JP5556810B2 - 改善された粒子内及び粒子間の架橋を有する浸漬成形合成ポリイソプレンラテックス物品 - Google Patents
改善された粒子内及び粒子間の架橋を有する浸漬成形合成ポリイソプレンラテックス物品 Download PDFInfo
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- JP5556810B2 JP5556810B2 JP2011507552A JP2011507552A JP5556810B2 JP 5556810 B2 JP5556810 B2 JP 5556810B2 JP 2011507552 A JP2011507552 A JP 2011507552A JP 2011507552 A JP2011507552 A JP 2011507552A JP 5556810 B2 JP5556810 B2 JP 5556810B2
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- Prior art keywords
- polyisoprene
- particles
- condom
- latex
- synthetic polyisoprene
- Prior art date
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- 229920000126 latex Polymers 0.000 title claims description 148
- 239000004816 latex Substances 0.000 title claims description 145
- 239000002245 particle Substances 0.000 title claims description 124
- 229920003051 synthetic elastomer Polymers 0.000 title claims description 100
- 238000004132 cross linking Methods 0.000 title claims description 20
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 80
- 229910052717 sulfur Inorganic materials 0.000 claims description 78
- 239000011593 sulfur Substances 0.000 claims description 76
- 229920001195 polyisoprene Polymers 0.000 claims description 67
- 239000000203 mixture Substances 0.000 claims description 62
- 238000000034 method Methods 0.000 claims description 47
- 239000011701 zinc Substances 0.000 claims description 36
- 229910052725 zinc Inorganic materials 0.000 claims description 35
- 238000004073 vulcanization Methods 0.000 claims description 33
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 31
- 239000004094 surface-active agent Substances 0.000 claims description 30
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 24
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 24
- 229920001971 elastomer Polymers 0.000 claims description 23
- -1 polyoxyethylene Polymers 0.000 claims description 22
- BOXSVZNGTQTENJ-UHFFFAOYSA-L zinc dibutyldithiocarbamate Chemical compound [Zn+2].CCCCN(C([S-])=S)CCCC.CCCCN(C([S-])=S)CCCC BOXSVZNGTQTENJ-UHFFFAOYSA-L 0.000 claims description 22
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 20
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 18
- RKQOSDAEEGPRER-UHFFFAOYSA-L zinc diethyldithiocarbamate Chemical compound [Zn+2].CCN(CC)C([S-])=S.CCN(CC)C([S-])=S RKQOSDAEEGPRER-UHFFFAOYSA-L 0.000 claims description 18
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 16
- RLEFZEWKMQQZOA-UHFFFAOYSA-M potassium;octanoate Chemical compound [K+].CCCCCCCC([O-])=O RLEFZEWKMQQZOA-UHFFFAOYSA-M 0.000 claims description 16
- HUMLQUKVJARKRN-UHFFFAOYSA-M sodium;n,n-dibutylcarbamodithioate Chemical compound [Na+].CCCCN(C([S-])=S)CCCC HUMLQUKVJARKRN-UHFFFAOYSA-M 0.000 claims description 14
- MBBWTVUFIXOUBE-UHFFFAOYSA-L zinc;dicarbamodithioate Chemical compound [Zn+2].NC([S-])=S.NC([S-])=S MBBWTVUFIXOUBE-UHFFFAOYSA-L 0.000 claims description 14
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- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 claims description 9
