracil Drugs 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/647—Triazoles; Hydrogenated triazoles
- A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/38—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< where at least one nitrogen atom is part of a heterocyclic ring; Thio analogues thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Description
該活性物質および該両親媒性物質を、水と混和性でない有機溶媒に溶解し、該溶液を水溶液と乱流混合し、場合によっては、該有機溶媒を除去する(場合によっては蒸発と組合された、乳化法);
溶融活性物質と該両親媒性物質とを含む溶融物を水溶液と混合し、冷却する(溶融乳化);あるいは
該活性物質を、該両親媒性物質の存在下で微粉砕する(微粉砕法)。
まず、3mmのガラスビーズおよびシェーカー(Red Devil)を使用して、16gのピラクロストロビンおよび0 / 1 / 2 / 4 g(ピラクロストロビンに対して0 / 6 / 11 / 25重量%)のエルカ酸を144gのプロピレングリコールに1時間懸濁させた。生じた尚も粒が粗い懸濁液を1kg/時間の流速で溶解セルの混合ノズルを介して運搬した。プロピレングリコールを200℃の温度および2kg/時間の送出速度でそこに運搬した。2つの流れを該溶解セル内で乱流混合し、ピラクロストロビンおよびエルカ酸の溶液を得た。
Claims (13)
- 2μm未満の粒径を有する固体活性物質粒子と両親媒性物質とを含む水性分散液であって、該両親媒性物質が脂肪族酸またはその塩であり、該脂肪族酸が、22〜36個の炭素原子を有する脂肪酸であり、10重量%以下まで20℃で水に可溶性であり、該活性物質に対して少なくとも15重量%であり且つ40重量%以下の両親媒性物質が存在する、上記水性分散液。
- 該脂肪族酸が、エルカ酸である、請求項1に記載の分散液。
- 該活性物質が10 g/l以下まで20℃で水に可溶性である、請求項1または2に記載の分散液。
- 該活性物質が農薬である、請求項1〜3のいずれか1項に記載の分散液。
- 該分散液に対して1〜60重量%の活性物質粒子が存在する、請求項1〜4のいずれか1項に記載の分散液。
- 該活性物質粒子が活性物質からなる、請求項1〜5のいずれか1項に記載の分散液。
- 該活性物質と該両親媒性物質とを接触させることによる、請求項1〜6のいずれか1項に記載の分散液の製造方法。
- 該活性物質が、水に不溶性である農薬である、請求項7に記載の方法。
- 請求項1〜6のいずれか1項に記載の水性分散液を乾燥させることにより得られる、2μm未満の粒径を有する活性物質粒子と両親媒性物質とを含む固体組成物。
- 水性分散液における2μm未満の粒径を有する活性物質粒子の成長を減速させるための、請求項1〜6のいずれか1項に記載の両親媒性物質の使用方法。
- 請求項1〜6のいずれか1項に記載の分散液または請求項9に記載の固体組成物の使用方法であって、それぞれの有害生物、それらの環境および/またはそれぞれの有害生物から保護されるべき植物、土壌および/または望ましくない植物および/または有用な植物および/またはそれらの環境に該分散液または該固体組成物を作用させることにより、植物病原性菌類および/または望ましくない植生および/または昆虫もしくはダニによる望ましくない攻撃を防除するための、および/または植物の成長を調節するための、上記使用方法。
- 請求項1〜6のいずれか1項に記載の分散液または請求項9に記載の固体組成物の使用方法であって、有用な植物の種子を該分散液または該固体組成物で処理することにより、植物に対する昆虫もしくはダニによる望ましくない攻撃を防除するための、および/または植物病原性菌類を防除するための、および/または望ましくない植生を防除するための、上記使用方法。
- 請求項1〜6のいずれか1項に記載の分散液または請求項9に記載の固体組成物を含む種子。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP08172206 | 2008-12-18 | ||
EP08172206.8 | 2008-12-18 | ||
PCT/EP2009/066837 WO2010079037A2 (de) | 2008-12-18 | 2009-12-10 | Wässrige dispersion umfassend pestizidpartikel und amphiphil |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2012512825A JP2012512825A (ja) | 2012-06-07 |
JP5568093B2 true JP5568093B2 (ja) | 2014-08-06 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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JP2011541347A Expired - Fee Related JP5568093B2 (ja) | 2008-12-18 | 2009-12-10 | 農薬粒子と両親媒性物質とを含む水性分散液 |
Country Status (6)
Country | Link |
---|---|
US (1) | US20110263422A1 (ja) |
EP (1) | EP2378868A2 (ja) |
JP (1) | JP5568093B2 (ja) |
CN (1) | CN102316726A (ja) |
BR (1) | BRPI0917771A2 (ja) |
WO (1) | WO2010079037A2 (ja) |
Families Citing this family (2)
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AR086882A1 (es) * | 2011-06-10 | 2014-01-29 | Huntsman Corp Australia Pty Ltd | Composicion y metodo para mejorar la estabilidad fisica de formulaciones agricolas en suspension basadas en aceite |
