JP5498150B2 - 難燃性クロロプレンゴム発泡体及びその製造方法 - Google Patents
難燃性クロロプレンゴム発泡体及びその製造方法 Download PDFInfo
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- JP5498150B2 JP5498150B2 JP2009288630A JP2009288630A JP5498150B2 JP 5498150 B2 JP5498150 B2 JP 5498150B2 JP 2009288630 A JP2009288630 A JP 2009288630A JP 2009288630 A JP2009288630 A JP 2009288630A JP 5498150 B2 JP5498150 B2 JP 5498150B2
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- foam
- chloroprene rubber
- agent
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- 239000006260 foam Substances 0.000 title claims description 40
- 239000003063 flame retardant Substances 0.000 title claims description 17
- 229920001084 poly(chloroprene) Polymers 0.000 title claims description 17
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 title claims description 14
- 238000004519 manufacturing process Methods 0.000 title claims description 7
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 32
- 239000012188 paraffin wax Substances 0.000 claims description 16
- 239000004088 foaming agent Substances 0.000 claims description 12
- 239000003431 cross linking reagent Substances 0.000 claims description 8
- 239000010734 process oil Substances 0.000 claims description 7
- 239000000945 filler Substances 0.000 claims description 5
- 229920001821 foam rubber Polymers 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 4
- 239000012744 reinforcing agent Substances 0.000 claims description 4
- 238000004132 cross linking Methods 0.000 claims description 3
- 239000004604 Blowing Agent Substances 0.000 claims description 2
- 238000004898 kneading Methods 0.000 claims description 2
- 238000005187 foaming Methods 0.000 description 14
- 239000000203 mixture Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 3
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 238000003825 pressing Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- ASRMWYDEZPXXBA-UHFFFAOYSA-N (sulfonylamino)urea Chemical class NC(=O)NN=S(=O)=O ASRMWYDEZPXXBA-UHFFFAOYSA-N 0.000 description 1
- NBOCQTNZUPTTEI-UHFFFAOYSA-N 4-[4-(hydrazinesulfonyl)phenoxy]benzenesulfonohydrazide Chemical compound C1=CC(S(=O)(=O)NN)=CC=C1OC1=CC=C(S(=O)(=O)NN)C=C1 NBOCQTNZUPTTEI-UHFFFAOYSA-N 0.000 description 1
- 239000004156 Azodicarbonamide Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- MWRWFPQBGSZWNV-UHFFFAOYSA-N Dinitrosopentamethylenetetramine Chemical compound C1N2CN(N=O)CN1CN(N=O)C2 MWRWFPQBGSZWNV-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 229920004415 Skyprene® B-31 Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000008065 acid anhydrides Chemical class 0.000 description 1
- 239000010692 aromatic oil Substances 0.000 description 1
- XOZUGNYVDXMRKW-AATRIKPKSA-N azodicarbonamide Chemical compound NC(=O)\N=N\C(N)=O XOZUGNYVDXMRKW-AATRIKPKSA-N 0.000 description 1
- 235000019399 azodicarbonamide Nutrition 0.000 description 1