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- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 claims description 8
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 claims description 8
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- ZWWQICJTBOCQLA-UHFFFAOYSA-N o-propan-2-yl (propan-2-yloxycarbothioyldisulfanyl)methanethioate Chemical compound CC(C)OC(=S)SSC(=S)OC(C)C ZWWQICJTBOCQLA-UHFFFAOYSA-N 0.000 claims description 8
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 8
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- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 4
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- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 claims description 3
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- 239000004636 vulcanized rubber Substances 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- YQRQKXXITPOJBH-UHFFFAOYSA-L zinc N-pyridin-2-ylcarbamodithioate Chemical compound N1=C(C=CC=C1)NC(=S)[S-].N1=C(C=CC=C1)NC(=S)[S-].[Zn+2] YQRQKXXITPOJBH-UHFFFAOYSA-L 0.000 description 1
- AJTDSZGYGLJFQY-UHFFFAOYSA-L zinc;n,n-diphenylcarbamodithioate Chemical compound [Zn+2].C=1C=CC=CC=1N(C(=S)[S-])C1=CC=CC=C1.C=1C=CC=CC=1N(C(=S)[S-])C1=CC=CC=C1 AJTDSZGYGLJFQY-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/08—Isoprene
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L15/00—Chemical aspects of, or use of materials for, bandages, dressings or absorbent pads
- A61L15/07—Stiffening bandages
- A61L15/12—Stiffening bandages containing macromolecular materials
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/0055—Plastic or rubber gloves
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/0055—Plastic or rubber gloves
- A41D19/0082—Details
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D19/00—Gloves
- A41D19/015—Protective gloves
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61B—DIAGNOSIS; SURGERY; IDENTIFICATION
- A61B42/00—Surgical gloves; Finger-stalls specially adapted for surgery; Devices for handling or treatment thereof
- A61B42/10—Surgical gloves
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F6/00—Contraceptive devices; Pessaries; Applicators therefor
- A61F6/02—Contraceptive devices; Pessaries; Applicators therefor for use by males
- A61F6/04—Condoms, sheaths or the like, e.g. combined with devices protecting against contagion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61F—FILTERS IMPLANTABLE INTO BLOOD VESSELS; PROSTHESES; DEVICES PROVIDING PATENCY TO, OR PREVENTING COLLAPSING OF, TUBULAR STRUCTURES OF THE BODY, e.g. STENTS; ORTHOPAEDIC, NURSING OR CONTRACEPTIVE DEVICES; FOMENTATION; TREATMENT OR PROTECTION OF EYES OR EARS; BANDAGES, DRESSINGS OR ABSORBENT PADS; FIRST-AID KITS
- A61F6/00—Contraceptive devices; Pessaries; Applicators therefor
- A61F6/02—Contraceptive devices; Pessaries; Applicators therefor for use by males
- A61F6/04—Condoms, sheaths or the like, e.g. combined with devices protecting against contagion