JP2013095739A (ja) * | 2011-11-04 | 2013-05-20 | Kyoyu Agri Kk | 有害節足動物防除組成物 |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
IL88076A (en) * | 1987-10-28 | 1993-01-14 | Nippon Shinyaku Co Ltd | Fat emulsions as drug carriers |
US5952004A (en) * | 1994-03-18 | 1999-09-14 | Shire Laboratories Inc. | Emulsified drug delivery systems |
US5447729A (en) * | 1994-04-07 | 1995-09-05 | Pharmavene, Inc. | Multilamellar drug delivery systems |
EP0808154B1 (en) * | 1995-02-06 | 2000-12-20 | Elan Pharma International Limited | Formulations of compounds as nanoparticulate dispersions in digestible oils or fatty acids |
US5883103A (en) * | 1995-06-07 | 1999-03-16 | Shire Laboratories Inc. | Oral acyclovir delivery |
AU7971201A (en) * | 2000-07-06 | 2002-01-14 | Huntsman Int Llc | Solid-suspending systems |
WO2003059063A1 (en) * | 2002-01-09 | 2003-07-24 | Summerdale, Inc. | Fungicide compositions |
JP2005053794A (ja) * | 2003-08-04 | 2005-03-03 | Tadashi Inoue | 無機系抗菌剤を含有した水性懸濁状農薬製剤 |
US9919979B2 (en) * | 2005-01-21 | 2018-03-20 | Bayer Cropscience Lp | Fertilizer-compatible composition |
JP4818653B2 (ja) * | 2005-07-25 | 2011-11-16 | 北興化学工業株式会社 | 殺虫効果の向上した農園芸用水性懸濁状農薬製剤 |
NZ608755A (en) * | 2006-02-27 | 2014-11-28 | Univ Northwest | Plant support formulation, vehicle for the delivery and translocation of phytologically beneficial substances and compositions containing same |
US20070237826A1 (en) * | 2006-04-05 | 2007-10-11 | Rao Kollipara K | Polymerized solid lipid nanoparticles for oral or mucosal delivery of therapeutic proteins and peptides |
TW200830991A (en) * | 2006-04-20 | 2008-08-01 | Biomor Israel Ltd | TTO-based disinfectants & anesthetics for use in aquaculture |
AU2007333947A1 (en) * | 2006-12-13 | 2008-06-26 | Innovaform Technologies, Llc | Pesticidal aggregates |
WO2008135093A1 (en) * | 2007-05-08 | 2008-11-13 | Nm Tech Nanomaterials Microdevice Technology Ltd. | Products comprising an anti-microbial composition based on titanium dioxide nanoparticles |
-
2009
- 2009-12-10 EP EP09765128A patent/EP2378868A2/de not_active Withdrawn
- 2009-12-10 BR BRPI0917771-0A patent/BRPI0917771A2/pt not_active IP Right Cessation
- 2009-12-10 CN CN2009801566771A patent/CN102316726A/zh active Pending
- 2009-12-10 JP JP2011541347A patent/JP5568093B2/ja not_active Expired - Fee Related
- 2009-12-10 WO PCT/EP2009/066837 patent/WO2010079037A2/de active Application Filing
- 2009-12-10 US US13/140,114 patent/US20110263422A1/en not_active Abandoned
Also Published As
Publication number | Publication date |
---|---|
CN102316726A (zh) | 2012-01-11 |
US20110263422A1 (en) | 2011-10-27 |
BRPI0917771A2 (pt) | 2015-08-04 |
EP2378868A2 (de) | 2011-10-26 |
JP2012512825A (ja) | 2012-06-07 |
WO2010079037A2 (de) | 2010-07-15 |
WO2010079037A3 (de) | 2011-05-12 |
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