JP5536106B2 - キノンメチド／アルキルヒドロキシルアミンの組み合わせを用いる、ビニル芳香族モノマーの重合阻害法 - Google Patents

キノンメチド／アルキルヒドロキシルアミンの組み合わせを用いる、ビニル芳香族モノマーの重合阻害法 Download PDF

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JP5536106B2
JP5536106B2 JP2011549218A JP2011549218A JP5536106B2 JP 5536106 B2 JP5536106 B2 JP 5536106B2 JP 2011549218 A JP2011549218 A JP 2011549218A JP 2011549218 A JP2011549218 A JP 2011549218A JP 5536106 B2 JP5536106 B2 JP 5536106B2
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inhibitor
retarder
combination
vinyl aromatic
alkylhydroxylamine
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Japanese (ja)
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JP2012516933A (ja
JP2012516933A5 (cg-RX-API-DMAC7.html
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ルイス，ビンセント，イー．
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ChampionX LLC
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Nalco Co LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C08F2/40—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation using retarding agents
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/20—Use of additives, e.g. for stabilisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F12/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F12/02—Monomers containing only one unsaturated aliphatic radical
    • C08F12/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F12/06—Hydrocarbons
    • C08F12/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K15/00—Anti-oxidant compositions; Compositions inhibiting chemical change
    • C09K15/04—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds
    • C09K15/06—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen
    • C09K15/08—Anti-oxidant compositions; Compositions inhibiting chemical change containing organic compounds containing oxygen containing a phenol or quinone moiety

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Polymers & Plastics (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Materials Engineering (AREA)
  • Polymerisation Methods In General (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
JP2011549218A 2009-02-05 2010-02-03 キノンメチド／アルキルヒドロキシルアミンの組み合わせを用いる、ビニル芳香族モノマーの重合阻害法 Active JP5536106B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US12/366,154 US7651635B1 (en) 2009-02-05 2009-02-05 Polymer inhibition of vinyl aromatic monomers using a quinone methide/alkyl hydroxylamine combination
US12/366,154 2009-02-05
PCT/US2010/022977 WO2010091040A1 (en) 2009-02-05 2010-02-03 Polymer inhibition of vinyl aromatic monomers using a quinone methide/alkyl hydroxomine combination

Publications (3)

Publication Number Publication Date
JP2012516933A JP2012516933A (ja) 2012-07-26
JP2012516933A5 JP2012516933A5 (cg-RX-API-DMAC7.html) 2013-03-21
JP5536106B2 true JP5536106B2 (ja) 2014-07-02

Family

ID=41559765

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JP2011549218A Active JP5536106B2 (ja) 2009-02-05 2010-02-03 キノンメチド／アルキルヒドロキシルアミンの組み合わせを用いる、ビニル芳香族モノマーの重合阻害法

Country Status (11)