- A61F2006/043—Condoms, sheaths or the like, e.g. combined with devices protecting against contagion with more than one barrier
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/48—Wearing apparel
- B29L2031/4842—Outerwear
- B29L2031/4864—Gloves
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
- Y10T428/31909—Next to second addition polymer from unsaturated monomers
- Y10T428/31924—Including polyene monomers
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- Health & Medical Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Biomedical Technology (AREA)
- Heart & Thoracic Surgery (AREA)
- Textile Engineering (AREA)
- Vascular Medicine (AREA)
- Reproductive Health (AREA)
- Surgery (AREA)
- Medical Informatics (AREA)
- Molecular Biology (AREA)
- Materials Engineering (AREA)
- Epidemiology (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Orthopedics, Nursing, And Contraception (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Gloves (AREA)
- Heating, Cooling, Or Curing Plastics Or The Like In General (AREA)
Description
Claims (26)
- (a)イソプロパノール指数試験においてイソプレン粒子の塊が非粘着性であることを示す度合いの前加硫及び(b)その後の硬化により得ることができる、ポリイソプレン粒子内架橋及びポリイソプレン粒子間架橋によって互いに結合された合成ポリイソプレン粒子を含む合成ポリイソプレンエラストマーコンドーム又は手袋であって、
(A)前記ポリイソプレン粒子内架橋及び前記ポリイソプレン粒子間架橋が、前記合成ポリイソプレンエラストマーコンドーム又は手袋中で均一であり、均一が以下の1以上によって判断されるものである、
(i)コンドーム又は手袋が、液体窒素温度で切断したときに実質的に貝殻状断面を示す、若しくは
(ii)コンドーム又は手袋が、室温で破裂したときに走査型電子顕微鏡で見ることができるポリイソプレン粒子内及びポリイソプレン粒子間の特徴が不在である破面を示す
、又は
(B)前記ポリイソプレン粒子内架橋及び前記ポリイソプレン粒子間架橋が、架橋間で約6800g/mol未満の分子量となるような高い密度を有する、
合成ポリイソプレンエラストマーコンドーム又は手袋。 - 前記コンドーム又は手袋が、液体窒素温度で破壊された場合に、実質的に貝殻状破壊を示す、請求項1に記載の合成ポリイソプレンエラストマーコンドーム又は手袋。
- 室温での物品の破断で得られた破面の走査型電子顕微鏡観察が、ポリイソプレン粒子内及びポリイソプレン粒子間の特徴の不在を示す、請求項1に記載の合成ポリイソプレンエラストマーコンドーム又は手袋。
- 液体窒素温度でのコンドーム又は手袋の破壊、室温での破断、又は両方によって得られた破面の走査型電子顕微鏡の亜鉛及び硫黄のx線地図観察が、亜鉛で修飾されているポリイソプレン粒子内の硫黄の存在を示す、請求項1に記載の合成ポリイソプレンエラストマーコンドーム又は手袋。
- 分子量が、架橋間で約6800g/mol未満である、請求項1に記載の合成ポリイソプレンエラストマーコンドーム又は手袋。
- 電子顕微鏡検査によるマイクロプローブ元素分析が、前記合成ポリイソプレン粒子を囲む亜鉛の蓄積を示す、請求項1に記載の合成ポリイソプレンエラストマーコンドーム又は手袋。
- 四酸化オスミウム処理物品のTEMが、イソプレン二重結合の均一性を示す、請求項1に記載の合成ポリイソプレンエラストマーコンドーム又は手袋。
- ポリイソプレン粒子内架橋及びポリイソプレン粒子間架橋の均一性が、粒子内領域及び粒子間領域の両方を非選択的に通る破面の走査型電子顕微鏡検査によって確認される、請求項1に記載の合成ポリイソプレンエラストマーコンドーム又は手袋。
- 可溶性硫黄、ジチオカルバメートの亜鉛錯体、カプリル酸カリウム、及びドデシルベンゼンスルホン酸ナトリウム(SDBS)の存在下で前加硫され、硬化されている、ポリイソプレン粒子内架橋及びポリイソプレン粒子間架橋によって互いに結合された合成ポリイソプレン粒子を含み、
(A)前記ポリイソプレン粒子内架橋及び前記ポリイソプレン粒子間架橋が均一であり、均一が以下の1以上によって判断されるものである、
(i)コンドームが、液体窒素温度で切断したときに実質的に貝殻状断面を示す、若しくは
(ii)コンドームが、室温で破裂したときに走査型電子顕微鏡で見ることができるポリイソプレン粒子内及びポリイソプレン粒子間の特徴が不在である破面を示す
、又は
(B)前記ポリイソプレン粒子内架橋及び前記ポリイソプレン粒子間架橋が、架橋間で約6800g/mol未満の分子量となるような高い密度を有する、合成ポリイソプレンコンドーム。 - 少なくとも30MPaの引張強度を有する、請求項9に記載のコンドーム。
- 少なくとも945%の破断時伸びを有する、請求項9に記載のコンドーム。
- 合成ポリイソプレン粒子の水性ラテックスに、可溶性硫黄、ジチオカルバミン酸亜鉛及び界面活性剤を含む前加硫組成物を添加するステップと、
前記ラテックス中の該合成ポリイソプレン粒子を前加硫するステップと、
前記ラテックスに後加硫組成物を添加するステップと、
手袋又はコンドームの形の、凝固剤なしの又は凝固剤被覆されたフォーマーを前記ラテックス中に1回以上浸漬させて、ラテックスフィルムを形成するステップと、
後加硫の間に前記ラテックスフィルムを硬化させて、合成ポリイソプレン粒子内に粒子間架橋を生成し、前記粒子間に粒子内架橋を生成するステップと
を含み、
(A)前記ポリイソプレン粒子内架橋及び前記ポリイソプレン粒子間架橋が、前記合成ポリイソプレンエラストマーコンドーム又は手袋中で均一であり、均一が以下の1以上によって判断されるものである、