- 229910052788 barium Inorganic materials 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- YACLQRRMGMJLJV-UHFFFAOYSA-N chloroprene Chemical compound ClC(=C)C=C YACLQRRMGMJLJV-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 150000007973 cyanuric acids Chemical class 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000012990 dithiocarbamate Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- WHDGWKAJBYRJJL-UHFFFAOYSA-K ferbam Chemical compound [Fe+3].CN(C)C([S-])=S.CN(C)C([S-])=S.CN(C)C([S-])=S WHDGWKAJBYRJJL-UHFFFAOYSA-K 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 150000002357 guanidines Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002832 nitroso derivatives Chemical class 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 150000004714 phosphonium salts Chemical group 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 239000012763 reinforcing filler Substances 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 238000010058 rubber compounding Methods 0.000 description 1
- 239000003566 sealing material Substances 0.000 description 1
- DUIOPKIIICUYRZ-UHFFFAOYSA-N semicarbazide Chemical compound NNC(N)=O DUIOPKIIICUYRZ-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- -1 toluenesulfonyl semicarbazide Chemical compound 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- DUBNHZYBDBBJHD-UHFFFAOYSA-L ziram Chemical compound [Zn+2].CN(C)C([S-])=S.CN(C)C([S-])=S DUBNHZYBDBBJHD-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Description
米国UL(Underwriters Laboratories)94の垂直燃焼試験方法に従って測定した。難燃性基準V−0に合格したものを難燃性ありとした。
比較例1
比較例2
比較例3
比較例4
Claims (2)
- クロロプレンゴム100重量部に塩素化パラフィン5〜20重量部、三酸化アンチモン10〜30重量部及び発泡剤、架橋剤、プロセスオイル、充填剤、補強剤を添加混練して加熱、発泡させ、次いで常圧下にて60〜100℃で加熱して後架橋させてなる難燃性ゴム発泡体。
- クロロプレンゴム100重量部に塩素化パラフィン5〜20重量部、三酸化アンチモン10〜30重量部及び発泡剤、架橋剤、プロセスオイル、充填剤、補強剤を添加混練し、密閉金型中に充填して加圧下に加熱し、発泡剤を部分的に分解後除圧して中間発泡体を取り出した後、再度常圧下に加熱して残存発泡剤を分解後除圧して発泡体を得、得られた発泡体を常圧下にて60〜100℃で加熱して後架橋させてなる難燃性ゴム発泡体の製造方法。
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JP2009288630A JP5498150B2 (ja) | 2009-12-21 | 2009-12-21 | 難燃性クロロプレンゴム発泡体及びその製造方法 |
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JP2009288630A JP5498150B2 (ja) | 2009-12-21 | 2009-12-21 | 難燃性クロロプレンゴム発泡体及びその製造方法 |
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JP2011127047A JP2011127047A (ja) | 2011-06-30 |
JP5498150B2 true JP5498150B2 (ja) | 2014-05-21 |
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JP2009288630A Expired - Fee Related JP5498150B2 (ja) | 2009-12-21 | 2009-12-21 | 難燃性クロロプレンゴム発泡体及びその製造方法 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP7144151B2 (ja) | 2018-02-07 | 2022-09-29 | シチズン時計株式会社 | 電子時計 |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5981116B2 (ja) * | 2011-09-29 | 2016-08-31 | 三和化工株式会社 | クロロプレンゴム連続気泡体及びその製造方法 |
JP7257656B2 (ja) | 2018-03-28 | 2023-04-14 | アトム株式会社 | 発泡体用ゴム組成物及び防振手袋 |
CN112608537A (zh) * | 2020-12-25 | 2021-04-06 | 易宝(福建)高分子材料股份公司 | 一种环保型高阻燃cr多元共混闭孔二次发泡材料及其制备方法 |
Family Cites Families (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0361037A (ja) * | 1989-07-28 | 1991-03-15 | Tomizo Yamamoto | 保温衣料部材 |
JP3903523B2 (ja) * | 1997-04-28 | 2007-04-11 | 東ソー株式会社 | 無圧オープン加硫高発泡スポンジ用クロロプレンゴム組成物 |
JP3181549B2 (ja) * | 1997-05-06 | 2001-07-03 | 世界長株式会社 | ゴム発泡体シ−ル部材及びその製造方法 |
JP2009249459A (ja) * | 2008-04-03 | 2009-10-29 | Yokohama Rubber Co Ltd:The | ゴム組成物、コンベヤベルト用ゴム組成物およびコンベヤベルト |
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- 2009-12-21 JP JP2009288630A patent/JP5498150B2/ja not_active Expired - Fee Related
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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JP7144151B2 (ja) | 2018-02-07 | 2022-09-29 | シチズン時計株式会社 | 電子時計 |
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