Country Link
US (1) US7651635B1 (cg-RX-API-DMAC7.html)
EP (1) EP2393765B1 (cg-RX-API-DMAC7.html)
JP (1) JP5536106B2 (cg-RX-API-DMAC7.html)
KR (1) KR101613760B1 (cg-RX-API-DMAC7.html)
CN (1) CN102307830B (cg-RX-API-DMAC7.html)
BR (1) BRPI1005420B1 (cg-RX-API-DMAC7.html)
CA (1) CA2750187C (cg-RX-API-DMAC7.html)
ES (1) ES2398053T3 (cg-RX-API-DMAC7.html)
SG (1) SG173564A1 (cg-RX-API-DMAC7.html)
TW (1) TWI461406B (cg-RX-API-DMAC7.html)
WO (1) WO2010091040A1 (cg-RX-API-DMAC7.html)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8691994B2 (en) 2011-02-03 2014-04-08 Nalco Company Multi-component polymerization inhibitors for ethylenically unsaturated monomers
US8884038B2 (en) * 2011-06-13 2014-11-11 Nalco Company Synthesis of 7-acetyleno quinone methide derivatives and their application as vinylic polymerization retarders
US9090526B2 (en) * 2011-06-13 2015-07-28 Nalco Company Synergistic combination for inhibiting polymerization of vinyl monomers
JP5759073B2 (ja) 2011-08-26 2015-08-05 ドルフ ケタール ケミカルズ（インド）プライベート リミテッドＤｏｒｆ Ｋｅｔａｌ Ｃｈｅｍｉｃａｌｓ（Ｉｎｄｉａ） Ｐｒｉｖａｔｅ Ｌｉｍｉｔｅｄ スチレンの重合を抑制及び阻害する添加剤組成物、製造方法、並びにその使用
PL2788303T3 (pl) * 2011-12-09 2015-12-31 Dorf Ketal Chemicals India Private Ltd Ulepszona kompozycja dodatków do kontroli i hamowania polimeryzacji aromatycznych monomerów winylowych oraz sposób jej stosowania
US9217107B2 (en) * 2011-12-26 2015-12-22 Dorf Ketal Chemicals (India) Private Limited Amine based additive composition for control and inhibition of polymerization of aromatic vinyl monomers, and method of use thereof
CA2880244C (en) 2012-08-24 2017-05-16 Dorf Ketal Chemicals (India) Private Limited Composition of quinone methide derivatives and amines for control and inhibition of polymerization of monomers, and method of preparation and use thereof
US9611336B2 (en) 2012-10-25 2017-04-04 Baker Hughes Incorporated Quinone compounds for inhibiting monomer polymerization
US9944577B2 (en) 2012-10-25 2018-04-17 Baker Hughes, A Ge Company, Llc Hydroquinone compounds for inhibiting monomer polymerization
IN2013MU01165A (cg-RX-API-DMAC7.html) * 2013-03-26 2015-04-24 Dorf Ketal Chemicals India Private Ltd
US9399622B2 (en) 2013-12-03 2016-07-26 Ecolab Usa Inc. Nitroxide hydroxylamine and phenylenediamine combinations as polymerization inhibitors for ethylenically unsaturated monomer processes
CN108884004B (zh) * 2016-02-13 2020-02-25 多尔夫凯塔尔化学制品（I）私人有限公司 用于控制和抑制乙烯基芳族单体聚合的组合物，及其使用方法
TWI826485B (zh) * 2018-07-13 2023-12-21 美商藝康美國公司 作為乙烯系單體之防垢劑之含氧胺及醌甲基化物之組合物
US11180578B2 (en) 2018-07-13 2021-11-23 Ecolab Usa Inc. Polymerization inhibitor and retarder compositions with amine stabilizer
TWI880966B (zh) * 2019-10-11 2025-04-21 美商藝康美國公司 醌甲基化物及銨鹽抗聚合劑組合物及方法
WO2025217595A1 (en) * 2024-04-12 2025-10-16 Bl Technologies, Inc. Boosted styrene polymerization retarder and method of use

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3390198A (en) * 1965-12-16 1968-06-25 Koppers Co Inc Tertiary-butyl-5-methyl catechol as polymerization inhibitor for hot styrene
US4003800A (en) 1976-01-02 1977-01-18 Gulf Research & Development Company Styrene purification process
US4409408A (en) * 1982-09-24 1983-10-11 Atlantic Richfield Company Inhibiting polymerization of vinyl aromatic monomers
IT1245845B (it) * 1990-09-17 1994-10-25 Montedipe Srl Processo per la depurazione di un monomero vinilaromatico.
US5446220A (en) 1994-08-24 1995-08-29 Betz Laboratories, Inc. Methods for inhibiting vinyl aromatic monomer polymerization
US5583247A (en) * 1995-04-14 1996-12-10 Ciba-Geigy Corporation 7-substituted quinone methides as inhibitors for unsaturated monomers
US6024894A (en) * 1998-03-25 2000-02-15 Betzdearborn Inc. Compositions and methods for inhibiting vinyl aromatic monomer polymerization
WO2002033026A1 (en) * 2000-10-16 2002-04-25 Uniroyal Chemical Company, Inc. Blends of quinone alkide and nitroxyl compounds as polymerization inhibitors
US6685823B2 (en) * 2000-10-16 2004-02-03 Uniroyal Chemical Company, Inc. C-nitrosoaniline compounds and their blends as polymerization inhibitors
US7084196B2 (en) * 2001-03-20 2006-08-01 Ciba Specialty Chemicals Corporation Flame retardant compositions
US6960279B2 (en) * 2002-05-06 2005-11-01 Fina Technology, Inc. Method for stabilizing vinyl aromatic monomers using selected polymerization inhibitors and polymers prepared therewith
WO2004083156A1 (ja) * 2003-03-17 2004-09-30 Hakuto Co., Ltd. 芳香族ビニル化合物の重合抑制剤および重合抑制方法

Also Published As

Publication number Publication date
KR20110122111A (ko) 2011-11-09
TWI461406B (zh) 2014-11-21
JP2012516933A (ja) 2012-07-26
KR101613760B1 (ko) 2016-04-19
ES2398053T3 (es) 2013-03-13
EP2393765A1 (en) 2011-12-14
WO2010091040A1 (en) 2010-08-12
BRPI1005420B1 (pt) 2021-05-11
CN102307830B (zh) 2014-10-22
TW201035046A (en) 2010-10-01
SG173564A1 (en) 2011-09-29
BRPI1005420A2 (pt) 2020-08-18
CA2750187A1 (en) 2010-08-12
CA2750187C (en) 2016-05-10
EP2393765B1 (en) 2012-12-26
CN102307830A (zh) 2012-01-04
US7651635B1 (en) 2010-01-26

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