(i)コンドームが、液体窒素温度で切断したときに実質的に貝殻状断面を示す、若しくは
(ii)コンドームが、室温で破裂したときに走査型電子顕微鏡で見ることができるポリイソプレン粒子内及びポリイソプレン粒子間の特徴が不在である破面を示す
、又は
(B)前記ポリイソプレン粒子内架橋及び前記ポリイソプレン粒子間架橋が、架橋間で約6800g/mol未満の分子量となるような高い密度を有する、
合成ポリイソプレンエラストマーコンドーム又は手袋を製造する方法。 - 前記物品がコンドームであり、前記フォーマーが凝固剤なしである、請求項12に記載の方法。
- 前記物品が手袋であり、前記フォーマーが凝固剤被覆されている、請求項12に記載の方法。
- 前記可溶性硫黄が、S8硫黄環を含む、請求項12に記載の方法。
- ジチオカルバミン酸亜鉛が、ジエチルジチオカルバミン酸亜鉛(ZDEC)、ジブチルジチオカルバミン酸亜鉛(ZDBC)、又はそれらの組合せを含む、請求項12に記載の方法。
- 前記界面活性剤が、カプリル酸カリウム、ポリオキシエチレンセチル/ステアリルエーテル、アルキルアリールスルホン酸塩、アルキルスルホン酸塩、オレフィンスルホン酸塩、アルコール硫酸塩、又はそれらの組合せを含む、請求項12に記載の方法。
- 前記界面活性剤が、ドデシルベンゼンスルホン酸ナトリウム(SDBS)、C14オレフィンスルホン酸塩、ラウリル硫酸ナトリウム、又はそれらの組合せを含む、請求項12に記載の方法。
- 前記後加硫組成物が、ジエチルジチオカルバミン酸ナトリウム(SDEC)、ジブチルジチオカルバミン酸ナトリウム(SDBC)、チウラム、キサントゲン、反応性酸化亜鉛及びそれらの組合せからなる群から選択される促進剤を含む、請求項12に記載の方法。
- 前記促進剤が、テトラエチルチウラムジスルフィドであるチウラムを含む、請求項19に記載の方法。
- 前記促進剤が、ジイソプロピルキサントゲンポリスルフィド(DXP)であるキサントゲンを含む、請求項19に記載の方法。
- 前記促進剤が、キサントゲンスルフィドであるキサントゲンを含む、請求項19に記載の方法。
- 前記促進剤が、ジイソプロピルキサントゲンであるキサントゲンを含む、請求項19に記載の方法。
- 前加硫ステップが、20℃〜30℃の範囲の温度で9時間〜2日間行われる、請求項12に記載の方法。
- 合成ラテックス粒子の前加硫の度合いが、イソプロパノール指数試験によって確認される、請求項12に記載の方法。
- 後加硫ステップの間の前記硬化が、120℃〜150℃の範囲の温度で8〜15分間行われる、請求項12に記載の方法。
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US4963708P | 2008-05-01 | 2008-05-01 | |
US61/049,637 | 2008-05-01 | ||
US12/194,118 US8087412B2 (en) | 2008-05-01 | 2008-08-19 | Dip-formed synthetic polyisoprene latex articles with improved intraparticle and interparticle crosslinks |
US12/194,118 | 2008-08-19 | ||
PCT/US2009/041756 WO2009134702A1 (en) | 2008-05-01 | 2009-04-27 | Dip-formed synthetic polyisoprene latex articles with improved intraparticle and interparticle crosslinks |
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MX2010007325A (es) | 2008-01-04 | 2012-12-06 | Bard Inc C R | Cateter de foley de poliisopreno sintetico. |
US8087412B2 (en) * | 2008-05-01 | 2012-01-03 | Ansell Healthcare Products Llc | Dip-formed synthetic polyisoprene latex articles with improved intraparticle and interparticle crosslinks |
JP2011526814A (ja) | 2008-06-30 | 2011-10-20 | シー.アール.バード,インコーポレイテッド | ポリウレタン/ポリイソプレンブレンドカテーテル |
EP2393650B1 (en) | 2009-02-05 | 2014-05-07 | Diptech Pte Limited | Production of elastomeric films |
KR101715213B1 (ko) * | 2010-06-25 | 2017-03-10 | 얼리젼스 코포레이션 | 알레르기 유발 가능성이 감소된 가황 조성물 |
US20130152943A1 (en) | 2011-12-19 | 2013-06-20 | Ansell Limited | Condom having a raised contoured surface and method and apparatus for manufacturing |
CN102975321B (zh) * | 2012-10-11 | 2015-03-25 | 上海名邦橡胶制品有限公司 | 一种采用聚异戊二烯胶乳制备避孕套的方法 |
EP2911891A4 (en) | 2012-10-18 | 2016-07-20 | Ansell Ltd | POLYMER ARTICLES WITH A DECORATION AND METHOD OF MANUFACTURE |
BR112015019097A2 (pt) | 2013-02-08 | 2017-07-18 | Council Scient Ind Res | carboditioato e o processo de preparação do mesmo |
GB201303796D0 (en) * | 2013-03-04 | 2013-04-17 | Futura Medical Dev Ltd | Condom |
US20150128329A1 (en) * | 2013-11-14 | 2015-05-14 | Ansell Limited | Polymeric compositions comprising polyisoprene |
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